Renewable low viscosity polyester-polyols for biodegradable thermoplastic polyurethanes

Rajput, Bhausaheb S.; Hai, Thien Phung; Gunawan, Natasha R.; Tessman, Marissa; Neelakantan, Nitin; Scofield, Gordon B.; Brizuela, Jose; Samoylov, Anton A.; Modi, Miheer; Shepherd, Jenna; Patel, Amal; Pomeroy, Robert S.; Pourahmady, Naser; Mayfield, Stephen P.; Burkart, Michael D.

doi:10.1002/app.53062

DOE OSTI · 2418604

Renewable low viscosity polyester-polyols for biodegradable thermoplastic polyurethanes

Rajput, Bhausaheb S.·Hai, Thien Phung·Gunawan, Natasha R.·Tessman, Marissa·Neelakantan, Nitin·Scofield, Gordon B.·Brizuela, Jose·Samoylov, Anton A.·Modi, Miheer·Shepherd, Jenna·Patel, Amal·Pomeroy, Robert S.·Pourahmady, Naser·Mayfield, Stephen P.·Burkart, Michael D.

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Abstract

In the transition to renewably sourced, biodegradable polymers, the preparation of low viscosity polyester-polyols has posed a challenge for renewable polyurethane (PU) development. Low viscosity polyols not only reduce the requirement for high process temperatures but also decrease manufacturing time. In our efforts to incorporate increasing ratios of bio-based monomers into renewable PUs, we mixed diacids such as even carbon sebacic acid and odd carbon azelaic acid along with a renewable diol. This provided library of 2000 g/mol molecular weight polyester-polyols, and structures were established by 1 H and 13 C NMR analysis. The prepared polyester-polyols offered lower viscosity and enable lower fabrication temperatures to make TPUs, and their structure and material metrics were evaluated. The formation of TPUs is ascertained from FTIR and NMR analysis. The final TPUs displayed good physical and mechanical properties. Further, these TPUs exhibited T g in the range of -56.5 to -39.7°C, corresponding to TPU soft block structure, and T m between 98.3 and 105.1°C originating from the hard segment. Prepared TPUs exhibit excellent biodegradation under compost environmental conditions. These TPUs showed up to 57% decrease in molecular weight by GPC analysis after 9 weeks of biodegradation, and respirometer analysis displayed up to 97% biodegradation over 120 days.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY biodegradable biopolymers and renewable polymers polyurethane thermoplastics

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Rajput, Bhausaheb S., Hai, Thien Phung, Gunawan, Natasha R., Tessman, Marissa, Neelakantan, Nitin, Scofield, Gordon B., Brizuela, Jose, Samoylov, Anton A., Modi, Miheer, Shepherd, Jenna, Patel, Amal, Pomeroy, Robert S., Pourahmady, Naser, Mayfield, Stephen P., Burkart, Michael D.. 2022-09-06. Renewable low viscosity polyester-polyols for biodegradable thermoplastic polyurethanes. https://doi.org/10.1002/app.53062

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