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Advanced Curation Preparation for Mars Sample Return and Cold Curation

NASA Curation is tasked with the care and distribution of NASA's sample collections, such as the Apollo lunar samples and cometary material collected by the Stardust spacecraft. Curation is also mandated to perform Advanced Curation research and development, which includes improving the curation of existing collections as well as preparing for future sample return missions. Advanced Curation has identified a suite of technologies and techniques that will require attention ahead of Mars sample return (MSR) and missions with cold curation (CCur) requirements, perhaps including comet sample return missions.

Fries, M. D.↗

The NASA OSIRIS-REx Sample Catalog: Samples Returned from Investigators

OSIRIS-REx is a sample return mission that collected carbon-rich material from B-type asteroid Bennu. After landing on September 24th, 2023, the science canister was transported to NASA Johnson Space Center (JSC) in Houston, Texas where it was opened and samples were processed by the curation team in pristine sample nitrogen gloveboxes. As the sample analysis phase of the OSIRIS-REx mission concludes, the Sample Analysis Team (SAT) has returned the majority of mission samples to NASA JSC curation and will return the remaining samples on a defined timetable. The curation team processed and documented as many of these samples as possible to include in the spring 2026 catalog update and are steadily working to process hundreds of more samples to include in the fall 2026 catalog update.

OSIRIS-REx↗

International cooperation for Mars exploration and sample return

The National Research Council's Space Studies Board has previously recommended that the next major phase of Mars exploration for the United States involve detailed in situ investigations of the surface of Mars and the return to earth for laboratory analysis of selected Martian surface samples. More recently, the European space science community has expressed general interest in the concept of cooperative Mars exploration and sample return. The USSR has now announced plans for a program of Mars exploration incorporating international cooperation. If the opportunity becomes available to participate in Mars exploration, interest is likely to emerge on the part of a number of other countries, such as Japan and Canada. The Space Studies Board's Committee on Cooperative Mars Exploration and Sample Return was asked by the National Aeronautics and Space Administration (NASA) to examine and report on the question of how Mars sample return missions might best be structured for effective implementation by NASA along with international partners. The committee examined alternatives ranging from scientific missions in which the United States would take a substantial lead, with international participation playing only an ancillary role, to missions in which international cooperation would be a basic part of the approach, with the international partners taking on comparably large mission responsibilities. On the basis of scientific strategies developed earlier by the Space Studies Board, the committee considered the scientific and technical basis of such collaboration and the most mutually beneficial arrangements for constructing successful cooperative missions, particularly with the USSR.

