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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Electrodeposited Sn–Cu@Sn dendrites for selective electrochemical CO 2 reduction to formic acid

Large-scale CO 2 electrolysis can be applied to store renewable energy in chemicals. Recent developments in gas diffusion electrodes now enable a commercially relevant current density. However, the low selectivity of the CO 2 reduction reaction (CO 2 RR) still hinders practical applications. The selectivity of the CO 2 RR highly depends on the electrocatalyst. Sn catalysts are considered promising cathode materials for the production of formic acid. The selectivity of Sn catalysts can be regulated by controlling their morphology or alloying them with secondary metals. In this work, we enhanced the selectivity of CO 2 reduction to formic acid by synthesizing Sn–Cu@Sn dendrites that have a core@shell architecture. The Sn–Cu@Sn dendrites were prepared by a scalable electro-deposition method. The electronic structure was modified to suppress a reaction pathway for CO production on the Sn surface. Notably, the Sn shell inhibited the cathodic corrosion of Cu during the CO 2 RR. On a gas diffusion electrode, the Sn–Cu@Sn dendrites exhibited 84.2% faraday efficiency to formic acid for 120 h with high stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Search for supersymmetry in final states with a single electron or muon using angular correlations and heavy-object identification in proton-proton collisions at $ \sqrt{s} $ = 13 TeV

A search for supersymmetry is presented in events with a single charged lepton, electron or muon, and multiple hadronic jets. The data correspond to an integrated luminosity of 138 fb –1 of proton-proton collisions at a center-of-mass energy of 13 TeV, recorded by the CMS experiment at the CERN LHC. The search targets gluino pair production, where the gluinos decay into final states with the lightest supersymmetric particle (LSP) and either a top quark-antiquark ($\text{t}\bar{\text{t}}$ pair, or a light-flavor quark-antiquark ($\text{q}\bar{\text{q}}$ pair and a virtual or on-shell W boson. The main backgrounds, $\text{t}\bar{\text{t}}$ pair and W+jets production, are suppressed by requirements on the azimuthal angle between the momenta of the lepton and of its reconstructed parent W boson candidate, and by top quark and W boson identification based on a machine-learning technique. The number of observed events is consistent with the expectations from standard model processes. Limits are evaluated on supersymmetric particle masses in the context of two simplified models of gluino pair production. Exclusions for gluino masses reach up to 2120 (2050) GeV at 95% confidence level for a model with gluino decay to a $\text{t}\bar{\text{t}}$ pair (a $\text{q}\bar{\text{q}}$ pair and a W boson) and the LSP. For the same models, limits on the mass of the LSP reach up to 1250 (1070) GeV.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Evaluating Polymer Properties with Different Additives for Carbon Capture and Other Applications

Anthropogenic climate change is one of this generation’s most pressing concerns, with the potential to completely alter the delicate balance we’ve struck with nature. Already, global temperatures have risen 1.29°C, leading to disrupted weather systems, extinctions, increased risks of wildfires, and sea level rise, to name a few effects. Carbon dioxide emission from the combustion of fossil fuels and other industrial activity is a large driver of this phenomenon, as it absorbs heat before it can be radiated away from Earth, trapping it. Carbon dioxide has reached unprecedented levels in our atmosphere, showing a 50% increase from preindustrial averages to a whopping 430 ppm. Thus, reducing the amount of carbon dioxide via carbon capture technology is an important endeavor that serves to benefit everyone. The Microencapsulated CO 2 Sorbent (MECS) team at Lawrence Livermore National Laboratory (LLNL) has turned to microencapsulation to approach this endeavor. Microcapsules provide an attractive approach to carbon capture, combining large surface areas for more efficient mass transfer, regenerative abilities, reduced solvent loss, and improved handling. Additionally, while existing carbon capture technology relies on industrial plants, capsules could present a modular approach to carbon capture, reducing the need for extensive physical infrastructure. The MECS team’s design consists of a polymer membrane that contains a liquid carbon sequestering sorbent, aqueous sodium carbonate. The carbon capturing reaction occurs in three distinct steps, the first of which is the dissolution of carbon dioxide into the sorbent solution and its conversion into carbonic acid (H 2 CO 3 ), shown in equations 1 and 2 respectively. Because this step hinges upon the ability of carbon dioxide to reach the solution inside the capsule, it is necessary that the microcapsule shell is permeable to carbon dioxide gas. The MECS team produces these microcapsules using the in-air droplet encapsulation apparatus (IDEA) shown in figure 1, which can produce uniform micron-scale droplets at speeds much faster than traditional single-dispersal microfluidic-based techniques. The IDEA Is 100 times faster than these current techniques and can reach up to 1000 times their speed when incorporating a multi-nozzle design. Additionally, because droplets are produced in-air via vibration, IDEA can decrease post-processing times and material waste by 99% and can fabricate microgels that are 10 to 100 times more viscous than can be produced via traditional microfluidics. While this design represents a breakthrough in the throughput, efficiency, and tunability of microcapsule production, it imposes a major constraint on the microcapsule curing process. Because microcapsule shells are crosslinked with UV light while falling 30 cm through the air, this gives them a reaction window of approximately 0.2 seconds. Thus, the system and shell formulations must be optimized such that the shells can be fully crosslinked within this very narrow window, prompting investigations into curing behavior.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Effect of competition of spherical and deformed shells in quasifission of superheavy nuclei

