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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Whatever happened to silicon carbide

The progress made in silicon carbide semiconductor devices in the 1955 to 1975 time frame is examined and reasons are given for the present lack of interest in the material. Its physical and chemical properties and methods of preparation are discussed. Fabrication techniques and the characteristics of silicon carbide devices are reviewed. It is concluded that a combination of economic factors and the lack of progress in fabrication techniques leaves no viable market for SiC devices in the near future.

Campbell, R. B.↗
NASA NTRS1982

Laboratory upwelled radiance and reflectance spectra of Kerr reservoir sediment waters

Reflectance, chromaticity, and several other physical and chemical properties were measured for various water mixtures of bottom sediments taken from two sites at Kerr Reservoir, Virginia. Mixture concentrations ranged from 5 to 1000 ppm by weight of total suspended solids (TSS) in filtered deionized tap water. The two sets of radiance and reflectance spectra obtained were similar in shape and magnitude for comparable values of TSS. Upwelled reflectance was observed to be a nonlinear function of TSS with the degree of curvature a function of wavelength. Sediment from the downstream site contained a greater amount of particulate organic carbon than from the upstream site. No strong conclusions can be made regarding the effects of this difference on the radiance and reflectance spectra. Near-infrared wavelengths appear useful for measuring highly turbid water with concentrations up to 1000 ppm or more. Chromaticity characteristics do not appear useful for monitoring sediment loads above 150 ppm.

Witte, W. G.↗
NASA NTRS1981

Requirements for optimization of electrodes and electrolyte for the iron/chromium Redox flow cell

Improved catalyzation techniques that included a pretreatment of carbon substrate and provided normalized carbon surface for uniform gold deposition were developed. This permits efficient use of different batches of carbon felt materials which initially vary significantly in their physical and surface chemical properties, as well as their electrochemical behavior. Further modification of gold impregnation technique gave the best performing electrodes. In addition to the linear sweep voltammetry, cyclic voltammetry was used to determine the effects of different activation procedures on the Cr(3)/Cr(2) Redox and H2 evolution reactions. The roles of carbon, gold and lead in the overall Redox cycle are identified. The behavior of the electrodes at both normal battery operating potentials and more extreme potentials is discussed preparing efficient and stable electrodes for the energy storage battery is implicated.

Jalan, V.↗
NASA NTRS1981

Studies of new perfluoroether elastomeric sealants

Channel and filleting sealants were developed successfully from cyano and diamidoxime terminated perfluoro alkylene ether prepolymers. The prepolymers were polymerized, formulated and tested. The polymers and/or formulations therefrom were evaluated as to their physical, mechanical and chemical properties (i.e., specific gravity, hardness, nonvolatile content, corrosion resistance, stress corrosion, pressure rupture resistance, low temperature flexibility, gap sealing efficiency, tensile strength and elongation, dynamic mechanical behavior, compression set, fuel resistance, thermal properties and processability). Other applications of the formulated polymrs and incorporation of the basic prepolymers into other polymeric systems were investigated. A cyano terminated perfluoro alkylene oxide triazine was formulated and partially evaluated. The channel sealant in its present formulation has excellent pressure rupture resistance and surpasses present MIL specifications before and after fuel and heat aging.

Basiulis, D. I.↗
NASA NTRS1981

Atmospheric structure of the outer planets from thermal emission data

Methods for determining atmospheric structure exploit the opacities provided by the collision induced H2 dipole and the nu4 fundamental of CH4. In addition to earth-based observations, useful measurements of thermal emission from Jupiter and Saturn have been or soon will be made by several spacecraft, with results cross-checked with independent radio occultaion results. For Uranus and Neptune, only a limited set of whole-disk earth-based data exists. All the outer planets show evidence for stratospheric temperature inversions; temperature minima range from about 105 K for Jupiter and 87 K for Saturn, to roughly 55 K for Uranus and Neptune. Remaining problems may be resolved by better quantitative understanding of gas and aerosol absorption and scattering properties, chemical composition, and non-LTE source functions. Ultimately, temperature structure results must be supplemented by quantitative energy equilibrium models which will allow some meaning to be given to the relationships between such characteristics as temperature, clouds, incident solar and planetary radiation, and chemical composition.

