Graphitized Biocarbon Derived from Hydrothermally Liquefied Low-Ash Corn Stover

Shell, Katelyn M.; Amar, Vinod S.; Bobb, Julian A.; Hernandez, Sergio; Shende, Rajesh V.; Gupta, Ram B.

doi:10.1021/acs.iecr.1c03820

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DOE OSTI · 3030708

Graphitized Biocarbon Derived from Hydrothermally Liquefied Low-Ash Corn Stover

Shell, Katelyn M.·Amar, Vinod S.·Bobb, Julian A.·Hernandez, Sergio·Shende, Rajesh V.·Gupta, Ram B.

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Abstract

Graphitized biocarbon can be utilized for energy storage applications such as supercapacitors. The scientific community have geared their attention to obtain such value-added product from abundantly available and low-cost biomass feedstock agricultural residues such as corn stover. Lignocellulosic components embedded within the cell wall of biomass substrates can provide a fine template for enhanced ion storage, transport, and rate capabilities, desirable for electrochemical storage. Presented is the utilization of homogenized low ash content corn stover milled and sieved to desired specifications, which underwent hydrothermal liquefaction in the presence of Ni-based catalytic salts at 275 o C. The hydrochar obtained by solid residue extracted from the reaction slurry was washed to acid neutral and subjected to catalytic activation using ZnCl 2 , followed by thermal annealing at 400 o C for morphological and pore size enhancement of the resulting biochar. Carbonization was performed on acid neutralized hydrochar at 850 °C to further enhance pore structures and increase graphitization for improved conductivity. Catalytic materials exhibited a specific capacitance of 316 F g -1 and held a 100% retention beyond 10,000 cycles. BET, Raman, XRD, cyclic voltammetry, chronopotentiometry, and EIS are discussed herein.

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Shell, Katelyn M., Amar, Vinod S., Bobb, Julian A., Hernandez, Sergio, Shende, Rajesh V., Gupta, Ram B.. 2021-12-29. Graphitized Biocarbon Derived from Hydrothermally Liquefied Low-Ash Corn Stover. https://doi.org/10.1021/acs.iecr.1c03820

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