Quasifission and fusion-fission represent the two most likely reaction outcomes to occur postcapture in collisions leading to superheavy nuclei. As such, understanding these mechanisms and how they relate to one another is key to understanding the intricate dynamics that drive the formation (or dissociation) of the nascent compound nuclei formed in fusion reactions. This understanding directly translates to a more informed picture of suitable reaction partners and can provide vital information for experimental efforts to study the physics and chemistry of superheavy elements. In this work we report results from time-dependent simulations of 48 Ca + 238 U and 50 Ti + 236 Th reactions at incident energies just above the Coulomb barrier with a focus on the quasifission process that prevent the formation of a fully equilibrated 286 Cn compound nucleus. We study these reactions systematically and consider a wide range of initial configurations to extract a robust estimate of primary fragment yields for the quasifission process. Multiple preferred exit channels are observed, with both spherical and deformed shell effects in the heavy and light fragments driving contributions to the production yields depending on the initial configuration of the system. Orientation effects of the deformed actinide targets are found to be a primary driver of which exit channels are populated. Here, the impact of moving away from a doubly magic projectile is explored with implications towards the reactions considered for current and future superheavy searches.

Gumbel, Richard [Michigan State University, East L↗
NASA NTRS1977

Charge-equilibrium and radiation of low-energy cosmic rays passing through interstellar medium

The charge equilibrium and radiation of an oxygen and an iron beam in the MeV per nucleon energy range, representing a typical beam of low-energy cosmic rays passing through the interstellar medium, is considered. Electron loss of the beam has been taken into account by means of the First Born approximation allowing for the target atom to remain unexcited, or to be excited to all possible states. Electron capture cross sections have been calculated by means of the scaled Oppenheimer-Brinkman-Kramers approximation, taking into account all atomic shells of the target atoms. Radiation of the beam due to electron capture into the excited states of the ion, collisional excitation and collisional inner-shell ionization of the ions has been considered. Effective X-ray production cross sections and multiplicities for the most energetic X-ray lines emitted by the Fe and O beams have been calculated.

Rule, D. W.↗
NASA NTRS1994

A software architecture for automating operations processes

The Operations Engineering Lab (OEL) at JPL has developed a software architecture based on an integrated toolkit approach for simplifying and automating mission operations tasks. The toolkit approach is based on building adaptable, reusable graphical tools that are integrated through a combination of libraries, scripts, and system-level user interface shells. The graphical interface shells are designed to integrate and visually guide a user through the complex steps in an operations process. They provide a user with an integrated system-level picture of an overall process, defining the required inputs and possible output through interactive on-screen graphics. The OEL has developed the software for building these process-oriented graphical user interface (GUI) shells. The OEL Shell development system (OEL Shell) is an extension of JPL's Widget Creation Library (WCL). The OEL Shell system can be used to easily build user interfaces for running complex processes, applications with extensive command-line interfaces, and tool-integration tasks. The interface shells display a logical process flow using arrows and box graphics. They also allow a user to select which output products are desired and which input sources are needed, eliminating the need to know which program and its associated command-line parameters must be executed in each case. The shells have also proved valuable for use as operations training tools because of the OEL Shell hypertext help environment. The OEL toolkit approach is guided by several principles, including the use of ASCII text file interfaces with a multimission format, Perl scripts for mission-specific adaptation code, and programs that include a simple command-line interface for batch mode processing. Projects can adapt the interface shells by simple changes to the resources configuration file. This approach has allowed the development of sophisticated, automated software systems that are easy, cheap, and fast to build. This paper will discuss our toolkit approach and the OEL Shell interface builder in the context of a real operations process example. The paper will discuss the design and implementation of a Ulysses toolkit for generating the mission sequence of events. The Sequence of Events Generation (SEG) system provides an adaptable multimission toolkit for producing a time-ordered listing and timeline display of spacecraft commands, state changes, and required ground activities.

