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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

A rare gas optics-free absolute EUV photon spectrometer for solar system studies

We have developed a prototype spectrometer for space applications which require long term absolute EUV photon flux measurements. In this recently developed spectrometer, the energy spectrum of the incoming photons is transformed directly into an electron energy spectrum by taking advantage of the photoelectric effect in one of several rare gases at low pressures. Using an electron energy spectrometer operating at a few eV, and followed by an electron multiplying detector, pulses due to individual electrons are counted. The overall efficiency of this process is essentially independent of gain drifts in the signal path, and the secular degradation of optical components which is often a problem in other techniques is avoided.

Daybell, M. D.↗
NASA NTRS1991

Instrument design and test results of the new all-reflection spatial heterodyne spectrometer

An all-reflection spatial heterodyne spectrometer (SHS) has been recently developed. The advantages over conventional high-resolution grating spectrometers are that the SHS requires no mechanical scanning, a self-compensating optical design permits easy alignment, and it is much smaller than other spectrometers of comparable resolution. Since all beam-splits and recombinations occur by reflection off of a diffraction grating, the interferometer is capable of operating well into the extreme ultraviolet (EUV) and possibly into the soft X-ray region. A description of the design and the characteristics of the instrument is presented. Also, test results, including sample interferograms as well as their Fourier-transformed spectra, at both visible and UV wavelengths are shown. Finally, we report on future developments and possible applications.

Bush, Brett C.↗
NASA NTRS1993

Data processing and calibration for tunable diode laser harmonic absorption spectrometers

Data processing and calibration methods are described for tunable diode laser absorption spectrometers which produce harmonic absorption spectra as raw data for measuring gas mixing ratios down to parts-per-trillion levels at a variety of pressures. The methods, which take advantage of modern computer speed, memory, and data storage capabilities, are applicable to the detection of weakly absorbing gases in quantitative industrial monitoring, in addition to aircraft and balloon atmospheric measurements for which they were designed. Algorithms for calibration and data analysis, including rejection of erroneous spectra, variation of effective integration time, spectral alignment prior to averaging, and plotting and archiving of results, have been tested on actual stratospheric laser spectra recorded by the Aircraft Laser Infrared Absorption Spectrometer (ALIAS) spectrometer in numerous flights of NASA's ER-2 aircraft.

May, Randy D.↗
NASA NTRS1991

Current instrument status of the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS)

An upgraded version of AVIRIS, an airborne imaging spectrometer based on a whiskbroom-type scanner coupled via optical fibers to four dispersive spectrometers, that has been in operation since 1987 is described. Emphasis is placed on specific AVIRIS subsystems including foreoptics, fiber optics, and an in-flight reference source; spectrometers and detector dewars; a scan drive mechanism; a signal chain; digital electronics; a tape recorder; calibration systems; and ground support requirements.

Eastwood, Michael L.↗
NASA NTRS1993

Expert system-based mineral mapping in northern Death Valley, California/Nevada, using the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS)

Integrated analysis of imaging spectrometer data and field spectral measurements were used in conjunction with conventional geologic field mapping to characterize bedrock and surficial geology at the northern end of Death Valley, California and Nevada. A knowledge-based expert system was used to automatically produce image maps showing the principal surface mineralogy from Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data. Linear spectral unmixing of the AVIRIS data allowed further determination of relative mineral, abundances and identification of mineral assemblages and mixtures. The imaging spectrometer data show the spatial distribution of spectrally distinct minerals occurring both as primary rockforming minerals and as alteration and weathering products. Field spectral measurements were used to verify the mineral maps and field mapping was used to extend the remote sensing results. Geographically referenced image maps produced from these data form new base maps from which to develop improved understanding of the processes of deposition and erosion affecting the present land surface.

Kruse, F. A.↗
NASA NTRS1994

Low-Power CMOS Digital Autocorrelator Spectrometer

Prototype digital autocorrelator spectrometer circuit designed and built as assembly of few very-large-scale integrated (VLSI) complementary metal oxide/semiconductor (CMOS) circuit chips. Spectrometer contains 128 frequency channels and operates at clock rate of as much as 40 MHz. Total dc power needed is only 6 W. Digital autocorrelator spectrometer consists of four 32-channel autocorrelator chips that collectively produce 128-point spectrum of input signal as computed by use of Fourier transform.

