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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Synchrotron brightness distribution of turbulent radio jets

Radio jets are considered as turbulent mixing regions and it is proposed that the essential small scale viscous dissipation in these jets is by emission of MHD waves and by their subsequent strong damping due, at least partly, to gyro-resonant acceleration of supra-thermal particles. A formula relating the synchrotron surface brightness of a radio jet to the turbulent power input is deduced from physical postulates, and is tested against the data for NGC315 and 3C31 (NGC383). The predicted brightness depends essentially on the collimation behavior of the jet, and, to a lesser extent, on the CH picture of a 'high' nozzle with accelerating flow. The conditions for forming a large scale jet at a high nozzle from a much smaller scale jet are discussed. The effect of entrainment on the prediction is discussed with the use of similarity solutions. Although entrainment is inevitably associated with the turbulent jet, it may or may not be a dominant factor depending on the ambient density profile.

Henriksen, R. N.↗
NASA NTRS1989

Sequentially evaporated thin Y-Ba-Co-O superconducting films on microwave substrates

The development of high T sub c superconducting thin films on various microwave substrates is of major interest in space electronic systems. Thin films of YBa2Cu3O(7-Delta) were formed on SrTiO3, MgO, ZrO2 coated Al2O3, and LaAlO3 substrates by multi-layer sequential evaporation and subsequent annealing in oxygen. The technique allows controlled deposition of Cu, BaF2 and Y layers, as well as the ZrO buffer layers, to achieve reproducibility for microwave circuit fabrication. The three layer structure of Cu/BaF2/Y is repeated a minimum of four times. The films were annealed in an ambient of oxygen bubbled through water at temperatures between 850 C and 900 C followed by slow cooling (-2 C/minute) to 450 C, a low temperature anneal, and slow cooling to room temperature. Annealing times ranged from 15 minutes to 5 hrs. at high temperature and 0 to 6 hr. at 450 C. Silver contacts for four probe electrical measurements were formed by evaporation followed with an anneal at 500 C. The films were characterized by resistance-temperature measurements, energy dispersive X-ray spectroscopy, X-ray diffraction, and scanning electron microscopy. Critical transition temperatures ranged from 30 K to 87 K as a function of the substrate, composition of the film, thicknesses of the layers, and annealing conditions. Microwave ring resonator circuits were also patterned on these MgO and LaAlO3 substrates.

Valco, G. J.↗
NASA NTRS2000

Kinetics of the Cl(2)P(J)) + CH4 Reaction: Effects of Secondary Chemistry Below 300 K

Absolute rate data for the Cl(2)P(J) + CH4 yields HCl + CH3 reaction have been obtained from 218 to 298 K by using the discharge-flow resonance fluorescence technique at I Torr total pressure. The result at 298 K is (10.1 +/- 0.6) x 10(exp -14) cu cm/molecule/s. The temperature dependence in Arrhenius form is (6.5 +/- 0.9 ) x 10(exp -12) exp[(-1235 +/- 34 )/T]. The errors given are one standard deviation; overall experimental error is estimated at +/- 15%. Because of the relatively large disagreement among earlier measurements at low temperatures, the results were examined for possible effects of non-Boltzmann spin distribution and vibrational excitation of CH4, secondary chemistry of CH3 radicals, and impurities in the CH4 source. There was no significant change in the observed rate constant when an efficient spin quencher, CF4, was added and estimates indicate that vibrational partitioning in CH4 should be at the ambient reactor temperature before the start of the reaction. The results were also independent of the source of Cl atoms (microwave discharge or thermal decomposition of Cl2) and whether CH4 was purified in-situ. However, the observed rate constant did depend on initial Cl atom concentrations and to a lesser extent on CH4 concentrations. Numerical simulations were used to assess the importance of secondary chemistry over a range of reactant concentrations

