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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Multi-scale nonlinear stress analysis of Nb 3 Sn superconducting accelerator magnets

A multi-scale nonlinear procedure to analyze the stress in Nb 3 Sn superconducting accelerator magnets is presented to address one of the most challenging obstacles currently facing the successful development of high-field superconducting magnets—the issue of stress management. The study demonstrates that gaskets (special nonlinear materials) are capable of modeling the complex nonlinear deformation behavior of insulation layers within the Nb 3 Sn coil block and that Hill materials (orthotropic materials utilizing the Hill yield criterion) are suitable to enable homogenization of the filamentary regions and the resin-impregnated Nb 3 Sn Rutherford cables. With the whole magnet under preload, cool-down, and Lorentz forces, the nonlinear behavior of the Nb 3 Sn coil was simulated, in three orthongonal axes, by the combined properties of the gaskets (insulation layers) and Hill materials (resin-impreganted cable). The procedure entailes minimal material assumptions because it incorporated measured stress-strain curves in the analysis. The coil was simulated to a high level of detail consisting of the insulation layers and resin-impregnated cables. The computed compressive azimuthal stresses of the cables were used to assess the stress-induced performance degradation. Through submodeling, the area-weighted average axial strains of the strands were computed and employed to evaluate the strain-induced performance degradation. The overall performance degradation of the Nb 3 Sn coil was thus obtained, and this information was subsequently used to guide the design of the overall magnet. Besides Nb 3 Sn magnets, this procedure can also be employed in the design of LTS, HTS, and room temperature magnets or in any composite structures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Volumetrically Absorbing Thermal Insulator (VATI) for High-temperature Receivers

This project seeks to exploit volumetric absorption of concentrated solar irradiation in a thin, high-temperature, thermally conductive medium. High efficiency thermal conversion is achieved by volumetric absorption of both incoming solar irradiation (short wavelength) and emitted irradiation (long wavelength), demonstrating a volumetrically absorbing thermally insulating (VATI) effect. The thermalized energy is conducted to the back wall, enclosing the working fluid (molten salt or supercritical CO 2 ). Reliance on conductive thermal transport requires a thermally conductive medium, in the absence of which large temperature gradients drive losses due to emission. The project’s outcomes are important to realize a cost-effective approach to reduce optical and thermal losses from CSP receivers at high temperatures (720°C). High-temperature stable and commercially available porous SiC structures (open-cell foams) were explored as a volumetrically absorbing and thermally insulating layer. To the best of our knowledge, the current state-of-the-art for industrially deployed coatings is Pyromark. However, Pyromark suffers degradation at 700+°C and diurnal temperature changes. This necessitates periodic recoating, and the downtime increases the overall levelized cost of energy (LCOE) production. On the other hand, contemporary research activities have generated significant advances in the development of selective emitter coatings, which present challenges with costs, scalability, and stability. The pursued approach alleviates these concerns by developing a receiver that utilizes the inherent structure of high-temperature stable porous materials to enable robust and cost-effective receivers which require no periodic maintenance downtimes. The overall goal of the project is to experimentally demonstrate a figure of merit (FOM) of 0.92 at a temperature of 720°C and solar irradiation of 1000x concentration with porous receivers. The relevant crystallographic (phase) optical and thermal properties of porous SiC were first characterized. Second, the 3-D geometry of the porous SiC was analyzed using micro-X-ray tomography and converted to CAD data using image processing analysis. Utilizing this 3-D geometry and relevant optical/thermal properties, Monte Carlo- Ray Tracing (MCRT) analysis was performed to extract important parameters governing solar-thermal energy conversion such as extinction coefficient (β, 1/m), scattering albedo (ω) and the scattering phase function (Φ). These properties were then integrated into an in-house radiative and conduction transport model to solve for temperature and transport fluxes characterizing the solar-thermal energy conversion. This model was utilized to predict the FOM for various SiC porous geometries and to identify the highest possible FOM. Testing of the optimized porous structures will be accomplished with a custom-built high-accuracy (< ±4%) FOM measurement test-stand and a 1000x solar concentrator. When neglecting convective losses and resistance at the open boundary and the back wall, the optimized SiC foam leads to a FOM of 0.84. This FOM does not surpass the performance of Pyromark 2500. Yet, conversely to Pyromark 2500, SiC is stable at high temperatures and does not degrade over time. Also, it is possible to boost the FOM of SiC by engineering its effective thermal conductivity and its scattering albedo. A FOM of 0.92 is predicted for an optimized foam by accounting for convective losses and resistance at the open boundary and the back wall. This largely exceeds the FOM of Pyromark 2500 (~0.86) predicted by neglecting convective losses and resistance. Therefore, further engineering of the foam could lead to unprecedented FOMs.