Chandra, Kumar M.↗
NASA NTRS1993

The Los Alamos neutron spectrometer for the Lunar Scout-1 mission

We review the current status of the Los Alamos program to develop a neutron spectrometer for the Lunar Scout-1 mission, which is the first of two such missions to obtain global compositional, gravity, topography, and image maps of the lunar surface during nominal one-year missions. The neutron spectrometer will measure fast and slow (epithermal and thermal) neutrons in the ranges of 0.5 MeV to 25 MeV and 0.01 eV to more than 1 keV, respectively. The neutron spectrometer will consist of two independent instruments, a fast-neutron one, and a thermal and epithermal one. The measured neutron fluxes are very sensitive to hydrogen in the top meter of the lunar surface and provide additional information about lunar composition.

Auchampaugh, George↗
NASA NTRS1992

A comparison of LOWTRAN-7 corrected Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data with ground spectral measurements

Atmospheric correction of imaging spectroscopy data is required for quantitative analysis. Different models were proposed for atmospheric correction of these data. LOWTRAN-7 is a low-resolution model and computer code for predicting atmospheric transmittance and background radiance from 0 to 50,00 cm(sup -1) which was developed by the Air Force Geophysics Laboratory. The Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data used are radiometrically calibrated and include the 28 Sep. 1989 Providence Fan flight line segment 07, California. It includes a dark gravel surface defined as a calibration site by the Geologic Remote Sensing Field Experiment (GRSFE). Several ground measurements of portable spectrometer DAEDALUS AA440 Spectrafax were taken during the GRSFE, July 1989 field campaign. Comparisons of the LOWTRAN-7 corrected AVIRIS data with the ground spectrometer measurement were made.

Xu, Peng-Yang↗
NASA NTRS1995

Far-infrared heterodyne spectrometer

A far-infrared heterodyne spectrometer was designed and built by our group for observations of atomic and molecular lines from interstellar clouds. Linewidths as narrow as 1 km/s can be expected from such regions, and so the spectrometer is designed with sub-km/s resolution so that observed line profiles will be resolved. Since its debut on the Kuiper Airborne Observatory (KAO) in 1985, the instrument has been used in regular annual flight programs from both Moffett Field, CA and Christchurch, NZ. The basic plan of the spectrometer remains unchanged from the original design presented at the previous airborne science symposium. Numerous improvements and updates to the technical capability have of course been included over the many years of operational service.

Boreiko, Rita T.↗
NASA NTRS1994

Shuttle Upper Atmosphere Mass Spectrometer Experimental Flight Results

Calibrated pressure measurements for species with mass-to-charge ratios up to 50 amu/e(-) were obtained trom the shuttle upper atmosphere mass spectrometer experiment during re-entry on the STS-35 mission. The principal experimental objective is to obtain measurements of freestream density in the hypersonic rarefied flow flight regime. Data were collected from 180 to about 87 km. However, data above 115 km were contaminated from a source of gas emanating from pressure transdueers connected in parallel to the mass spectrometer. At lower altitudes, the pressure transducer data are compared to the mass spectrometer total pressure with excellent agreement. Near the orifice entrance, a significant amount of CO2 was generated from chemical reactions. The freestream density in the rarefied flow flight regime is calculated using an orifice pressure coefficient model based upon direct simulation Monte Carlo results. This density, when compared with the 1976 U.S. Standard Atmosphere model, exhibits the wavelike nature seen on previous flights using accelerometry. Selected spectra are presented at higher altitudes (320 km) showing the effects of the ingestion of gases from a forward fuselage fuel dump.

Blanchard, R. C.↗
NASA NTRS1997

Performance of an INTEGRAL spectrometer model

Model calculations for the INTEGRAL spectrometer (SPI) onboard the future INTErnational Gamma Ray Astrophysics Laboratory (INTEGAL) are presented, where the sensitivity for narrow lines is based on estimates of the background level and the detection efficiency. The instrumental background rates are explained as the sum of various components that depend on the cosmic ray intensity and the spectrometer characteristics, such as the mass distribution around the Ge detectors, the passive material, the characteristics of the detector system and the background reduction techniques. Extended background calculations were performed with Monte Carlo simulations and using semi-empirical and calculated neutron and proton cross sections. In order to improve the INTEGRAL spectrometer sensitivity, several designs and background reduction techniques were compared for an instrument with a fixed detector volume.

