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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Multiple spacecraft Michelson stellar interferometer

Results of an orbital analysis and performance assessment of SAMSI (Spacecraft Array for Michelson Spatial Interferometry) are presented. The device considered includes two one-meter telescopes in orbits which are identical except for slightly different inclinations; the telescopes achieve separations as large as 10 km and relay starlight to a central station which has a one-meter optical delay line in one interferometer arm. It is shown that a 1000-km altitude, zero mean inclination orbit affords natural scanning of the 10-km baseline with departures from optical pathlength equality which are well within the corrective capacity of the optical delay line. Electric propulsion is completely adequate to provide the required spacecraft motions, principally those needed for repointing. Resolution of 0.00001 arcsec and magnitude limits of 15 to 20 are achievable.

Stachnik, R. V.↗
NASA NTRS1989

Remote sensing of the troposphere by infrared emission spectroscopy

This paper describes the concept of a cryogenic IR imaging Fourier transform spectrometer, called the Tropospheric Emission Spectrometer (TES), designed for observations of the troposphere and lower stratosphere from a near-earth orbit, using natural thermal emission and reflected sunlight. The principal molecular species to be measured by TES are O3, CO, CO2, N2O, H2O, H2O2, NO, NO2, HNO3, NH3, CH4, C2H6, C2H2, SO2, COS, CFCl3, and CF2Cl2. The TES is scheduled for a launch on the second polar platform of the Earth Observing System in 1998.

Beer, Reinhard↗
NASA NTRS1992

EnviroNET

EnviroNET is a service/facility that provides users with on-line, dial-up technical information concerning environmental conditions likely to be encountered by instruments and experimental arrangements carried aboard spacecraft. EnviroNET incorporates at present a combination of expository text and numerical tables amounting to about two million characters (bytes), plus FORTRAN programs that model the space environment. The topics covered are presented in viewgraph form and include the following: advantages of EnviroNET; thermal and humidity; vibration and acoustics; electromagnetic interference; loads and low frequency dynamics; microbial and toxic contaminants; molecular contamination; natural environment; orbiter motion; particulate environment; surface interactions; spacecraft anomalies; and interactive graphics facility.

Vansant, Tim↗
NASA NTRS1984

Launch vehicle integration requirements for SP-100

SP-100 is the designation for a nuclear reactor-based power plant being developed for both civil and military missions beginning in the 1990s for such potential space applications as communication satellites, space radar, electric propulsion and space stations. Typically, a system using the SP-100 along with a selected upper stage system would be launched by the National Space Transportation System (NSTS) Space Shuttle System into a near-earth orbit, deployed, and through upper stage propulsion burn(s) be inserted/transferred to its mission orbit. The nature of the advanced design SP-100 gives rise to a set of issues that require special attention to assure that payloads using this power plant are physically and functionally compatible with the NSTS and meet the safety requirements thereof. The purpose of this document is to define and present the requirements and interface provisions that, when satisfied, will ensure technical compatibility between SP-100 systems and the NSTS.

Shaw, L. T., Jr.↗
NASA NTRS2001

The Space Debris Environment for the ISS Orbit

With thirty-five planned missions over the next five years, the International Space Station (ISS) will be the focus for manned space activity. At least 6 different vehicles will transport crew and supplies to and from the nominally 400 km, 51.6 degree orbit. When completed, the ISS will be the largest space structure ever assembled and hence the largest target for space debris. Recent work at the Johnson Space Center has focused on updating the existing space debris models. The Orbital Debris Engineering Model, has been restructured to take advantage of state of the art desktop computing capability and revised with recent measurements from Haystack and Goldstone radars, additional analysis of LDEF and STS impacts, and the most recent SSN catalog. The new model also contains the capability to extrapolate the current environment in time to the year 2030. A revised meteoroid model based on the work of Divine has also been developed, and is called the JSC Meteoroid Model. The new model defines flux on the target per unit angle per unit speed, and for Earth orbit, includes the meteor showers. This paper quantifies the space debris environment for the ISS orbit from natural and anthropogenic sources. Particle flux and velocity distributions as functions of size and angle are be given for particles 10 microns and larger for altitudes from 350 to 450 km. The environment is projected forward in time until 2030.

Theall, Jeff↗
NASA NTRS2018

Subsetting Satellite Level 2 Data at NASA GES DISC

Working with Level 2 satellite swath data can prove challenging for many users. The variety of metadata, high resolution, and orbit-based nature of such data makes it difficult to acquire and manage. The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) has developed a general-purpose Level 2 Subsetting service that facilitates access to Level 2 data products. The Level 2 Subsetter enables users to sub-sample swath and gridded data in a variety of ways: by location (in a lat/lon box, within a circle of given radius, or at a specific point), by time (via swath segments or collections of granules), by any nonspatial dimension, or by selecting specific variables. The Level 2 Subsetting service also allows users to specify output data configuration and file format. In this presentation, we will detail and demonstrate the capabilities of this new service.