14 SOLAR ENERGY↗
NASA NTRS1998

Evaluation and Selection of Replacement Thermal Control Materials for the Hubble Space Telescope

The mechanical and optical properties of the metallized Teflon(Registered Trademark) FEP thermal control materials on the Hubble Space Telescope (HST) have degraded over the nearly seven years the telescope has been in orbit. Given the damage to the outer layer of the multi-layer insulation (MLI) that was apparent during the second servicing mission (SM2), the decision was made to replace the outer layer during subsequent servicing missions. A Failure Review Board was established to investigate the damage to the MLI and identify a replacement material. The replacement material had to meet the stringent thermal requirements of the spacecraft and maintain structural integrity for at least ten years. Ten candidate materials were selected and exposed to ten-year HST-equivalent doses of simulated orbital environments. Samples of the candidates were exposed sequentially to low and high energy electrons and protons, atomic oxygen, x-ray radiation, ultraviolet radiation and thermal cycling. Following the exposures, the mechanical integrity and optical properties of the candidates were investigated using Optical Microscopy, Scanning Electron Microscopy (SEM), and a Laboratory Portable Spectroreflectometer (LPSR). Based on the results of these simulations and analyses, the FRB selected a replacement material and two alternates that showed the highest likelihood of providing the requisite thermal properties and surviving for ten years in orbit.q

Townsend, Jacqueline A.↗
NASA NTRS1998

Ground-Based Testing of Replacement Thermal Control Materials for the Hubble Space Telescope

The mechanical and optical properties of the metallized Teflon FEP thermal control materials on the Hubble Space Telescope (HST) have degraded over the nearly seven years the telescope has been in orbit. Given the damage to the outer layer of the multi-layer insulation (MLI) that was apparent during the second servicing mission (SM2), the decision was made to replace the outer layer during subsequent servicing missions. A Failure Review Board was established to investigate the damage to the MLI and identify a replacement material. The replacement material had to meet the stringent thermal requirements of the spacecraft and maintain mechanical integrity for at least ten years. Ten candidate materials were selected and exposed to ten-year HST-equivalent doses of simulated orbital environments. Samples of the candidates were exposed sequentially to low and high energy electrons and protons, atomic oxygen, x-ray radiation, ultraviolet radiation and thermal cycling. Following the exposures, the mechanical integrity and optical properties of the candidates were investigated using Optical Microscopy, Scanning Electron Microscopy (SEM), a Laboratory Portable Spectroreflectometer (LPSR) and a Lambda 9 Spectroreflectometer. Based on the results of these simulations and analyses, the Failure Review Board selected a replacement material and two alternates that showed the highest likelihood of providing the requisite thermal properties and surviving for ten years in orbit.

Townsend, Jacqueline A.↗
NASA NTRS2011

Sustainably Sourced, Thermally Resistant, Radiation Hard Biopolymer

This material represents a breakthrough in the production, manufacturing, and application of thermal protection system (TPS) materials and radiation shielding, as this represents the first effort to develop a non-metallic, non-ceramic, biomaterial-based, sustainable TPS with the capability to also act as radiation shielding. Until now, the standing philosophy for radiation shielding involved carrying the shielding at liftoff or utilizing onboard water sources. This shielding material could be grown onboard and applied as needed prior to different radiation landscapes (commonly seen during missions involving gravitational assists). The material is a bioplastic material. Bioplastics are any combination of a biopolymer and a plasticizer. In this case, the biopolymer is a starch-based material and a commonly accessible plasticizer. Starch molecules are composed of two major polymers: amylase and amylopectin. The biopolymer phenolic compounds are common to the ablative thermal protection system family of materials. With similar constituents come similar chemical ablation processes, with the potential to have comparable, if not better, ablation characteristics. It can also be used as a flame-resistant barrier for commercial applications in buildings, homes, cars, and heater firewall material. The biopolymer is observed to undergo chemical transformations (oxidative and structural degradation) at radiation doses that are 1,000 times the maximum dose of an unmanned mission (10-25 Mrad), indicating that it would be a viable candidate for robust radiation shielding. As a comparison, the total integrated radiation dose for a three-year manned mission to Mars is 0.1 krad, far below the radiation limit at which starch molecules degrade. For electron radiation, the biopolymer starches show minimal deterioration when exposed to energies greater than 180 keV. This flame-resistant, thermal-insulating material is non-hazardous and may be sustainably sourced. It poses no hazardous waste threats during its lifecycle. The material composition is radiation-tolerant up to megarad doses, indicating its use as a radiation shielding material. It is lightweight, non-metallic, and able to be mechanically densified, permitting a tunable gradient of thermal and radiation protection as needed. The dual-use (thermal and radiation shielding), sustainable nature of this material makes it suitable for both industrial applications as a sustainable/green building material, and for space applications as thermal protection material and radiation shield.