Orton, G. S.↗
NASA NTRS1983

Mineralogy and chemistry of planets and meteorites

The data collection and the interpretation with respect to the mineralogy of meteoritic and terrestrial samples are summarized. The key conclusion is that the Moon underwent a series of melting episodes with complex crystal-liquid differentiation. It was not possible to determine whether the Moon melted completely or only partially. The stage is now set for a systematical geochemical and geophysical survey of the Moon. Emphasis was moved to meteorites in order to sort out their interrelationships from the viewpoint of mineral chemistry. Several parent bodies are needed for the achondrites with different chemical properties. Exploration of Mars is required to test ideas based on the possible assignment of shergottites, nakhlites and chassignite to this planet. Early rocks on the Earth have properties consistent with a heavy bombardment and strong volcanic activity prior to 4 billion years ago.

Source record↗
NASA NTRS1983

Handbook of photothermal test data on encapsulant materials

Laboratory tests performed to characterize candidate encapsulation materials with respect to changes in their physical and chemical properties caused by photothermal aging are described. Several key material properties relating directly to material degradation and deterioration of performance were identified and were monitored as functions of aging conditions and time. A status report on accelerated testing activities is provided and experimental data are presented. It will be updated periodically as more data become available.

Liang, R. H.↗
NASA NTRS1982

Evolution of the Tharsis province of Mars - The importance of heterogeneous lithospheric thickness and volcanic construction

A new model for the origin and evolution of the Tharsis province that emphasizes that the topography of Tharsis may be produced largely by construction, rather than uplift, is proposed. Underlying the model is the premise that the elastic lithosphere of Mars was laterally heterogeneous early in Martian history; such heterogeneity is discernible later in Martian history from the variable tectonic response of the lithosphere to local surface loads. It is contended that the mechanism for the evolution of Tharsis described here led to permanent topographic and gravity highs and a greatly thickened crust in the Tharsis region. An important advantage of the model is that no anomalous dynamical or chemical properties need be sustained in the Martian mantle beneath Tharsis for billions of years. The mantle beneath Tharsis is thus seen as playing a passive rather than an active role in the regional volcanic and tectonic activity, much like the role of the mantle beneath major midocean ridges on earth.

Solomon, S. C.↗
NASA NTRS1983

Silicon nitride: A ceramic material with outstanding resistance to thermal shock and corrosion

The known physical, mechanical and chemical properties of reaction-sintered silicon nitride are summarized. This material deserves interest especially because of its unusually good resistance to thermal shock and corrosion at high temperatures. Two types are distinguished: reaction-sintered (porous) and hot-pressed (dense) Si3N4. Only the reaction-sintered material which is being produced today in large scale as crucibles, pipes, nozzles and tiles is considered.

Huebner, K. H.↗
NASA NTRS1984

Luneburg lens and optical matrix algebra research

Planar, as opposed to channelized, integrated optical circuits (IOCs) were stressed as the basis for computational devices. Both fully-parallel and systolic architectures are considered and the tradeoffs between the two device types are discussed. The Kalman filter approach is a most important computational method for many NASA problems. This approach to deriving a best-fit estimate for the state vector describing a large system leads to matrix sizes which are beyond the predicted capacities of planar IOCs. This problem is overcome by matrix partitioning, and several architectures for accomplishing this are described. The Luneburg lens work has involved development of lens design techniques, design of mask arrangements for producing lenses of desired shape, investigation of optical and chemical properties of arsenic trisulfide films, deposition of lenses both by thermal evaporation and by RF sputtering, optical testing of these lenses, modification of lens properties through ultraviolet irradiation, and comparison of measured lens properties with those expected from ray trace analyses.

Wood, V. E.↗
NASA NTRS1984

Space exposure of composite materials for large space structures (A0134)

The objective of this experiment is to evaluate the effects of the near-Earth orbital environment on the physical and chemical properties of laminated continuous-filament composites and composites resin films for use in large space structures and advanced spacecraft. The experiment is passive and occupies about one-half of a 6-in.-deep peripheral tray. Specimens of composite materials and polymeric and resin films are arranged above and below the experiment mounting plate to enable both exposure and nonexposure to sunlight. This provides a comparison of the effects of ultraviolet plus vacuum plus thermal cycling and those of vacuum plus thermal cycling on these materials. The experiment tray is thermally isolated from the Long Duration Exposure Facility structure to allow the material specimens to experience a wide range of thermal cycles. Tensile and compression specimens will be used to evaluate the laminated composite materials. A number of the specimens are precut and ready for testing after space exposure, whereas other specimens will be prepared from larger samples.

