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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Dynamic nanodomains dictate macroscopic properties in lead halide perovskites

Lead halide perovskites have emerged as promising materials for solar energy conversion and X-ray detection owing to their remarkable optoelectronic properties. However, the microscopic origins of their superior performance remain unclear. Here we show that low-symmetry dynamic nanodomains present in the high-symmetry average cubic phases, whose characteristics are dictated by the A-site cation, govern the macroscopic behaviour. We combine X-ray diffuse scattering, inelastic neutron spectroscopy, hyperspectral photoluminescence microscopy and machine-learning-assisted molecular dynamics simulations to directly correlate local nanoscale dynamics with macroscopic optoelectronic response. Our approach reveals that methylammonium-based perovskites form densely packed, anisotropic dynamic nanodomains with out-of-phase octahedral tilting, whereas formamidinium-based systems develop sparse, isotropic, spherical nanodomains with in-phase tilting, even when crystallography reveals cubic symmetry on average. We demonstrate that these sparsely distributed isotropic nanodomains present in formamidinium-based systems reduce electronic dynamic disorder, resulting in a beneficial optoelectronic response, thereby enhancing the performance of formamidinium-based lead halide perovskite devices. By elucidating the influence of the A-site cation on local dynamic nanodomains, and consequently, on the macroscopic properties, we propose leveraging this relationship to engineer the optoelectronic response of these materials, propelling further advancements in perovskite-based photovoltaics, optoelectronics and X-ray imaging.

Materials Science↗

SERENA: Particle Instrument Suite for Determining the Sun-Mercury Interaction from BepiColombo

The ESA-JAXA BepiColombo mission to Mercury will provide simultaneous measurements from two spacecraft, offering an unprecedented opportunity to investigate magnetospheric and exospheric particle dynamics at Mercury as well as their interactions with solar wind, solar radiation, and interplanetary dust. The particle instrument suite SERENA (Search for Exospheric Refilling and Emitted Natural Abundances) is flying in space on-board the BepiColombo Mercury Planetary Orbiter (MPO) and is the only instrument for ion and neutral particle detection aboard the MPO. It comprises four independent sensors: ELENA for neutral particle flow detection, Strofio for neutral gas detection, PICAM for planetary ions observations, and MIPA, mostly for solar wind ion measurements. SERENA is managed by a System Control Unit located inside the ELENA box. In the present paper the scientific goals of this suite are described, and then the four units are detailed, as well as their major features and calibration results. Finally, the SERENA operational activities are shown during the orbital path around Mercury, with also some reference to the activities planned during the long cruise phase.

79 ASTRONOMY AND ASTROPHYSICS↗

Using Machine Learning Tools to Predict Compressor Stall

Clean energy has become an increasingly important consideration in today’s power systems. As the push for clean energy continues, many coal-fired power plants are being decommissioned in favor of renewable power sources such as wind and solar. However, the intermittent nature of renewables means that dynamic load following traditional power systems is crucial to grid stability. With high flexibility and fast response at a wide range of operating conditions, gas turbine systems are poised to become the main load following component in the power grid. Yet, rapid changes in load can lead to fluid flow instabilities in gas turbine power systems. These instabilities often lead to compressor surge and stall, which are some of the most critical problems facing the safe and efficient operation of compressors in turbomachinery today. Although the topic of compressor surge and stall has been extensively researched, no methods for early prediction have been proven effective. This study explores the utilization of machine learning tools to predict compressor stall. The long short-term memory (LSTM) model, a form of recurrent neural network (RNN), was trained using real compressor stall datasets from a 100 kW recuperated gas turbine power system designed for hybrid configuration. Two variations of the LSTM model, classification and regression, were tested to determine optimal performance. The regression scheme was determined to be the most accurate approach, and a tool for predicting compressor stall was developed using this configuration. Overall, results show that the tool is capable of predicting stalls 5–20 ms before they occur. With a high-speed controller capable of 5 ms time-steps, mitigating action could be taken to prevent compressor stall before it occurs.