Jean, P.↗
NASA NTRS1997

Design of An Improved Miniature Ion Neutral Mass Spectrometer for NASA Applications

The ion optics of NASA's Ion Neutral Mass Spectrometer (INMS) sensor was simulated with three dimensional models of the open source, the quadrupole deflector, the exit lens system and the quadrupole mass analyzer to design more compact models with lower weight. Comparison of calculated transmission with experimental results shows good agreement. Transmission analyses with varying geometrical parameters and voltages throw light on possible ways of reducing the size of the sensor. Trajectories of ions of mass 1-99 amu were simulated to analyze and optimize transmission. Analysis of open source transmission with varying angle of attack shows that the angular acceptance can be considerably increased by programming the voltages on the ion trap/ collimator. Analysis of transmission sensitivity to voltages and misalignments of the quadrupole deflector rods indicate that increased transmission is possible with a geometrically asymmetrical deflector and a deflector can be designed with much lower sensitivities of transmission. Bringing the disks closer together can decrease the size of the quadrupole deflector and also increase transmission. The exit lens system can be redesigned to be smaller by eliminating at least one electrode entirely without loss of transmission. Ceramic materials were investigated to find suitable candidates for use in the construction of lighter weight mass spectrometer. A high-sensitivity, high-resolution portable gas chromatograph mass spectrometer with a mass range of 2-700 amu has been built and will be commercialized in Phase 3.

Swaminathan, Viji K.↗
NASA NTRS1994

An Optics Free Spectrometer for the Extreme Ultraviolet

The optics-free spectrometer is a photon spectrometer. It provides the photon spectrum of a broadband source by converting photons of energy E into electrons of energy E', according to the Einstein relation, E' = E - Ei. E, is the ionization threshold of the gas target of interest (any of the rare gases are suitable) and E is the incoming photon energy. As is evident from the above equation, only a single order spectrum is produced throughout the energy range between the first and second ionization potentials of the rare gas used. Photons with energy above the second ionization potential produce two groups of electrons, but they are readily distinguished from each other. This feature makes this device extremely useful for determining the true spectrum of a continuum source or a many line source. The principle of operation and the laboratory results obtained with a representative configuration of the optics-free spectrometer are presented.

Judge, D. L.↗
NASA NTRS1999

Interchange for Joint Research Entitled: Miniature Laser Spectrometer for Stable Isotope Measurements

As a first step in successfully measuring carbon isotopes optically we have previously demonstrated the measurement of C-13/C-12 to a precision of 0.1% using a tunable diode laser and CO2 spectral lines in the 2300/cm spectral region. This precision of 0.1% (1 per mil) for carbon isotopes is a value sufficiently precise to provide important isotopic data of interest to astrobiologists. The precision presently attainable in gases is sufficient to permit our instrument to be used in the measurement of isotopic ratios of interest to astrobiologists as well as geologists and planetary scientists. A small stable isotope laser spectrometer with a 10 cm path gas cell was designed and constructed. The cell was integrated with a liquid nitrogen cooled tunable diode laser and indium antimonide detector for evaluation. Using the small gas cell, preliminary measurements of 13C/12C in CO2 were made employing single-beam sequential acquisitions of the required spectral data. The results indicate an accuracy of 0.1% which is sufficiently high to make meaningful measurements of martian samples. In addition, improvements in the spectrometer gas handling system have been made to markedly reduce C-13/C-12 isotopic fractionation during sample gas cell loading which we expect will lead to further improvements in precision and accuracy. An important part of making isotopic ratio measurements in solid samples using diode lasers is the conversion of the elements of interest to molecules that have absorption spectra in the mid-ir spectral range accessible by tunable diode lasers. In this project we have investigated the necessary sample preparation procedures to extract carbon, an element of astrobiological importance, from model soil compounds and to convert it to CO2, a molecule with appropriate optical absorption characteristics for reliable laser spectrometer isotopic ratio measurements of 13C/12C. We have considered calcium carbonate as a model for a component of the martian regolith, and we have formulated a simple heating protocol for extracting carbon in the form of CO2.

Becker, J. F.↗
NASA NTRS2000

Using the World Primary Standard Dobson Spectrometer to Monitor the Stability of a Multi-Instrument Satellite Ozone Dataset

NASA is creating a long term satellite ozone time series by combining data from multiple instruments: Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) (1978 - 1993), Meteor 3 TOMS (1991 - 1994), Earth Probe TOMS (1996 - present), Nimbus 7 SB-JV (1978 - 1990), NOAA-9 Solar Backscatter UV Spectrometer (SBUV/2) (1984 - 1997), NOAA-11 SBUV/2 (1989 - 1994), and NOAA-14 SBUV/2 (1995 - present). The stability of individual data sets and possible instrument-to-instrument differences are best checked by comparison with ground-based measurements. We have examined the time dependence of the calibrations of these instruments by comparing satellite derived ozone with that measured by the world primary standard Dobson spectrometer No. 83. This instrument has been maintained since 1962 as a standard for total ozone to an uncertainty of plus or minus 0.5%. Measurements of AD pair ozone made with instrument No. 83 at Mauna Loa observatory most summers since 1979 were compared with coincident TOMS and SBUV(/2) ozone measurements. The comparison shows that the various instruments were stable relative to instrument No. 83 to within about plus or minus 1%, but that there are instrument-to-instrument biases of as much as 3%. Earth Probe TOMS, for example, is 1% to 2% high relative to Nimbus 7 TOMS when the world standard instrument is used as a transfer standard. Similar results are seen when comparisons are made with an ensemble of 41 Dobson stations throughout the world, demonstrating that the ensemble as a whole is stable despite the fact that many instruments within the ensemble have clear calibration changes.