Wayne S Slemp↗
NASA NTRS1984

Effects of solar radiation on glasses

The effects of solar radiation and space environment on glasses in space flight by exposing glass specimens to the space environment was determined. The occurrence of optical, mechanical, and chemical property changes was analyzed. The property changes of samples receiving differing cumulative solar radiation exposure are compared.

Nichols, R. L.↗
NASA NTRS1984

Silicon nitride films deposited with an electron beam created plasma

The electron beam assisted chemical vapor deposition (EBCVD) of silicon nitride films using NH3, N2, and SiH4 as the reactant gases is reported. The films have been deposited on aluminum, SiO2, and polysilicon film substrates as well as on crystalline silicon substrates. The range of experimental conditions under which silicon nitrides have been deposited includes substrate temperatures from 50 to 400 C, electron beam currents of 2-40 mA, electron beam energies of 1-5 keV, total ambient pressures of 0.1-0.4 Torr, and NH3/SiH4 mass flow ratios of 1-80. The physical, electrical, and chemical properties of the EBCVD films are discussed.

Bishop, D. C.↗
NASA NTRS1984

No sulfur flows on Io

Physical and chemical properties of elemental sulfur are incompatible with the suggestion that the colored flows associated with volcanoes on Io are quenched unstable allotropes of sulfur. Either the volcanic flows are not sulfur, or some mechanism other than quenching is required to produce colored forms of sulfur in them. The properties of sulfur are unsuited to the production and survival of colored unstable allotropes on Io. The color of this object is probably due to some other material, possibly iron compounds.

Young, A. T.↗
NASA NTRS1986

Imide Cyclotriphosphazene/Hexafluoroisopropylidene Polymers

Useful physical and chemical properties observed in compounds obtained by thermally-induced melt polymerization of maleimido-phenoxy cyclotriphosphazenes linked through hexafluoroisopropylidene-diphthalimide groups. Polymers exhibit high strength, high thermal stability, and high char yields, and appear to be excellent candidates for fabricating composite materials.

Fohlen, G. M.↗
NASA NTRS1984

Chemical Signatures Associated with the Freshening of Northern Atlantic Waters Between 1972 and 1981

Further insight into the possible causes of the freshening of deep water in the northern Atlantic between the GEOSECS survey (1972) and the TTO survey (1981) is provided by measurements of dissolved silica and dissolved oxygen. As all the northern end member waters are low in dissolved silica content and high in dissolved oxygen content, the message carried by these chemical properties of silica has to do with the extent to which the waters in the northern Atlantic have mixed with the high silica content waters of Antarctic origin. A change in the degree and pattern of this intrusion is noted between the GEOSECS and TTO surveys.

Broecker, W. S.↗
NASA NTRS1983

Spectral reflectance of surface soils - A statistical analysis

The relationship of the physical and chemical properties of soils to their spectral reflectance as measured at six wavebands of Thematic Mapper (TM) aboard NASA's Landsat-4 satellite was examined. The results of performing regressions of over 20 soil properties on the six TM bands indicated that organic matter, water, clay, cation exchange capacity, and calcium were the properties most readily predicted from TM data. The middle infrared bands, bands 5 and 7, were the best bands for predicting soil properties, and the near infrared band, band 4, was nearly as good. Clustering 234 soil samples on the TM bands and characterizing the clusters on the basis of soil properties revealed several clear relationships between properties and reflectance. Discriminant analysis found organic matter, fine sand, base saturation, sand, extractable acidity, and water to be significant in discriminating among clusters.

Crouse, K. R.↗
NASA NTRS1985

Biochemical processes in sagebrush ecosystems: Interactions with terrain

The objectives of a biogeochemical study of sagebrush ecosystems in Wyoming and their interactions with terrain are as follows: to describe the vegetational pattern on the landscape and elucidate controlling variables, to measure the soil properties and chemical cycling properties associated with the vegetation units, to associate soil properties with vegetation properties as measured on the ground, to develop remote sensing capabilities for vegetation and surface characteristics of the sagebrush landscape, to develop a system of sensing snow cover and indexing seasonal soil to moisture; and to develop relationships between temporal Thematic Mapper (TM) data and vegetation phenological state.

Matson, P.↗