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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13

Fuel Properties and Kinetics

The Co-Optimization of Fuels and Engines (CoOptima) program is focused on a two-pronged approach to develop new, lower net-carbon fuels and advanced engine technologies in tandem. This effort brings nine national labs and several university and industry partners together to simultaneously identify new fuel candidates and to further engine technology development in the light-, medium-, and heavy-duty vehicle sectors with a focus on fuel economy and emission reduction. The fuel properties and kinetics project is aimed at achieving a better understanding of fuel property kinetics and how they impact engine performance such that more efficient and lower emitting engines can be made a reality. Several promising biofuel candidates were identified through tiered screening approaches and were evaluated utilizing unique bench-scale measurement techniques. Kinetic models were developed to describe autoignition and soot pre-cursor formation mechanisms to identify the most promising candidates that advanced various combustion strategies.

ADVANCED PROPULSION SYSTEMS↗

Observation of Current-Driven Features of 2.5 Mev Ion Bunch With Complete and Efficient 5D Measurements at the SNS Beam Test Facility

The SNS Beam Test Facility research program is focused detailed studies of beam distributions for medium-energy ion beams, with the goal of reconstructing realistic 6D bunch distributions to enable halo prediction. For complete characterization of the initial distribution, scan time scales exponentially with scan dimension. Currently, a full 6D measurement with ~10 points across most dimensions requires 30 hours. However, measurement of the 5D distribution f(x, x’,y,y’,w) can be done very rapidly using a hybrid slit/screen method. This approach requires ~4 hours to obtain at least 32 points/dimension, with very high resolution (0.5 keV) in the energy distribution. This presentation reports on the approach and results for 5D characterization of the initial RFQ-formed bunch. This includes higher-resolution views of previously reported transverse-longitudinal dependence and additional interplane dependencies that were not previously reported.

Ruisard, Kiersten↗

Applications of Cementitious Materials within the DOE Complex - 17548

Cementitious materials are used in a variety of ways for the containment, treatment and disposal of waste. This document explores some of these applications and provides a review of how cementitious materials have been used across the Department of Energy (DOE) complex. The intent is to highlight cementitious waste formulations, installations, experimental work, and modeling efforts supported by a variety of DOE programs. Further focus is provided regarding how/where cementitious materials are used for: waste stream treatment, production of containment structures, closure of tanks, in-situ decommissioning of reactors, and environmental restoration. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Using EPA's Risk Assessment Tools for Superfund When Addressing Removal Actions and Late-Phase Response to Terrorist Attacks - 18228

EPA's Office of Superfund Remediation and Technology Innovation (OSRTI) has three internet based calculators, or risk assessment models, for developing risk based Preliminary Remediation Goals (PRGs) for radioactively contaminated CERCLA sites. These PRG calculators are EPA's recommended methodology for developing risk-based concentrations for remedial actions for soil and water (PRG), inside buildings (BPRG), and outside hard surfaces (SPRG). EPA has three equivalent calculators for dose assessment, which are the Dose Compliance Concentration (DCC) calculator for soil and water, inside buildings (BDCC), and outside hard surfaces (SDCC). The three PRG calculators also include default PRG tables provided for each of the calculators showing concentrations corresponding to 1 x 10-6 when the calculators are run using all of their default parameters. This presentation will provide information on how users may employ these tools beyond their original intended uses in the remedial program, to develop risk based cleanup levels during the late-phase portion of an actual response after a Radiological Dispersal Device (RDD) or Improvised Nuclear Device (IND) terrorist attack or a major accident at a Nuclear Power Plant (NPP), or a simulation during an exercise of an RDD/IND/NPP event, they may want to run the calculator using more site-specific data. This presentation will provide information on how users may employ these tools beyond their original intended uses in the remedial program, and focus on some of the more conservative default parameters that are likely candidates for replacement by site-specific information. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

FY24 Laboratory Directed Research and Development Annual Report

The Laboratory Directed Research and Development (LDRD) program yields foundational scientific research and development (R&D) essential to growing SRNL’s core competencies, in alignment with SRNL’s Strategic Plan to provide long-term benefits to the Department of Energy (DOE), the National Nuclear Security Administration (NNSA), and other customers and stakeholders. Five strategic goals are outlined in SRNL’s strategic plan: 1) Provide applied science and engineering for EM’s active clean-up sites and LM’s post closure management sites 2) Provide science-based solutions for gaps identified in nonproliferation strategic vision and support the government in activities impacting national security 3) Lead Science, Technology & Engineering as the central technical authority for processing tritium loaded reservoirs and support production of plutonium pits 4) Align science and energy security programs by focusing modern modeling, simulation, and data analytics tools on materials engineering and performance applications 5) Build a workforce for the future