Huwe, Paul↗
NASA NTRS2014

Remote Sensing of Above Cloud Aerosols

The direct and indirect radiative effects of aerosols suspended in the atmosphere above clouds (ACA) are a highly uncertain component of both regional and global climate. Much of this uncertainty is observational in nature most orbital remote sensing algorithms were not designed to simultaneously retrieve aerosol and cloud optical properties in the same vertical column. Thus the climate modeling community has limited data to inform model development efforts, which encapsulate the current understanding of climate. Furthermore, field measurements have identified regions with consistent ACA, and regional simulations show that the radiative forcing may be significant. For this reason, there has been a recent push to develop the ability to determine ACA distribution, optical properties and cloud interactions, while also providing a means to validate models. Several algorithms have been created that utilize existing instruments for these purposes. However, the observational data sources, algorithm characteristics, geophysical assumptions and retrieved products from these methods are highly variable. This chapter is a review of these techniques, their uncertainties, and the associated validation efforts. We will also discuss the future of ACA remote sensing, both with regards to new instruments and the potential for new algorithms.

Aerosols↗
DOE OSTI2022

Plutonium Hybrid Materials: A Platform to Explore Assembly and Metal–Ligand Bonding

In this work, we report the synthesis of five new hybrid materials containing the [PuCl 6 ] 2- anion and charge balancing, non-covalent interaction donating 4-X-pyridinium (X = H, Cl, Br, I) cations. Single crystals of the title compounds were grown and harvested from acidic, chloride-rich, aqueous media and their structures were determined via X-ray diffraction. Compounds 1-4, (4XPyH) 2 [PuCl 6 ] and 5, (4IPyH) 4 [PuCl 6 ] · 2Cl, exhibit two distinct sheet-like structure types. Structurally relevant non-covalent interactions were tabulated from crystallographic data and verified computationally using electrostatic surface potential maps and the quantum theory of atoms in molecules (QTAIM) approach. The strength of the hydrogen and halogen bonds was quantified using Kohn-Sham density functional theory and a hierarchy of acceptor-donor pairings established. In turn, the PuIV-Cl bonds were studied using the QTAIM and natural localized molecular orbital (NLMO) approaches to delineate the underlying bond mechanism and hybrid atomic orbital contributions therein. Energy decomposition (ED) and natural ED analyses were also explored to probe the bond mechanism and, more broadly, explore the efficacy of these techniques in studying these anionic systems. The results of the PuIV-Cl bond analyses were compared across composition via analogous treatments of previously reported [PuO 2 Cl 4 ] 2- and [PuCl 3 (H 2 O) 5 ] molecular units. In summary, our study indicates that the Pu-Cl bonds are predominately ionic, yet exhibit small varying degrees of covalent character that increase from [PuCl 3 (H 2 O) 5 ], [PuO 2 Cl 4 ] 2- , to [PuCl 6 ] 2- , while the participation of the Pu based s/d and f orbitals concurrently decrease and increase, respectively.

transuranic↗
NASA NTRS1989

Approximate angular distribution and spectra for geomagnetically trapped protons in low-earth orbit

The highly anisotropic nature of the radiation in the low-earth orbit has been ignored for most spacecraft shielding calculations made to date because the standard environmental models describe the omnidirectional flux only, because the varying attitude of the spacecraft in the environment is assumed to average out the effect and because of the added complexity of the calculation. The Space Station is planned to be stabilized with respect to the velocity vector and local vertical. Thus it will pass through the South Atlantic Anomaly where most of the radiation flux is encountered in much the same attitude on each pass. Any calculation including a complex shielding geometry should thus consider the angular distributuon of the incident radiation. An approximate trapped proton angular distribution is presented which includes both the 'pan caked' distribution relative to the magnetic field direction and the east-west effect which is energy dependent. This distribution is then used with a planar shielding geometry to obtain an estimate of the effect of the anisotropy on radiation dose rates in spacecraft.

