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At least 199 records · Page 11

Development and testing of a portable wind sensitive directional air sampler

A portable wind-sensitive directional air sampler has been developed as part of an air pollution source identification system. The system is designed to identify sources of air pollution based on the directional collection of field air samples and their analysis for TSP and trace element characteristics. Sources can be identified by analyzing the data on the basis of pattern recognition concepts. Functional testing of a prototype sampler is described; all items exhibited performance and life sufficient to carry out field performance test operations. Life testing of the wind direction sensor and the directional porting valves, which are critical to reliable operation, was emphasized with successful results.

Deyo, J.↗

Concentrations of CH4, CO, CO2, H2, H2O and N2O in the upper stratosphere

On 23 May 1973 a cryogenic air sampler was flown on an Aerobee rocket from White Sands Missile Range. A large air sample was collected between 40 and 50 km altitude and successfully recovered for water vapor and trace gas analysis. The results were as follows: water vapor, 4.0 (+1.3 or - 0.9) ppmV; methane, 0.37 + or - 0.01 ppmV; molecular hydrogen, 0.47 + or - 0.02 ppmV; carbon monoxide, 0.05 + or - 0.01 ppmV; carbon dioxide, 316.2 + or - 2.8 ppmV; and nitrous oxide, 3 + or - 7 ppb.

Ehhalt, D. H.↗

Space Shuttle Trace Gas Analyzer

A Trace Gas Analyzer (TGA) with the ability to detect the presence of toxic contaminants in the Space Shuttle atmosphere within the subparts-per-million range is under development. The design is a modification of the miniaturized Gas Chromatograph-Mass Spectrometer (GCMS) developed for the Viking Mars Lander. An ambient air sample is injected onto the GC column from a constant volume sample loop and separated into individual compounds for identification by the MS. The GC-MS interface consists of an effluent divider and a silver-paladium separator, an electrochemical cell which removes more than 99.99% of the hydrogen carrier gas. The hydrogen is reclaimed and repressurized without affecting the separator efficiency, a feature which enables a considerable weight reduction in the carrier gas supply system.

Dencker, W.↗

Measurements of atmospheric ozone made from a GASP-equipped 747 airliner Mid-March, 1975

This paper presents data on the ozone mixing ratio, static air temperature, wind speed, and wind direction obtained at altitudes from 8 to 12 km during several flights of a commercial airliner equipped with a fully automated air-sampling system developed for the NASA Global Atmospheric Sampling Program (GASP). The objectives of GASP are reviewed, and the data-gathering techniques are described. Two data sets are discussed which illustrate variations of the upper-tropospheric and lower-stratospheric ozone mixing ratios as a function of geographical location and aircraft altitude. Good agreement is found between the GASP data and the tropopause height obtained from National Meteorological Center gridded data.

Falconer, P. D.↗

Status of NASA aircraft engine emission reduction and upper atmosphere measurement programs

Advanced emission reduction techniques for five existing aircraft gas turbine engines are evaluated. Progress made toward meeting the 1979 EPA standards in rig tests of combustors for the five engines is reported. Results of fundamental combustion studies suggest the possibility of a new generation of jet engine combustor technology that would reduce oxides-of-nitrogen (NOx) emissions far below levels currently demonstrated in the engine-related programs. The Global Air Sampling Program (GAS) is now in full operation and is providing data on constituent measurements of ozone and other minor upper-atmosphere species related to aircraft emissions.

Rudey, R. A.↗

Ion chromatographic determination of anions collected on filters at altitudes between 9.6 and 13.7 kilometers

The investigation of atmospheric pollution to determine the anion-containing particulates in the atmosphere at altitudes between 9.6 and 13.7 km is discussed. Air samples collected on cellulose fiber discs impregnated with dibutoxyethylphthalate require very sensitive methods of analysis. It is concluded that ion chromatography is suited for the determination of anions collected on the filters. Methods to control contamination and interfering side reactions are described.