Clark, Sue [Savannah River National Laboratory (SR↗

Lessons learned from the development and implementation of a workforce training curriculum for advanced controls for high performance HVAC systems

Over the past decade, academic research on advanced controls has slowly transitioned into new software platforms, giving rise to various companies developing and deploying these innovative products, including solutions for light commercial HVAC systems. However, the current workforce remains widely unprepared to install, maintain and operate these systems, particularly complex software-based control platforms, as most workforce training programs still focus on traditional building automation for large commercial buildings. This paper presents the development and piloting of curriculum for three key types of professionals: ● Technicians (trade-level): installing and maintaining modern high-performance HVAC systems and controls ● Programmers (undergrad-level): developing and implementing advanced controls ● Engineers and energy professionals (undergrad/grad-level): managing and evaluating system performance We share details of the material developed including training videos, open-source software, instruction manuals. We also present the results of a pilot implementation of the training materials with real students.

Casillas, Armando↗

Programs Enabling Deep Technology Transfer from National Labs

To maximize the technology transfer potential, it is important to create an ecosystem for the inventors to adapt the technologies developed for basic science to successful commercial ventures. In this white paper we present a brief overview of technology transfer programs at high energy physics (HEP) laboratories with a focus on the programs at Fermilab and KEK, and identify opportunities and recommendations for increasing partnerships and commercialization at HEP-centric laboratories.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

The Dynamics and Thermodynamics of Gaseous Molecule-Ions. Final report

The overall objectives of this research effort were to expand the capabilities of spectroscopic and ion chemistry tools for the structural characterization of polyatomic ions of relevance to the broad mission of the Department of Energy. Mass spectrometry currently plays an important role in virtually all of the molecular sciences by virtue of the value of the accurate measurement of mass and the structural information that can be derived from various structural probes based on, for example, ion chemistry, ion mobility, and ion spectroscopy. Mass spectrometry has long played important roles in supporting the missions of the Department of Energy and its predecessor agencies, particularly in the area of isotopic analysis of nuclides. Molecular mass spectrometry has played increasingly important roles is many aspects of the production and use of energy as the nation has diversified its energy portfolio. There is an ongoing need for the expansion of the measurement capabilities associated with molecular mass spectrometry that involves both technological developments as well as improved understanding of the chemical and physical processes that take place upon ionization and ion analysis in a mass spectrometer. Advances in mass spectrometry have impacted science broadly and further advances will be required to meet the needs of current energy and environmental research. This program has historically focused on the structural characterization of polyatomic ions, usually within the context of a tandem mass spectrometry experiment. A wide variety of physical and chemical processes can take place within a mass spectrometer and advantage can be taken of such processes to enhance the quality and quantity of information that can be derived for a given chemical system of interest. For example, ions can undergo interactions with neutral molecules/atoms, light, surfaces, electrons, or oppositely charged ions. The outcomes of all such interactions can be sensitive to the structures of the ions and are therefore candidates for probes of ion structure. This program has historically focused on the chemistry and physics associated with ion/neutral interactions at both low and high translational energies, and ion/ion reactions. The former area has involved the study of ion/molecule reactions at thermal energies and the extensive study of collisional activation under a wide variety of conditions. A major area of emphasis has been collisional activation in electrodynamic ion traps. The study of gas-phase ion/ion reactions within the context of tandem mass spectrometry was initiated in this program and has grown to be a major research area in this group. Most of the focus in ion/ion chemistry has been on proton transfer and electron transfer reactions and some of the work in the previous budget period was directed, in particular, to fundamental aspects of electron transfer. Recently, the discovery of selective covalent ion/ion reactions has opened up new vistas for research that will expand significantly the capabilities of tandem mass spectrometry for the structural characterization of polyatomic ions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hanford Single-Shell Tank and Double-Shell Tank Integrity Programs - 16390

