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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Test Plan to Investigate the Optimal Cure Schedule of an Epoxy Resin for Its Application as an Adhesive in Optocouplers

Epoxy resins are polymeric materials that are known for their versatility, low cost, and strong thermal and mechanical properties. They can be used as coatings, adhesives, automotive primers, and have become staples in electronics, aerospace composites and semiconductor encapsulates. Recently, LANL has experienced a decline in the quality of a specialized electronic device, called an optocoupler, which is normally acquired from commercial suppliers. Because of this, a group at LANL is exploring the feasibility of in-house manufacturing of an optocoupler that is better suited for their application. The current prototype has resulted in adhesive failure after being exposed to several thermal cycles. There is a need to investigate the possible reasons for this failure, particularly how the cure schedule of the epoxy might affect its adhesive strength over time and in cycled temperatures. To assist in this investigation, a test plan has been developed involving multiple experiments using thermomechanical analysis (TMA), dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC).

36 MATERIALS SCIENCE↗
DOE OSTI2021

Sustainable Functional Epoxies through Boric Acid Templating

Thermoset polymers (e.g. epoxies, vulcanizable rubbers, polyurethanes, etc.) are crosslinked materials with excellent thermal, chemical, and mechanical stability; these properties make thermoset materials attractive for use in harsh applications and environments. Unfortunately, material robustness means that these materials persist in the environment with very slow degradation over long periods of time. Balancing the benefits of material performance with sustainability is a challenge in need of novel solutions. Here, we aimed to address this challenge by incorporating boronic acid-amine complexes into epoxy thermoset chemistries, facilitating degradation of the material under pH neutral to alkaline conditions; in this scenario, water acts as an initiator to remove boron species, creating a porous structure with an enhanced surface area that makes the material more amenable to environmental degradation. Furthermore, the expulsion of the boron leaves the residual pores rich in amines which can be exploited for CO 2 absorption or other functionalization. We demonstrated the formation of novel boron species from neat mixing of amine compounds with boric acid, including one complex that appears highly stable under nitrogen atmosphere up to 600 °C. While degradation of the materials under static, alkaline conditions (our “trigger”) was inconclusive at the time of this writing, dynamic conditions appeared more promising. Additionally, we showed that increasing boronic acid content created materials more resistant to thermal degradation, thus improving performance under typical high temperature use conditions.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Calibrating the SPECTACULAR constitutive model using legacy Sandia data for two filled epoxy systems: 828/CTBN/DEA/GMB and 828/DEA/GMB

The SPECTACULAR model is a development extension of the Simplified Potential Energy Clock (SPEC) model. Both models are nonlinear viscoelastic constitutive models used to predict a wide range of time-dependent behaviors in epoxies and other glass-forming materials. This report documents the procedures used to generate SPECTACULAR calibrations for two particulate-filled epoxy systems, 828/CTBN/DEA/GMB and 828/DEA/GMB. No previous SPECTACULAR or SPEC calibration exists for 828/CTBN/DEA/GMB, while a legacy SPEC calibration exists for 828/DEA/GMB. To generate the SPECTACULAR calibrations, a step-by-step procedure was executed to determine parameters in groups with minimal coupling between parameter groups. This procedure has often been deployed to calibrate SPEC, therefore the resulting SPECTACULAR calibration is backwards compatible with SPEC (i.e. none of the extensions specific to SPECTACULAR are used). The calibration procedure used legacy Sandia experimental data stored on the Polymer Properties Database website. The experiments used for calibration included shear master curves, isofrequency temperature sweeps under oscillatory shear, the bulk modulus at room temperature, the thermal strain during a temperature sweep, and compression through yield at multiple temperatures below the glass transition temperature. Overall, the calibrated models fit the experimental data remarkably well. However, the glassy shear modulus varies depending on the experiment used to calibrate it. For instance, the shear master curve, isofrequency temperature sweep under oscillatory shear, and the Young's modulus in glassy compression yield values for the glassy shear modulus at the reference temperature that vary by as much as 15 %. Also, for 828/CTBN/DEA/GMB, the temperature dependence of the glassy shear modulus when fit to the Young's modulus at different temperatures is approximately four times larger than when it is determined from the isofrequency temperature sweep under oscillatory shear. For 828/DEA/GMB, the temperature dependence of the shear modulus determined from the isofrequency temperature sweep under oscillatory shear accurately predicts the Young's modulus at different temperatures. When choosing values for the shear modulus, fitting the glassy compression data was prioritized. The new and legacy calibrations for 828/DEA/GMB are similar and appear to have been calibrated from the same data. However, the new calibration improves the fit to the thermal strain data. In addition to the standard calibrations, development calibrations were produced that take advantage of development features of SPECTACULAR , including an updated equilibrium Helmholtz free energy that eliminates undesirable behavior found in previous work. In addition to the previously mentioned experimental data, the development calibrations require data for the heat capacity during a stress-free temperature sweep to calibrate thermal terms.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Epoxy / Silicone Potting Material Removal for Greater Recovery of Circuit Boards