Pugel, Diane↗
DOE OSTI2020

Fiberboard Properties and Degradation Rates for Storage of 9975 Shipping Package in KAC (2020 Status Report)

Savannah River Site (SRS) stores plutonium materials within model 9975 shipping packages in the K-Area Complex (KAC). The 9975 shipping package consists of a 35 gallon stainless steel drum, Celotex fiberboard insulation, lead shield, and primary and secondary containment vessels. The 9975 shipping package design, performance, and analysis for safe transport of radioactive material are described in the Safety Analysis Report for Packaging (SARP). Celotex fiberboard provides three safety functions: thermal insulation to limit internal temperature during a fire, criticality control, and resistance to package crushing. The fiberboard material must retain its dimensions and density within certain ranges to provide the required impact resistance, criticality control, and fire resistance. The SRS Surveillance Program monitors material performance to establish a basis for service life and ensures the continued integrity of 9975 packages. Fiberboard samples, taken from multiple fiberboard assemblies fabricated from cane and softwood fiberboard, have been conditioning in elevated temperature environments since 2005. The samples are periodically examined to monitor thermal, mechanical, and physical properties, and assess degradation trends. Fiberboard properties of interest that are evaluated to demonstrate acceptable long-term performance include dimensional stability, density, compressive strength, thermal conductivity, and specific heat capacity. Duplicate samples from multiple package sources have been tested to identify the range of variability in fiberboard properties and degradation rates. Baseline and long-term testing of fiberboard material properties have been reported previously; reference 6 summarized experimental results of cane and softwood fiberboard through May 2019 and presented degradation models for the measured properties. This report presents the cumulative data collected through June 2020 and the corresponding updated aging models.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1975

EV space suit gloves (passive)

A pair of pressure and thermal insulating overgloves to be used with an Extravehicular (EV) suit assembly was designed, developed, fabricated, and tested. The design features extensive use of Nomex felt materials in lieu of the multiple layer insulation formerly used with the Apollo thermal glove. The glove theoretically satisfies all of the thermal requirements. The presence of the thermal glove does not degrade pressure glove tactility by more than the acceptable 10% value. On the other hand, the thermal glove generally degrades pressure glove mobility by more than the acceptable 10% value, primarily in the area of the fingers. Life cycling tests were completed with minimal problems. The thermal glove/pressure glove ensemble was also tested for comfort; the test subjects found no problems with the thermal glove although they did report difficulties with pressure points on the pressure glove which were independent of the thermal glove.

Fletcher, E. G.↗
NASA NTRS2002

X-38 De-orbit Propulsion Stage MLI Performance Test

This paper presents a performance test of the X-38 Deorbit Propulsion Stage (DPS) Multi-Layer Insulation (MLI) system. The purpose of this test is to determine if MLI performance meets or exceeds thermal analyses requirements and if there is performance degradation due to seams.

Kittredge, Ken↗
NASA NTRSDate not supplied

Evaluation of Contact Separation Force Testing as a Screening Methodology for Electrical Socket Contacts

During system level testing intermittent and permanent open circuit failures of mated, crimp removable, electrical contact pairs were experienced. The root cause of the failures was determined to be low (but not zero) contact forces applied by the socket contact tines against the engaging pin. The low contact force reduces the effectiveness of the wiping action of the socket tines against the pin. The observed failure mode may be produced when insufficient wiping during mate, demate and small relative movement in use allows for the accumulation of debris or insulating films that electrically separate the contact pair. The investigation identified at least three manufacturing process control problems associated with the socket contacts that enabled shipment of contacts susceptible to developing low contact forces: (1) Improper heat treatment of the socket tines resulting in plastic rather than elastic behavior; (2) Overly thinned socket tines at their base resulting in reduced pin retention forces; (3) Insufficient screening tests to identify parts susceptible to the aforementioned failure mechanisms. The results from an extensive screening program of socket contacts utilizing the industry standard contact separation force test procedures are described herein. The investigation shows this method to be capable of identifying initially weak sockets. However, sockets whose contact retention forces may degrade during use may not be screened out by pin retention testing alone. Further investigations are required to correlate low contact retention forces with increased electrical contact resistance in the presence of insulating films that may accumulate in the use environment.