Wang, J. J.↗
NASA NTRS1983

High-velocity iron absorption lines in supernova remnant 1006

The very strong, broad absorption lines of a sdOB star continuum shown in the International Ultraviolet Explorer spectrum of the Schweizer-Middleditch star projected near the center of supernova remnant SNR 1006 are investigated. It is found that strong Fe(+) resonance absorption lines are present whose centers show zero radial velocity while their profiles are broadened by approximately 5000-6000 km/s. Also identified are redshifted Si(+), Si(2+), and Si(3+) lines at velocities of approximately 5000 km/s. Results show that the absorptions must occur in the ejecta of the supernova. The strength and symmetric width of the Fe(+) line indicates that the bulk of the ejecta is iron, in agreement with the current theory for the origin of Type I supernova. It is suggested that the previous failure to detect strong Fe emission lines in the X-ray spectra of this and other young Type I SNRs may be a result of the ejecta not having had time to interact significantly with the ambient medium. In addition, the presence of redshifted adsorption lines due to supernova ejecta in its spectrum shows that this star is located behind the SNR and is not physically associated with it.

Wu, C.-C.↗
DOE OSTI2020

A versatile Johansson-type tender x-ray emission spectrometer

We present a high energy resolution x-ray spectrometer for the tender x-ray regime (1.6–5.0 keV) that was designed and operated at Stanford Synchrotron Radiation Lightsource. The instrument is developed on a Rowland geometry (500 mm of radius) using cylindrically bent Johansson analyzers and a position sensitive detector. By placing the sample inside the Rowland circle, the spectrometer operates in an energy-dispersive mode with a subnatural line-width energy resolution (~0.32 eV at 2400 eV), even when an extended incident x-ray beam is used across a wide range of diffraction angles (~30° to 65°). The spectrometer is enclosed in a vacuum chamber, and a sample chamber with independent ambient conditions is introduced to enable a versatile and fast-access sample environment (e.g., solid/gas/liquid samples, in situ cells, and radioactive materials). The design, capabilities, and performance are presented and discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1994

Raman-shifting an ArF excimer laser to generate new lines for obtaining optical diagnostic based information in flow fields

The application of tunable excimer lasers in combustion and flow diagnostics is almost routine nowadays. The properties of this laser system that enable density and temperature measurements in supersonic and hypersonic flow fields to be conducted are its high power, high repetition rate, and high spectral brightness. The limitation imposed by this system on these measurements is the paucity of lines in the wavelength region, the vacuum-ultraviolet, where species of interest, such as OH, N2, O2, H2, H2O, CO, NO, etc., are susceptible to electronic excitation to high-lying states. To circumvent this problem one normally resorts to nonlinear optical techniques such as frequency conversion via stimulated Raman scattering (SRS), more commonly known as Raman shifting or Raman mixing, to extend these nonintrusive and nonperturbing techniques to the shorter wavelengths in the VUV region and, for that matter, to longer wavelengths in the infrared region, if the need arises. The theoretical basis of SRS and its application are well documented in the literature. In essence, the Raman shift is a consequence of the inelastic scattering of the incident radiation by the sample. Most of the scattered radiation from the molecules of the sample is unchanged in frequency. However, a small fraction of the incident radiation is changed in frequency. This shift is a result of the fact that some of the incident photons on colliding with the molecules of the sample give up some of their energy and emerge with a lower energy resulting in the lower-frequency Stokes radiation. Other incident photons may increase their energy by colliding with the vibrationally excited molecules of the medium and emerge as higher-frequency antistokes radiation. The generation of the latter is the main objective of this project. The process, however, depends on several factors, including the beam quality of the pump laser, the cross-section of the gaseous medium, the gas pressure, and the ambient temperature of the gas near the focal region. Furthermore, since the Raman shifting process is polarization sensitive, it is necessary to have all of the laser energy in a single polarization. These factors were taken into consideration in the execution of the project. The implementation of the Raman shift was accomplished by focusing the 193 nm output of an ArF excimer laser (Lamda-Physik LPX 150) into a 1-meter long high pressure recirculating Raman cell filled with H2 gas. The laser system was modified in order to improve the mode quality of the pump beam to enhance the Raman shifting. To accomplish this feat, a prism beam expander and grating on the oscillator discharge provided wavelength tuning over the excimer gain profile. Furthermore, a triple-pass configuration, as opposed to unstable resonator optics, was employed in the operation of the amplifier cavity so that when the oscillator output radiation, focused by a 51-cm focal length fused silica lens through a 50 micron pinhole (serving as a spatial filter) and recollimated with a 25-cm focal length lens, was fed into the amplifier, it was injection locked, thereby providing tunable radiation with relatively low divergence. The forward scattered radiation emanating from the impingement of the modified pump beam on the Raman cell was detected using an energy meter after the latter had been separated from it using a dispersing prism.