Watts, J. W.↗
DOE OSTI2022

BiCuI 4 (Pyridine) 5 a neutral ligand-supported compound of BiI 3 and CuI

Reaction of equimolar pyridine (Py) solutions BiI 3 and CuI produces the Py-supported 1:1 bimetallic complex BiCuI 4 (Py) 5 in quantitative yield. The title complex is only the second neutral complex to feature Cu–I–Bi bridging and shows an octahedral trans-[BiI 4 (Py) 2 ] unit joined to a distorted tetrahedral CuI(Py) 3 unit by an iodide bridge. The complex shows low thermal stability, decomposing under modest heating or vacuum to produce a mixture of BiI 3 and CuI. Thus, it is a potential entry/precursor to BiI 3 /CuI chemistry. Natural Localized Molecular Orbital (NLMO) calculations were performed to analyze the nature of the Cu–I–Bi bonds, revealing that the title compound lies on the cusp of being [Cu(Py) 3 ] + [BiI 4 (Py) 2 ] – . Diffuse reflectance spectroscopy measurements show a strong absorption band with an optical bandgap energy of 1.94 eV. Theoretical density of states (DOS) and time-dependent density functional theory (TD-DFT) experiments to map the electronic structure assign the primary electronic transition as a mixed halide/metal-to-ligand charge transfer between Cu–I–Bi donor orbitals and Py π* acceptor orbitals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1987

Optimization of orbital assignment and specification of service areas in satellite communications

The mathematical nature of the orbital and frequency assignment problem for communications satellites is explored, and it is shown that choosing the correct permutations of the orbit locations and frequency assignments is an important step in arriving at values which satisfy the signal-quality requirements. Two methods are proposed to achieve better spectrum/orbit utilization. The first, called the delta S concept, leads to orbital assignment solutions via either mixed-integer or restricted basis entry linear programming techniques; the method guarantees good single-entry carrier-to-interference ratio results. In the second, a basis for specifying service areas is proposed for the Fixed Satellite Service. It is suggested that service areas should be specified according to the communications-demand density in conjunction with the delta S concept in order to enable the system planner to specify more satellites and provide more communications supply.

Wang, Cou-Way↗
NASA NTRS2018

Smallsat Navigation via the Deep Space Network: Inner Solar Systems Missions

The space industry has seen an explosion in the number of operational SmallSats in Earth orbit, with a natural interest in extending SmallSat capabilities outside of low Earth orbit. As with larger missions, near-term deep-space SmallSats will rely on the Deep Space Network or similar facilities. Given the predicted growth in the number of deep space missions, effective use of DSN resources will be more critical than ever. Our investigation provides an initial survey of expected inner Solar System navigation performance for DSN radiometric data types, from two-way Doppler and ranging to one-way equivalents, including delta differential one-way range and alternative tracking strategies.

Wood, Lincoln J.↗
NASA NTRS2002

Natural and Induced Environment in Low Earth Orbit

The long-term exposure of astronauts on the developing International Space Station (ISS) requires an accurate knowledge of the internal exposure environment for human risk assessment and other onboard processes. The natural environment is moderated by the solar wind which varies over the solar cycle. The neutron environment within the Shuttle in low Earth orbit has two sources. A time dependent model for the ambient environment is used to evaluate the natural and induced environment. The induced neutron environment is evaluated using measurements on STS-31 and STS-36 near the 1990 solar maximum.

Wilson, John W.↗
DOE OSTI2023

Spin-orbital correlations from complex orbital order in MgV 2⁢ O 4

MgV 2 ⁢O 4 is a spinel based on magnetic V 3+ ions, which host both spin (𝑆 = 1) and orbital (𝑙 eff = 1) moments. Owing to the underlying pyrochlore coordination of the magnetic sites, the spins in MgV 2 ⁢O 4 only antiferromagnetically order once the frustrating interactions imposed by the 𝐹⁡𝑑⁢$\overline{3}$⁢𝑚 lattice are broken through an orbitally-driven structural distortion at T 𝑆 ≃ ⁢60 K. Consequently, a Néel transition occurs at T 𝑁 ≃ ⁢40 K. Low-temperature spatial ordering of the electronic orbitals is fundamental to both the structural and magnetic properties; however, considerable discussion on whether it can be described by complex or real orbital ordering is ambiguous. We apply neutron spectroscopy to resolve the nature of the orbital ground state and characterize hysteretic spin-orbital correlations using x-ray and neutron diffraction. Neutron spectroscopy finds multiple excitation bands and we parametrize these in terms of a multilevel (or excitonic) theory based on the orbitally degenerate ground state. Meaningful for the orbital ground state, we report an “optical-like” mode at high energies that we attribute to a crystal-field-like excitation from the spin-orbital 𝑗 eff = 2 ground-state manifold to an excited 𝑗 eff =1 energy level. We parametrize the magnetic excitations in terms of a Hamiltonian with spin-orbit coupling and local crystalline electric field distortions resulting from deviations from perfect octahedra surrounding the V 3+ ions. We suggest that this provides compelling evidence for complex orbital order in MgV 2⁢ O 4 . We then apply the consequences of this model to understand hysteretic effects in the magnetic diffuse scattering where we propose that MgV 2⁢ O 4 displays a high-temperature orbital memory of the low-temperature spin order.