Christopher Green↗
DOE OSTI2025

Demonstration and characterization of insertable passive thermal switches for dynamic building envelopes

A dynamic building envelope integrated with thermal energy storage, such as phase change material (PCM), is an emerging technology that offers a promising solution to improve the energy efficiency of buildings. This study reports the development of insertable thermal switches, which modulate thermal resistance, thereby making building envelopes dynamic and enhancing the use of free ambient heating and cooling. The reported thermal switches are passive, meaning they work solely based on indoor and outdoor temperatures. A single switch when inserted into 10 × 10-in (0.064-m 2 ) XPS foam board insulation demonstrates effective thermal conductivity of 0.050 W/m-K in the resistive state and 0.285 W/m-K in the conductive state. Thermal switches exhibit an effective switching ratio of 5.7, with no noticeable degradation in performance over 770 cycles. Additionally, when integrated into a wall sample containing a PCM layer, switches significantly reduce the PCM solidification time by 43.2% during the cooling process.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1990

Segmented Coil Fails In Steps

Electromagnetic coil degrades in steps when faults occur, continues to operate at reduced level instead of failing catastrophically. Made in segments connected in series and separated by electrically insulating barriers. Fault does not damage adjacent components or create hazard. Used to control valves in such critical applications as cooling systems of power generators and chemical process equipment, where flammable liquids or gases handled. Also adapts to electrical control of motors.

Stedman, Ronald S.↗
NASA NTRS2019

Sublimation Protection Coatings for Thermoelectric Materials for Space Power Applications

The compounds such as Yb14MnSb11 are relatively new p-type thermoelectric materials, respectively. NASA's interest in these material are to replace the state-of-the-art Si-Ge legs of the current radioisotope thermoelectric generators (RTGs). Ideally, the hot end of this leg would operate at 1000 degrees C in the vacuum of space. These materials, however, suffer from a high sublimation rate at elevated temperatures and would require a coating in order to survive the required RTG lifetime of 14 years. The purpose of present work is to develop sublimation protection coatings for Yb14MnSb11 at temperatures up to 1000 degrees C. Coatings for Yb14MnSb11 present many challenges. The coating must not significantly react or interdiffuse with the substrate thereby degrading the substrate or consuming the coating, must remain intact and not crack or spall during thermal cycling prior to launch, and must be a good insulator both electrically and thermally so as not to provide a short circuit for either electron flow or heat through the coating rather than through the leg. Based on these requirements, several oxides have been selected as possible coating candidates. This paper discusses the development of slurry processes to deposit these oxides coatings on thermoelectric materials.

Sublimation↗
DOE OSTI2023

Thermal energy storage in concrete utilizing a thermosiphon heat exchanger

The performance of a lab-scale concrete thermal energy storage (TES) module with a 2-kWh thermal capacity is evaluated at temperatures up to 400 °C. The TES module uses conventional normal weight concrete with thermal and mechanical properties that are tailored for use as a solid thermal energy storage media. A thermosiphon heat exchanger is used to provide rapid heat transfer into the concrete module, which is reinforced with a steel pipe outer shell. The charging and discharging cycles are examined to assess the thermal performance of the concrete and thermosiphon. Based on the results of testing, the thermosiphon is able to repeatably charge the concrete module from 300 to 400 °C over a 4-h period. After 2250 total hours of charge and discharge cycles, there was no observed delamination between the concrete and the thermosiphon or the steel jacket reinforcement. Non-destructive measurements of the concrete indicated no significant degradation of the solid storage media. The experimental results are then used to validate a numerical model of the concrete TES module for parametric study. Finally, varying insulation conditions were analyzed using this model to determine practical configurations for regular operation of the proposed concrete TES module.

25 ENERGY STORAGE↗
DOE OSTI2026

Fluorinated Glyme Solvents to Extend Lithium-Sulfur Battery Life (Final Technical Report, Unlimited)

