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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

The DECam MAGIC Survey: Investigating the Jet Stellar Stream with Photometric Metallicities

Stellar streams are dynamically fragile structures formed by the tidal disruption of dwarf galaxies and stellar clusters. These objects are valuable tracers of the gravitational potential and accretion history of the Milky Way, and are key probes for the presence and interactions of starless dark matter subhalos. The Jet stream is a $\sim 30^\circ$-long stellar stream that is situated at 30.4 kpc and originates from a disrupted globular cluster. It consists of metal-poor stars that follow a retrograde orbit, reducing the impulse imparted from the Milky Way bar and making it especially sensitive to gravitational perturbations from dark matter subhalos. This paper investigates the known extent of the Jet stream by leveraging photometric metallicities derived from a narrowband filter centered on the Ca II H&K lines at $\sim$3950A on the Dark Energy Camera (DECam), as part of the Mapping the Ancient Galaxy in CaHK (MAGIC) survey. The wide field-of-view of DECam enables the efficient derivation of photometric metallicities for stars across the full extent of the stream, allowing for a metallicity-based selection to identify likely members. We demonstrate the efficacy of photometric metallicities in isolating stream members when used with Gaia DR3 proper motions, identifying a sample of 213 candidate Jet stream member stars. This then allows for the study of stream morphology, through which we identify a clear fanning of the stream toward the end farther from the Milky Way bar. We provide a list of candidate members, enabling spectroscopic follow-up of the Jet stream to facilitate further studies of its dynamics.

Do, Ha Q. [Chicago U., Astron. Astrophys. Ctr.] (O↗

Coordination Polymer Electrocatalysts Enable Efficient CO‐to‐Acetate Conversion

Abstract Upgrading carbon dioxide/monoxide to multi‐carbon C 2+ products using renewable electricity offers one route to more sustainable fuel and chemical production. One of the most appealing products is acetate, the profitable electrosynthesis of which demands a catalyst with higher efficiency. Here, a coordination polymer (CP) catalyst is reported that consists of Cu(I) and benzimidazole units linked via Cu(I)‐imidazole coordination bonds, which enables selective reduction of CO to acetate with a 61% Faradaic efficiency at −0.59 volts versus the reversible hydrogen electrode at a current density of 400 mA cm −2 in flow cells. The catalyst is integrated in a cation exchange membrane‐based membrane electrode assembly that enables stable acetate electrosynthesis for 190 h, while achieving direct collection of concentrated acetate (3.3 molar) from the cathodic liquid stream, an average single‐pass utilization of 50% toward CO‐to‐acetate conversion, and an average acetate full‐cell energy efficiency of 15% at a current density of 250 mA cm −2 .

Luo, Mingchuan↗

A framework for calibrating and validating an air loop dynamic model in an HVAC system in Modelica

The use of Modelica for simulating the dynamic behaviors of building heating, ventilation, and air conditioning (HVAC) systems has gained popularity. Calibration of a model that represents large and complex HVAC systems in Modelica involves the determination of hundreds of parameters using real-world operation data. Considering the coupling effects among various components, such a calibration process is complex and time-consuming. In this study, we propose a systematic framework to efficiently calibrate and validate a complex HVAC system model in Modelica. The framework includes strategies to solicit real-system operation data and to decouple the model. The goal of this calibration framework is to accurately and efficiently determine a set of Modelica model parameters that provide a good match between the simulated and real system behaviors. To demonstrate the validity of the framework, it was applied to calibrate the parameters of a Modelica model of the air loop subsystem of a real AHU-VAV system. The results show that the calibrated model can generate simulated results, including VAV air flow rate, outdoor air flow, and fan power consumption, that match well with the operational data of the real system. The coefficient of the variation of the root mean square error, CV(RMSE), of the air flow rate and power consumption are 14.6 % and 11.5 %, respectively. The results prove that the framework is valid and effective, and it can be used to calibrate other complex HVAC system Modelica models in the future.