Levy, Eugene H.↗

The Importance of Contamination Knowledge - Insights into Mars Sample Return

The Astromaterials Acquisition and Curation Office at NASA Johnson Space Center (JSC), in Houston, TX (henceforth Curation Office) manages the curation of all past, present, and future extraterrestrial samples returned by NASA missions and shared collections from international partners, preserving their integrity for future scientific study while providing the samples to the international community in a fair and unbiased way. The Curation Office also curates all reference and witness materials for each mission (e.g., flight and non-flight hardware coupons; lubricants; non-flight, flight-like, and flown witness plates). These reference and witness materials provide the scientific community with the fundamental ability to reconstruct the contamination/alteration history of the sample collection through the course of the mission, with the overall goal of strengthening the scientific conclusions drawn from the study of returned materials. The information gained from characterizing the physical, biological, inorganic, and organic chemical properties of reference and witness materials is defined as the Contamination Knowledge (CK) of the sample collection. Unlike the data collected for Contamination Control (CC) and Planetary Protection (PP), CK is exclusively concerned with preserving reference and witness materials for study by future scientists upon sample return. Although CC and PP data collected for sample integrity and forward contamination purposes can be complementary to CK, they are two separate data sets with distinct objectives. A robust collection of samples for CK is necessary to allow the extraterrestrial material in a returned sample to be distinguished from terrestrial contamination. Traditionally CK is utilized by sample scientists in order to accomplish the mission’s scientific objectives, however this information can also be utilized by the Office of Planetary Protection to help evaluate the presence of any back contamination. Mars 2020, the first phase of a potential multipart Mars Sample Return (MSR) campaign, is expected to contribute to NASA’s Mars Exploration Program Science Goals by filling in knowledge gaps concerning: 1) the existence of past or present life on Mars, 2) the past and present climate of Mars, 3) the geology of Mars, and 4) hazards associated with human exploration of Mars. Although there is debate concerning which samples will best answer these questions, the necessity for proper sample blanks is well-understood. The CC and PP requirements, driven by the restricted Class V mission designation, are the most stringent of any sample return mission in recent history. The extremely low levels of allowable terrestrial contamination on the spacecraft and rover can complicate these analyses given the detection limits of current analytical instrumentation, especially in the case of biological contamination. By collecting and curating unanalyzed samples specifically for CK, future sample scientists will not be relegated to: 1) relying on data collected using possibly obsolete tools and techniques for return sample blanks, or 2) using remnants of extracted and/or cultured samples from ATLO (Assembly, Test, and Launch Operations), which could be incompatible with the desired experimental endpoints or state-of-the-art techniques available at the time of sample return.The addition of biological experimental endpoints to a sample return campaign’s objectives broadens the requisite range in preservation environments (e.g. inert ultra-pure nitrogen gaseous environment at 18 degrees Centigrade versus less than or equal to minus 80 degrees Centigrade) and types of CK samples. As a result, the Curation Office will also curate the following CK samples at less than or equal to minus 80 degrees Centigrade for the Mars 2020 mission: 1) unanalyzed swabs and wipes in sterile containers, 2) all recirculation filters from the clean rooms used for sample and caching subsystem assembly and all filters from the laminar flow benches used to assemble sample intimate hardware, and 3) witness plates collecting airborne contamination within the assembly clean rooms. It has been Curation Office policy since the Apollo missions to preserve as many pristine samples as possible for future scientific research. Although CK is required to be collected for all stages of the MSR campaign, the CK for the Mars 2020 mission is the most critical for understanding contamination in the returned samples given the intimacy between the Martian samples and the Mars 2020 flight hardware. This presentation highlights the importance of CK for sample return missions as well as the traditional and novel types of CK samples required for a successful MSR campaign.

Harrington, A. D.↗

Artemis Curation: Preparing for Sample Return from the Lunar South Pole

Space Policy Directive-1 mandates that “the United States will lead the return of humans to the Moon for long-term exploration and utilization, followed by human missions to Mars and other destinations.” In addition, the Vice President stated that “It is the stated policy of this administration and the United States of America to return American astronauts to the Moon within the next five years,” that is, by 2024. These efforts, under the umbrella of the recently formed Artemis Program, include such historic goals as the flight of the first woman to the Moon and the exploration of the lunar south-polar region. Among the top priorities of the Artemis Program is the return of a suite of geologic samples, providing new and significant opportunities for progressing lunar science and human exploration. In particular, successful sample return is necessary for understanding the history of volatiles in the Solar System and the evolution of the Earth-Moon system, fully constraining the hazards of the lunar polar environment for astronauts, and providing the necessary data for constraining the abundance and distribution of resources for in-situ resource utilization (ISRU). Here we summarize the ef-forts of the Astromaterials Acquisition and Curation Office (hereafter referred to as the Curation Office) to ensure the success of Artemis sample return (per NASA Policy Directive (NPD) 7100.10E).

Mitchell, J. L.↗

Hybrid chemical-electric trajectories for a Mars Sample Return orbiter

The Earth return orbiter component of a Mars sample return campaign is a high total impulse mission with challenging timeline constraints. These competing demands mean a hybrid chemical-electric propulsion architecture may be needed for a feasible design, with chemical propulsion providing timely impulse and electric propulsion providing high volume impulse. We describe an approach to map out the hybrid trajectory design space and create a database to use in conjunction with a spacecraft design tool, enabling co-optimization of trajectory and spacecraft. This method is applied to both the outbound and inbound legs of a Mars sample return mission concept.