This project investigated a number of partially fluorinated glymes (PFGs) as electrolyte cosolvents to improve the performance of lithium-sulfur (Li-S) batteries. A major issue in Li-S cells is the electrochemical reaction of sulfur in the cathode to form lithium polysulfides (LPS) that dissolve in the electrolyte. Those LPS are electrochemically and chemically reactive at the lithium anode, resulting in lithium sulfide deposition on the anode and also electrochemical reaction at both the anode and cathode, leading to a “polysulfide shuttle” and reduced coulombic efficiency (CE) and self-discharge of the cell. PFGs reduce the solubility of LPS while maintaining good solubility of lithium salts such as LiTFSI. By adjusting the amount of PFG as cosolvent in the electrolyte, we showed that the solubility of LPS in the electrolyte can be tuned. (It is not desirable to completely eliminate LPS in the electrolyte, as they facilitate electrochemical reaction of the electrically insulating S 8 and Li 2 S within the cathode by shuttling charge between them and the conductive carbon.) Another issue in Li-S cells is degradation of the Li anode over many cycles of stripping (discharge) and plating (charge). We showed that PFGs have a beneficial effect on the physical morphology of the Li anode, SEI formation, and the CE of a Li-Li cell. Among the many PFGs tested, we found the best performance from PFGs designated PFG2 and PFG5, and these two PFGs were thoroughly studied. A systematic coin-cell study of electrolyte solvents of 90:10, 80:20, or 70:30 DME:PFG (DME = 1,2-dimethoxyethane) revealed some systematic trends: a higher percentage of PFG solvent led to substantially longer cycle life, but at the same time reduced specific capacity (mAh/g(S)) and cell capacity at higher rates. These studies used LiFSI as the electrolyte salt, as it was found to extend cycle life compared to LiTFSI. Finally, the addition of a small amount of 1,3-dioxolane (DOL) to the electrolyte was found to be beneficial. The overall optimal electrolyte solution was found to be 0.6 M LiFSI + 0.5 M LiNO 3 in 75:5:20 DME/DOL/PFG (either PFG2 or PFG5).

25 ENERGY STORAGE↗
NASA NTRS1997

In-Flight Flow Visualization Using Infrared Thermography

The feasibility of remote infrared thermography of aircraft surfaces during flight to visualize the extent of laminar flow on a target aircraft has been examined. In general, it was determined that such thermograms can be taken successfully using an existing airplane/thermography system (NASA Dryden's F-18 with infrared imaging pod) and that the transition pattern and, thus, the extent of laminar flow can be extracted from these thermograms. Depending on the in-flight distance between the F-18 and the target aircraft, the thermograms can have a spatial resolution of as little as 0.1 inches. The field of view provided by the present remote system is superior to that of prior stationary infrared thermography systems mounted in the fuselage or vertical tail of a subject aircraft. An additional advantage of the present experimental technique is that the target aircraft requires no or minimal modifications. An image processing procedure was developed which improves the signal-to-noise ratio of the thermograms. Problems encountered during the analog recording of the thermograms (banding of video images) made it impossible to evaluate the adequacy of the present imaging system and image processing procedure to detect transition on untreated metal surfaces. The high reflectance, high thermal difussivity, and low emittance of metal surfaces tend to degrade the images to an extent that it is very difficult to extract transition information from them. The application of a thin (0.005 inches) self-adhesive insulating film to the surface is shown to solve this problem satisfactorily. In addition to the problem of infrared based transition detection on untreated metal surfaces, future flight tests will also concentrate on the visualization of other flow phenomena such as flow separation and reattachment.

vanDam, C. P.↗
DOE OSTI2024

Permafrost Formation in a Meandering River Floodplain

Abstract Permafrost influences 25% of land in the Northern Hemisphere, where it stabilizes the ground beneath communities and infrastructure and sequesters carbon. However, the coevolution of permafrost, river dynamics, and vegetation in Arctic environments remains poorly understood. As rivers meander, they erode the floodplain at cutbanks and build new land through bar deposition, creating sequences of landforms with distinct formation ages. Here we mapped these sequences along the Koyukuk River floodplain, Alaska, analyzing permafrost occurrence, and landform and vegetation types. We used radiocarbon and optically stimulated luminescence (OSL) dating to develop a floodplain age map. Deposit ages ranged from modern to 10 ka, with more younger deposits near the modern channel. Permafrost rapidly reached 50% areal extent in all deposits older than 200 years then gradually increased up to ∼85% extent for deposits greater than 4 Kyr old. Permafrost extent correlated with increases in black spruce and wetland abundance, as well as increases in permafrost extent within wetland, and shrub and scrub vegetation classes. We developed an inverse model to constrain permafrost formation rate as a function of air temperature. Permafrost extent initially increased by ∼25% per century, in pace with vegetation succession, before decelerating to <10% per millennia as insulating overbank mud and moss slowly accumulated. Modern permafrost extent on the Koyukuk floodplain therefore reflects a dynamic balance between widespread, time‐varying permafrost formation and rapid, localized degradation due to cutbank erosion that might trigger a rapid loss of permafrost with climatic warming.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1990

Antireduction Insulator For Solid-Electrolyte Cell

Depletion of oxygen from electrolyte prevented. Proposed to add layer of electrical insulation between solid electrolyte and portion of porous negative electrode under negative metal contact in solid-electrolyte cell. Helps maintain efficiency of cell by preventing "shadow" effect degrading portion of electrolyte under negative contact and sometimes near seals.

Shlichta, Paul J.↗