Li, Yicheng↗

Dynamically tunable second-harmonic generation using hybrid nanostructures incorporating phase-change chalcogenides

Nonlinear metasurfaces with high conversion efficiencies have been vastly investigated. However, strong dynamic tunability of such devices is limited in conventional passive plasmonic and dielectric material platforms. Germanium antimony telluride (GST) is a promising phase-change chalcogenide for the reconfiguration of metamaterials due to strong nonvolatile changes of the real and imaginary parts of the refraction index through amorphous-crystalline phase change. The orderly structured GST has an even higher potential in tunable second-harmonic generation (SHG) with a non-centrosymmetric crystal structure at the crystalline phase, while the amorphous phase of GST does not exhibit bulk second-order nonlinearity. Here, we experimentally demonstrate SHG switches by actively controlling the crystalline phase of GST for a GST-based hybrid metasurface featuring a gap-surface plasmon resonance, and a quarter-wave asymmetric Fabry–Perot (F–P) cavity incorporating GST. We obtain SHG switches with modulation depths as high as ~ 20 dB for the wavelengths at the on-state resonance. We also demonstrate the feasibility of multi-level SHG modulation by leveraging three controlled GST phases, i.e., amorphous, semi-crystalline, and crystalline, for the gap-surface plasmon hybrid device, which features stronger light–matter interaction and has higher resonant SHG efficiencies than the asymmetric F–P cavity device at respective GST phases. This research reveals that GST-based dynamic SHG switches can be potentially employed in practical applications, such as microscopy, optical communication, and photonic computing in the nonlinear regime.

42 ENGINEERING↗

Ferroelectric materials toward next-generation electromechanical technologies

Ferroelectric materials have been widely used in various electromechanical devices, from ultrasonic transducers and actuators to mechanical energy harvesters. The key performance metrics of these devices, such as sensitivity, efficiency, and bandwidth of ultrasonic transducers, are largely determined by the piezoelectric properties. This Review highlights recent research progress in improving the piezoelectricity of ferroelectric materials and offers potential strategies for further enhancement to meet the ever-increasing demands for high-performance piezoelectric devices and systems. Here, it provides insights into the future development of ferroelectrics to address the increasing demands of emerging applications, including photoacoustic imaging and piezoelectric fans and motors in integrated circuit–enabled electronic devices. Additionally, it emphasizes the need to consider environmental impacts across the entire life cycle of ferroelectrics, from sourcing and manufacturing to usage and disposal.

36 MATERIALS SCIENCE↗

Laser-Induced Recoverable Fluorescence Quenching of Perovskite Films at a Microscopic Grain Scale

Understanding the fundamental properties of metal-halide perovskite materials is driving the development of novel optoelectronic applications. Here, in this paper, we report the observation of a recoverable laser-induced fluorescence quenching phenomenon in perovskite films with a microscopic grain-scale restriction, accompanied by spectral variations. This fluorescence quenching depends on the laser intensity and the dwell time under Auger recombination dominated conditions. These features indicate that the perovskite lattice deformation may take the main responsibility for the transient and show a new aspect to understand halide perovskite photo-stability. We further modulate this phenomenon by adjusting the charge carrier recombination and extraction, revealing that efficient carrier transfer can improve the bleaching resistance of perovskite grains. Our results provide future opportunities to attain high-performance devices by tuning the perovskite lattice disorder and harvesting the energetic carriers.