Otterson, D. A.↗

Evaluation of a hydrogen chloride detector for environmental monitoring

The paper describes a hydrogen chloride detector designed to monitor concentrations of hydrogen chloride gas in the ambient environment. The detector was developed for NASA for use in launch vehicle effluent monitoring. The detector operates on chemiluminescence principles with a lower detection limit of less than 5 x 10 to the -3rd ppm (by volume). The hydrogen chloride in the air sample reacts with a bromide-bromate coating in the inlet tube of the instrument producing bromine. Bromine is then quantitated by chemiluminescent oxidation of luminol. The visible light generated in the chemiluminescent reaction is proportional to the hydrogen chloride concentration of the sampled airstream. The detector is most suited to laboratory or field studies where hydrogen chloride is the dominant pollutant, as compared to the interfering species. Interferences include strong acids, acid-forming gases, and halogen gases. Of the interferences investigated the most serious in these groups are hydrochloric and sulfuric acid, sulfur dioxide, and chlorine, respectively. The detector has been in use since 1974 and has been found to be highly portable, rugged, and stable under extreme environmental conditions.

Gregory, G. L.↗

High-flying Mini-Sniffer RPV - Mars bound

The Mini-Sniffer is a small unmanned survey aircraft developed by NASA to conduct turbulence and atmospheric pollution measurements from ground level to an altitude of 90,000 ft. Carrying a 25-lb air sampling apparatus, the Mini-Sniffer typically cruises for one hour at 70,000 ft before being remotely piloted back to earth. A hydrazine monopropellant engine powers the craft, while a PCM telemetering system and a radar transponder provide control functions. Development of a high-performance low-Reynolds-number airfoil could make the research craft suitable for a low-altitude terrain-following mission on Mars.

Reed, R. D.↗

Recommendations of the panels: Panel on in-flight measurements

The attenuation factor for aircraft other than the B-747 in reducing the ambient ozone concentrations which enter the cabin is obtained. The need to continue NASA Global Air Sampling Program measurements was expressed for three main purposes; testing new filters, correlation of complaints with ozone levels, and ambient ozone data. The need to continue cooperation between NASA and industry is indicated. Concern with regard to the correlation of ozone levels and complaints was given. The need to measure the variability of ozone within the aircraft cabin was investigated. The requirement for an onboard ozone monitor on all aircraft is discussed.

Rogers, J.↗

Measurement of NO and O3 from aircraft: 1977 tropical convergence zone experiment

As part of the Ames Research Center program to explore the nature of stratosphere-troposphere exchange processes occurring in the Intertropical Convergence Zone, simultaneous in situ measurements of nitric oxide and ozone mixing ratios were made with the Ames stratospheric air sampler SAS 2. The SAS 2 is a second-generation system; it employs four parallel sensors and was designed primarily for measurements at altitudes of 60,000 ft and above on the U-2 stratospheric research aircraft. The only modifications required for this study was the addition of an air sample flow restrictor. Data were obtained with the SAS 2 system on July 26, 27, 30 and 31, 1977. Generally, 30-min measurements were made at each of six altitudes ranging from 45,000 ft to 70,000 ft, and separated by 5,000 ft intervals.

Starr, W. L.↗

Polar nephelometer for atmospheric particulate studies

A unique polar nephelometer was designed and constructed for the measurement of atmospheric particulate characteristics. The nephelometer produces visible light from a self-contained laser to irradiate an air sample drawn into the instrument. The light scattered from the particulates and molecules in the sample is detected as a function of scattering angle for each of four different incident light polarizations. These measurements are used to determine the particulate scattering matrix which is a function of the size, shape, and index of refraction of the particles. The region of sensitivity for the measurements corresponds to the size range of particles that strongly affects visible radiative transfer in the atmosphere, which is the primary application for the derived information.

Hansen, M. Z.↗

Recent assessment of the performance and accuracy of a chemiluminescent rocket sonde for upper atmospheric ozone measurements

The chemiluminescent rocket ozonesonde utilizing rhodamine-B as a detector and self-pumping for air sampling has been improved. The instrument employs standard meteorological sounding systems and is the only technique available for routine nighttime ozone measurements above balloon altitudes. The chemiluminescent detector, when properly calibrated, is shown to be specific to ozone, stable, and of sufficient sensitivity for accurate measurements of ozone from about 65-20 km. An error analysis indicates that the measured ozone profiles have an absolute accuracy of about + or - 12% and a precision of about + or - 6%. Approximately 20 flights have been conducted for geophysical investigations, while additional flights were conducted with other rocket and satellite ozone soundings for comparisons. In general, these comparisons showed good agreement.

