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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Nucleation Behavior of Oxygen-Acetylene Torch-Produced Diamond Films

A mechanism is presented for the nucleation of diamond in the combustion flame environment. A series of six experiments and two associated simulations provide results from which the mechanism was derived. A substantial portion of the prior literature was reviewed and the data and conclusions from the previous experimenters were found to support the proposed mechanism. The nucleation mechanism builds on the work of previous researchers but presents an approach to nucleation in a detail and direction not fully presented heretofore. This work identifies the gas phase as the controlling environment for the initial formation steps leading to nucleation. The developed mechanism explains some of the difficulty which has been found in producing single crystal epitaxial films. An experiment which modified the initial gas phase precursor using methane and carbon monoxide is presented. Addition of methane into the precursor gases was found to be responsible for pillaring of the films. Atomic force microscopy surface roughness data provides a reasonable look at suppression of nucleation by carbon monoxide. Surface finish data was taken on crystals which were open to the nucleation environment and generally parallel to the substrate surface. The test surfaces were measured as an independent measure of the instantaneous nucleation environent. A gas flow and substrate experiment changed the conditions on the surface of the sample by increasing the gas flow rate while remaining on a consistent point of the atomic constituent diagram, and by changing the carbide potential of the substrate. Two tip modification experiments looked at the behavior of gas phase nucleation by modifying the shape and behavior of the flame plasma in which the diamond nucleation is suspected to occur. Diamond nucleation and growth was additionally examined using a high-velocity oxygen fuel gun and C3H6 as the fuel gas phase precursor with addition of carbon monoxide gas 01 addition of liquid toluene.

Roberts, F. E.↗
NASA NTRS2018

Modification of Radiator Pigments by Atomic Layer Deposition (ALD)

The optical and physical properties of spacecraft radiator coatings are dictated by orbital environmental conditions. For example, coatings must adequately dissipate charge buildup when orbital conditions, such as polar, geostationary or gravity neutral, result in surface charging. Current dissipation techniques include depositing a layer of ITO (indium tin oxide) on the radiator surface in a high temperature process. Other examples include the application of variable emittance coatings such as the use of VO2 to optimize radiator size, allowing for a decrease in heater power budget. The application of these enhanced coatings must be such that the properties in question are tailored to mission-specific requirements. Modification of these coatings can be accomplished during coating application preprocessing by using a deposition technique prevalent in the semiconductor micro processing industry called Atomic Layer Deposition (ALD). The preprocessing is rendered directly on the coating dry pigment before binding. ALD is a cost effective nano-manufacturing technique that allows for the conformal coating of substrates with atomic-level thickness control in a benign temperature and pressure environment. Through the introduction of paired precursor gases, thin films can be deposited on a myriad of substrates ranging from glass, polymers, aerogels, metals, powders, and other high aspect-ratio micro- and nano-structures. By providing atomic-level control, where single layers of atoms can be deposited, the fabrication of metal transparent films, precise nano-laminates, and coatings of nano-channels and pores is achievable. We have demonstrated a method for the ALD of In2O3 and ITO films on a variety of substrates from Si(100) wafers, glass slides, and on Z93P pigments (patent pending). The results indicate excellent growth of 4-22 nm thick films demonstrating an order of magnitude decrease in resistivity on the pigments.

ITO↗
NASA NTRS2015

Development of the Science Data System for the International Space Station Cold Atom Lab

Cold Atom Laboratory (CAL) is a facility that will enable scientists to study ultra-cold quantum gases in a microgravity environment on the International Space Station (ISS) beginning in 2016. The primary science data for each experiment consists of two images taken in quick succession. The first image is of the trapped cold atoms and the second image is of the background. The two images are subtracted to obtain optical density. These raw Level 0 atom and background images are processed into the Level 1 optical density data product, and then into the Level 2 data products: atom number, Magneto-Optical Trap (MOT) lifetime, magnetic chip-trap atom lifetime, and condensate fraction. These products can also be used as diagnostics of the instrument health. With experiments being conducted for 8 hours every day, the amount of data being generated poses many technical challenges, such as downlinking and managing the required data volume. A parallel processing design is described, implemented, and benchmarked. In addition to optimizing the data pipeline, accuracy and speed in producing the Level 1 and 2 data products is key. Algorithms for feature recognition are explored, facilitating image cropping and accurate atom number calculations.