36 MATERIALS SCIENCE↗

Fleet-Level Fuel Impact of Hybrid-Electric Aircraft in United States

Here, this paper examines the impact of two potential solutions for increasing fuel efficiency and reducing emissions in commercial aviation: hybrid-electric propulsion and the use of drop-in synthetic aviation fuels (SAFs). The authors modeled three representative aircraft employed in the U.S. domestic market: a 70-seat regional turboprop, a 100-seat airliner, and a 180-seat airliner. These aircraft were retrofitted with hybrid-electric propulsion systems that integrate batteries and electric motors to provide additional torque to the propeller or fan. The authors explored various technological scenarios involving different battery specific energies, electric motor specific powers, and other relevant parameters. Flight performance models were used to analyze the range–payload capabilities of these new hybrid-electric aircraft and to compare them with their conventional counterparts. Subsequently, the authors virtually deployed the hybrid-electric aircraft on 2019 U.S. domestic commercial flights to assess the types and lengths of flights that could be serviced by this new fleet. We then compared the resulting fuel consumption, energy use, and emissions with those of a conventional fleet using a combination of jet fuel and SAF.

SAF↗

Deep Reinforcement Learning Based Control of Wind Turbines for Fast Frequency Response

In order to fulfill vital auxiliary grid services, such as load regulation, spin and non-spin reserve provision, and frequency support during emergencies, there is often a requirement for certain wind farms to operate in de-loaded modes. Leveraging the swift response capabilities of wind farms, this study demonstrates that reserving power in de-loaded modes can significantly enhance power grid stability and reliability during system contingencies. Controlling wind farms optimally for frequency support is intricate due to the nonlinearity of models and controllers and the complexity of wind farm interactions with power systems. Here, to address this challenge, this paper introduces a novel approach that integrates wind turbines into reinforcement learning-based solutions for frequency response. This innovative methodology utilizes the state-of-the-art reinforcement learning algorithm known as the surrogate-gradient-based evolutionary strategy. The proposed learning-based algorithm provides continuous control of wind farm output to rapidly stabilize system frequency and prevent unnecessary trips of under-frequency load shedding relays. To facilitate efficient training, parallel computing techniques are employed. The proposed methodology is evaluated on a modified IEEE-39 bus system, and simulation results reveal its efficacy in reliably supporting power system frequency and preventing the need for unnecessary load shedding.

Gao, Wei [Argonne National Laboratory (ANL), Argon↗

Loss circulation prevention in geothermal drilling by shape memory polymer

Geothermal formations are naturally fractured with large fracture openings and networks. This can often lead to frequent drilling fluid loss events which is a major contributor to the cost and non-productive time in geothermal drilling. Development of smarter technologies and methods to tackle problem lost circulation is vital for geothermal drilling cost reduction required for geothermal energy to be recognized as a competitive alternative energy source. Mitigation of this problem and other drilling problems such as stuck pipe can minimize overall project cost. In this report, a thermoset shape memory polymer that can be activated by formation natural heat was assessed to seal near wellbore fractures in geothermal wells. The performance of the shape memory polymer (SMP) was evaluated using artificial fractures created in aluminum discs and cylindrical granite cores. Rheology and particle size distribution were considered. A novel testing setup was built for this work, which allows testing of sealing efficiency under dynamic conditions at high temperature. Analysis showed that the SMP has efficiently succeeded in forming a strong plug inside the fractures and stopped fluid loss at high sealing pressure. This smart loss circulation material can expand within the fractures to reduces non-drilling time and strengthen the wellbore in high-temperature drilling operations.

58 GEOSCIENCES↗

5G Enabled Transformative Co-design and Co-simulation Framework for Grid Decarbonization and Modernization

5G is a breakthrough technology to enable a fully mobile and connected society, and a 5G-enabled digital continuum will be one of the critical foundations for clean energy economy and grid modernization. The clean energy transformation not only requires innovative manufacturing, algorithm, application, and cross-domain co-simulation, but also a systematic evaluation and comprehensive support on the microelectronic and architectural computing customization to enable and maximize the high renewable penetration in the future power grid. The co-design of decarbonized grid, reliable yet efficient communication, and affordable yet ubiquitous computing will unlock the potential of almost any available tools for the undergoing clean energy transformation. 5G is also an opportunity to rethink the paradigm of infrastructure planning, as computing will be one of the core services for society alongside electricity and communication services.