Koker, Edmond B.↗
DOE OSTI2025

Microscopic Characterization of Pb 10−x Cu x (PO 4 ) 6 O by 31 P and 63/65 Cu NMR Measurements

The report of the first room-temperature, ambient-pressure superconductivity in copper-doped lead apatite Pb 10−x Cu x (PO 4 ) 6 O has attracted lots of attention. However, subsequent studies revealed the presence of numerous impurity phases in the polycrystalline sample, and the sharp superconducting-like transition is not due to a superconducting transition but most likely due to a reduction in resistivity caused by the first-order structural phase transition of Cu 2 S at around 385 K from the β phase at high temperature to the γ phase at low temperature. Before now, only bulk measurements have been performed on a Pb 10−x Cu x (PO 4 ) 6 O powder sample, which could be affected by the impurity phases, masking the intrinsic properties of Pb 10−x Cu x (PO 4 ) 6 O. In this study, 31 P and 63/65 Cu nuclear magnetic resonance (NMR) measurements have been performed on a Pb 10−x Cu x (PO 4 ) 6 O powder sample to investigate its physical properties from a microscopic point of view. Our NMR data evidence the non-magnetic insulating nature of Pb 10−x Cu x (PO 4 ) 6 O without any trace of electron correlation effects. Furthermore, the 63/65 Cu NMR results suggest that no copper or very little copper is substituted for Pb in Pb 10 (PO 4 ) 6 O prepared by sintering Pb 2 SO 5 and Cu 3 P.

lead apatite↗
NASA NTRS2001

Indium Single-Ion Frequency Standard

A single laser-cooled indium ion is a promising candidate for an ultimate resolution optical time or frequency standard. It can be shown that single ions from group IIIA of the periodic table (indium, thallium, etc.) can have extremely small systematic errors. In addition to being free from Doppler, transit-time and collisional shifts, these ions are also quite insensitive to perturbations from ambient magnetic and electric fields (mainly due to the use of a J=0-0 transition for spectroscopy). Of all group IIIA ions, indium seems to be the most practical, since it is heavy enough to have a tolerable intercombination cooling transition rate and (unlike thallium) has transitions which are easily accessible with frequency multiplied continuous-wave lasers. A single indium ion standard has a potential inaccuracy of one part in 10(exp 18) for integration times of 10(exp 6) seconds. We have made substantial progress during the grant period in constructing a frequency standard based upon a single indium ion. At the beginning of the grant period, single indium ions were being successfully trapped, but the lasers and optical systems were inadequate to achieve the desired goal. We have considerably improved the stability of the dye laser used to cool the ions and locked it to a molecular resonance line, making it possible to observe stable cooling-line fluorescence from a single indium ion for reasonable periods of time, as required by the demands of precision spectroscopy. We have substantially improved the single-ion fluorescence signal with significant benefits for the detection efficiency of forbidden transitions using the 'shelving' technique. Finally, we have constructed a compact, efficient UV 'clock' laser and observed 'clock' transitions in single indium ions using this laser system. We will elaborate on these accomplishments.

