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DOE OSTI · 2532513

A Rapid Microfluidic Neptunium Extraction Using a Supported Liquid Membrane Module

Cicchetti, Nic [Univ. of Nevada, Las Vegas, NV (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)] (ORCID:0000000186419803)·Glennon, Kevin J. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)] (ORCID:0000000193509161)·Parsons-Davis, Tashi [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)]·Shusterman, Jennifer A. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)] (ORCID:0000000301811545)·Gelis, Artem V. [Univ. of Nevada, Las Vegas, NV (United States)] (ORCID:0000000254871472)
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Abstract

Extraction of neptunium from acidic matrices is important for its quantification, but its complex redox chemistry can cause variable yields. This study develops a microfluidic redox extraction for rapidly separating neptunium from submilliliter samples, achieving up to 90% process yield in less than 10 min for samples as small as 100 μL, with over 97% steady-state yield achieved after 20 min. It uses a supported liquid membrane module loaded with 30 vol % tributyl phosphate in n-dodecane, which performs forward- and back-extractions in a single, continuous step. Neptunium is first oxidized to +6 for extraction and then reduced during stripping. Bromate was selected as an oxidant over permanganate for its greater compatibility with the organic phase, achieving complete oxidation in under 30 s. Ascorbic acid and hydrogen peroxide were both effective reductants. Finally, the system’s high yield and rapid kinetics make it promising for future separations from complex mixtures.

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38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRYanimal feedextractioninorganic acids and basesmembranesoxides

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Cicchetti, Nic [Univ. of Nevada, Las Vegas, NV (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)] (ORCID:0000000186419803), Glennon, Kevin J. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)] (ORCID:0000000193509161), Parsons-Davis, Tashi [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)], Shusterman, Jennifer A. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)] (ORCID:0000000301811545), Gelis, Artem V. [Univ. of Nevada, Las Vegas, NV (United States)] (ORCID:0000000254871472). 2024-12-05. A Rapid Microfluidic Neptunium Extraction Using a Supported Liquid Membrane Module. https://doi.org/10.1021/acs.iecr.4c02993

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