This report documents an exploratory research project, “Epoxy/Silicone Potting Material Removal for Greater Recovery of Circuit Boards,” that investigated micro abrasion and laser ablation as potential cost effective methods for removal of epoxy and silicone potting material from printed circuit boards (PCBs) to expose components for testing and repair. The ability to cost effectively remove such PCB potting materials will improve PCB repair, remanufacture, and reuse opportunities with potential for sizable reductions in material use, E-waste, and energy. Laser ablation was identified as a method potentially warranting further investigation, in particular for epoxy based potting materials.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2025

Optimizing Adhesion: Evaluating B-Stage Epoxy for Bonding [Poster]

The application of increased pressure during the curing process of B-stage epoxy has been hypothesized to enhance the adhesive properties and bond strength in printed wiring board (PWB) assembly. This study aimed to investigate the correlation between pressure application and the performance of B-stage epoxy.

42 ENGINEERING↗
DOE OSTI2021

Corrosion Behavior of Laser-Interference Structured AA2024 Coated with a Chromate-Containing Epoxy Primer

In this study, the corrosion behavior of laser-interference treated AA2024-T3 specimens, which are coated with a primer, is presented. The surface of as-received AA2024-T3 specimens were laser-interference structured by splitting the primary beam of a Q-switched Nd:YAG pulsed nanosecond laser into two beams and focusing them to the same spot on the specimen surface. After being stored in plastic cases for up to 70 d, without any additional cleaning, the specimens were spray painted with a chromate-containing epoxy primer, CA7233, compliant to MIL-PRF-23377 Type I Class C2 specification. The corrosion behavior of laser-interference specimens was assessed against that of specimens prepared by chromated conversion coating and sulfuric acid anodizing treatments. After the ASTM B117 corrosion exposure, it was found that the laser processed specimens exhibited only few blisters. On one hand, most specimens prepared at a laser fluence of 1.78 J/cm 2 , without any additional chemical cleaning, were found to develop one very small blister after only 96 h of exposure. However, the growth of these blisters was not significant even after 1,000 h of salt spray exposure. On the other hand, only a fraction of the specimens prepared at a laser fluence of 1.24 J/cm 2 and acetone wiped right after the laser structuring were found to develop several tiny blisters after 790 h and longer exposure. Overall, it was found that the corrosion damage was minimized at a laser rastering speed of 4 mm/s, a condition for which only 33% of specimens developed very minor corrosion damage. Furthermore, the ASTM D1654 creepage ratings, which was used to evaluate the corrosion damage along the scribe lines, were found to be at least nine for all coated panels. These results indicate that the laser-interference technique with the additional acetone wiping has the potential to be further developed as a nonchemical surface preparation technique for chromate-containing epoxy primers coating systems.

36 MATERIALS SCIENCE↗
NASA NTRS1965

Epoxy-resin patterns speed shell-molding of aluminum parts

Half patterns cast from commercial epoxy resin containing aluminum powder are used for shell-molding of aluminum parts. The half patterns are cast in plastic molds of the original wooden pattern. Ten serviceable sand resin molds are made from each epoxy pattern.

Source record↗
NASA NTRS1968

Cure of epoxy resins determined by simple tests

Rapid visual and simple quantitative tests indicate the degree of cure of particular epoxy resin binders in prepreg stock. It is possible that these tests may be extended to a number of different epoxy formulations.

Ladaki, M.↗
NASA NTRS1973

Large boron--epoxy filament-wound pressure vessels

Advanced composite material used to fabricate pressure vessel is prepeg (partially cured) consisting of continuous, parallel boron filaments in epoxy resin matrix arranged to form tape. To fabricate chamber, tape is wound on form which must be removable after composite has been cured. Configuration of boron--epoxy composite pressure vessel was determined by computer program.

Jensen, W. M.↗
NASA NTRS1974

Comparison of fracture mechanisms for carbon-epoxy composites under tensile loading

The effects of oxidative surface treatments and differences in resin crack sensitivity on the tensile properties of carbon-epoxy composites have been investigated. A comparison of the fracture mechanisms for two different fiber batches was made in both model and engineering composites, using unmodified and modified epoxy resin. It has been observed that two distinct characteristics occur in the fracture surfaces of most engineering composites; first, fibers which fracture at the surface result in cleavage failure and, second, those which have fractured elsewhere and pulled out. A detailed discussion of these observations is contained in this paper.

Mazzio, V. F.↗
NASA NTRS1975

Impact response of graphite-epoxy flat laminates using projectiles that simulate aircraft engine encounters

An investigation of the response of a graphite-epoxy material to foreign object impact was made by impacting spherical projectiles of gelatin, ice, and steel normally on flat panels. The observed damage was classified as transverse (stress wave delamination and cracking), penetrative, or structural (gross failure): the minimum, or threshold, velocity to cause each class of damage was established as a function of projectile characteristics. Steel projectiles had the lowest transverse damage threshold, followed by gelatin and ice. Making use of the threshold velocities and assuming that the normal component of velocity produces the damage in nonnormal impacts, a set of impact angles and velocities was established for each projectile material which would result in damage to composite fan blades. Analysis of the operating parameters of a typical turbine fan blade shows that small steel projectiles are most likely to cause delamination and penetration damage to unprotected graphite-epoxy composite fan blades.

