Defect-impurity relationships in electron- damaged silicon.
Defect impurity relation in electron damaged p-type silicon and electron irradiation effect on float zone n-type silicon
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Defect impurity relation in electron damaged p-type silicon and electron irradiation effect on float zone n-type silicon
ZnSe and ZnSeTe single crystals were grown by physical vapor transport (PVT) technique horizontally and vertically. The grown ZnSe and ZnSeTe single crystals were characterized by low temperature photoluminescence at 5 to 10 K using the 3.4 eV emission of an argon laser. The intensity of the sharp near band edge defect lines at 2.799, 2.783 eV and the intrinsic free exciton line at 2.802 eV were mapped on various crystal surfaces with different orientations to the gravitational field. The results show the effects of gravity vector orientation on the defect segregation. Comparison of the photoluminescence spectra of the ZeSe crystal before and after annealing in the Zn vapor shows that the 2.783 eV line of ZnSe crystal is related to the zinc vacancy. The photoluminescence spectra of the ternary ZnSeTe crystal were characterized by a single broad band from 2.2 to 2.4 eV, with a Full Width at Half Maximum (FWHM) of about 100 meV. The temperature dependence of the peak position and intensity were determined from 7 to 150 K.
The paper discusses structural defects in low-cost silicon sheets and their effect on the electronic properties related to solar cell performance. Experimental data are presented on the influence of grain boundaries on minority carrier diffusion length, impurity defect interaction, and variable surface recombination velocity. An analytical model of the effect of grain boundaries on solar cell performance is constructed based on these results.
The Magneto-Optic Imaging system is being used for the detection of defects in airframes and other aircraft structures. The system has been successfully applied to detecting surface cracks, but has difficulty in the detection of sub-surface defects such as corrosion. The intent of the grant was to understand the physics of the MOI better, in order to use it effectively for detecting corrosion and for classifying surface defects. Finite element analysis, image classification, and image processing are addressed.
Perception of oculogravic illusion in normal and labyrinthine-defective subjects related to water immersion
Motion sickness susceptibility during parabolic flight, comparing weightlessness and hypergravity effects on normal and labyrinthine-defective subjects
Lithium counterdoped n+/p silicon solar cells were irradiated with 1 MV electrons and their post irradiation performance and low temperature annealing properties were compared to that of the 0.35 ohm cm control cells. Cells fabricated from float zone and Czochralski grown silicon were investigated. It was found that the float zone cells exhibited superior radiation resistance compared to the control cells, while no improvement was noted for the Czochralski grown cells. Room temperature and 60 C annealing studies were conducted. The annealing was found to be a combination of first and second order kinetics for short times. It was suggested that the principal annealing mechanism was migration of lithium to a radiation induced defect with subsequent neutralization of the defect by combination with lithium. The effects of base lithium gradient were investigated. It was found that cells with negative base lithium gradients exhibited poor radiation resistance and performance compared to those with positive or no lithium gradients; the latter being preferred for overall performance and radiation resistance.
New applications for high current, low energy hydrogen ion implants on single crystal and polycrystal silicon grain boundaries are discussed. The effects of low energy hydrogen ion beams on crystalline Si surfaces are considered. The effect of these beams on bulk defects in crystalline Si is addressed. Specific applications of H+ implants to crystalline Si processing are discussed. In all of the situations reported on, the hydrogen beams were produced using a high current Kaufman ion source.
The variation of the energy release rate (ERP) at the tip of a crack penetrating an elastic inclusion is analyzed using an approach involving modeling the random array of microcracks or other defects by an elastic inclusion with effective elastic properties. Computations are carried out using a finite element procedure. The eight-noded isoparametric serendipity element with the shift of the midpoint to the quarter-point is used to simulate the singularity at the crack tip, and the crack growth is accommodated by implementing a mesh regeneration technique. The ERP values were calculated for various crack tip positions which simulate the process of the crack approaching and penetrating the inclusion.
