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DOE OSTI · 2000326

PET-RAFT polymerization under flow chemistry and surface-initiated reactions

Rong, Li‐Han·Caldona, Eugene B.·Advincula, Rigoberto C.
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Abstract

Recently, photoinduced electron/energy transfer reversible addition–fragmentation chain transfer (PET-RAFT) polymerization has been developed and gaining wide acceptance. PET-RAFT polymerization uses visible light to initiate the reaction and is compatible with ambient conditions and green solvents. It also maintains the ability to produce well-defined polymers and possesses high potential as an alternative to the conventional RAFT technique. Here, this review aims to summarize the fundamentals of PET-RAFT polymerization, highlight two of the most commonly studied applications of PET-RAFT process (i.e. flow chemistry and surface-initiated polymerization), and explore perspectives and new possibilities of the technique.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYPET-RAFTflow chemistrypolymer brushessurface-initiated

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Rong, Li‐Han, Caldona, Eugene B., Advincula, Rigoberto C.. 2022-11-04. PET-RAFT polymerization under flow chemistry and surface-initiated reactions. https://doi.org/10.1002/pi.6475

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