McPeters, R.D.↗
NASA NTRS2000

Spectral Anomalies in the 11 and 12 micron Region From the Mariner Mars 7 Infrared Spectrometer

Two hundred-forty infrared spectra acquired by the 1969 Mariner Mars 7 Infrared Spectrometer (IRS), spanning the wavelength region 1.8-14.4 micron (5550-690/cm), have recently been recovered and calibrated in both wavelength and intensity. An examination of these IRS spectra has revealed absorptions at 11.25 and 12.5 micron that have not previously been reported for Mars. A search of the literature and spectral data bases shows that materials that exhibit a doublet at 11.25 and 12.5 micron are rare. In this paper we examine potential causes for these features and include a detailed discussion of carbonates, goethite, CO2 ice, and water ice. CO2 ice and water ice measured in transmission do not exhibit bands that match those recorded at 11.25 and 12.5 micron for Mars, which indicates that CO2 or water ice clouds are not the source of these features. Since these bands show no clear correlation with atmospheric path length, they are most likely caused by a surface material. In the IRS database they appear to be exceptionally intense in the western part of the Hellas basin. Goethite exhibits bands that are a good spectral match, but confirming whether goethite causes the features will require additional studies of the 20-50 micron region. These studies will require laboratory measurements of weathering coatings and an examination of spectra recorded of Mars by the 1971 Mariner Mars Infrared Interferometer Spectrometer (IRIS; 5-50 micron 2000200/cm) and the 1996 Thermal Emission Spectrometer (TES; 6-50 micron 1667-200/cm).

Kirkland, Laurel E.↗
NASA NTRS2001

Development of a Submillimeter-Wavelength Immersion Grating Spectrometer

The broad goal of this project was to develop a broadband, moderate-resolution spectrometer for submillimeter wavelengths. Our original approach was to build an immersion grating spectrometer, and as such, the first step was to identify the best material (lowest loss, highest index) for the grating medium, and to characterize its properties at the foreseen optical-bench operating temperature of 1.5 K. To this end, we put our initial efforts into upgrading an existing laboratory submillimeter Fourier transform spectrometer, which allowed us to carry out the requisite materials measurements. The associated cryogenic detector dewar was also redesigned and rebuilt to carry out this work. This dewar houses the 1.5 K detector and the filter wheel used in the materials characterization. Our goal was to have the beam propagate through the samples as uniformly as possible, so the optics were redesigned to allow for the samples to be traversed by a well-defined collimated beam. The optics redesign also placed the samples at an image of the aperture stop located within the FTS. After the rebuild, we moved into the testing phase.

Phillips, T. G.↗
NASA NTRS2001

A Quadrupole Ion Trap Mass Spectrometer for Quantitative Analysis of Nitrogen-Purged Compartments within the Space Shuttle

To enter orbit, the Space Shuttle burns 1.8 million liters of liquid hydrogen combined with 0.8 million liters of liquid oxygen through three rocket engines mounted in the aft. NASA monitors the nitrogen-purged aft compartment for increased levels of hydrogen or oxygen in order to detect and determine the severity of a cryogenic fuel leak. Current monitoring is accomplished with a group of mass spectrometer systems located as much as 400 feet away from the Shuttle. It can take up to 45 seconds for gas to reach the mass spectrometer, which precludes monitoring for leaks in the final moments before liftoff (the orbiter engines are started at T-00:06 seconds). To remedy the situation, NASA is developing a small rugged mass spectrometer to be used as point-sensors around the Space Shuttle. As part of this project, numerous mass analyzer technologies are being investigated. Presented here are the preliminary results for one such technology, quadrupole ion trap mass spectrometry (QITMS). A compact QITMS system has been developed in-house at the University of Florida for monitoring trace levels of four primary gases, hydrogen, helium, oxygen, and argon, all in a nitrogen background. Since commercially available QITMS systems are incapable of mass analysis at m/z(exp 2), the home-built system is preferred for the evaluation of QITMS technology.

Ottens, Andrew K.↗