5G↗

Engineering Thermally Resilient and Kinetically Active Reversible Protonic Ceramic Cells via Interfacial Design

Achieving concurrent fast electrode kinetics and long-term thermo-mechanical durability remains a critical challenge for reversible protonic ceramic electrochemical cells (R-PCECs). Herein, we report an interfacial engineering strategy that integrates a perovs.kite-type PrBaRu0.1Co1.9O5+δ (PBRC) nanoparticle layer onto a PrBa0.5Sr0.5Co1.5Fe0.5O5+δ (PBSCF) substrate (PBRC-PBSCF), together with a modified pellet-assisted sintering approach to fabricate dense BaZr0.4Ce0.4Y0.1Yb0.1O3-δ (BZCYYb4411) electrolytes. The in situ reconstructed heterointerface enhances oxygen reduction/evolution reaction (ORR/OER) kinetics, promotes H2O adsorption/dissociation, and improves steam tolerance, as verified by electrochemical measurements and interfacial microstructural analyses. Density functional theory reveals that Ru-induced electronic modulation at the PBRC-PBSCF interface lowers the energy of oxygen vacancy formation and optimizes the position of the O 2p band center, thereby accelerating oxygen redox kinetics and stabilizing the interface. The resulting R-PCECs deliver an excellent peak power density of 1.112 W cm−2 and an electrolysis current density of −1.257 A cm−2 at 1.3 V in 3% H2O wet air at 600°C, with a reasonable faradaic efficiency. Furthermore, the cells demonstrate excellent stability, sustaining 100 h of thermal cycling (400–600°C, 200°C h−1) in both fuel cell and electrolysis modes, with 600 h of stability in electrolysis mode (600°C, −0.5 to −2 A cm−2).

30 DIRECT ENERGY CONVERSION↗

Formation of misfit dislocation arrays and helium nanochannels near copper surface assisted by high-temperature graphene deposition

Misfit dislocation arrays (MDAs) at semi-coherent heterogeneous interface have been demonstrated effectiveness to trap and then outgas helium (He) for alleviating void swelling in metals, but limited by atomic-level thin film deposition that is difficult to scale-up for industrial production. In this work, we proposed an innovative strategy that could generate semi-coherent homophase interfaces in a same grain by varying surface energy density assisted by high-temperature graphene (Gr) deposition. This strategy transforms strain energy and surface energy, two originally distinctive processes into successive processes, and demonstrates experimentally and theoretically by introducing {111} copper (Cu) in a {100} Cu grain. Subsequent He implantation and electrical resistivity measurement results suggest that high-density MDAs originated at this {111}/{100} interface could form stable He nanochannels near Cu surface with Gr assistance, manifesting by ultra-low increased ratio of the electrical resistivity (i.e. ~3800% of Cu vs. ~90% of Gr/Cu) after He implantation. Finally, the present findings may provide a new strategy for efficiently managing He and achieving surface protection of advanced metals, merely by depositing a super-rigid material on metal surface to greatly reduce surface energy density.

36 MATERIALS SCIENCE↗

High-Efficiency Reversible Alkaline Membrane Fuel Cells

The proposed project will explore oxidation-resistant alkaline membrane/ionomers and corrosion-resistant bifunctional catalysts to enable reversible alkaline membrane fuel cells (AMFCs). The project will for the first time demonstrate a reversible AMFC with greater than 50% RTE at 1000 mA/cm 2 without introducing any salts or bases in the aqueous feed.