Miller, Kevin J.↗
NASA NTRS2010

X-Ray Optics for the 2020's

X-ray optics is an essential and enabling technology for x-ray astronomy. This slide presentation presents the authors views on the requirements for x-ray optics as progress is made toward building IXO and preparing for the 2020's. The presentation reviews the status of several technologies that are being developed and outlines the steps that we as a community needs to take to move toward x-ray optics meeting the five key requirements: (1) high angular resolution, (2) large effective area, (3) low mass, (4) fast production, and (5) low cost. There is discussion of segmentation vs full shell, size of the mirror segment, mirror segment frabrication, post-slumping figure improvement, and characterization of coating quality.

Zhang, Will↗
DOE OSTI2025

Geothermal well testing pressure prediction by using a hybrid transformer model system: FORGE well use case

Geothermal has huge potential to become an indispensable component in achieving the goal of sustainable energy economy, given its capability to provide consistent baseload power to the electric grid. Injection tests are crucial in geothermal energy system as they naturally help to evaluate reservoir properties, understand fluid flow and even enhance reservoir performance. In this research, we developed a hybrid model system that integrates machine learning (ML) regression, a physics-based mathematical model, and transformer deep learning. Trained and validated using FORGE injection test dataset, this system can forecast the pressure variations both upward and downward over time. The pressure prediction achieved prediction accuracy within 3-6% variance of true pressure values. The system can significantly save time and reduce costs by testing only a few cycles and then using model predictions for further analysis, instead of conducting additional real injection cycle tests. The developed model system also holds promise for designing injection test processes and maintaining well production in geothermal energy. Presented at the IMAGE ‘25 Conference led by Shell.

FORGE↗
DOE OSTI2025

Discerning structure sensitivity of Ni-core Pd-shell nanoparticles for enhanced nitrite reduction

Denitrification using Pd-based catalysts converts N-oxyanions into harmless products. However, the metal cost and scarcity are barriers to application. In this work, we synthesize water-suspended, structure-controlled Ni-core/Pd-shell nanoparticles (Ni@Pd NPs) that show Pd-catalyzed nitrite (NO 2 − ) reduction catalysis promoted by Ni. The NPs immobilized on Al 2 O 3 (0.47 wt % Pd and 0.74 wt % Ni) have higher NH 4 + selectivity and higher catalytic activity than wet-impregnated Pd/Al 2 O 3 (1.0 wt % Pd), i.e., 315.4 vs. 132.1 Lg surface Pd −1 min −1 . X-ray photoelectron spectroscopy (XPS) and CO-diffuse reflectance infrared Fourier transform spectroscopy (CO-DRIFTS) analyses show that Ni increases Pd electron density, which is proposed to lower the bond dissociation energy barrier for nitric oxide surface intermediate. Low-coordinated Pd atoms correlate to high activity and low NH 4 + selectivity. Using CatCost software, we estimate Ni@Pd/Al 2 O 3 to have a ∼40% lower manufacturing cost compared to wet-impregnated Pd/Al 2 O 3 . This rationally designed catalyst illustrates how nickel promotes Pd catalysis and how Pd usage can be lowered for denitrification and other hydrogenation reactions.

CO-DRIFTS↗
DOE OSTI2023

First observation of 28 O

Subjecting a physical system to extreme conditions is one of the means often used to obtain a better understanding and deeper insight into its organization and structure. In the case of the atomic nucleus, one such approach is to investigate isotopes that have very different neutron-to-proton ($N/Z$) ratios than in stable nuclei. Light, neutron-rich isotopes exhibit the most asymmetric $N/Z$ ratios and those lying beyond the limits of binding, which undergo spontaneous neutron emission and exist only as very short-lived resonances (about 10 -21 s), provide the most stringent tests of modern nuclear-structure theories. Here we report on the first observation of 28 O and 27 O through their decay into 24 O and four and three neutrons, respectively. The 28 O nucleus is of particular interest as, with the $Z$ = 8 and $N$ = 20 magic numbers, it is expected in the standard shell-model picture of nuclear structure to be one of a relatively small number of so-called ‘doubly magic’ nuclei. Furthermore, both 27 O and 28 O were found to exist as narrow, low-lying resonances and their decay energies are compared here to the results of sophisticated theoretical modelling, including a large-scale shell-model calculation and a newly developed statistical approach. In both cases, the underlying nuclear interactions were derived from effective field theories of quantum chromodynamics. Finally, it is shown that the cross-section for the production of 28 O from a 29 F beam is consistent with it not exhibiting a closed $N$ = 20 shell structure.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2020

