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NASA NTRS1991

Emission from dust in visual reflection nebulae at infrared and submillimeter wavelengths

Far-IR and submillimeter images of five bright visual reflection nebulae, IC 446, NGC2247, NGC 2245, NGC 7023, and CED 201 are presented and used with composite IR spectra to derive parameters such as the fraction of nebulae emission attributed to molecule-sized grains, the range of nebulae grain albedos, gas densities, and gas cloud geometries. The results show that 30-45 percent of the nebulae emission lies at wavelengths of less than 30 microns. The variation in IR luminosity may be related to variations in nebulae gas density and less than optimal gas cloud geometries rather than to anomalous grain albedos. Relative extinction efficincies of roughly 1000-5000 are inferred for stellar photospheres with effective wavelengths of roughly 0.25-0.5 micron. The resultant mass-extinction coefficient is roughly 10-50 sq cm/g.

Casey, Sean C.↗

NASA NTRS1991

A model of the brightness of moonlight

In this paper, measurements of the sky brightness from the 2800-m level of Mauna Kea are reported. In addition, a model is presented for predicting the moonlight as a function of the moon's phase, the zenith distance of the moon, the zenith distance of the sky position, the angular separation of the moon and sky position, and the local extinction coefficient. The model equations can be quickly calculated on a pocket calculator. A comparison of the model with lunar data and with some Russian solar data shows the accuracy of the predictions to range from 8 percent to 23 percent.

Krisciunas, Kevin↗

NASA NTRS1992

Multiple scattering effects on spaceborne lidar

A semianalytic Monte Carlo code originally developed for oceanographic calculations (Poole et al., 1981) has been modified for use in studying multiple scattering of space-based lidar. The approach is very similar to that described by Kunkel and Weinman (1976). The trajectory of each photon is followed from the transmitter through multiple scattering until the photon is either scattered backward out of the atmosphere, scattered forward into the ground and absorbed, or scattered out the sides of the cloud. The probability that the photon will return directly to the detector is computed and summed over all significant scattering events within the field of view of the detector. Multiple scattering of the lidar pulse causes an apparent increase in the transmittance of the medium. Multiple scattering effects for space-based lidar are more significant than for ground-based lidar due to the much larger beam diameter in the atmosphere. These larger diameters are due not only to the greater range between the lidar and the scattering volume, but also the need to maintain relatively large beam divergences to satisfy eye safety restrictions on the laser irradiance at the Earth's surface. The simulations presented here are for a wavelength of 1064 nm and the Deirmendjian C1 phase function, which yields an extinction coefficient of 17.259/km. We have looked at two cases: a space-based lidar at 296 km observing a C1 cloud 293 km from the lidar and, for comparison purposes, a ground-based lidar looking at a C1 cloud with a base height of either 2 km or 5 km. The C1 size distribution roughly approximates that of stratocumulus or altocumulus clouds (aufm Kampe and Weickmann, 1957).

Winker, David M.↗

NASA NTRS1992

Time and polarization dependent double scattering calculations of lidar returns from water clouds

We describe and present results of a double scattering lidar model which we use to calculate lidar returns from water clouds. The model is used in conjunction with the Phillips Laboratory's (Geophysics Directorate) low altitude Nd:YAG lidar system to determine microphysical properties of water clouds. The model determines the Stokes parameters of the backscattered lidar radiation, from media composed of spherical particles, as a function of time. The Stokes parameters of the radiation of the lidar return are determined, at each time, by considering all radiation which has traveled the same path length from transmitter to receiver while making two successive single scatters. Each single scatter is considered a Mie scatter. We have also developed a Mie scattering program for use with the double scattering model. Each single scatter takes into account the polarization of the incident and scattered radiation. Inputs to the double scattering mode include the receiver area and field of view, the receiver integration time, the extinction coefficient as a function of distance into the cloud, the particle size distribution (assumed independent of position), and the complex index of refraction of the spherical particles.

Garner, R. C.↗

NASA NTRS1992

Biomass Burning Airborne and Spaceborne Experiment in the Amazonas (BASE-A)

Results are presented on measurements of the trace gas and particulate matter emissions due to biomass burning during deforestation and grassland fires in South America, conducted as part of the Biomass Burning Airborne and Spaceborne Experiment in the Amazonas in September 1989. Field observations by an instrumented aircraft were used to estimate concentrations of O3, CO2, CO, CH4, and particulate matter. Fires were observed from satellite imagery, and the smoke optical thickness, particle size, and profiles of the extinction coefficient were measured from the aircraft and from the ground. Four smoke plumes were sampled, three vertical profiles were measured, and extensive ground measurements of smoke optical characteristics were carried out for different smoke types. The simultaneous measurements of the trace gases, smoke particles, and the distribution of fires were used to correlate biomass burning with the elevated levels of ozone.