bose einstein condensate↗
DOE OSTI2022

Photoionization branching ratios of spin-orbit doublets far above thresholds: Interchannel and relativistic effects in the noble gases

Photoionization branching ratios of all of the spin-orbit doublets in the noble gas atoms Ne, Ar, Kr, and Xe have been investigated theoretically at energies well above the thresholds. The results confirm in all cases that the general behavior of the branching ratios is to decrease monotonically below their statistical value with increasing photon energy. Here, this effect gets more pronounced with increasing Z. In addition, the branching ratios can be strongly affected by interchannel coupling with inner shell photoionization channels. Although these effects are strongest in the neighborhood of the inner shell thresholds, they can persist over a broad range of energies,

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1997

Studies for the Loss of Atomic and Molecular Species from Io

The general objective of this project is to advance our theoretical understanding of Io's atmosphere by studying how various atomic and molecular species are lost from this atmosphere and are distributed near the satellite and in the circumplanetary environment of Jupiter. The project is divided into well-defined studies described for the likely dominant atmospheric gases involving species of the SO2 family (SO2, SO, 02, 0, S) and for the trace atmospheric gas atomic sodium. The relative abundance of the members of the S02 family and Na (and its parent Na(x)) at the satellite exobase and their relative spatial densities beyond in the extended corona of lo are not well known but will depend upon a number of factors including the upward transport rate of gases from below, the velocity distribution and corresponding escape rate of gases at the exobase, and the operative magnetospheric/solar-photon driven chemistry for the different gases. This question of relative abundance will be studied in this project.

Smyth, William H.↗
NASA NTRS2004

Removing Spectral Diagnostics of Galactic and Stellar X-Ray Emission from Charged Exchange Recombination

Our research uses the electron beam ion trap (EBIT) at the Lawrence Livermore National Laboratory to study X-ray emission from the charge exchange (CX) of highly charged ions with neutral gases. The resulting data help to fill a void in existing experimental and theoretical understanding of this atomic physics process, and are needed to explain all or part of the observed X-ray emission from the soft X-ray background, stellar winds, the Galactic Center and Galactic Ridge, supernova ejecta, and photoionized nebulae. Appreciation of the astrophysical relevance of our work continues to grow with the publication of roughly a dozen papers in the past four years describing Chandra and XMM observations of geocoronal and heliospheric CX emission, the temporal variation of such emission and correlation with X-ray emission enhancements observed by ROSAT, the theoretical spatial distribution of that emission, and CX emission around other stars. A similar number of papers were also published during that time describing CX emission from planets and comets. We expect that the launch of ASTRSE2, with its second-generation XRS microcalo- (with 6-eV resolution), will reveal even more clearly the contributions of CX to astrophysical emission. In our EBIT work we collected CX spectra from such ions as H-like and He-like Ne, Ar, and Fe. Our early measurements were made with a high-purity Ge detector, but during the second year we began operation of the first-generation XRS microcalorimeter (a twin of the XRS on ASTRO-E) and greatly improved the resolution of our measurements from roughly 150 eV (FWHM) with the Ge detectors to 10 eV with the XRS. We found that saturation of the XRS counting apparatus, which we described in our proposal as a potential concern, is not a problem for studying CX. During the course of our research, we expanded the number of injection gases permitted by the LLNL safety team, purchased and eventually operated an atomic H source, and clearly demonstrated the feasibility of our longer-range plan. For example, we successfully injected He into EBIT (not a small feat because of the difficulty of maintaining a good vacuum with He and avoiding electrical breakdown) to collect a H-like oxygen CX spectrum. The highest energy CX spectrum recorded with the XRS to date is that of the Ar K-shell emission. These measurements provided the first observation of the relative intensity ratios of resolved He-like singlet and triplet n=2->1 lines. We also carried out measurements of He-like Ne as a function of collision energy (i.e., ion temperature). Significant differences in the resulting x-ray spectra were noted. In all cases, the intensity of high-n H-like Lyman lines is significantly higher than current theoretical CX models predict.