Nagourney, Warren↗
DOE OSTI2020

Discrete Open-Shell Tris(bipyridinium radical cationic) Inclusion Complexes in the Solid State

In the solid state the properties of organic radicals depend heavily on radical-radical interactions that are influenced by the superstructure of the crystalline phase. Here, we report the synthesis and characterization of a substituted tetracationic cyclophane, cyclobis(paraquat-p-1,4- dimethoxyphenylene), and outline how its bisradical dicationic redox state associates with the methyl viologen radical cation (MV •+ ) to give a trisradical tricationic inclusion complex. The (super)structures of the reduced cyclophane and this 1:1 complex in the solid-state deviate from the analogous (super)structures observed for the reduced state of cyclobis(paraquat-p-phenylene) and that of its trisradical tricationic complex. Titration experiments with a range of guests reveal that the methoxy substituents on the para-xylenyl do not influence significantly of the binding affinity of the cyclophane for small neutral guests, whereas the affinity decreases by an order of magnitude for larger radical cationic guests such as MV •+ . X-Ray diffraction reveals that the solid- state structures of the tricationic trisradical complexes to be a discrete entity with weak intermolecular orbital overlap between the neighboring complexes. Transient nutation EPR experiment and DFT calculations confirm that the complex has a doublet spin configuration in the ground state as a result of the strong orbital overlap within the complex, while the quartet-state spin configuration is higher in energy and so is inaccessible at ambient temperature. The superconducting quantum interference device (SQUID) measurement reveals that trisradical tricationic complexes interact antiferromagnetically (J/k = - 2.33 K) and form a 1D Heisenberg antiferromagnetic chain along the a-axis in the crystal. Furthermore, these results offer new insights into the design and synthesis of organic magnetic materials based on host-guest inclusion complexes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1981

Pioneer fly-by of Saturn and its rings

Results acquired by the imaging photopolarimeter on board Pioneer 11 during the spacecraft fly-by of Saturn and its rings on September 1, 1979 are reviewed. Analysis of the broadband photometry and polarimetry obtained of the Saturn atmosphere has been used to determine a cloud top height of 300 mb and a scale height of the aerosol distribution about 1/4 that of the ambient gas, and to point out differences between the forward scattering and belt and zone characteristics of the Saturn and Jupiter atmospheres. Images of Saturn's rings have been used to derive a profile of ring optical depth between 1.22 and 2.35 Saturn radii, and reveal new divisions and thin rings and azimuthal variations in the brightness of the A ring not observable from earth. Linear polarization observations of Titan in red and blue light reveal that the aerosols near the top of the atmosphere have radii less than about 0.09 micron and that the optical thickness of the small aerosol layer is about 0.6 above an effectively depolarizing surface, and indicate radii of 2845 + or - 25 km and 2880 + or - 22 km in red and blue light, respectively. Earth-based and spacecraft data are consistent with the formation of rings structures as a result of Poynting-Robertson drag and gravitational satellite resonances with the original ice and rock particles.

Gehrels, T.↗
NASA NTRS1989

Some Observations on Transitory Stall in Conical Diffusers

Results from an experimental investigation on the flow through conical diffusers are presented. The mean and fluctuating velocity fields are compared for three diffusers with total diffusion angles of 16, 20 and 24 degrees, in the throat Mach number (M sub t) range of 0.05 to 0.95. Each of the diffusers were 14 cm long and had a 5.08 cm inlet diameter, and the flow exited into the ambient. The boundary layer at the throat was thin with the throat diameter (D sub t) to momentum thickness (O) ratio being as high as 800 at M(sub t) = 0.4. While the 16 deg diffuser flow exited with a top-hat mean velocity profile, increasing losses due to increasing separation resulted in fuller profiles for the 20 and 24 degree cases. A detailed flow field study was conducted for the 16 deg. diffuser. The u'-spectrum, measured at the exit plane, exhibited a peak apparently due to the ensuing jet column instability throughout the M(sub t) range covered. In addition, a much lower frequency spectral peak also occurred in the M(sub t) range of 0.3 to 0.7. Both of the spectral peaks were due to axisymmetric flow fluctuations. A self-sustaining flow oscillation occurred in the M(sub t) range of 0.6 to 0.85, emitting a loud tone, when the jet column instability frequency matched the resonance frequency of the diffuser. Limited data showed that artificial acoustic excitation was effective in reducing the flow fluctuations, with a resultant increase in the pressure recovery, at low M(sub t).