42 ENGINEERING↗

ESCARGOT: Mapping Vertical Phase Spiral Characteristics Throughout the Real and Simulated Milky Way

Abstract The recent discovery of a spiral pattern in the vertical kinematic structure in the solar neighborhood provides a prime opportunity to study nonequilibrium dynamics in the Milky Way from local stellar kinematics. Furthermore, results from simulations indicate that even in a limited volume, differences in stellar orbital histories allow us to trace variations in the initial perturbation across large regions of the disk. We present ESCARGOT , a novel algorithm for studying these variations in both simulated and observed data sets. ESCARGOT automatically extracts key quantities from the structure of a given phase spiral, including the time since perturbation and the perturbation mode. We test ESCARGOT on simulated data and show that it is capable of accurately recovering information about the time since the perturbation occurred as well as subtle differences in phase spiral morphology due to stellar locations in the disk at the time of perturbation. We apply ESCARGOT to kinematic data from data release 3 of the Gaia mission in bins of guiding radius. We show that similar structural differences in morphology occur in the Gaia phase spirals as a function of stellar orbital history. These results indicate that the phase spirals are the product of a complex dynamical response in the disk with large-scale coupling between different regions of phase space.

Darragh-Ford, Elise (ORCID:0000000288005652)↗

Data from: "Snowmelt Timing Regulates Community Composition, Phenology, and Physiological Performance of Alpine Plants"

This archive contains data that were used to support conclusions drawn in “Snowmelt Timing Regulates Community Composition, Phenology, and Physiological Performance of Alpine Plants”, by Winkler et al., 2018. Data were collected throughout the 2009 growing season on Niwot Ridge, Colorado, before the site became part of the Alpine Treeline Warming Experiment (ATWE). Geospatial files are included in this archive to provide additional locational context. The files in this data package consist of five comma-separated-values (.csv) files, one keyhole markup language (.kml) file, and two ESRI shapefiles (.shp). The .csv files can be opened by Microsoft Excel, R, or any simple text-editor software, such as TextEdit (MacOS) or Notepad (Windows). The .kml files can be opened by Google Maps or Google Earth, and the .shp files are compatible with GIS softwares such as ESRI’s ArcGIS suite, and QGIS.------------------------------------------------------------------------------------------------------------------------------------------------------------------------------We asked how plant community composition, phenology, plant water relations, and photosynthetic gas exchange of alpine-restricted and wide-ranging species differ in their responses to a ca. 40-day snowmelt gradient in the Colorado Rocky mountains (Lewisia pygmaea, Sibbaldia procumbens, and Hymenoxys grandiflora were alpine-restricted and Artemisia scopulorum, Carex rupestris, and Geum rossii were wide-ranging species). To do this, we measured percent cover and flowering initiation across 20 plots varying in snowmelt timing and measured net photosynthesis and stomatal conductance in multiple individuals of each target species in these plots in 2009.As hypothesized, species richness and foliar cover increased with earlier snowmelt, due to a greater abundance of wide-ranging species present in earlier melting plots. Flowering initiation occurred earlier with earlier snowmelt for 12 out of 19 species analyzed, while flowering duration was shortened with later snowmelt for six species (all but one were wide ranging species). We observed >50% declines in net photosynthesis from July to September as soil moisture and plant water potentials declined. Early-season stomatal conductance was higher in wide-ranging species, indicating a more competitive strategy for water acquisition when soil moisture is high. Even so, there were no associated differences in photosynthesis or transpiration, suggesting no strong differences between these groups in physiology.

54 ENVIRONMENTAL SCIENCES↗

Pro2R: Procurement of Ramping Product and Regulation in CAISO Using Probabilistic Solar Power Forecasts

This presentation summarizes the objectives and findings from the project titled, "Pro2R: Coordinated Procurement of Ramping Product & Regulation in CAISO Using Probabilistic Solar Power Forecasts," funded by DOE SETO. The goal is to develop cutting edge probabilistic solar power forecasting methods, and integrate them into ISO market operations. The team has integrated in two ways: 1) to procure ramping product and regulation requirements (ancillary services) in the California ISO market, and 2) to develop an open source visitation and ramp alert related situational awareness using probabilistic forecasts. This deck also summarizes the results from the use of machine learning methods to relate probabilistic solar forecasts to the the needs for flexible ramp product in the California ISO system.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Why Are There so Few Reports of High-Energy Electron Drift Resonances? Role of Radial Phase Space Density Gradients