Wargelin, Brad↗
DOE OSTI2020

Contact in the Unitary Fermi Gas across the Superfluid Phase Transition

A quantity known as the contact is a fundamental thermodynamic property of quantum many-body systems with short-range interactions. Determination of the temperature dependence of the contact for the unitary Fermi gas of infinite scattering length has been a major challenge, with different calculations yielding qualitatively different results. Here we use finite-temperature auxiliary-field quantum Monte Carlo (AFMC) methods on the lattice within the canonical ensemble to calculate the temperature dependence of the contact for the homogeneous spin-balanced unitary Fermi gas. We extrapolate to the continuum limit for 40, 66, and 114 particles, eliminating systematic errors due to finite-range effects. We observe a dramatic decrease in the contact as the superfluid critical temperature is approached from below, followed by a gradual weak decrease as the temperature increases in the normal phase. Our theoretical results are in excellent agreement with the most recent precision ultracold atomic gas experiments. Here, we also present results for the energy as a function of temperature in the continuum limit.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1974

Diffusion with chemical reaction: An attempt to explain number density anomalies in experiments involving alkali vapor

The mutual diffusion of two reacting gases is examined which takes place in a bath of inert gas atoms. Solutions are obtained between concentric spheres, each sphere acting as a source for one of the reactants. The calculational model is used to illustrate severe number density gradients observed in absorption experiments with alkali vapor. Severe gradients result when sq root k/D R is approximately 5 where k, D, and R are respectively the second order rate constant, the multicomponent diffusion constant, and the geometrical dimension of the experiment.

Snow, W. L.↗
NASA NTRS1980

Mass spectrometric measurements of the neutral gas composition of the thermosphere and exosphere of Venus

The neutral gas composition and density in the thermosphere of Venus is being measured with a quadrupole mass spectrometer on the Pioneer Venus orbiter. Data are obtained near periapsis once per day approximately 150-250 km above the surface. The principal gases in the thermosphere are CO2, CO, N2, O, N, and He. Atomic oxygen is the major constituent above 155 km on the dayside and also on the nightside up to 180 km when helium becomes the major constituent. The average values of CO2, CO, N2, O, and N remain nearly constant during day and night, but an abrupt change occurs across the terminator from a high dayside value to a low nightside value. The helium density varies in the opposite way, and a distinct bulge was observed at night near the morning terminator. The data have been used as the basis of an empirical model. Large orbit to orbit variations in densities were also observed on the nightside, suggesting perhaps strong turbulent motion in the atmosphere below. Kinetic temperatures inferred from scale heights are approximately 285 K on the dayside and 110 K at night. The average global temperature obtained from the model is 199 K.

Niemann, H. B.↗
NASA NTRS1988

Surface compositional and structural aspects of Martian samples

There are many excellent reasons to examine the surface composition of a wide range of Martian samples. The existing spectral data indicate that many dust and soil particles have a thin Fe(+3) layer with a typical particle size in the 10 micrometer to 400 micrometer range. In view of the high CO2 content of the atmosphere, one might expect that surface carbonates should be present. In addition to chemisorbed material there will probably exist physisorbed atmospheric components of the atmosphere including oxygen, nitrogen and water vapor. The latter could possibly give rise to some hydrated minerals. Using ultra-high-vacuum/mass spectrographic techniques it should be possible to detect physisorbed and moderately strong chemisorbed species on the particle surfaces with a temperature programmed degassing procedure. In some instances such an approach is capable of helping distinguish between volcanic and impact generated materials by detecting the presence of fumerolic gases. Such gases typically condense on the exterior of the ejected particles. Additionally surface atomic and chemical compositions should be examined by a combination of modern surface analytical techniques. The combination we currently have in Buffalo at SUNY would appear to be one of the best available including ESCA (150 micrometer spot capability) Auger (SAM) with 300 A focussing for surface compositional surveys, SIMS for high sensitivity trace element detection and ISS for immediate surface layer analysis.