Zaman, K. B. M. Q.↗
NASA NTRS1990

Some observations on transitory stall in conical diffusers

Results from an experimental investigation on the flow through conical diffusers are presented. The mean and fluctuating velocity fields are compared for three diffusers with total diffusion angles of 16, 20 and 24 degrees, in the throat Mach number (M sub t) range of 0.05 to 0.95. Each of the diffusers were 14 cm long and had a 5.08 cm inlet diameter, and the flow exited into the ambient. The boundary layer at the throat was thin with the throat diameter (D sub t) to momentum thickness (O) ratio being as high as 800 at M(sub t) = 0.4. While the 16 deg diffuser flow exited with a top-hat mean velocity profile, increasing losses due to increasing separation resulted in fuller profiles for the 20 and 24 degrees cases. A detailed flow field study was conducted for the 16 deg diffuser. The u'-spectrum, measured at the exit plane, exhibited a peak apparently due to the ensuing jet column instability throughout the M(sub t) range covered. In addition, a much lower frequency spectral peak also occurred in the M(sub t) range of 0.3 to 0.7. Both of the spectral peaks were due to axisymmetric flow fluctuations. A self-sustaining flow oscillation occurred in the M(sub t) range of 0.6 to 0.85, emitting a loud tone, when the jet column instability frequency matched the resonance frequency of the diffuser. Limited data showed that artificial acoustic excitation was effective in reducing the flow fluctuations, with a resultant increase in the pressure recovery, at low M(sub t).

Zaman, K. B. M. Q.↗
DOE OSTI2023

Polarization and properties of low-frequency waves in warm magnetized two-fluid plasma

This paper presents the derivation of a general wave dispersion relation for warm magnetized plasma under the two-fluid formalism. The discussion is quite general except for the assumption of low frequency and slow phase speed, for which the displacement current is negligible, under the implicit assumption that the plasma is sufficiently dense to satisfy the condition ωpe>ωce, where ωpe and ωce denote the plasma oscillation frequency and electron gyro frequency, respectively. The present discussion does not invoke charge neutrality associated with the fluctuations although it is implicitly satisfied. The resulting dispersion relation that includes the fluid thermal effects shows that there are three eigen modes, which include those corresponding to ideal MHD, namely, fast, slow, and kinetic Alfvén waves, as well as higher-frequency modes including the ion and electron cyclotron and lower-hybrid resonances. The fluid effects in the ideal MHD wave branches are influenced by the finite Larmor radius scales, and when the wave number in the cross field direction is comparable to these values, the fluid effects become significant. It is found that the Larmor radius should be interpreted in the sense as ion-acoustic gyro-radius instead of ion thermal gyro radius only. That is, it is found that the electrons also contribute to the non-ideal effect associated with the kinetic Alfvén wave. A comprehensive explanation of the polarization of each mode is also presented. The present findings indicate that the polarity may change its sign only for the kinetic Alfvén mode branch and that such a transition is based on the propagation angle. When such a change does take place, it is found that the kinetic Alfvén wave transits to an ion-acoustic mode. For each branch, it is also found that the electric field along the ambient magnetic field is purely transverse.

Physics↗
DOE OSTI2020

Collaborative Research: Natural Organic Matter and Microbial Controls on Mobilization/Immobilization of I and Pu in Soils and Waters Affected by Radionuclide Releases in USA and Japan