Models of monochromatic Pc5 (2–7 mHz) ultralow frequency (ULF) wave interactions with high energy (greater than ~1 MeV) electrons predict drift resonant interactions that can cause rapid radial transport and acceleration. There are few reports of electron drift resonance at energies greater than ~1 MeV, in contrast to lower energies; moreover, all previous reports occur in the aftermath of interplanetary shocks. These two facts are difficult to reconcile with theory and numerical simulations predicting that greater than ~1 MeV drift resonances should occur more often and in a wider variety of driving conditions. In this study, we show that a combination of observational sampling biases and nominal radial phase space density gradients is one explanation for this discrepancy between theory and observations. In particular, we examine electron dynamics in two case studies with very similar satellite coverage, solar wind conditions, and Pc5 wave properties, yet with different radial phase space density profiles. Using global wave and particle observations, we show that the events have vastly different particle responses despite having similar wave properties. Placing these results in context with past studies, we further show here that nominal radial PSD gradients near geostationary orbit can mask the expected drift resonance particle response and explain (1) the small number of past greater than ~1 MeV drift resonance reports and (2) the restriction of these reports to interplanetary shock events. We argue that future observational studies characterizing radial transport via drift resonance should examine global particle dynamics, including observations of the radial phase space density profile.

79 ASTRONOMY AND ASTROPHYSICS↗

Regulation of Solar Wind Electron Temperature Anisotropy by Collisions and Instabilities

Abstract Typical solar wind electrons are modeled as being composed of a dense but less energetic thermal “core” population plus a tenuous but energetic “halo” population with varying degrees of temperature anisotropies for both species. In this paper, we seek a fundamental explanation of how these solar wind core and halo electron temperature anisotropies are regulated by combined effects of collisions and instability excitations. The observed solar wind core/halo electron data in ( β ∥ , T ⊥ / T ∥ ) phase space show that their respective occurrence distributions are confined within an area enclosed by outer boundaries. Here, T ⊥ / T ∥ is the ratio of perpendicular and parallel temperatures and β ∥ is the ratio of parallel thermal energy to background magnetic field energy. While it is known that the boundary on the high- β ∥ side is constrained by the temperature anisotropy-driven plasma instability threshold conditions, the low- β ∥ boundary remains largely unexplained. The present paper provides a baseline explanation for the low- β ∥ boundary based upon the collisional relaxation process. By combining the instability and collisional dynamics it is shown that the observed distribution of the solar wind electrons in the ( β ∥ , T ⊥ / T ∥ ) phase space is adequately explained, both for the “core” and “halo” components.

Yoon, Peter H. (ORCID:0000000181343790)↗

The cosmic waltz of Coma Berenices and Latyshev 2 (Group X)

Context. Open clusters (OCs) are fundamental benchmarks where theories of star formation and stellar evolution can be tested and validated. Coma Berenices (Coma Ber) and Latyshev 2 (Group X) are the second and third OCs closest to the Sun, making them excellent targets to search for low-mass stars and ultra-cool dwarfs. In addition, this pair will experience a flyby in 10–16 Myr, making it a benchmark to test pair interactions of OCs. Aims. We aim to analyse the membership, luminosity, mass, phase-space (i.e. positions and velocities), and energy distributions for Coma Ber and Latyshev 2 and test the hypothesis of the mixing of their populations at the encounter time. Methods. We developed a new phase-space membership methodology and applied it to Gaia data. With the recovered members, we inferred the phase-space, luminosity, and mass distributions using publicly available Bayesian inference codes. Then, with a publicly available orbit integration code and members’ positions and velocities, we integrated their orbits 20 Myr into the future. Results. In Coma Ber, we identified 302 candidate members distributed in the core and tidal tails. The tails are dynamically cold and asymmetrically populated. The stellar system called Group X is made of two structures: the disrupted OC Latyshev 2 (186 candidate members) and a loose stellar association called Mecayotl 1 (146 candidate members), and both of them will fly by Coma Ber in 11.3 ± 0.5 Myr and 14.0 ± 0.6 Myr, respectively, and each other in 8.1 ± 1.3 Myr. Conclusions. We study the dynamical properties of the core and tails of Coma Ber and also confirm the existence of the OC Latyshev 2 and its neighbour stellar association Mecayotl 1. Although these three systems will experience encounters, we find no evidence supporting the mixing of their populations.