Lock, Rob↗

Development of Ballistic Limit Equations in Support of the Mars Sample Return Mission

NASA and the European Space Agency (ESA) are currently planning the Mars Sample Return campaign, comprising missions whose combined objective is to bring the first samples of Mars material back to Earth for detailed study. At present, the NASA-ESA plan is to return samples to Earth using three missions to be launched over the next 5-10 years. The final component, the Earth Entry System (EES), is intended to bring the Mars samples back to the Earth, where it will land following safe entry through the Earth's atmosphere. There is a concern regarding the risk of biological contamination of the Earth’s biosphere from returned Martian samples if, for example, the structural integrity of the EES were compromised during its return mission due to a perforation of a critical surface resulting from a high-speed meteoroid impact. To assess the risks associated with such an event, NASA is developing equations that predict the damage that various EES elements will sustain as a result of such an impact, as well as equations that predict whether or not a particular system will sustain a critical failure following such an impact. In this paper, we review recent progress in the development of such equations for the EES forebody and the EES aftbody, the two elements of the EES that are most exposed to the meteoroid environment. Limitations of the BLEs are also discussed, which can also be used to further inform the next steps in the BLE development.

William P. Schonberg↗

Advances in X-ray Instruments to Support Mars Sample Return

The Mars 2020 Perseverance rover is currently collecting drill cores of ancient igneous and sedimentary rock in and around Jezero crater for potential transport to Earth. These samples from the martian surface will enable detailed mineralogical, geochemical, and petrological measurements to characterize ancient depositional and diagenetic environments, quantitatively age-date the samples, and identify the building blocks for life or evidence for life itself. Furthermore, these drill cores are especially precious because they may represent the most pristine samples from the martian surface and our best chance at identifying martian life, as future sample return missions may be conducted by humans that can introduce biological contaminants to the samples. Because of the importance of these samples, we must take great care in their handling, curation, and preliminary analyses so that they are preserved for scientific measurements for decades to come. In-situ measurements by Perseverance have identified minerals that further warrant special treatment of the returned samples. Hydrated sulfate carbonate, swelling clay minerals, and oxychlorine salts are extremely sensitive to changes in temperature and relative humidity. The structures of hydrated sulfates and oxychlorine minerals, in particular, readily change when exposed to different conditions, meaning the mineral assemblage of the as-returned samples may be lost if the samples aren’t handled properly. Characterizing the as-returned mineral assemblage, particularly of the salts, is essential for reconstructing past aqueous conditions and habitability. To characterize the as-returned mineral assemblage, the samples must be analyzed rapidly before phase changes occur and/or under controlled conditions (e.g., within a glove box). Significant recent advances in X-ray instrumentation for robotic exploration of the solar system have resulted in high-resolution miniaturized instruments that would provide mineralogical, geochemical, and petrological information on the returned martian samples without degradation of the mineral assemblage. Here, we describe a combined X-ray diffractometer/X-ray fluorescence spectrometer (XRD/XRF), an X-ray computed tomographic (XCT) instrument, and a scanned beam XRF mapping instrument that could be used in a glove box so that the martian samples remain under controlled conditions.

