Planarization of p -GaN surfaces on MOCVD grown V-defect engineered GaN-based LEDs

Tak, Tanay; Quevedo, Alejandro; Wu, Feng; Gandrothula, Srinivas; Ewing, Jacob J.; Gee, Stephen; Nakamura, Shuji; DenBaars, Steven P.; Speck, James S.

doi:10.1063/5.0200424

DOE OSTI · 3023025

Planarization of p -GaN surfaces on MOCVD grown V-defect engineered GaN-based LEDs

Tak, Tanay·Quevedo, Alejandro·Wu, Feng·Gandrothula, Srinivas·Ewing, Jacob J.·Gee, Stephen·Nakamura, Shuji·DenBaars, Steven P.·Speck, James S.

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Abstract

The large polarization barriers between the quantum wells and quantum barriers in long-wavelength GaN-based light-emitting diodes (LEDs) inhibit their performance by requiring excess driving voltages to reach standard operating current densities. Lateral injection of carriers directly into quantum wells is required to circumvent this issue. V-defects are naturally occurring inverted hexagonal defects with semipolar {$10\bar{1}1$}-plane sidewalls generated on surface depressions from threading dislocations. LEDs engineered to intentionally generate V-defects below the active region of the LED can achieve lateral carrier injection through the V-defect sidewalls and have already been able to demonstrate world record wall-plug efficiencies for LEDs in the green-red wavelengths. V-defects can be enlarged during kinetically limited growth where the growth rate of the c-plane GaN is faster than that of their sidewalls, leaving them unfilled. We report on the metal organic chemical vapor deposition growth conditions required to fill in V-defects with p-GaN during epitaxial growth of the LED post the active region. Circular transmission length measurements of Pd/Au contacts processed on p-GaN surfaces with various amounts of unfilled V-defects showed no significant difference in their sheet resistance and specific contact resistance. J–V measurements of LEDs grown with varying unfilled V-defect densities showed no significant difference in the forward bias regime. However, in the reverse bias regime, catastrophic breakdown occurred at markedly lower voltages for samples with larger unfilled V-defect densities. This suggests that unfilled V-defects may act as hotspots for device failure, and planarizing LED surfaces may help prevent early degradation of LED devices.

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Chemical vapor deposition Crystallographic defects Electrical properties and parameters Epitaxy Light emitting diodes Quantum wells Scanning electron microscopy Semiconductor materials Superlattices

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Tak, Tanay, Quevedo, Alejandro, Wu, Feng, Gandrothula, Srinivas, Ewing, Jacob J., Gee, Stephen, Nakamura, Shuji, DenBaars, Steven P., Speck, James S.. 2024-04-22. Planarization of p -GaN surfaces on MOCVD grown V-defect engineered GaN-based LEDs. https://doi.org/10.1063/5.0200424

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