Kaufman, Y. J.↗

NASA NTRS1993

Low cloud investigations for project FIRE: Island studies of cloud properties, surface radiation, and boundary layer dynamics. A simulation of the reflectivity over a stratocumulus cloud deck by the Monte Carlo method

The radiation field over a broken stratocumulus cloud deck is simulated by the Monte Carlo method. We conducted four experiments to investigate the main factor for the observed shortwave reflectively over the FIRE flight 2 leg 5, in which reflectivity decreases almost linearly from the cloud center to cloud edge while the cloud top height and the brightness temperature remain almost constant through out the clouds. From our results, the geometry effect, however, did not contribute significantly to what has been observed. We found that the variation of the volume extinction coefficient as a function of its relative position in the cloud affects the reflectivity efficiently. Additional check of the brightness temperature of each experiment also confirms this conclusion. The cloud microphysical data showed some interesting features. We found that the cloud droplet spectrum is nearly log-normal distributed when the clouds were solid. However, whether the shift of cloud droplet spectrum toward the larger end is not certain. The decrease of number density from cloud center to cloud edges seems to have more significant effects on the optical properties.

Ackerman, Thomas P.↗

NASA NTRS1993

Optical properties and spectral emissivities at 632.8 nm in the titanium-aluminum system

Optical properties (including spectral emissivity, refractive index, and extinction coefficient) of liquid Ti-Al alloys were measured as functions of temperature (including temperatures up to 350 K below the equilibrium liquidus temperatures), using laser ellipsometry at 632.8 nm. The experiments were conducted under containerless conditions, using electromagnetic levitation and heating supplemented by CO2 laser beam heating. It is shown that the emissivities of liquid Ti-Al alloy vary with temperature in a manner that can be understood by the same theories which are applicable to solid metals, for regions near to and above the liquidus temperature. At temperatures below the liquidus temperature, the optical properties of highly undercooled liquid Ti-Al alloys are not dependent on temperature.

Krishnan, S.↗

NASA NTRS1992

A comparison of cirrus clouds determined by ISCCP and SAGE-II and their relation to convection in the tropics

Results of tropical thin cirrus cloud retrievals using International Satellite Cloud Climatology Project (ISCCP) and Stratospheric Aerosol and Gaseous Experiment (SAGE-II) data from January 1985 are presented. A preliminary analysis of the results shows that thin cirrus increases with increasing height in both data sets, and SAGE-II exhibits a high frequency of occurrence. The thin cirrus extinction coefficient shows maxima around the convective regions of South America and the western Pacific Ocean.

Christopher, Sundar A.↗

NASA NTRS1991

High-reflective multilayers as narrowband VUV filters

A novel coating has been developed for the 120-230 nm wavelength VUV region which yields significantly higher reflectivity over selectable bandwidths and can be used to fabricate high-performance narrowband reflection filters; the spectral properties of such filters are greatly enhanced through their use in tandem. The coating uses a combination of high and low refractive index dielectric pairs. The proper choice of high-low ratio reduces the effects of VUV absorption for high refractive index films whose extinction coefficient is much higher than for a low-index material.

Zukic, Muamer↗

NASA NTRS1993

Calculation of the angular radiance distribution for a coupled atmosphere and canopy

The radiative transfer equations for a coupled atmosphere and canopy are solved numerically by an improved Gauss-Seidel iteration algorithm. The radiation field is decomposed into three components: unscattered sunlight, single scattering, and multiple scattering radiance for which the corresponding equations and boundary conditions are set up and their analytical or iterational solutions are explicitly derived. The classic Gauss-Seidel algorithm has been widely applied in atmospheric research. This is its first application for calculating the multiple scattering radiance of a coupled atmosphere and canopy. This algorithm enables us to obtain the internal radiation field as well as radiances at boundaries. Any form of bidirectional reflectance distribution function (BRDF) as a boundary condition can be easily incorporated into the iteration procedure. The hotspot effect of the canopy is accommodated by means of the modification of the extinction coefficients of upward single scattering radiation and unscattered sunlight using the formulation of Nilson and Kuusk. To reduce the computation for the case of large optical thickness, an improved iteration formula is derived to speed convergence. The upwelling radiances have been evaluated for different atmospheric conditions, leaf area index (LAI), leaf angle distribution (LAD), leaf size and so on. The formulation presented in this paper is also well suited to analyze the relative magnitude of multiple scattering radiance and single scattering radiance in both the visible and near infrared regions.

