Bioinspired aligned magnetic features in aerogels for humidity sensing

Alexander, Josh; Baskaran, Karthikeyan; Harward, Allison; Carlson, Krista; Naleway, Steven E.

doi:10.1016/j.matchemphys.2021.124852

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Bioinspired aligned magnetic features in aerogels for humidity sensing

Alexander, Josh·Baskaran, Karthikeyan·Harward, Allison·Carlson, Krista·Naleway, Steven E.

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Abstract

Many natural plant tissues, such as pinecones, utilize structures to transduce changes in humidity into movement or strain. These often employ layered structures with aligned features in order to create differential stress across the material as different portions swell at different rates. Here, by replicating these types of structures in synthetic materials we can create structures that respond to humidity in a similar manner. Taking these aligned features as inspiration, silica aerogels with tailored humidity reactive properties were created. This behavior was achieved by creating aligned features in these aerogels using a Helmholtz coil to produce a uniform magnetic field that aligned ferrofluid droplets into chains and needle like features. These magnetite-based structures were shown to retain their superparamagnetic properties, allowing them to easily be removed from the aerogels, leaving a large number of aligned channels. Aerogels with the removed needles experienced significantly different strains than both unmodified aerogels and aerogels with the aligned features still in place. Aerogels with these tunable aligned features could be used in humidity sensors that can transduce changes in humidity into strain and could be used in applications such as volatile organic compound capture.

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Alexander, Josh, Baskaran, Karthikeyan, Harward, Allison, Carlson, Krista, Naleway, Steven E.. 2021-06-18. Bioinspired aligned magnetic features in aerogels for humidity sensing. https://doi.org/10.1016/j.matchemphys.2021.124852

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