This research study is investigating the effects of a microgravity environment during the crystal growth of selected II-VI semiconducting alloys on their compositional, metallurgical, electrical and optical properties. The on-going work includes both Bridgman-Stockbarger and solvent growth methods, as well as growth in a magnetic field. The materials investigated are II-VI, Hg(1-x)Zn(x)Te, and Hg(1-x)Zn(x)Se, where x is between 0 and 1 inclusive, with particular emphasis on x-values appropriate for infrared detection and imaging in the 5 to 30 micron wavelength region. Wide separation between the liquidus and solidus of the phase diagrams with consequent segregation during solidification and problems associated with the high volatility of one of the components (Hg), make the preparation of homogeneous, high-quality, bulk crystals of the alloys an extremely difficult nearly an impossible task in a gravitational environment. The three-fold objectives of the on-going investigation are as follows: (1) To determine the relative contributions of gravitationally-driven fluid flows to the compositional redistribution observed during the unidirectional crystal growth of selected semiconducting solid solution alloys having large separation between the liquidus and solidus of the constitutional phase diagram; (2) To ascertain the potential role of irregular fluid flows and hydrostatic pressure effects in generation of extended crystal defects and second-phase inclusions in the crystals; and, (3) To obtain a limited amount of "high quality" materials needed for bulk crystal property characterizations and for the fabrication of various device structures needed to establish ultimate material performance limits. The flight portion of the study was to be accomplished by performing growth experiments using the Crystal Growth Furnace (CGF) manifested to fly on various Spacelab missions.
The effect of thermal diffusively on the defect detectability in Carbon/Epoxy composite panels by transient thermography is presented in this paper. A series of Finite Element Models were constructed and analyzed to simulate the transient heat transfer phenomenon during Thermographic Non-destructive Evaluation (TNDE) of composite panels with square defects. Six common carbon fibers were considered. The models were built for composites with various combinations of fibers and volumetric ratios. Finite Element Analysis of these models showed the trends of the detectable range and the maximum thermal contrast versus the thermal diffusivity of various composites. Additionally, the trends of defect size to depth ratio and the thermal contrast has been investigated.
A large number of essential cellular processes occur at the interfaces between water and membranes. The selectivity and dynamics of these processes are largely determined by the structural and electrical properties of the water-membrane interface. We investigate these properties by the molecular dynamics method. Over the time scales of the simulations, the membrane undergoes fluctuations described by the capillary wave model. These fluctuations produce occasional thinning defects in the membrane which provide effective pathways for passive transport of ions and small molecules across the membrane. Ions moving through the membrane markedly disrupt its structure and allow for significant water penetration into the membrane interior. Selectivity of transport, with respect to ionic charge, is determined by the interfacial electrostatic potential. Many small molecules. of potential significance in catalysis, bioenergetics and pharmacology, are shown to bind to the interface. The energetics and dynamics of this process will be discussed.
The many challenges with 0201 passive component assembly can be attributed to the solder paste volume, pad design, aperture design, board finish, type of solder paste, pick-and-place, and reflow profile. A Design-of-Experiment (DOE) study was carried out to investigate the effects of these parameters on assembly defects and reliability.