E. B. Rampe↗

Noble Gases in Samples Returned From Asteroids Ryugu and Bennu

Introduction: The asteroid sample return missions, JAXA’s Hayabusa2 [1] and NASA’s OSIRIS-REx [2], fromC-rich asteroids Ryugu and Bennu offer unique opportunities to sample pristine early solar system material, unaffected by terrestrial weathering and contamination, and with a known geological context. The comparison with most primi-tive members of carbonaceous –and inner solar system ordinary and enstatite– chondrite classes allows us to (i) assess the variation (or the lack of thereof) of the distribution of the most volatile elements throughout the entire early solar system, (ii) determine the effects of parent body thermal and aqueous alteration, and (iii) learn about the dynamic evolution and history of the various parent bodies, as sampled by both return missions and meteorite delivery. Here we will present noble gas data obtained from newly received particles from Ryugu and Bennu. Samples & Analysis: We received nine particles allocated by JAXA, with masses of 0.5-1.7 mg mass: four col-lected during Hayabusa2’s first touchdown (chamber A) and five from a small artificial crater (chamber C). We received three particles from Bennu of 0.07, 0.89 and 0.94 mg mass (OREX-800032-102/3/4). All particles were processed, allocated, weighed, and transferred into our UHV sample chamber within pure N2, to prevent any contact with air. We examined all He-Xe isotopes with our custom-built mass spectrometer “Albatros” ([3,4]). Gases were extracted individually from each particle by melting induced by a 1064 μm Nd:YAG IR laser in 2–4 heating steps. Large amounts of water and other reactive volatiles were released, consistent with the presence of abundant volatiles from both Ryugu and Bennu. Residues of Ryugu particles remaining after lasering, subsequently exposed to air, were additionally extracted in a crucible to verify complete gas extraction. Only the particle that still showed a “crystalline” structure after lasering contained detectable Ryugu noble gases, whereas all other particles turned immediately into glassy spheres by laser heating and lacked any gas. Results & Discussion: Ryugu and Bennu matter contains noble gases similar to the most pristine, unheated aqueously altered meteorites, e.g., CM or CI chondrites [5,6]. Remarkably, all four chamber A samples that originated from Ryugu’s surface show solar wind (SW) Ne (trapped (20Ne/22Ne)tr ~12–13), whereas all five chamber C samples do not ((20Ne/22Ne)tr ~9.0–10.7 consistent with the presence of non-solar trapped Ne components such as Q and HL). This demonstrates that JAXA’s sampling strategy succeeded: Chamber C samples analyzed in this work originated from areas shielded from SW, slightly below the surface, that was sampled after the impactor excavated material. The three Bennu particles populate the same range as the Ryugu particles in Ne isotope space with one particle containing SW suggesting that it was part of the uppermost surface layer of Bennu during sampling, while Ne in the smallest sample can be explained best by mixing Ne from presolar diamonds and SiC or graphite, and that in the third one by mixing of, e.g., Q and HL. Using cosmic ray production rates given by [7] yields preliminary exposure ages for Ryugu particles in the same range as determined in [7]. There is, as expected, also no systematic difference between samples from chambers A and C because both sample sets were likely collected within the uppermost layer of Ryugu, which were not shielded from cosmic rays. The concentration of cosmogenic (cos) Ne in the Bennu particle, where Necos was resolvable, is in the same range as found for Ryugu, suggesting roughly similar exposure time to cosmic rays for 5–8 Ma for all particles examined here. The Xe isotopic compositions of all particles are consistent with those of phase Q, with small additions of Xe-HL from presolar diamonds and excess 129Xe* from short-lived 129I decay. The comparably high 129Xe*/129XeQ ratio is similar in all samples, suggesting similar initial I concentrations and closure to Xe loss –or the incorporation of a well-mixed Xe reservoir. The Bennu material was in brief contact with air in the capsule, after atmospheric entry and before storage in pure N2 in a clean room. Both, the –most diagnostic– Xe isotopes and the Ar/Xe vs. Kr/Xe systematics prove that the noble gases are not affected by terrestrial contamination, in contrast to many CI, CY, and CM chondrites found on Earth [5,6], illustrating the importance of sample return. He-Xe concentrations in all particles unaffected bySW are comparable to but at the upper end of ranges reported [5-7]. In accordance with the strong aqueous alteration experienced on the parent bodies of Ryugu and Bennu [1,2], all samples lack the Ar-rich and water-susceptible noble gas components found in less aqueously altered CMs or CRs [e.g., 5,8] and all COs.

Henner Busemann↗

Assessing the Sampleability of Bennu’s Surface for the OSIRIS-REx Asteroid Sample Return Mission

NASA’s first asteroid sample return mission, OSIRIS-REx, collected a sample from the surface of near-Earth asteroid Bennu in October 2020 and will deliver it to Earth in September 2023. Selecting a sample collection site on Bennu’s surface was challenging due to the surprising lack of large ponded deposits of regolith particles exclusively fine enough (≤ 2 cm diameter) to be ingested by the spacecraft’s Touch-and-Go Sample Acquisition Mechanism (TAGSAM). Here we describe the Sampleability Map of Bennu, which was constructed to aid in the selection of candidate sampling sites and to estimate the probability of collecting sufficient sample. “Sampleability” is a numeric score that expresses the compatibility of a given area’s surface properties with the sampling mechanism. The algorithm that determines sampleability is a best fit functional form to an extensive suite of laboratory testing outcomes tracking the TAGSAM performance as a function of four observable properties of the target asteroid. The algorithm and testing were designed to measure and subsequently predict TAGSAM collection amounts as a function of the minimum particle size, maximum particle size, particle size frequency distribution, and the tilt of the TAGSAM head off the surface. The sampleability algorithm operated at two general scales, consistent with the resolution and coverage of data collected during the mission. The first scale was global and evaluated nearly the full surface. Due to Bennu’s unexpected boulder coverage and lack of ponded regolith deposits, the global sampleability efforts relied heavily on additional strategies to find and characterize regions of interest based on quantifying and avoiding areas heavily covered by material too large to be collected. The second scale was site-specific and used higher-resolution data to predict collected mass at a given contact location. The rigorous sampleability assessments gave the mission confidence to select the best possible sample collection site and directly enabled successful collection of hundreds of grams of material.

