Friction characteristics of sputtered solid film lubricants
Solid film lubricants deposited by DC and RF sputtering on metal and glass surfaces, determining friction characteristics by electron microscopy
Spalvins, T.↗
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Coatings from copolymers of tetraphenoxysilane and p,p(1)-biphenol
Resultant resin from copolymers is highly crosslinked and completely aromatic. Procedure develops polyaryoxysilane structure in situ after the substrate has first been coated with a prepolymer. Resins are useful as protective coatings for metals, ceramics, glass, and other materials that accommodate relatively high curing temperatures.
Dunnavant, W. R.↗
Electronic and physical properties of materials
Thermal and elastic properties of polymers, and electronic properties of glasses and metals
Source record↗
Apollo telescope mount SEC camera tube spares program
An important engineering improvement was made during the Spares Program. The thermionic cathode structure was modified to bring the cathode temperature to a more suitable value and shields were placed over the glass-to-metal interface of the stem leads to reduce the possibility of interelectrode leakage. The cathode temperature change has resulted in a corresponding change in the recommended operating conditions for the heater of the thermionic cathode. All tubes built during the 1972-1973 ATM Spares Program should be operated with a heater current of 150 mA (6.3 volts). Operation at lower currents and voltages adversely affects the life of these tubes.
Green, M.↗
Effect of surface topography on structural growth of thick sputtered films
Primarily thick sputtered S-Monel, silver, and 304 stainless steel coatings were deposited on mica, glass, and metal substrates with various surface finishes to investigate the structural growth of the coating by scanning electron microscopy. Compositional changes within the coating were analyzed by X-ray dispersion microscopy. Defects in the surface finish act as preferential nucleation sites and form isolated and complex nodules and various surface overgrowths in the coating. These nodules do not disappear after full annealing. Further, they have undesirable effects on mechanial properties; cracks are initiated at the nodules when the coating is stressed by mechanical forces. These effects are illustrated by micrographs. Nodular growth within a coating can be minimized or eliminated by reducing the surface roughness.
Spalvins, T.↗
Growth defects in thick ion-plated coatings
Industrial ion plating conditions were selected to deposit metallic coatings such as copper, gold, and chromium 2 micrometer thick on metal and glass substrates. The surface finishes of 304 stainless steel, copper, and brass were utilized with mechanically and electrolytically polished surfaces. Nodular growth occurred in these coatings during ion plating as revealed by scanning electron microscopy. Surface irregularities such as scratches, steps, ledges, and so forth are responsible for outward growth, the typical cone type, whereas surface contaminants and loosely settled foreign particles are responsible for lateral growth; namely, the extreme localized surface outgrowths. These defect crystallographic features create porosity in the coatings when subjected to stresses and strains.
Spalvins, T.↗
Morphological growth of sputtered MoS2 films
Sputtered MoS2 films from 300 A to 20,000 A thick were deposited on metal and glass surfaces. The substrate effects such as surface temperature, finish, pretreatment and chemistry as they affect the film formation characteristics were investigated by optical, electron transmission, electron diffraction, and scanning electron microscopy. Substrate temperature and surface chemistry were found to be the prime variables as to the formation of a crystalline or amorphous film. The friction characteristics are strictly influenced by the type of film formed. Surface chemistry and surface pretreatment account for compound formation and corresponding grain growth, which directly affect the adhesion characteristics, resulting in poor adherence. The type of surface finish (topography) as related to scratches, impurities, inhomogeneities, etc., are favorable nucleation sites for the growth of isolated and complex nodules within the film, and various complex surface overgrowths on the film. These nodular growth features have progressively more undesirable effects on the film behavior as the film thickness increases.
Spalvins, T.↗
Ultra-high-vacuum electrical feedthrough
Device for cathodic sputtering utilizes cathode dark-space region adjacent to high negative-potential surfaces. Feedthrough is made of metal and glass, is helium leaktight, and is bakeable; it can be incorporated into any vacuum apparatus.
Gavaler, J. R.↗
Universal solar-cell terminal
Terminal, which replaces stakes or lugs in conventional design with loop receptacles for wires from cell and harness, uses dissimilar bonding properties (metal-to-glass and/or ceramics) of iron-nickel-cobalt alloy in conjunction with standard termination.
Bashin, S.↗
Development of an economical silicon solar cell
The growth of electronically viable silicon films on inexpensive foreign substrates is studied, with the objective of creating a technology to radically reduce the overall cost of the silicon employed in photovoltaic solar energy conversion. The approach employed is to enhance crystalline ordering during film nucleation by confining arriving silicon atoms to a narrow band traveling across a substrate, i.e., the Lateral Growth Technique (LGT). The efforts have employed physical vapor deposition of silicon in a vacuum evaporator on glass and metal substrates with both slit masks and single defining edges, and subsequent chemical vapor deposition (CVD) of thicker films on these thin film structures by pyrolysis of silane at higher temperatures.
Lindmayer, J.↗
Morphological growth of sputtered MoS2 films
Sputtered MoS2 films from 300 A to 20,000 A thick were deposited on metal and glass surfaces. The substrate effects such as surface temperature, finish, pretreatment, and chemistry as they affect the film formation characteristics were investigated by optical, electron transmission, electron diffraction, and scanning electron microscopy. Substrate temperature and surface chemistry were found to be the prime variables as to the formation of a crystalline or amorphous film. The friction characteristics are strictly influenced by the type of film formed. Surface chemistry and surface pretreatment account for compound formation and corresponding grain growth, which directly affect the adhesion characteristics, resulting in poor adherence. Scratches, impurities, inhomogeneities, etc., are favorable nucleation sites for the growth of isolated and complex nodules within the film.