Liang, Shunlin↗

NASA NTRS1993

VUV thin films, chapter 7

The application of thin film technology to the vacuum ultraviolet (VUV) wavelength region from 120 nm to 230 nm has not been fully exploited in the past because of absorption effects which complicate the accurate determination of the optical functions of dielectric materials. The problem therefore reduces to that of determining the real and imaginary parts of a complex optical function, namely the frequency dependent refractive index n and extinction coefficient k. We discuss techniques for the inverse retrieval of n and k for dielectric materials at VUV wavelengths from measurements of their reflectance and transmittance. Suitable substrate and film materials are identified for application in the VUV. Such applications include coatings for the fabrication of narrow and broadband filters and beamsplitters. The availability of such devices open the VUV regime to high resolution photometry, interferometry and polarimetry both for space based and laboratory applications. This chapter deals with the optics of absorbing multilayers, the determination of the optical functions for several useful materials, and the design of VUV multilayer stacks as applied to the design of narrow and broadband reflection and transmission filters and beamsplitters. Experimental techniques are discussed briefly, and several examples of the optical functions derived for selected materials are presented.

Zukic, Muamer↗

NASA NTRS1993

Optical properties and emissivities of liquid metals and alloys

This paper presents the results from our on-going program to investigate the optical properties of liquid metals and alloys at elevated temperatures. Ellipsometric and polarimetric techniques have been used to investigate the optical properties of materials in the 1000 - 3000 K temperature range and in the 0.3 - 0.1 mu m wavelength range. The ellipsometric and polarimetric techniques are described and the characteristics of the instruments are presented. The measurements are conducted by reflecting a polarized laser beam from an electromagnetically levitated liquid metal or alloy specimen. A Rotating Analyzer Ellipsometer (RAE) or a four-detector Division-of-Amplitude Photopolarimeter (DOAP) is used to determine the polarimetric properties of the light reflected at an angle of incidence of approximately 68 deg. Optical properties of the specimen which are calculated from these measurements include the index of refraction, extinction coefficient, normal spectral emissivity, and spectral hemispherical emissivity. These properties have been determined at various wavelengths and temperatures for liquid Ag, Al, Au, Cu, Nb, Ni, Pd, Pt, Si, Ti, Ti-Al alloys, U, and Zr. We also describe new experiments using pulsed-dye laser spectroscopic ellipsometry for studies of the wavelength dependence of the emissivities and optical properties of materials at high temperature. Preliminary results are given for liquid Al. The application of four-detector polarimetry for rapid determination of surface emissivity and true temperature is also described. Characteristics of these devices are presented. An example of the accuracy of this instrument in measurements of the melting point of zirconium is illustrated.

Krishnan, Shankar↗

NASA NTRS1994

Emittance Theory for Thin Film Selective Emitter

Thin films of high temperature garnet materials such as yttrium aluminum garnet (YAG) doped with rare earths are currently being investigated as selective emitters. This paper presents a radiative transfer analysis of the thin film emitter. From this analysis the emitter efficiency and power density are calculated. Results based on measured extinction coefficients for erbium-YAG and holmium-YAG are presented. These results indicated that emitter efficiencies of 50 percent and power densities of several watts/sq cm are attainable at moderate temperatures (less than 1750 K).

Chubb, Donald L.↗

NASA NTRS1994

Rare earth garnet selective emitter

Thin film Ho-YAG and Er-YAG emitters with a platinum substrate exhibit high spectral emittance in the emission band (epsilon(sub lambda) approximately equal to 0.74, ((4)l(sub 15/2)) - ( (4)l(sub13/2)), for Er-YAG and epsilon(sub lambda) approximately equal to 0.65, ((5)l(sub 7))-((5)l(sub 8)) for Ho-YAG) at excellent candidates for high efficiency selective emitters in the thermophotovoltaics (TPV) systems operating at moderate temperatures (1200-1500K). Spectral emittance measurements of the thin films were made (1.2 less than lambda less than 3.0 microns) and compared to the theoretical emittances calculated using measured values of the spectral extinction coefficient. In this paper we present the results for a new class of rare earth ion selective emitters. These emitters are thin sections (less than 1 mm) of yttrium aluminum garnet (YAG) single crystal with a rare earth substitutional impurity. This paper presents normal spectral emittance, epsilon(sub lambda), measurements of holmium (Ho), and erbium (Er) doped YAG thin film selective emitters at 1500 K, and compares those results with the theoretical spectral emittance.