30 DIRECT ENERGY CONVERSION↗

A Computational Review of Privacy-Preserving Mechanisms for the Smart Grid

Smart grid technologies have rapidly become one of the largest and most comprehensive sources of data for the modern utility. For the most part, data streams are seen as an essential tool that enable utilities to carry their day-to-day business operations, but they also create the need for efficient and secure data management strategies. In the context of the smart grid, ensuring data privacy is becoming an increasing concern due to a combination of factors that range from shifts in operational paradigms and rapid technology evolution to changes in legislation. Furthermore, researchers have highlighted the risks associated with improperly protected energy records. For example, energy consumption data from homes could be used to infer the behaviors and habits of home occupants through activity recognition or user profiling (Fan, 2017), which may lead to unfair service pricing, targeted advertising, or other personal security violations. Similarly, Electric Vehicles’ (EVs) charging metadata could be used to reveal private information about the owner such as their payment methods, preferred charging stations, and other locational and timing information that could be used to reconstruct the vehicle owner’s behaviors. The privacy of user data, even when used for statistical analysis or machine learning training processes, also needs to be carefully considered, as an individual’s private traits may still be vulnerable if their inclusion/exclusion greatly impacts the result or could be linked to a public dataset through cross-reference. The breach of user privacy also has severe impacts for organizations that store, transmit, or work on the data in the form of diminishing the public’s trust in them while potentially incurring legal consequences (e.g., fines and suspensions under the European Union General Data Protection Regulation, Health Insurance Portability and Accountability Act, etc.). Because of these risks, several privacy-preserving mechanisms are available to help organizations comply with privacy legislations and prevent the unauthorized and malicious use of user data. In light of these concerns, this report focuses on performing a computational review of privacy-preserving mechanisms that have received a significant amount of interest in literature. It specifically focuses on 1) homomorphic encryption, 2) zero-knowledge proofs, 3) differential privacy, and 4) federated learning. It is worth noting that although many of the methods presented in this document rely on cryptographic primitives, their intent is not to provide perfect secrecy, but rather to enable users to maintain privacy, and thus they shall not be compared or equated to other constructs that are aimed to address cybersecurity constructs.

24 POWER TRANSMISSION AND DISTRIBUTION↗

LA100 Equity Strategies. Chapter 10: Household Transportation Electrification

The LA100 Equity Strategies project integrates community guidance with robust research, modeling, and analysis to identify strategy options that can increase equitable outcomes in Los Angeles' clean energy transition. This chapter focuses on residential electric vehicle (EV) incentive programs and multimodal electrified transportation services as means to increase equity in household transportation electrification. Specifically, NREL modeled EV adoption and affordability under business-as-usual and enhanced low-income incentives scenarios and transportation-related energy burdens under multimodal electric travel scenarios, including shared EVs, e-bikes, and improved transit services. Based on our analysis and community guidance, we identified strategies for 1)?increasing equity in new and used light-duty EV adoption and EV charging infrastructure distribution, focused on household used EV ownership and home charging access and 2) affordable, time-efficient, and equitable multimodal electrified transportation options, specifically considering the non-vehicle-owning population. Research was guided by input from the community engagement process, and associated equity strategies are presented in alignment with that guidance.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Cold Climate Air-Source Heat Pump Demonstration and Analysis: Experimental Study on Cold Temperature Performance

Space heating energy is the largest end use for U.S. residential buildings, accounting for nearly 45% of residential building energy consumption nationwide, and approximately 51% of space heating energy is consumed on-site by combusting natural gas (EIA 2020a). In Colorado, approximately 53% of the statewide residential building energy consumption goes to space heating, 76% of which is provided by natural gas (EIA 2020a). Heat pumps are an efficient, electric alternative space heating technology and have been proven viable for decades. However, historically air-source heat pumps (ASHPs) have been limited to temperate climates because of (1) subpar performance at extremely cold outdoor air temperatures, (2) the need for air conditioning in summer months, and (3) the availability of natural gas in colder climates. Relatively recent advances to cold climate ASHP technology, which typically relies on inverter-driven, variable-speed compressors and variable-speed fans, have significantly improved low-temperature heat pump performance, enabling the technology to potentially save energy for many homes in cold climates.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