Waste at Hanford is stored in 149 single-shell tanks and 28 double-shell tanks. Concerns related to aging radioactive waste storage facilities throughout the DOE complex led to Brookhaven National Laboratory (BNL) developing guidelines for structural integrity programs for tank systems. The committee of experts who developed these guidelines is commonly known as the Tank Structural Integrity Panel (TSIP). The DOE has subsequently adopted these guidelines, and requires site operators to have a program consistent with them. The Double-Shell Tank (DST) integrity is maintained with a variety of activities such as ultrasonic and visual inspections, chemistry controls, corrosion monitoring and structural analyses methods. In October 2012, Washington River Protection Solutions, LLC (WRPS) determined that the primary tank of 241-AY-102 was leaking. WRPS contracted a panel of experts from industry and academia to provide advice and recommendations for the DST Integrity Program. The panel focused on three concerns: - No Early warning - Determine why the existing DST Integrity Program did not predict a primary tank failure or provide early warning of the pending failure. - Program improvements - Recommend activities to either predict a primary tank failure or increase the probability of early warning. - Forensic recommendations - The panel provided additional recommendations regarding forensic assessment of Tank 241-AY-102 (AY-102) to facilitate a conclusion on why the leak occurred. WRPS has prepared a response to the concerns of the panel coupled with recommendations for project action to strengthen the DST Integrity Program [4]. The purpose of this DST Integrity Improvement Plan is to translate the recommendations to specific project activities that are technically and practically responsive. To improve the understanding of the Single-Shell Tank (SST) integrity, WRPS, the Department of Energy-Office of River Protection tank operations contractor, developed an enhanced Single-Shell Tank Integrity Project (SSTIP) in 2009. An expert panel on SST integrity, consisting of various subject matter experts in industry and academia, was created to provide recommendations supporting the development of the project. This panel developed 33 recommendations in four main areas of interest: structural integrity, liner degradation, leak integrity and prevention, and mitigation of contamination migration. In late 2010, seventeen of these recommendations were used to develop the basis for the M-45-10-1 Change Package for the Hanford Federal Agreement and Compliance Order, also known as the Tri-Party Agreement. The change package identified two phases of work for SST integrity. The initial phase, which was completed in 2015, was focused on efforts to envelope the integrity of the tanks. It was divided into two primary areas of investigation: structural integrity and leak integrity. If necessary, based on the outcome from the initial work, a second phase would be focused on further definition of the integrity of the tanks and liners. The two combined phases are designed to support the formal integrity assessment of the Hanford SSTs in 2018 by an Independent Qualified Registered Professional Engineer. This paper will summarize the current status of the DST and SST Integrity Programs and discuss the ongoing efforts to improve these programs. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

OPTD: Out-of-Pile Transient Database

The DOE Advanced Reactor Technology program has supported knowledge preservation efforts to recover and preserve fuel data from the US sodium cooled fast reactor (SFR) program. Efforts have focused on establishing databases of experimental data generated during the Integral Fast Reactor program (at EBR-II, FFTF, and TREAT) as well as during related out-of-pile examinations of the fuel irradiated at EBR-II. The information in these databases is essential to support further development and licensing activities for advanced fast reactor designs. OPTD, a newly-created database of out-of-pile furnace transient tests on metallic fuel, includes records of 62 tests on irradiated fuel pins conducted in furnace apparatuses constructed in the Alpha-Gamma Hot Cell Facility at ANL. Record discovery is ongoing, and at present, the database includes hundreds of documents describing these tests and related results. Access is currently available to Department of Energy researchers and can be extended to members of industry and the public as the content is approved for distribution. This report describes the out-of-pile furnace testing program, the content available in the database, and the structure of the web-accessible interface.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Summary Report for Out-of-Pile Transient Testing Database Development

The DOE Advanced Reactor Technology program has supported knowledge preservation efforts to recover and preserve fuel data from the US sodium cooled fast reactor (SFR) program. Efforts have focused on establishing databases of experimental data generated during the Integral Fast Reactor program (at EBR-II, FFTF, and TREAT) as well as during related out-of-pile examinations of the fuel irradiated at EBR-II. The information in these databases is essential to support further development and licensing activities for advanced fast reactor designs. OPTD is a database of out-of-pile furnace transient tests on metallic fuel. It includes records of 62 tests on irradiated fuel pins conducted in furnace apparatuses constructed in the Alpha-Gamma Hot Cell Facility at ANL. This report describes efforts during FY19 to improve visibility and access, expand the content of, and improve the user experience with the FIPD and OPTD databases.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Infrared Metamaterials

This document serves as the final report for the AFRL SBIR Program "Directionally-Tailored Infrared Emission and/or Transmission" AF 1 O-BT30 The focus of this program was in the development and design of a thermal emission surface with thermal emission directed away from broadside in the L WIR band. In the report, a basic overview is provided covering past research efforts in thermal emission surfaces and the fundamental science of directional emitters. Multiple sets of designs are investigated as candidate directional emission surfaces: dark element, image, and end-fire linear array, broadside emitter, and waveguide emitter. Based on program results, both the broadside emitter and waveguide emitter designs appear to meet the needs of the AF directional emission requirements. These designs offer a range of directional emission behavior (controllable emission beamwidth and bandwidth) and scale well to mass production. The designs require additional environmental testing, but appear to be suitable for space application as well. All goals of the program appear to have been met and the team is looking forward to future development.