Hilsenrath, E.↗

A cloud condensation nucleus spectrometer designed for airborne measurements

The spectrometer is a simple extension of the continuous flow diffusion chamber (CFDC) operated in the vertical mode. The principal new design features of the instrument are its rapid time response and ability to rapidly measure the CCN activity spectrum. The activity spectrum of CCN in an air sample is measured by simultaneously operating the spectrometer at four supersaturations. The CCN spectrometer consists of four essentially indepenent CFDC's in a parallel array. Each CFDC is 61 cm long, 10 cm wide, and consists of two vertical parallel plates 1 cm apart, maintained at different temperatures. Each CFDC has a single particle optical counter located at the center of its base.

Radke, L. F.↗

Measurement of trace levels of chlorine in the stratosphere

Mathematical models of stratospheric ozone have predicted a reduction in the total ozone due to chlorofluoromethanes released into the atmosphere. Analytical procedures for the collection of air in the stratosphere and for analysis of these air samples for trace levels of chlorine, regardless of the state of chemical composition were developed. Calibration experiments are conducted in order to validate all methods and procedures. Results of neutron activation analysis calibration procedures using standard chlorine gases are included.

Warren, D. C.↗

Operational evaluation of thunderstorm penetration test flights during project Storm Hazards '80

The National Aeronautics and Space Administration is conducting a research project called Storm Hazards '80 in order to study the prediction, detectability and avoidance of the hazards of severe storms for aircraft operations. The project, using a highly instrumented NASA F-106B airplane to penetrate thunderstorms, gathered and correlated data from both airborne and ground based instrumentation. The objectives of this project are to determine the effects of lightning on the design and operation of aircraft composite structures and digital electronic systems. The data will be used to determine the correlation of lightning hazards with other severe storm hazards, such as heavy precipitation, hail, turbulence and wind-shear, in order to develop an initial data base for use in design and avoidance. The NASA F-106B was equipped with a weather radar, stormscope, lightning measurement instrumentation and air sampling equipment. This paper will focus on the operational aspects of thunderstorm penetrations and the pilot techniques used to avoid the extremely hazardous portions of the storm such as the tornadoes and hail. It will deal with the effects of the storm elements on the aircraft hardware, avionics and the crew.

Keyser, G. L., Jr.↗

Differences in the concentrations of atmospheric trace gases in and above the tropical boundary layer

Weekly air samples were collected at Cape Kumakahi (0 km) and at nearby Mauna Loa Observatory (3.4 km) which is above the boundary layer. EC/GC and GC/FID techniques were used to measure CH3I, CHCl3, CO and CH4 which are largely natural in origin, and C2Cl4, CCl4, CH3CCl3, (F-11), CCl2F2, (F-12), CHClF, (F-22) and C2F3Cl3 (F-113), which are due to anthropogenic (CCl3F) etc. activities. It was found that all these gases are significantly (alpha is equal to or less than 0.05) more abundant in the boundary layer than above it.

Rasmussen, R. A.↗

Participation of ethylene in gravitropism

In shoots of many plants, of which tomato (Lycopersicon esculentum Mill.) is an example, ethylene production is substantially increased during gravitropism. As a first step toward elucidating the role of ethylene in gravitropism, detailed time courses of ethylene production in isolated hypocotyl segments and whole plants were measured for gravistimulated and upright tomato seedlings. In the first experiment, seedlings were set upright or laid horizontal and then, at 15 min intervals, sets of hypocotyls were excised and sealed into gas tight vials. A steady long term rise in ethylene production begins after 15 min gravistimulation. It is possible that this increase is a consequence of the accumulation of indoleacetic acid (IAA) in the lower tissue of the hypocotyle. In a second kind of experiment, whole seedlings were enclosed in sealed chambers and air samples were withdrawn at 5 min intervals. Stimulated seedlings produced more ethylene than controls during the first 5 min interval, but not appreciably more during the second. This suggests the possibility that the ethylene production induced during the first 5 min occurs immediately rather than after a lag, and thus much too soon to be controlled by redistribution of IAA.

Harrison, M.↗