Frustrated magnetism↗
NASA NTRS2019

PSR J2234+0611: A New Laboratory for Stellar Evolution

We report the timing results for PSR J2234+0611, a 3.6 ms pulsar in a 32 day, eccentric (e = 0.13) orbit with a helium white dwarf. The precise timing and eccentric nature of the orbit allow measurements of an unusual number of parameters: (a) a precise proper motion of 27.10(3) mas yr−1 and a parallax of 1.05(4) mas resulting in a pulsar distance of 0.95(4) kpc; enabling an estimate of the transverse velocity, 123(5) km s−1. Together with previously published spectroscopic measurements of the systemic radial velocity, this allows a 3D determination of the system’s velocity; (b) precise measurements of the rate of advance of periastron yields a total system mass of 1.6518 +0.0033-0.0035 Msun; (c) a Shapiro delay measurement, h3 = 82 ± 14 ns, despite the orbital inclination not being near 90°; combined with the measurement of the total mass yields a pulsar mass of 1.353 +0.014-0.017 Msun and a companion mass of 0.298 +0.015-0.0120 Msun; (d) we measure precisely the secular variation of the projected semimajor axis and detect a significant annual orbital parallax; together these allow a determination of the 3D orbital geometry of the system, including an unambiguous orbital inclination (i = 138.7 +2.5-2.2 deg) and a position angle for the line of nodes ( omega = 44 +5-4 deg). We discuss the component masses to investigate the hypotheses previously advanced to explain the origin of eccentric MSPs. The unprecedented determination of the 3D position, motion, and orbital orientation of the system, plus the precise pulsar and WD masses and the latter’s optical detection make this system a unique test of our understanding of white dwarfs and their atmospheres.

K Stovall↗
DOE OSTI2020

Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15N NMR Spectroscopy

The solid-state 15N NMR powder spectra of the thorium nitride complex, [K(18-crown-6)(THF)2][(R2N)3Th(m-15N)(Th(NR2)3] ([K][1-15N], R = SiMe3), and the thorium amide complex, [Th(NR2)3(15NH2)] (2-15N) were recorded. The spectrum for [K][1-15N] represents the first reported solid-state 15N NMR data for an actinide nitride complex. The experimentally measured tensor spans are 847 ppm for [K][1-15N] and 237 ppm for 2-15N. Both shielding tensors exhibit a near-zero asymmetry parameter, which for [K][1-15N] is consistent with a local rotational symmetry of its 15N-labelled nitride ligand. For 2-15N, the lack of asymmetry can be rationalized by a quasi-free Th-NH2 bond rotation in the solid-state. DFT calculations overestimate the tensor span somewhat for [K][1-15N], but provide isotropic shifts in good agreement with both the solid-state and solution values for both complexes. Natural localized molecular orbital (NLMO) analyses of the nuclear shielding reveal that the larger tensor span in [K][1-15N] vs. 2-15N is primarily a consequence of more pronounced covalency of the N-Th bonds, and large spin-orbit coupling due to significant Th 5f orbital contribution to those bonds, impacting the principal components of the shielding tensor perpendicular to the Th-N-Th axis. Overall, our analysis confirms the involvement of the 5f orbitals in Th-N multiple bonds, and further demonstrates the value of solid-state NMR spectroscopy for interrogating actinide-ligand bonding.

actinides, covalent bonding, Nuclear Magnetic Reso↗
NASA NTRS1985

SAMSI: An orbiting spatial interferometer for micro-arc second astronomical observations

The concept and performance of (SAMSI) Spacecraft Array for Michelson Spatial Interferometry, an orbiting spatial interferometer comprised of three free-flying spacecraft, two collector telescopes and a central mixing station are described. In the one-dimensional interferometry mode orbits exist which provide natural scanning of the baseline. These orbits place extremely small demands on thrusters and fuel consumption. Resolution of 0.00001 arcsecond and magnitude limits of mv = 15 to 20 are achievable in a single orbit. In the imaging mode, SAMSI could synthesize images equivalent to those produced by equal diameter filled apertures in space, making use of the fuel resupply capability of a space station. Simulations indicate that image reconstruction can be performed with milliarcsecond resolution to a visual magnitude 12 in 12 hr of spiral scanning integration time.

Stachnik, R. V.↗