36 MATERIALS SCIENCE↗

External Access to the TREXR Database

The DOE Advanced Reactor Technology program has supported knowledge preservation efforts to recover and preserve fuel data from the US sodium cooled fast reactor (SFR) program. Efforts have focused on establishing databases of experimental data gene rated during the Integral Fast Reactor program (at EBR-II, FFTF, and TREAT) as well as during related out-of-pile examinations. The information in these databases is essential to support further development and licensing activities of advanced fast reactor designs.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Energy Program Innovation Cluster for Equity and Health in Grid-Interactive Efficient Buildings (Final Technical Report)

The EPIC Buildings program was created to target Central New York’s (CNY) Energy Program Innovation Cluster, focused on developing energy hardware innovations for next-generation grid-interactive efficient buildings (GEB). The goals of the program were to establish and grow a sustainable regional innovation cluster for GEB in CNY and support the ambitious transition to achieve net-zero emissions by 2050.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Chapter 13: Assessing Persistence and Other Evaluation Issues Cross-Cutting Protocol. The Uniform Methods Project: Methods for Determining Energy Efficiency Savings for Specific Measures

Addressing other evaluation issues that have been raised in the context of energy efficiency programs, this chapter focuses on methods used to address the persistence of energy savings, which is an important input to the benefit/cost analysis of energy efficiency programs and portfolios. In addition to discussing 'persistence' (which refers to the stream of benefits over time from an energy efficiency measure or program), this chapter provides a summary treatment of these issues -Synergies across programs -Rebound -Dual baselines -Errors in variables (the measurement and/or accuracy of input variables to the evaluation).

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Energy Efficient Clothes Dryer with IR Heating and Electrostatic Precipitator

The project goal was to develop a revolutionary energy saving technology for residential clothes drying. The team developed an IR (infrared) heating system and NESP (Nebulizer and Electro-Static Precipitator) for integration into a ventless clothes dryer. The proposed technology addresses two of the major inefficiencies in current electric vented dryers by providing effective energy transfer for the removal of the water and recapture of the vapor latent heat. The IR heaters operating in the mid wave (2.5-10um) are very efficient as they target the 3-micron peak absorption of the water molecule. This allows direct energy absorption, unlike conventional element heaters where heat is transferred by convection. The low power NESP removes water vapor from the exhausted stream and recaptures the latent heat in the ESP (Electro-Static Precipitator) exchanger section. This allows the warm dry air to be recirculated back into the drum for additional efficiency savings. The remaining majority of the dryer hardware stays the same. Summing the efficiency gain from the two subcomponents we anticipated the EF (Efficiency Factor) to exceed the goal of 4.04. EF is obtained by dividing the weight (lbs) of water removed by the energy (kWhr) used, where the test load size is 8.45 lbs of bone dry clothing wetted to 57.5% or 4.8lbs of water, and dried to a remaining moisture content of 2.5-5%. Additional benefits include not having to recondition (heat or cool) the large amounts of make-up air to replace the air exhausted by a vented dryer. It was anticipated that the NESP/heat exchanger would be the most challenging and highest risk element in the program. Therefore, the team focused their efforts during Phase 1 of the program on the design, construction, testing, and optimization of the NESP/heat exchanger. At the end Phase 1, the team compared the performance of the NESP/heat exchanger with the system level requirements and made a Go/No-Go decision on proceeding with the second portion of the program. Phase 2 of the program was structured to develop the IR heating system and then integrate it and the NESP/heat exchanger into a residential clothes dryer prototype for final testing. The proposed technology utilizes heat recovery which is known to have the biggest impact on dryer efficiency. The two current mainstream recovery approaches are air to air exchangers and heat pump condenser systems. Air to air exchanges can be very efficient but require large surface areas which are prone to fouling from uncaptured lint. Dryers based on heat pump condenser recovery systems have shown efficiency improvements of 20–60% and are commercially available. The issue with a heat pump condenser approach is the added cost, as typical prices are twice that of standard vented dryers and they are only available in small to medium capacities. The energy factor (EF) for these systems is 5.50 to 6.88 pounds/kWh compared to conventional dryers at 2.75 to 3.67 pounds/kWh. The efficiency improvements for the proposed technology come from the use of IR heating and the NESP. As the concept is in its infancy, and these improvements were difficult to predict without experimental data, assumptions were made based on available literature. IR radiant drying times, when compared to convection, are typically 30% less. This is a result of the fact that radiant energy heats directly and is absorbed at and below the surface, unlike convection heating, that must conduct the heat through the boundary film of air at the clothes surface and rely on wicking of the moisture to the surface. The second area of improvement comes from the NESP. The NESP operation is as follows: 1. Highly charged, micron sized, droplets of water are injected into the dryer exhaust by the Nebulizer. 2. These charged droplets attract water molecules and continue to grow in size, until losing their charge. During this process, latent heat is rejected back into the air stream. 3. The large droplets enter the ESP, where they are recharged and drawn to the ESP wall, to be extracted at the bottom of the ESP. The warm dry air is then recirculated back into the dryer. The proposed technology, at the time of the proposal submission was estimated to have an EF of 4.79. At program completion we have designed, built, tested, integrated and optimized the proposed technologies into a prototype “high efficiency” residential clothes dryer. Testing of the integrated prototype dryer provided insight into the technical effectiveness and economic feasibility of the proposed technologies. The program has the potential of greatly impacting energy savings. The predicted EF of the proposed technology is 4.79, yielding an energy savings of 42% when compared to conventional electric vented dryers. Given there are approximately 84 million dryers in the US consuming ~64 billion kWh per year, a net savings of 27 billion kWh per year or 0.092 quads could be realized. Since the dryer is not vented, make up air from the room is not needed, adding an additional savings of ~1kWh per load, or 23.8 billion kWh per year. In addition, it is envisioned that the proposed ESP, when successful, would potentially find applications in industrial and residential dehumidification.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Reflecting Sunlight: Recommendations for Solar Geoengineering Research and Research Governance