In this project, the relationship between natural organic matter (NOM) and two radioactive elements that are relevant to nuclear waste disposal were studied: Plutonium (Pu) and Iodine. The human and environmental risks associated with Pu stem mainly from the very long half-lives of several of its isotopes ( 238 Pu, 88 yr; 239 Pu, 24,100 yr; 240 Pu, 6560 yr) and its radiotoxicity. Understanding Pu biogeochemical behavior in both near-field (>10-11M) and far-field scales (<10-11M) is imperative to the development of approaches for reprocessing Pu, remediation of Pu contamination and accurate assessment of risks posed by disposal practices for Pu-bearing wastes. The environmental mobility of Pu can be affected by redox potential, pH, adsorption, precipitation, complexation, colloid formation, and microbial activity, of which the first characteristic has the most profound influence. Numerous studies have shown high affinity of Pu towards NOM, as well as to mineral phases. NOM is ubiquitous in the environment, e.g., both fulvic and humic acids are able to reduce Pu(V,VI) to Pu(IV) and the redox potential of NOM is positively related to the abundance of phenolic/acidic OH groups. NOM can either facilitate or limit actinide migration, depending on specific biogeochemical conditions including pH, mineral and organic matter characteristics, etc. The other radionuclide of interest is radioiodine ( 129 I). 129I is a major by-product of nuclear fission and of serious concern to the Department of Energy (DOE) as it is among the top risk drivers at existing and potential radiowaste-contaminated sites. The risk of 129 I stems largely from its high bioconcentration factor (90% of the body’s iodine is accumulated in the thyroid), a high inventory at source terms, a very long-half life (16M years), and rapid mobility in the subsurface environment. As a consequence, 129 I has the lowest drinking water standard (1 pCi/L) among all radionuclides in the Federal Register. With a novel and sensitive gas chromatography-mass spectrometry (GC-MS) method developed in our lab, it is possible to quickly and simultaneously determine the distribution of 129 I and stable 127 I forms in environments, as low as 2 pCi/L for 129 I. This method was subsequently validated using accelerator mass spectroscopy, AMS. IO 3 - and organo-I were determined as major species in the groundwater of SRS and the Hanford Site, contrary to thermodynamic predictions that I- should be the dominant species at these sites. Mobility of 129 I was also demonstrated to depend greatly on the I species and its concentration, sediment pH, and redox state, with times to achieve equilibrium taking up to 12 weeks. Along the groundwater pathway in the F-Area of SRS, 129 I- supplied from the seepage basins was transformed to 129 IO 3 - and organo- 129 I with increasing iodine sediment sorption, causing the lower total 127 I and 129 I concentrations along the gradient transect of the waste plume. By contrast, groundwater 129 I concentrations in the wetlands (as high as 1617.3 pCi/L) were greatly elevated with respect to the source term (159.3 pCi/L). While the NOM promoted the uptake of 129 I to the wetland sediment, it also promoted the formation of soluble organic fraction. A small fraction of NOM that is bound to iodine can behave as a mobile organo-I source. Iodide was enzymatically incorporated into NOM, whereas both iodide and iodate were abiotically bound to NOM, under certain conditions. Iodate removal from the mobile aqueous phase can also occur through incorporation into carbonate (e.g., at the Hanford Site, USA). Thus immobilization and re-mobilization of iodine species were influenced by pH, Eh and the presence of NOM and metal oxides, which adds to the complexity of site remediation action. A ground-breaking result was to elucidate the products (i.e. organo-iodine moieties formed via enzymatic and non-enzymatic processes) at the molecular level by nuclear magnetic resonance (NMR) and electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICRMS). We found that iodine-NOM interactions may be influenced by NOM hydrophobic aliphatic moieties. From the perspective of ESI-FTICRMS, organo-iodine formulas were ascribed to the groups of unsaturated hydrocarbons, lignins and proteins. Iodate is likely abiotically reduced to reactive iodine species by lignin- and tannin-like compounds or carboxylic-rich alicyclic molecules (CRAM). We also investigated microbial mechanisms in iodine incorporation into NOM. We established that soil bacteria isolated from F-Area of SRS did not accumulate significant amounts of I- (0.2-2%). Intracellular uptake of I- decreases with increasing pH when pH ranged from 4 to 6. In contrast, 44 out of 84 strains isolated from the F-Area of SRS can transform I- to IO 3 - and organo-iodine. In some cases, oxidation was facilitated in the presence of H 2 O 2 . Microbes can also excrete organic acids that enhance I- oxidation by lowering the ambient pH and reacting with H 2 O 2 to form peroxy carboxylic acids. At lower pH values (≤5), H 2 O 2 hydrolysis was the driving force for iodide-oxidation; whereas, at pH ≥ 6, spontaneous decomposition of peroxy carboxylic acids, originating from H 2 O 2 and organic acids were the primary cause of iodide oxidation. Lastly, it was determined that microbial processes involved in Mn (II) are capable of directly oxidizing I- via enzymatic catalysis (i.e., multicopper oxidases), or indirectly through the formation of reactive oxygen species (ROS) and/or biogenic manganese oxides. ROS-mediated oxidation of I- was found to predominate at pH >5, whereas the enzymatic and Mn oxide pathways were more active at pH < 5. Together, this project has resulted in 9 publications in high-impact journals, and the training of 1 Ph.D and 4 undergraduate students.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1994