Infrared Photon Pair-Production in Ligand-Sensitized Lanthanide Nanocrystals

This report details spectroscopic characterizations of rare-earth, core-shell nanoparticles decorated with the f -element chelator 3,4,3-LI(1,2-HOPO). Evidence of photon downconversion is corroborated through detailed power dependence measurements, which suggest two-photon decay paths are active in these materials, albeit only representing a minority contribution of the sum luminescence, with emission being dominated by normal, Stokes' shifted fluorescence. Specifically, ultraviolet ligand photosensitization of Nd 3+ ions in a NaGdF 4 host shell results in energy transfer to a Nd 3+ /Yb 3+ -doped NaGdF 4 nanoparticle core. The population and subsequent decay of core, Yb 3+ 2 F 5/2 states result in a spectral shift of 620 nm, manifested in a NIR emission displaying luminescence profiles diagnostic of Yb 3+ and Nd 3+ excited state decays. Emphasis is placed on the generality of this material architecture for realizing ligand-pumped, multi-photon downconversion, with the Nd 3+ /Yb 3+ system presented here functioning as a working prototype for a design principle that may be readily extended to other lanthanide pairs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Nondestructive neutron imaging diagnosis of acidic gas reduction catalyst after 400-Hour operation in natural gas furnace

Residential natural gas furnaces are the primary space-heating devices in US homes, leading to substantial environmental impact caused by the acidic components in the furnace combustion gases. Here, to experimentally demonstrate acidic gas reduction in a furnace, a monolithic catalyst was fabricated and was called the AGR. A commercially-available condensing furnace was retrofitted with the AGR, and a 400-hour reliability and durability test was conducted. The results showed that the AGR significantly reduced acidic gases in the flue gas and produced condensate with neutral pH. Challenges were also revealed: inappropriate condensate drainage caused incomplete combustion and amorphous carbon deposits. To nondestructively survey the internal state of the AGR, neutron computed tomography (NCT) was employed to produce spatially resolved 2D and 3D representations of the 2-L, aged AGR component. The NCT results confirm the integrity of the AGR component, which consists of two blocks, without deformation or damage to AGR channels. The distribution of the particle accumulation in the middle of the top block was visibly heavier than the entrance and exit of the top block. The representative cross-section views revealed significant aggregation in the central region but not at the rim. The spatially resolved details provide in-depth diagnosis, evaluation, and understanding of the AGR. The insights can enable new AGR designs that realize a uniform and self-cleaning flow pattern, alleviate significant particle aggregation, and thus enhance AGR-enabled furnace performance. The neutron imaging method demonstrates the good potential that can diagnose faults and improve the design, optimization, and production processes of novel catalysts and other components or systems with heavy metal shell.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Physics-Driven Construction of Compact Primitive Gaussian Density Fitting Basis Sets

We present a model-assisted density fitting (MADF) basis set generator, an algorithm for generating primitive atomic Gaussian density fitting (DF) basis sets (DFBSs) from a contracted Gaussian orbital basis set (OBS). The MADF algorithm produces DFBSs suitable for accurate robust DF approximation of 2-particle interactions in mean-field and correlated electronic structures. The algorithm is designed to (a) saturate the OBS product space by a large regularized set of primitive solid-harmonic Gaussian shells with nonuniform distribution of exponents, followed by (b) pruning of the shells according to their contributions to the 2- body energy of a correlated atomic ensemble. Building the DFBS generator model almost exclusively on mathematical and physical principles allows one to limit the number of parameters that control the density fitting error to three, with a single set of parameters sufficient for computations with all basis cardinal numbers, with and without correlation of core electrons, with and without scalar and spin-dependent relativistic effects, spanning almost all of the Periodic Table. Performance assessment included basis sets up to quadruple-ζ quality from several major basis set families, using molecules composed of main-group, d-block, and f-block elements. The resulting DF errors in Hartree−Fock and second-order MP2 energies (with relativistic all-electron treatments, when appropriate) were on the order of 20 and 10 μE h per electron, respectively.

Approximation↗
NASA NTRS1951

Experimental Investigation of Air-Cooled Turbine Blades in Turbojet Engine. 7: Rotor-Blade Fabrication Procedures

An experimental investigation was conducted to determine the cooling effectiveness of a wide variety of air-cooled turbine-blade configurations. The blades, which were tested in the turbine of a - commercial turbojet engine that was modified for this investigation by replacing two of the original blades with air-cooled blades located diametrically opposite each other, are untwisted, have no aerodynamic taper, and have essentially the same external profile. The cooling-passage configuration is different for each blade, however. The fabrication procedures were varied and often unique. The blades were fabricated using methods most suitable for obtaining a small number of blades for use in the cooling investigations and therefore not all the fabrication procedures would be directly applicable to production processes, although some of the ideas and steps might be useful. Blade shells were obtained by both casting and forming. The cast shells were either welded to the blade base or cast integrally with the base. The formed shells were attached to the base by a brazing and two welding methods. Additional surface area was supplied in the coolant passages by the addition of fins or tubes that were S-brazed. to the shell. A number of blades with special leading- and trailing-edge designs that provided added cooling to these areas were fabricated. The cooling effectiveness and purposes of the various blade configurations are discussed briefly.