Asteroid exploration↗

Mars rover sample return mission utilizing in situ production of the return propellants

This paper presents an unmanned Mars sample return mission that utilizes propellants manufactured in situ from the Martian atmosphere for the return trip. A key goal of the mission is to demonstrate the considerable benefits that can be realized through the use of indigenous resources and to test the viability of this approach as a precursor to manned missions to Mars. Two in situ propellant combinations, methane/oxygen and carbon monoxide/oxygen, are compared to imported terrestrial hydrogen/oxygen within a single mission architecture, using a single Earth launch vehicle. The mission is assumed to be launched from Earth in 2003. Upon reaching Mars, the landing vehicle aerobrakes, deploys a small satellite, and lands on the Martian surface. Once on the ground, the propellant production unit is activated, and the product gases are liquefied and stored in the empty tanks of the Earth Return Vehicle (ERV). Power for these activities is provided by a dynamic isotope power system. A semiautonomous rover, powered by the indigenous propellants, gathers between 25 and 30 kg of soil and rock samples which are loaded aboard the ERV for return to Earth. After a surface stay time of approximately 1.5 years, the ERV leaves Mars for the return voyage to Earth. When the vehicle reaches the vicinity of Earth, the sample return capsule detaches, and is captured and circularized in LEO via aerobraking maneuvers.

Bruckner, A. P.↗

Lunar Sample Return Entry Systems Analysis

The Lunar Prospector and Clementine missions have revealed deposits of water-ice located at the South Pole-Aitken Basin of the lunar surface. Due to the scarce amount of previous successful sample return missions and the recent discovery of water-ice, the National Research Council (NRC) Decadal Survey recommended prioritizing the development of a Lunar Sample Return Mission Architecture. The NRC Decadal survey ranked the return of cryogenic samples that could potentially aid in current scientific investigations and identify sites for in-situ resource utilization to support future exploration missions. This study aims to identify the key technical challenges and operational constraints involved in returning cryogenic samples in pristine condition. A detailed classification of defined ground rules and assumptions, justification of mission events and high level functional requirements reinforces the proposed concept of operations. In support of the drafted architecture, a comprehensive analysis on design and environmental constraints are documented for the Earth return vehicle, sample container and thermal protection entry system. The design and thermal analysis is comprised of quantitative dimensions for mass and volume, flight performance parameters and thermal system performance limitations. Further refinement of the high level functional requirements is imperative for determining the optimal approach for returning cryopreserved lunar samples.

Lunar Sample Return↗

Advanced Curation: Solving Current and Future Sample Return Problems

Advanced Curation is a wide-ranging and comprehensive research and development effort at NASA Johnson Space Center that identifies and remediates sample related issues. For current collections, Advanced Curation investigates new cleaning, verification, and analytical techniques to assess their suitability for improving curation processes. Specific needs are also assessed for future sample return missions. For each need, a written plan is drawn up to achieve the requirement. The plan draws while upon current Curation practices, input from Curators, the analytical expertise of the Astromaterials Research and Exploration Science (ARES) team, and suitable standards maintained by ISO, IEST, NIST and other institutions. Additionally, new technologies are adopted on the bases of need and availability. Implementation plans are tested using customized trial programs with statistically robust courses of measurement, and are iterated if necessary until an implementable protocol is established. Upcoming and potential NASA missions such as OSIRIS-REx, the Asteroid Retrieval Mission (ARM), sample return missions in the New Frontiers program, and Mars sample return (MSR) all feature new difficulties and specialized sample handling requirements. The Mars 2020 mission in particular poses a suite of challenges since the mission will cache martian samples for possible return to Earth. In anticipation of future MSR, the following problems are among those under investigation: What is the most efficient means to achieve the less than 1.0 ng/sq cm total organic carbon (TOC) cleanliness required for all sample handling hardware? How do we maintain and verify cleanliness at this level? The Mars 2020 Organic Contamination Panel (OCP) predicts that organic carbon, if present, will be present at the "one to tens" of ppb level in martian near-surface samples. The same samples will likely contain wt% perchlorate salts, or approximately 1,000,000x as much perchlorate oxidizer as organic carbon. The chemical kinetics of this reaction are poorly understood at present under the conditions of cached or curated martian samples. Among other parameters, what is the maximum temperature allowed during storage in order to preserve native martian organic compounds for analysis? What is the best means to collect headspace gases from cached martian (and other) samples? This gas will contain not only martian atmosphere but also off-gassed volatiles from the cached solids.