Focused interplanetary transport of approximately 1 MeV solar energetic protons through self-generated Alfven waves

We present a model of the focused transport of approximately 1 MeV solar energetic protons through interplanetary Alfven waves that the protons themselves amplify or damp. It is based on the quasi-linear theory but with a phenomenological pitch angle diffusion coefficient in the 'resonance gap.' For initial Alfven wave distributions that give mean free paths greater than approximately 0.5 AU for approximately 1 MeV protons in the inner heliosphere, the model predicts greater than roughly an order of magnitude amplification (damping) in the outward (inward) propagating resonant Alfven waves at less than or approximately equal to o.3 AU heliocentric distance. As the strength of proton source is increased, the peak differential proton intensity at approximately 1 MeV at 1 AU increases to a maximum of approximately 250 particles (/(sq cm)(s)(sr)(MeV)) and then decreases slowly. It may be attenuated by a factor of 5 or more relative to the case without wave evolution, provided that the proton source is sufficiently intense that the resulting peak differential intensity of approximately 1 MeV protons at 1 AU exceeds approximately 200 particles (/(sq cm)(s)(sr)(MeV)). Therefore, in large solar proton events, (1) one may have to take into account self-amplified waves in studying solar particle propagation, (2) the number of accelerated protons escaping from a flare or interplanetary shock may have been underestimated in past studies by a significant factor, and (3) accelerated protons escaping from a traveling interplanetary shock at r less than or approximately equal to 0.3 AU should amplify the ambient hydromagnetic waves siginificantly to make the shock an efficient accelerator, even if initially the mean free path is greater than or approximately equal to 1 AU.

Ng, C. K.↗
DOE OSTI2020

Mixtures of octanol and an ionic liquid: Structure and transport

Ionic liquids (ILs) with long alkyl substituents are amphiphilic, which leads to a bicontinuous liquid structure. The strongly interacting anionic and cationic head groups form a long range charge network, with the hydrocarbon tails forming a nonpolar domain. Such nonpolar domains have been shown to dissolve a variety of neutral organic solvents. In mixtures of ILs with solvents the neutral organic molecules residing in the nonpolar domains experience different environments and friction from the charged cations and anions. Thus, the neutral molecules diffuse much faster than predicted by hydrodynamic scaling using the average viscosity of the mixture. Here, we report studies on the structure and transport properties of mixtures of 1-octanol with the IL trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)imide (P 6,6,6,14 + /NTf 2 – ). The majority of the atom fraction in the P 6,6,6,14 + cation comprises four hydrocarbon substituents. The unique amphiphilic nature of ILs with the P 6,6,6,14 + cation makes 1-octanol fully miscible with the IL at ambient temperatures. X-ray scattering experiments show that the IL structure persists in the mixtures for 1-octanol mole fractions as large as x oct = 0.90. The self-diffusion coefficients of the three molecular species in the mixtures were measured by NMR experiments. The self-diffusion of the P 6,6,6,14 + cation is well described by the Stokes–Einstein equation, while the diffusivity of the NTf 2 – anion is slightly lower than the hydrodynamic prediction. The measured diffusivities of octanol in these mixtures are 1.3–4 times higher than the hydrodynamic predictions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRSDate not supplied