Long, Roger A.↗
NASA NTRS1994

Diamond turning in the production of x ray optics

A demonstration x-ray optic has been produced by diamond turning and replication techniques that could revolutionize the fabrication of advanced mirror assemblies. The prototype optic was developed as part of the Advanced X-ray Astrophysics Facility - Spectrographic project (AXAF-S). The initial part of the project was aimed at developing and testing the replica technique so that it could potentially be used for the production of the entire mirror array comprised of up to 50 individual mirror shells.

Fawcett, Steven C.↗
NASA NTRS1993

Software Products

MAST is a decision support system to help in the management of dairy herds. Data is collected on dairy herds around the country and processed at regional centers. One center is Cornell University, where Dr. Lawrence Jones and his team developed MAST. The system draws conclusions from the data and summarizes it graphically. CLIPS, which is embedded in MAST, gives the system the ability to make decisions without user interaction. With this technique, dairy managers can identify herd problems quickly, resulting in improved animal health and higher milk quality. CLIPS (C Language Integrated Production System) was developed by NASA's Johnson Space Center. It is a shell for developing expert systems designed to permit research, development and delivery on conventional computers.

Source record↗
DOE OSTI2025

Production of Radioactive 22 Na in Core-collapse Supernovae: The Ne-E(L) Component in Presolar Grains and Its Possible Consequences on Supernova Observations

Presolar graphite grains carry the isotopic signatures of their parent stars. A significant fraction of presolar graphites show isotopic abundance anomalies relative to solar for elements such as O, Si, Mg, and Ca, which are compatible with nucleosynthesis in core-collapse supernovae (CCSNe). Therefore, they must have condensed from CCSN ejecta before the formation of the Sun. Their most puzzling abundance signature is the 22 Ne-enriched component Ne-E(L), interpreted as the effect of the radioactive decay of 22 Na (T 1/2 = 2.6 yr). Previous works have shown that if H is ingested into the He shell and not fully destroyed before the explosion, the CCSN shock in the He-shell material produces large amounts of 22 Na. Here we focus on such CCSN models, showing a radioactive 26 Al production compatible with grain measurements, and analyze the conditions of 22Na nucleosynthesis. In these models, 22 Na is mostly made in the He shell, with a total ejected mass varying between 2.6 × 10 −3 M ⊙ and 1.9 × 10 −6 M ⊙ . We show that such 22 Na may already impact the CCSN light curve 500 days after the explosion, and at later stages it can be the main source powering the CCSN light curve for up to a few years before 44 Ti decay becomes dominant. Based on the CCSN yields above, the 1274.53 keV γ-ray flux due to 22 Na decay could be observable for years after the first CCSN light is detected, depending on the distance. This makes CCSNe possible sites to detect a 22 Na γ-ray signature consistently with the Ne-E(L) component found in presolar graphites. Finally, we discuss the potential contribution from 22 Na decay to the Galactic positron annihilation rate.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1993

The Iridium (tm) system: Personal communications anytime, anyplace

The Iridium system is designed to provide handheld personal communications between diverse locations around the world at any time and without prior knowledge of the location of the personal units. This paper provides an overview of the system, the services it provides, its operation, and an overview of the commercial practices and relatively high volume satellite production techniques which will make the system cost effective. A constellation of 66 satellites will provide an orbiting, spherical-shell, infrastructure for this global calling capability. The satellites act as tall cellular towers and allow convenient operation for portable handheld telephones. The system will provide a full range of services including voice, paging, data, geolocation, and fax capabilities. Motorola is a world leader in the production of high volume, high quality, reliable telecommunications hardware. One of Iridium's goals is to apply these production techniques to high reliability space hardware. Concurrent engineering, high performance work teams, advanced manufacturing technologies, and improved assembly and test methods are some of the techniques that will keep the Iridium system cost effective. Mobile, global, flexible personal communications are coming that will allow anyone to call or receive a call from/to anyplace at anytime. The Iridium system will provide communications where none exist today. This connectivity will allow increased information transfer, open new markets for various business endeavors, and in general increase productivity and development.

Hatlelid, John E.↗