Lowe, Roland A.↗

NASA NTRS1994

The Global Oscillation Network Group site survey, 2: Results

The Global Oscillation Network Group (GONG) Project will place a network of instruments around the world to observe solar oscillations as continuously as possible for three years. The Project has now chosen the six network sites based on analysis of survey data from fifteen sites around the world. The chosen sites are: Big Bear Solar Observatory, California; Mauna Loa Solar Observatory, Hawaii; Learmonth Solar Observatory, Australia; Udaipur Solar Observatory, India; Observatorio del Teide, Tenerife; and Cerro Tololo Interamerican Observatory, Chile. Total solar intensity at each site yields information on local cloud cover, extinction coefficient, and transparency fluctuations. In addition, the performance of 192 reasonable networks assembled from the individual site records is compared using a statistical principal components analysis. An accompanying paper descibes the analysis methods in detail; here we present the results of both the network and individual site analyses. The selected network has a duty cycle of 93.3%, in good agreement with numerical simulations. The power spectrum of the network observing window shows a first diurnal sidelobe height of 3 x 10(exp -4) with respect to the central component, an improvement of a factor of 1300 over a single site. The background level of the network spectrum is lower by a factor of 50 compared to a single-site spectrum.

Hill, Frank↗

NASA NTRS1994

Observations of lower-stratospheric ClONO2, HNO3, and aerosol by the UARS CLAES experiment between January 1992 and April 1993

This paper discusses simultaneous measurements of stratospheric ClONO2, HNO3, temperature, and aerosol extinction coefficient by the Cryogenic Limb Array Etalon Spectrometer (CLAES) on the NASA Upper Atmosphere Research Satellite (UARS), obtained over the period 9 January 1992 through 23 April 1993. The discussion concentrates on the stratosphere region near 21 km of particular interest to heterogeneously driven ozone depletion. For periods between 12 June and 1 September 1992 at latitudes poleward of about 60 deg S, when temperatures were below type I polar stratospheric cloud (PSC) formation thresholds throughout the lower stratosphere, CLAES observed high levels of PSCs coincident with highly depleted fields of both HNO3 and ClONO2. By 17 September, the incidence of PSCs had greatly diminished in the lower stratosphere, but both CLONO2 and HNO3 remained highly depleted. These observations are consistent with the removal of gaseous HNO3 through the formation of nitric acid trihydrate (NAT) particles and the removal of ClONO2 through heterogeneous reactions on the particle surfaces. They also suggest substantial denitrification of the lower Antarctic vortex through sedimentation of PSC particles. In the Northern Hemisphere winter of 1992/93 far fewer PSCs were observed in the Arctic lower-stratosphere vortex, which had shorter periods and more localized regions of cold temperatures. Both HNO3 and ClONO2 maintained much higher levels inside the Arctic vortex than seen in the Antarctic throughout the winter/spring period. Following 28 February 1993 when Arctic vortex temperatures rose above 195 K, ClONO2 was observed in large quantities (greater than 2.1 ppbv near 21 km) inside the vortex. The persistence of relatively high levels of HNO3 inside the Arctic spring vortex compared with the low levels seen in the Antarctic spring vortex suggest a much lower level of denitrification in the Arctic.

Roche, A. E.↗

NASA NTRS1995

Comparison between SAGE II and ISCCP high-level clouds. 1: Global and zonal mean cloud amounts

Global high-level clouds identified in Stratospheric Aerosol and Gas Experiment II (SAGE II) occultation measurements for January and July in the period 1985 to 1990 are compared with near-nadir-looking observations from the International Satellite Cloud Climatology Project (ISCCP). Global and zonal mean high-level cloud amounts from the two data sets agree very well, if clouds with layer extinction coefficients of less than 0.008/km at 1.02 micrometers wavelength are removed from the SAGE II results and all detected clouds are interpreted to have an average horizontal size of about 75 km along the 200 km transimission path length of the SAGE II observations. The SAGE II results are much more sensitive to variations of assumed cloud size than to variations of detection threshold. The geographical distribution of cloud fractions shows good agreement, but systematic regional differences also indicate that the average cloud size varies somewhat among different climate regimes. The more sensitive SAGE II results show that about one third of all high-level clouds are missed by ISCCP but that these clouds have very low optical thicknesses (less than 0.1 at 0.6 micrometers wavelength). SAGE II sampling error in monthly zonal cloud fraction is shown to produce no bias, to be less than the intraseasonal natural variability, but to be comparable with the natural variability at longer time scales.

Liao, Xiaohan↗

NASA NTRS1994

Indices of refraction for the HITRAN compilation

Indices of refraction of sulfuric acid solutions, water, and ice, which will become part of the HITRAN database, are discussed. Representative calculations are presented for the sulfate aerosol, to illustrate the broadband spectral features of i.r. aerosol extinction spectra. Values of the sulfuric acid mass density are used in an application of the Lorentz-Lorenz equation, which is used to estimate the sensitivity of extinction coefficients to temperature dependent refractive indices.

Massie, S. T.↗