Calibration and Validation of the SHERLOC Instrument Operating in Jezero Crater, Mars

The Scanning Habitable Environments with Raman and Luminescence for Organics and Chemistry (SHERLOC) is an instrument onboard the Mars 2020 Perseverance rover. It consists of a spectrometer that measures deep ultraviolet (DUV) resonance Raman and native fluorescence photons generated through surface interactions with a 248.6 nm pulsed laser. Two microscopic imagers, the Autofocus Context Imager (ACI) and the Wide-Angle Topographic Sensor for Operations and eNgineering (WATSON), provide high-resolution context images of SHERLOC targets. The ACI is co-boresighted with the spectrometer. To ensure proper calibration, the SHERLOC calibration target (SCT) is mounted on the front of the rover and consists of ten different materials. The SCT was designed, fabricated, assembled, and tested by Jacobs Technology, Inc., and NASA Johnson Space Center. The dimensions of the calibration target housing are 150 x 89 x 33 mm and it weighs ~437 g. The ten targets are arranged in two rows; the first six are hard targets (AlGaN for Raman and fluorescence, diffuse transmission target, a slice of the SaU008 Mars meteorite, an intensity maze, and polycarbonate over geocache coin) and the remaining four are soft-goods targets (Vectran, Ortho-Fabric, Teflon, and nGimat-coated Teflon). The hard targets calibrate the spectrometer’s Raman and fluorescence spectral accuracy, ambient light reflection, and Raman response curve, while the soft-goods targets are spacesuit materials that function as human exploration targets, some of which are also used for spectral calibration. SHERLOC also has an internal calibration target consisting of AlGaN on sapphire (275 nm) located inside the ACI opaque dust cover to ensure proper instrument functioning between calibration target analyses. Initial SHERLOC, ACI, and WATSON calibration and validation on Mars was performed using the internal calibration target on sols 59, 83, 98, and 141; WATSON imaging of the SCT on sols 26 and 62, and SHERLOC spectroscopy and ACI imaging of the SCT on sol 59. These early data provide initial insights into instrument performance and the stability and degradation of the calibration target materials relative to the Martian surface and dust environment. Early observations also have implications for future astronaut spacesuit materials.

Trevor G Graff↗
NASA NTRS1994

Effect of magnetic field geometry on the wave signature of the pickup of interstellar neutrals

By using the technique of Johnstone et al. (1991), the asymptotic wave spectrum induced by the pickup of interstellar ions in the heliosphere is derived. This approach is independent of quasi-linear theory. The asymptotic wave spectrum is calculated from the standard resonance condition by assuming that the asymptotic ion distribution is bispherical and by using conservation of energy. The calculation places no restriction on either the ratio of Alfven speed to solar wind flow speed or the particle pitch angle. Spectra for various geometries (relative orientations of the magnetic field and solar wind velocity) are calculated. Absolute upper limits to the expected wave enhancements are calculated. These upper limits are compared to the background fluctuation spectrum extrapolated from 0.87 AU, assuming a spectral index of -5/3 and radial dependences of -2 and -3. The heliocentric radial distances at which the peaks in the various geometry-dependent wave spectra are expected to be observable above the background are identified. Peaks due to pickup hydrogen at the proton gyrofrequency are found to be always stronger relative to the background in parallel than in perpendicular geometries. The parallel-geometry excitations consist only of sunward propagating waves. In perpendicular geometries a peak also occurs, this time near 0.1 of the proton gyrofrequency (corresponding to the peak calculated by Lee and Ip (1987)). However, the steep spectral dependence of the ambient wave field makes it unlikely that this peak will be observed inside 20 AU. A similar result holds for the case of pickup-helium induced excitation at the helium gyrofrequency. Inside 10 AU, peaks at these lower frequencies tend to be obscured by the steep frequency dependence (proportional to -5/3) of the ambient spectrum and then are only observable in parallel geometries.

Williams, L. L.↗