The National Academies of Sciences, Engineering, and Medicine (NASEM) report "Reflecting Sunlight: Recommendations for Solar Geoengineering Research and Research Governance" focused on three atmospheric-based Solar Geoengineering strategies: Stratospheric Aerosol Injection, Marine Cloud Brightening, Cirrus Cloud Thinning. The study recommends that a national (and internationally-coordinated) Solar Geoengineering research program be established and coordinated by the U.S. Global Change Research Program—with a focus on developing information needed by decision makers, not advancing a path to deployment. The study recommends a detailed framework for governance of this research, at both national and international levels. The study also recommends a detailed research agenda for this program, encompassing over a dozen transdisciplinary research topics that can be loosely grouped into the categories of (i) technical dimensions and impacts, (ii) social dimensions, and (iii) context and goals for solar geoengineering research itself.

54 ENVIRONMENTAL SCIENCES↗

Microphysical-macrophysical interactions in low cloud systems over the Eastern North Atlantic

How low clouds over the oceans respond to changes in atmospheric greenhouse gases and aerosol particles is poorly understood. Climate model disagreement in these responses limits the accuracy of predictions of future climate. Processes governing the behavior of marine low cloud need to be improved in models and comprehensive long-term observations provide important constraints. Cloud structure and impacts on climate are shaped by processes operating on a wide range of time and space scales, which interact to modulate cloud dynamics, boundary layer structure, and precipitation. The Atmospheric Radiation Measurement (ARM) Eastern North Atlantic (ENA) site at Graciosa Island (Azores, 28°W 39°N) began taking measurements in late 2013 to address the need for comprehensive cloud, aerosol, and meteorological observations in a remote marine low cloud environment. The site straddles the boundary between the subtropical and midlatitude climate zones in the eastern North Atlantic and experiences a great diversity of meteorological and cloud conditions. In addition, the ENA site is downwind of the North American continent and is periodically impacted by continental aerosol particles transported there on the prevailing winds. In response to a 2014 proposal call, our team (ENA Site Science Team) laid out a strategy to accelerate research focused on understanding the multi-scale interactions that shape cloud properties by maximizing the utility of the observational capabilities of the ENA site. The proposed work aligned with the scientific directions of the ASR Working Groups. The team, together with collaborators, conducted a program of research focused upon multi-scale cloud processes. The team worked with scientists both within and outside the Atmospheric System Research (ASR) program, and with the ARM infrastructure to ensure that the full potential of the ENA site is realized. The suite of instruments at the ENA site has been increasing since the site’s inception and is now essentially complete. In 2019, we laid out a two-year extension of the research, and were granted an extension of the Site Science award.

54 ENVIRONMENTAL SCIENCES↗