Spalvins, T.↗
Microstructural and wear properties of sputtered carbides and silicides
Sputtered Cr3C2, Cr3Si2, and MoSi2 wear-resistant films (0.05 to 3.5 microns thick) were deposited on metal and glass surfaces. Electron transmission, electron diffraction, and scanning electron microscopy were used to determine the microstructural appearance. Strong adherence was obtained with these sputtered films. Internal stresses and defect crystallographic growth structures of various configurations within the film have progressively more undesirable effects for film thicknesses greater than 1.5 microns. Sliding contact and rolling element bearing tests were performed with these sputtered films. Bearings sputtered with a duplex coating (0.1-micron-thick undercoating of Cr3Si2 and subsequently 0.6-micron coating of MoS2) produced marked improvement over straight MoS2 films.
Spalvins, T.↗
Drop dynamics in space
Experiments to study the dynamics of liquid drops are being planned to be performed in the weightless environment of Spacelab. The liquids will range from superfluid helium through ordinary liquid to molten metals and glasses. The experiments will be conducted in a chamber now being developed which utilizes the forces and torques produced by acoustic waves excited within the chamber. None of the currently available facilities (drop towers, sounding rockets, or zero-g aircraft flights) can provide a sustained weightless environment, since the resulting zero-g periods are from 3 sec to 5 min. Spaceflight, however, will provide weightlessness for periods of one week, or more, allowing truly laboratory-like experiments to be conducted on free liquid drops and bubbles. In this paper we discuss both the drop dynamics experiments proposed for Spacelab and the acoustic chamber: its operation and current testing for these and other experiments.
Wang, T. G.↗
Microstructural and wear properties of sputtered carbides and silicides
Sputtered Cr3C2, Cr3Si2, and MoSi2 wear-resistant films (0.05 to 3.5 microns thick) were deposited on metal and glass surfaces. Electron transmission, electron diffraction, and scanning electron microscopy were used to determine the microstructural appearance. Strong adherence was obtained with these sputtered films. Internal stresses and defect crystallographic growth structures of various configurations within the film have progressively more undesirable effects for film thicknesses greater than 1.5 microns. Sliding contact and rolling-element bearing tests were also performed with these sputtered films.
Spalvins, T.↗
Seal problems of lithium cells
The problem of leakage through a seal in lithium cells is addressed. The use of ceramic and glass-to-metal seals is briefly discussed. Comments are presented from the Workshop participants.
Gross, S.↗
Space Resources and Space Settlements
This publication contains the technical papers from the five task groups that took part in the 1977 Ames Summer Study on Space Settlements and Industrialization Using Nonterrestrial Materials. The study was sponsored by the following NASA Headquarters organizations: Office of Space Science, Office of Aeronautics and Space Technology, and Office of Space Transportation Systems. The NASA Ames Research Center hosted the study and provided administrative support through its Life Sciences Directorate. Expert assistance in the many aspects of the study came from NASA Headquarters, NASA centers, universities, industry, and from individual consultants. This summer study was the largest and most comprehensive investigation of space manufacturing and habitation to date; forty senior research workers and ten students participated. The six-week study was preceded by several months of planning and preparation, and was followed by extensive work on manuscript checking, review, and assembly. The study topics reflected the research areas requiring the most intensive attention as ofrnid-1977; they were: Group I: Regenerative life-support systems and controlled environment agriculture. Group II: Parametric studies of efficient habitats in space. Time and cost analysis of a space manufacturing program plan. Group III: Detection and analysis of special classes of asteroids suitable as material resources for space manufacturing; studies of retrieval missions. Group IV: Electromagnetic mass drivers for use as interorbital engines, as devices to launch lunar material into space, and as tugs for the retrieval of asteroidal material. Group V: Chemical processing of non terrestrial material in space; manufacture of metals and glass fibers, beneficiation, and design of processing plants. These five task groups each produced two or more technical papers, signed by the contributing members. The papers were subjected to independent peer review by scientists not connected with the study. During the course of the study, frequent formal and informal exchanges of information occurred between task groups, so that the entire effort evolved in a coherent fashion and was directed toward common goals. However, each group remained responsible for the choice of its topics and for its conclusions. A listing of all the participants is given on pages vii-x. It would be inappropriate for me to single out particular people or groups for special mention, since all involved applied their skills with dedication and enthusiasm. Instead, I thank everyone for their contributions to the success of the study, and also for making it a united and warmly cooperative personal experience.
John Billingham↗
Transducer for extreme temperatures and pressures
Transducer with limits of 500 C and 10 kilobars responds to mechanical vibrations up to 20 kHz. Vibration pickup performs well in nuclear reactors, turbines, and other extreme environments. Low pressure problems of outgassing and "virtual" leakage experienced with conventional transducers potted in epoxy are eliminated with use of glass and metal supports. Interior opens to atmosphere, preventing buildup of pressure-induced stresses. Spring holds transducer against housing, reducing strain distortion.
Nadler, H.↗
Research on graphite reinforced glass matrix composites
High levels of mechanical performance in tension, flexure, fatigue, and creep loading situations of graphite fiber reinforced glass matrix composites are discussed. At test temperatures of up to 813 K it was found that the major limiting factor was the oxidative instability of the reinforcing graphite fibers. Particular points to note include the following: (1) a wide variety of graphite fibers were found to be comparable with the glass matrix composite fabrication process; (2) choice of fiber, to a large extent, controlled resultant composite performance; (3) composite fatigue performance was found to be excellent at both 300 K and 703 K; (4) composite creep and stress rupture at temperatures of up to 813 K was limited by the oxidative stability of the fiber; (5) exceptionally low values of composite thermal expansion coefficient were attributable to the dimensional stability of both matrix and fiber; and (6) component fabricability was demonstrated through the hot pressing of hot sections and brazing using glass and metal joining phases.
Prewo, K. M.↗