79 ASTRONOMY AND ASTROPHYSICS↗

Feedback and Oscillations: Constructing Feedback Systems for Root Cause Analysis of Oscillations in Power Grids

Dynamic phenomena linked to inverter-based resources (IBRs) have gained global attention. Several IBR-induced dynamics have caused bulk power system-connected wind or solar power plants to trip, and some have even led to widespread outages. In addition, many oscillations have been observed involving IBR power plants. In 2023, the IEEE Power & Energy Society (PES) IBR Subsynchronous Oscillations (SSO) task force published a journal article, “Real-World Subsynchronous Oscillation Events in Power Grids With High Penetrations of Inverter-Based Resources,” in which 19 IBR oscillation events were examined for their causation. Earlier in 2020, another PES task force article, “Definition and Classification of Power System Stability-Revisited & Extended,” authored by prominent academics, introduced converter-driven stability as a new category of stability. The international power grid industry community also took action by publishing the CIGRE Green Book, Power System Dynamic Modelling and Analysis in Evolving Networks (led by Babak Badrzadeh and Zia Emin) in 2024. In August 2024, the Energy Systems Integration Group (ESIG) released a practical guide led by Nick Miller, “Diagnosis and Mitigation of Observed Oscillations in IBR-Dominant Power System: A Practical Guide.” The goal of the guide is to assist practicing engineers in making initial judgments and conducting detailed analyses about oscillations. Finally, when addressing the classification of stability and oscillations, the guide emphasizes a causality-based taxonomy for grouping, such as voltage control-induced oscillations, synchronization-induced oscillations, and frequency or active power control-induced oscillations.

Fan, Lingling [Univ. of South Florida, Tampa, FL (↗

Gerischer Electrochemistry Today

Semiconductor photoelectrochemistry is a dynamic and interdisciplinary field at the forefront of research in solar fuels, energy conversion, and catalysis. Here, this Perspective captures the collective insights from the second Gerischer Electrochemistry Today Symposium, held at Colorado State University in Fort Collins, CO, in August 2024, which convened leading researchers, early-career scientists, and industry partners to define the critical next steps for the field. Through interactive sessions, technical talks, panel discussions, and training initiatives─including a Semiconductor Electrochemistry Bootcamp─the symposium emphasized three pillars of advancement: (i) facilitating the exchange of new ideas in semiconductor electrochemistry and charge separation; (ii) fostering the development of future researchers, research topics, and participation in the semiconductor workforce; and (iii) building community. This Energy Focus distills key themes from the meeting and identifies major knowledge gaps in the following areas: mechanisms of charge separation and recombination, role of defects and disorder, dynamic and operando characterization methods, interfacial chemistry and surface passivation, theoretical and modeling limitations, and standardization and benchmarking. The inclusive and collaborative structure of the symposium enabled the generation of this comprehensive report that will serve as a roadmap for fundamental and applied research in the rapidly evolving field of semiconductor electrochemistry over the next decade.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dynamic Wind Loading on CSP Collectors Caused by Turbulent Wind Fluctuations: Insights from a 2-Year Field Campaign