Preston, J. L., Jr.↗
NASA NTRS1976

Exploratory study on the effects of novel diamine curing agents and isocyanate precursors on the properties of new epoxy and urethane adhesives

The effects of novel aromatic diamine structures on the adhesive properties of epoxy and polyurethane adhesives were studied. Aromatic diamines based on benzophenone and diphenyl-methane isomers were evaluated as curing agents for epoxy resins and benzophenone and diphenyl-methane based diamine isomers were evaluated as curing agents for polyurethane adhesives. Polyurethane adhesives were prepared based on m, m prime-diisocyanato-diphenyl-methane and m, m prime-diisocyanato-benzophenone. The m, m prime-diisocayanato-diphenyl-methane based adhesive had properties comparable to state-of-the-art adhesives. The m, m prime-diisocyanato-benzophenone based adhesive was extremely reactive.

Glasgow, D. G.↗
NASA NTRS1975

X-ray method shows fibers fail during fatigue of boron-epoxy laminates

A method proposed for studying progressive fiber fracture in boron-epoxy laminates during fatigue tests is described. It is based on the intensity of X-ray absorption of the tungsten core in the boron filaments as contrasted with that of the boron and epoxy matrix. When the laminate is X-rayed, the image of the tungsten in the born filaments is recorded on a photographic plate. Breaks in the boron laminates can be easily identified by magnifying the photographic plates. The method is suitable for studying broken boron filaments in most matrix materials, and may supply key information for developing realistic fatigue and fracture models.

Roderick, G. L.↗
NASA NTRS1976

Electrical properties of epoxies and film resistors

The reliability of hybrid microcircuits has been enhanced in recent years by the use of organic adhesives as a replacement for solder and eutectics. The epoxies have been the most effective and widely used material for this application. Methods for measuring the electrical and mechanical properties of epoxies are developed. Data are given for selected conductive adhesives at high and low frequencies. The temperature coefficients of resistance of thick film resistors are presented.

Sergent, J. E.↗
NASA NTRS1976

Development, manufacturing, and test of graphite-epoxy composite spoilers for flight service on 737 transport aircraft

A total of 114 spoiler units were fabricated in a production shop environment, utilizing three graphite epoxy material systems. Production planning paper was generated for each spoiler unit to completely document each production step of each spoiler unit. The graphite epoxy skins were laid up on production tooling using both mechanical and hand layup techniques. Inspection techniques utilized MRB type assessment in the abscence of quality requirements. Each completed spoiler was subjected to ultrasonic inspection utilizing a multicolor recording system that documented each inspection result. In addition, one static test spoiler was sectioned after the test to examine the adhesive filleting to the honeycomb core. Visual examination of the cured adhesives showed excellent results.

Stoecklin, R. L.↗
NASA NTRS1978

Design and Fabrication of a Ring-Stiffened Graphite-Epoxy Corrugated Cylindrical Shell

Design and fabrication of supplement test panels that represent key portions of the cylinder are described, as are supporting tests of coupons, sample joints, and stiffening ring elements. The cylindrical shell is a ring-stiffened, open corrugation design that uses T300/5208 graphite-epoxy tape as the basic material for the shell wall and stiffening rings. The test cylinder is designed to withstand bending loads producing the relatively low maximum load intensity in the shell wall of 1,576 N/cm. The resulting shell wall weight, including stiffening rings and fasteners, is 0.0156 kg/m. The shell weight achieved in the graphite-epoxy cylinder represents a weight saving of approximately 23 percent, compared to a comparable aluminum shell. A unique fabrication approach was used in which the cylinder wall was built in three flat segments, which were then wrapped to the cylindrical shape. Such an approach, made possible by the flexibility of the thin corrugated wall in a radial direction, proved to be a simple approach to building the test cylinder. Based on tooling and fabrication methods in this program, the projected costs of a production run of 100 units are reported.

Johnson, R., Jr.↗
NASA NTRS1979

Feasibility Study of Graphite Epoxy Antenna for a Microwave Limb Sounder Radiometer (MLSR)

Results are presented of a feasibility study to design graphite epoxy antenna reflectors for a jet propulsion laboratory microwave limb sounder instrument (MLSR). Two general configurations of the offset elliptic parabolic reflectors are presented that will meet the requirements on geometry and reflector accuracy. The designs consist of sandwich construction for the primary reflectors, secondary reflector support structure and cross-tie members between reflector pairs. Graphite epoxy materials of 3 and 6 plies are used in the facesheets of the sandwich. An aluminum honeycomb is used for the core. A built-in adjustment system is proposed to reduce surface distortions during assembly. The manufacturing and environmental effects are expected to result in surface distortions less than .0015 inch and pointing errors less than .002 degree.

Source record↗