Fries, M.↗

Small Spacecraft Sample Return Mission Concept to Support Gateway and Lunar Science

Sustaining long-term presence at the Moon will likely require innovative and cost-effective approaches for frequentand affordable payload return. NASA Ames Research Center and the Deep Space Logistics team at Kennedy SpaceCenter (which manages the Gateway Logistics Services missions) have investigated the development of a small spacecraft-based sample return capability to complement the limited sample return capacity available with the earlyOrion missions. The goal is to demonstrate a cost-effective capability as part of an early Deep Space Logisticsmission and provide up to 10 kg (~ 4 L volume) of scientific payload returned from the Gateway. The mission concept envisions the progressive addition of sample return capabilities, including returning temperature- andacceleration-sensitive payloads, and evolution into a commercially provided service, similar to existing International Space Station payload return logistics. An overview of payload science and technology use cases and smallspacecraft mission concepts will be presented to engage scientists, payload developers and mission planners who are considering lunar exploration activities that will require the return of high-value samples from the Gateway and/or the lunar surface.

Alan M Cassell↗

Arc Jet Testing of Carbon Phenolic for Mars Sample Return and Future NASA Missions

The objective of the Mars Sample Return (MSR) Mission is to return a sample of MArtian soil to Earth. The Earth Entry Vehicle (EEV) brings te samples through the atmosphere to the ground.The program aims to: Model aerothermal environment during EEV flight; On the basis of results, select potential TPS materials for EEV forebody; Fabricate TPS materials; Test the materials in the arc jet environment representative of predicted flight environment;Evaluate material performance; Compare results of modeling predictions with test results.

Laub, Bernard↗

Cryogenic Curation: Isolated Technology and Mission Operational Requirements for Sample Return

Future lunar, Mars, asteroid, and comet sample return missions may collect samples that have been preserved at sub-freezing or even cryogenic temperatures. For such samples, the study of volatiles and temperature-sensitive minerals will have high priority. Valuable geochemical and mineralogical information will be lost if such samples are allowed to reach ambient temperatures on Earth. The ability to store, document, subdivide, and transport extraterrestrial geologic samples while maintaining sub-freezing or cryogenic temperatures, possibly as low as 40 K, is required for the complete scientific study of samples from cold environments.

Calaway, Michael J.↗

Iterating on a Design – Further Developments in the Evolution of the Ballistic Limit Equations for the Mars Sample Return Project

The goal of the Mars Sample Return–Capture, Containment, and Return System Project is to retrieve samples launched from the Martian surface and return them to Earth for detailed analysis. An important part of this project is the design of the system’s micrometeoroid protection system, which protects the Earth Entry System and the collected samples during their journey back to Earth. As mission parameters and the micrometeoroid and orbital debris threat became better understood, the design of the micrometeoroid protection system evolved. A key element used in the shield development process is the ballistic limit equation, which is an equation that is used to determine whether or not a particular structural element or system will end up in a failed state as a result of a specified impact. As the design of the Earth Entry System and the micrometeoroid protection system evolved, a new set of ballistic limit equations was needed to better predict and assess the performance of developing shield system designs in anticipation of possible damage from micrometeoroid and orbital debris particle impacts. This paper provides a summary of how a set of initial BLEs were either extended or modified so that the resulting equations were better suited to new types of target configurations being considered, as well as how additional ballistic limit equations were developed where none previously existed.

William P Schonberg↗

Lunar sample return via the interPlanetary superhighway

The Lunar Sample Return mission consists of two spacecraft, a communications module, and a lander/sample return module carried to the Moon by another ship. Knowledge of the InterPlanetary Superhighway tunnels and their dynamics provided a quick back-of-the-envelope estimation of the timing and costing of such libration missions which compared well with fully integrated solutions.

lunar sample return InterPlanetary SuperHighway Mo↗