Concentrating Solar Power (CSP) is a promising solar technology for electricity generation with thermal energy storage and with the additional benefit of industrial heat production. Wind loading on CSP collector structures, such as parabolic troughs or heliostats, is one of the primary drivers of their structural design costs. In particular, dynamic wind loading is a major source of uncertainty in the collector design process, which heavily relies on wind tunnel testing. In the field, the turbulent nature of the incoming wind creates fluctuating loads (support structure loads and resulting mirror deflections) on the collectors, with impacts on fatigue lifetime and optical performance. As is well known, wind tunnel tests cannot entirely reproduce the complex turbulent wind conditions typically observed at full-scale plants. To shed light on this topic, NREL initiated a field campaign at the operational Nevada Solar One (NSO) powerplant that uses parabolic troughs as solar collectors. The aim of the project is a detailed characterization of prevailing wind and turbulence conditions and resulting operational loads on parabolic troughs. We use the published 2-year dataset of high-resolution combined wind and structural loads measurements [1] to characterize the dynamic structural wind response. For quantifying dynamic wind loading, we apply the concept of admittance functions, which are spectral transfer functions that couple the turbulent wind to resulting structural loads (aerodynamic admittance), and to the structural response (mechanical admittance). In practice, aerodynamic admittance describes which turbulent eddy sizes are effective in creating structural loads. The mechanical admittance describes in which frequency ranges these loads are reinforced or dampened by the structure. While these functions are an established concept in civil engineering, their recent application to a single full-scale heliostat [2] proved their broader applicability to CSP collectors. Here, we present a characterization of admittance functions for full-scale parabolic trough collectors and show how wind characteristics (mean wind speed and direction, turbulent kinetic energy, turbulent length scales), the sun-tracking trough angle, and row position alter the admittance functions. Further, we study to which extent the admittance functions are universal for a specific trough geometry and how our findings compare to reported heliostat results. References [1] https://data.openei.org/submissions/5938. [2] Blume, K., Roger, M., and Pitz-Paal, R. 2023b. "Simplified analytical model to describe wind loads and wind-induced tracking deviations of heliostats." Solar Energy, 256, 96-109. https://doi.org/10.1016/j.solener.2023.03.055.

admittance functions↗

Dynamic oxidation of (Mn,Co) 3 O 4 -Coated interconnects for solid oxide electrolysis cells

Solid oxide electrolysis cell stacks are expected to experience dynamic conditions when using renewable electricity derived from wind or solar power. To address this scenario, (Mn,Co) 3 O 4 (MCO)-coated Crofer 22 APU interconnect coupons are subjected to thermal cycling, and intermittent current density, with gas compositions relevant to high-temperature electrolysis (elevated steam:hydrogen ratio and oxygen content). Defects are also intentionally introduced in the MCO coating, to assess whether the difference in oxidation properties of the adjacent coated and uncoated (defective) surfaces causes sufficient stress to damage the protective oxide scale. Specimens with defects are subjected to oxidation for 1000 h at 800 °C, or thermal cycling. Before thermal cycling, some specimens are pre-oxidized to create a thick oxide scale to mimic the scale thickness expected after ~30 kh operation. In all cases, the coating and oxide scale remain well adhered with no cracking observed. Area-specific resistance (ASR) is monitored in both single-atmosphere and dual-atmosphere conditions, and the ASR is stable and is not impacted by dynamic cycling of the current density. Finally, this work provides confidence that the MCO coated interconnect will function as needed in dynamic operation conditions, even with coating defects.

08 HYDROGEN↗

Potential Themis-family Asteroid Contribution to the Jupiter-family Comet Population

Recent dynamical analyses suggest that some Jupiter family comets (JFCs) may originate in the main asteroid belt instead of the outer solar system. This possibility is particularly interesting given evidence that icy main-belt objects are known to be present in the Themis asteroid family. We report results from dynamical analyses specifically investigating the possibility that icy Themis family members could contribute to the observed population of JFCs. Numerical integrations show that such dynamical evolution is indeed possible via a combination of eccentricity excitation apparently driven by the nearby 2:1 mean-motion resonance with Jupiter, gravitational interactions with planets other than Jupiter, and the Yarkovsky effect. We estimate that, at any given time, there may be tens of objects from the Themis family on JFC-like orbits with the potential to mimic active JFCs from the outer solar system, although not all, or even any, may necessarily be observably active. We find that dynamically evolved Themis family objects on JFC-like orbits have semimajor axes between 3.15 and 3.40 au for the vast majority of their time on such orbits, consistent with the strong role that the 2:1 mean-motion resonance with Jupiter likely plays in their dynamical evolution. We conclude that a contribution from the Themis family to the active JFC population is plausible, although further work is needed to better characterize this contribution.

