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DOE OSTI · 1995211

Trace Actinide Signatures of a Bulk Neptunium Sample

Reilly, Sean D.·Patton, Genna M.·Murillo, Jesse·Oldham, Warren J.·Miller, Jeffrey L.·LaMont, Stephen P.·Sanborn, Matthew E.·May, Iain·Gaunt, Andrew J.·Hanson, Susan K.
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Abstract

In nuclear forensic analyses, measurements of actinide elements in a sample can assist with identifying interdicted or unknown materials. While these radiochemical signatures have been extensively investigated in uranium materials, less is known about bulk neptunium samples. This paper describes the measurement of trace actinide concentrations and isotopic profiles in a 237 Np oxide sample. Uranium, plutonium, americium, and curium concentrations and isotopic profiles in the sample were determined and deemed potentially useful for distinguishing different sources of 237 Np. Furthermore, several different potential radiochronometry systems were also investigated; discordant results indicate that the Np sample was never completely purified of other actinide elements, or that subsequent contamination of the sample occurred. Few prior studies of neptunium materials have been reported, and these data suggest that trace actinide constituents could provide unique signatures to identify material out of regulatory control.

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73 NUCLEAR PHYSICS AND RADIATION PHYSICSActinidesIntegral ExperimentsIsotopesMaterialsNuclear Criticality Safety Program (NCSP)Organic polymersUranium

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Reilly, Sean D., Patton, Genna M., Murillo, Jesse, Oldham, Warren J., Miller, Jeffrey L., LaMont, Stephen P., Sanborn, Matthew E., May, Iain, Gaunt, Andrew J., Hanson, Susan K.. 2023-06-01. Trace Actinide Signatures of a Bulk Neptunium Sample. https://doi.org/10.1021/acs.analchem.3c01682

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