An advanced model turbofan was tested in the NASA Glenn 9- by 15-Foot Low Speed Wind Tunnel (9x15 LSWT) to explore far field acoustic effects associated with rotor Trailing-Edge-Blowing (TEB) for a modern, 1.294 stage pressure ratio turbofan model. The TEB rotor (Fan9) was designed to be aerodynamically similar to the previously tested Fan1, and used the same stator and nacelle hardware. Fan9 was designed with trailing edge blowing slots using an external air supply directed through the rotor hub. The TEB flow was heated to approximate the average fan exit temperature at each fan test speed. Rotor root blockage inserts were used to block TEB to all but the outer 40 and 20% span in addition to full-span blowing. A configuration with full-span TEB on alternate rotor blades was also tested. Far field acoustic data were taken at takeoff/approach conditions at 0.10 tunnel Mach. Far-field acoustic results showed that full-span blowing near 2.0% of the total flow could reduce the overall sound power level by about 2 dB. This noise reduction was observed in both the rotor-stator interaction tones and for the spectral broadband noise levels. Blowing only the outer span region was not very effective for lowering noise, and actually increased the far field noise level in some instances. Full-span blowing of alternate blades at 1.0% of the overall flow rate (equivalent to full-span blowing of all blades at 2.0% flow) showed a more modest noise decrease relative to full-span blowing of all blades. Detailed hot film measurements of the TEB rotor wake at 2.0% flow showed that TEB was not every effective for filling in the wake defect at approach fan speed toward the tip region, but did result in overfilling the wake toward the hub. Downstream turbulence measurements supported this finding, and support the observed reduction in spectral broadband noise.
For directly imaging exoplanets, NASA is considering space mission designs that use an external occulter as the principal starlight suppression system. These occulter designs range in diameter from 16 to 40 meters and separation distance from 8,000 to 60,000 kilometers for telescopes with primary diameters of 0.5 to 4 meters. Occulter shapes are solutions to an optimization problem which seeks to maximize suppression in the shadow subject to constraints such as size, separation, and wavelengths. These designs are based on scalar diffraction theory and must be verified experimentally to demonstrate predicted on-orbit performance. Due to the large sizes and separations involved the experiment must be scaled to lab size. We are currently expanding the existing experimental test-bed at Princeton to enable scaling of occulters operating at flight Fresnel sizes. Here we examine the effect on suppression performance of edge defects and their scaling to test-bed size.
The gust response of a coupled hingeless rotor-fuselage system is studied in both hover and forward flight. Each rotor blade undergoes flap bending, lag bending, and torsional deflections. The blades are discretized into beam elements, each with fifteen nodal degrees of freedom. The fuselage is permitted three translational (vertical, longitudinal, and lateral) and two rotational (pitch and roll) degrees of freedom. The formulation considers a three-dimensional gust field wherein each gust velocity component can have an arbitrary variation in space and time. Aerodynamic loads are obtained using quasisteady strip theory. Wake-induced effects are introduced through dynamic inflow modeling. Dynamic stall and reverse flow effects are also included. Equations governing the rotor-fuselage gust response are linearized about the vehicle propulsive trim state and the blade steady-state defected positions, and solved by time integration. The effects of several parameters on the helicopter gust response are illustrated, including dynamic inflow, lag stiffness, forward speed, gust profile, gust penetration rate, and gust velocity direction.
Oxygen and carbon are the predominant impurities in Czochralski-grown silicon. The incorporation of oxygen and carbon during crystal growth is reviewed and device effects are discussed. Methods for controlling oxygen and carbon incorporation during crystal growth are discussed and results supporting a segregation coefficient of k=0.5 for oxygen are presented. The nucleation and precipitation behavior of oxygen is complex. Temperature and doping level effects which add insight into the role of point defects in the nucleation process are highlighted. In general, precipitation is found to be retarded in N+ and P+ silicon. The types and quantities of defects resulting from the oxygen precipitates is of interest as they are technologically useful in the process called intrinsic gettering. A comparison is made between the available defect sites and the quantities of metallic impurities present in a typical wafer which need to be gettered. Finally, a discussion of the denuded-zone, intrinsic-gettered (DZ-IG) structure on device properties is presented.
Models for connecting two or three carbon nanotubes (CNT) using topological defects (i.e., pentagons and heptagons) are presented for the characterization of experimentally observed L, T and Y CNT junctions. The effects of the separation and orientation of the topological defects on the structures and energetics of these junctions are investigated using the nonlocal density function theory (DFT) and semi-empirical molecular orbital (AM1) calculations, and the Brenner empirical potential molecular mechanics simulations. The potential applications of L, Y and T CNT junctions in nanoelectronic devices are also discussed.