79 ASTRONOMY AND ASTROPHYSICS↗

Ultrafast Electron Transfer in Au-Cyanobacteria Hybrid for Solar to Chemical Production

The rise of inorganic-biohybrid organisms for solar-to-chemical production has spurred mechanistic investigations into the dynamics of the biotic-abiotic interface to drive the development of next-generation hybrid systems. The model system, cyanobacteria-gold nanoparticle hybrids, combines a light harvester with a photosynthetic bacterium to drive the reduction of CO2 to glycerol with improved efficiency and increased glycerol production by 14.6%, in comparison to cyanobacteria only. In this work, we report insights into this unique photochemical behavior and propose a charge-transfer pathway from Au nanoparticle to cyanobacteria. Transient absorption (TA) spectroscopy revealed that photoexcited electron transfer rates are on the order of a few ps to the potential electron acceptor in photosystem II. This work represents a promising platform to utilize a conventional spectroscopic methodology to extract insights from more complex biotic-abiotic hybrid systems.

charge transfer↗

Light induced ion migration studies in perovskite solar cell using nonlinear impedance spectroscopy

Complex interactions between mobile ions and charge carriers in perovskite solar cells (PSCs) make it challenging to fully understand their dynamic interplay. Exposure to light further complicates these interactions, altering the system’s dynamics and inducing nonlinear effects that lead to changes in the J−V curve. Understanding these effects is crucial for improving the operational stability of PSCs. Impedance spectroscopy (IS) is a powerful technique for evaluating relaxation processes in the frequency domain; however, it is limited in capturing nonlinear contributions. Here, in this work, nonlinear impedance spectroscopy (NLIS) is employed to analyze the higher harmonic response to AC perturbation, both in the dark and after short-term light exposure. A shift in the low-frequency (LF) higher harmonic peak is observed after open-circuit light exposure, attributed to an altered electric field suggesting ion re-distribution, whereas closed-circuit exposure shows no LF shift, indicating minimal ion movement. Additionally, light exposure reduces higher-order admittance, more notably in open-circuit conditions, suggesting decreased recombination. Temperature-dependent analysis was conducted to characterize the activation energy of migrating species, identifying iodide as the dominant migrating ion.

14 SOLAR ENERGY↗

Application of New Los Alamos OPLIB Opacities in Solar Modeling Using the Mesa Code

The Sun provides the only local laboratory to test our understanding of stellar physics. The production, then, of valid dynamical models of the Sun is critical to how we think about other stars. Despite improvements in modeling methodologies and abundance measurements, solar models continue to reproduce errors in convection zone depth and surface helium abundance compared to helioseismic observations. Using the 1D stellar evolution code MESAstar, this work first evaluates the effect of changes to timestep resolution and mixing length theory on model outputs. A standard test case is then constructed with both GS98 and AGSS09 abundances using OP and OPAL opacities before implementing the new Los Alamos OPLIB opacities. It is shown that, when using GS98 abundances, OPLIB opacities improve agreement with helioseismic inference of the convection zone base radius, R czb , by 1.68-σ and 1.19-σ compared to OP and OPAL, respectively, while worsening agreement with the inferred envelope helium mass fraction, Y surf , by 0.63-σ and 0.98-σ for OP and OPAL.

14 SOLAR ENERGY↗

Low embodied energy and carbon, high lifetime silicon boules via a combined chemical vapor deposition/float zone process

This work evaluates a new process route to making float zone (Fz)-quality silicon wafers using a combination of computational fluid dynamics (CFD) modeling and technoeconomic analysis. Our analysis finds that the new process competes with Czochralski (Cz)-grown wafers on a levelized cost of energy system level. The new process also decreases embodied energy and carbon of silicon photovoltaics (PV) by ~6x circumventing the energy-costly Siemens process used in polycrystalline silicon (poly-Si) production plants to generate feedstock for Fz and Cz boules. Instead of using poly-Si from the Siemens process to feed crystallization, the new process uses the high-purity, trichlorosilane (TCS) precursor gas to grow a poly-Si feed rod in-situ during a modified Fz1,2 boule growth process. The gas-to-boule float zone process enables opportunity to produce high-purity (low metals and oxygen content), uniformly doped single crystal silicon boules and wafers with high bulk lifetimes (τ bulk > 15 ms) to enable higher efficiency cells (>27 %) with fewer known degradation mechanisms than Czochralski (Cz)-grown wafers. These benefits reduce the levelized cost of electricity (LCOE) of PV-produced electricity. Here we show the results of our CFD and chemical modeling of the process to prove feasibility and economic viability.

14 SOLAR ENERGY↗