Cadenhead, D. A.↗
NASA NTRS1992

Viscosity of dissociating gases

Recent calculations of the viscosity of iodine suggest that existing predictions of viscosities of high-temperature (up to several thousands degrees) gases should be revised, with much more attention being paid to the atomic and molecular interactions in the gas. As the gas starts to dissociate, the frequency of atom-molecule and atom-atom interactions increases, and those collisions must be taken into account in calculations of viscosity at high temperature. In this study, the iodine is chosen as an example, and the dependence of its viscosity on the gas dissociation degree is shown. Several possible channels for I+I interaction are considered in addition to I+I2 and I2+I2 collisions, and the resulting collision integrals are averaged over all the important channels.

Kang, S. H.↗
DOE OSTI2024

A model for trapping and re-solution regarding intra-granular bubbles in UO 2 , linked to atomic-scale simulations

In the literature, a clear definition of the irradiation re-solution frequency of gas from bubbles in the UO 2 fuel is absent. Moreover, for intra-granular bubbles, a detailed calculation of the cumulated displaced gas quantities in function of the distance from the radius of the bubble after a re-solution event has never been published. The assessment of these two elements is very useful if we want to increase the adherence of fission gas release codes to our present knowledge of the behavior of fission gases. Hence, we suggest to link the definition of the re-solution frequency to atomic-scale simulations. Furthermore, we present the cumulated displaced gas quantities obtained from Molecular Dynamics calculations, from which we have derived a re-solution profile that can be exploited to better consider the irradiation re-solution phenomenon inside Fission Gas Release codes. On top of that, we have built a new trapping/re-solution model for intra-granular bubbles linked to Molecular Dynamics simulations that can be easily incorporated into Fission Gas Release codes. In conclusion, we also check that the model is properly built through the comparison of the new model against a reference.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

Optimal strategies for optical quantum memories using long-lived noble-gas spins

Nuclear spins of noble gases exhibit exceptionally long coherence times and can potentially serve as a long-lived storage medium for quantum information. We analyze and compare the performance of two mechanisms for mapping the quantum state of light onto the collective spin state of noble gases. The first mechanism utilizes collisional exchange with the electronic spin state of metastable noble-gas atoms, while the second relies on spin-exchange collisions with ground-state alkali-metal atoms. We describe the operation of an optical quantum memory relying on these two mechanisms using a compact model and study strategies that optimize the memory storage efficiency. Through numerical simulations, we identify optimal sequences for storing optical signals with different signal bandwidths and electronic spin relaxation rates. This work highlights the qualitative difference between the two approaches for using noble gases as long-lived quantum memories at noncryogenic conditions and outlines the regimes in which they are expected to be efficient.

atomic ensemble↗
NASA NTRS1979

Dynamical effects on the global distribution of thermospheric atomic oxygen

Results are presented of calculations pertaining to the effects of global-scale dynamical processes on the coupled seasonal and diurnal variations of atomic oxygen in the altitude range 90-500 km. The calculations are based on a three-dimensional numerical model of thermospheric dynamics which treats the three gases N2, O2, and O simultaneously, coupled together by collisional processes. The model is described, and the results of the calculations under both equinox and solstice conditions and a comparison with observational data are discussed. It is shown that none of these gases can be considered to be in hydrostatic equilibrium below about 200 km, and that global-scale winds cause the observed winter enhancement of atomic oxygen.

Straus, J. M.↗