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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Droplet size effects on NO/x/ formation in a one-dimensional monodisperse spray combustion system

A one-dimensional monodisperse aerosol spray combustion facility is described and experimental results of post flame NO/NO(x) emissions are presented. Four different hydrocarbon fuels were studied: isopropanol, methanol, n-heptane, and n-octane. The results indicate an optimum droplet size in the range of 48-58 microns for minimizing NO/NO(x) production for all of the test fuels. This NO(x) behavior is associated with droplet interactions and the transition from diffusive type of spray burning to that of a prevaporized and premixed case. Decreasing the droplet size results in a trend of increasing droplet interactions, which suppresses temperatures and reduces NO(x). This trend continues until prevaporization effects begin to dominate and the system tends towards the premixed limit. The occurrence of the minimum NO(x) point at different droplet diameters for the different fuels appears to be governed by the extent of prevaporization of the fuel in the spray, and is consistent with theoretical calculations based on each fuel's physical properties.

Sarv, H.↗
NASA NTRS1991

Droplet-turbulence interactions in subcritical and supercritical evaporating sprays

The objective of this research is to obtain an improved understanding of droplet turbulence interactions in vaporizing liquid sprays under conditions typical of those encountered in liquid fueled rocket engines. The interaction between liquid droplets and the surrounding turbulent gas flow affects droplet dispersion, droplet collisions, droplet vaporization and gas-phase, fuel-oxidant mixing, and therefore has a significant effect on the engine's combustion characteristics. An example of this is the role which droplet-turbulence interactions are believed to play in combustion instabilities. Despite their importance, droplet-turbulence interactions and their effect on liquid fueled rocket engine performance are not well understood. This is particularly true under supercritical conditions, where many conventional concepts, such as surface tension, no longer apply. Our limited understanding of droplet-turbulence interactions, under both subcritical conditions, represents a major limitation in our ability to design improved liquid previously unavailable information and valuable new insights which will directly impact the design of future liquid fueled rocket engines, as well as, allow for the development of significantly improved spray combustion models, making such models useful design tools.

Santavicca, Domenic A.↗
NASA NTRS2005

Emissions Prediction and Measurement for Liquid-Fueled TVC Combustor with and without Water Injection

An investigation is performed to evaluate the performance of a computational fluid dynamics (CFD) tool for the prediction of the reacting flow in a liquid-fueled combustor that uses water injection for control of pollutant emissions. The experiment consists of a multisector, liquid-fueled combustor rig operated at different inlet pressures and temperatures, and over a range of fuel/air and water/fuel ratios. Fuel can be injected directly into the main combustion airstream and into the cavities. Test rig performance is characterized by combustor exit quantities such as temperature and emissions measurements using rakes and overall pressure drop from upstream plenum to combustor exit. Visualization of the flame is performed using gray scale and color still photographs and high-frame-rate videos. CFD simulations are performed utilizing a methodology that includes computer-aided design (CAD) solid modeling of the geometry, parallel processing over networked computers, and graphical and quantitative post-processing. Physical models include liquid fuel droplet dynamics and evaporation, with combustion modeled using a hybrid finite-rate chemistry model developed for Jet-A fuel. CFD and experimental results are compared for cases with cavity-only fueling, while numerical studies of cavity and main fueling was also performed. Predicted and measured trends in combustor exit temperature, CO and NOx are in general agreement at the different water/fuel loading rates, although quantitative differences exist between the predictions and measurements.

Brankovic, A.↗
NASA NTRS1991

Ignition and combustion of metallized propellants

The overall objective is the development of a fundamental understanding of the ignition and combustion of aluminum-based slurry (or gel) propellant droplets using a combination of experiment and analysis. Specific objectives are the following: (1) The development and application of a burner/spray rig and single particle optical diagnosis to study the detailed ignition and combustion behavior of small droplets; (2) Understanding the role of surfactants and gellants (or other additives) in promoting or inhibiting secondary atomization of propellant droplets; and (3) The extension of previously developed analytical models and the development of new models to address the phenomena associated with microexplosions (secondary atomization).

Turns, Stephen R.↗
NASA NTRS1988

Finite-rate water condensation in combustion-heated wind tunnels

A quasi-one-dimensional method for computing finite rate nucleation and droplet growth of water in a supersonic expansion of combustion products is presented. Sample computations are included for the Langley 8 foot High Temperature Tunnel, but the method can also be applied to other combustion heated wind tunnels. The sample results indicate that the free stream static pressure can be in the range of 25 to 60 percent greater than that computed for isentropic nozzle flow without water condensation. The method provides a tool for examining the effects of water condensation on static state properties and velocity of the supersonic stream in combustion heated wind tunnels.

Erickson, Wayne D.↗
NASA NTRS1985

Oxides of Nitrogen Emissions from the Combustion of Monodisperse Liquid Fuel Sprays

A study of NO sub x formation in a one dimensional monodisperse spray combustion system, which allowed independent droplet size variation, was conducted. Temperature, NO and NO sub x concentrations were measured in the transition region, encompassing a 26 to 74 micron droplet size range. Emission measurements of hydrocarbons, carbon monoxide, carbon dioxide and oxygen were also made. The equivalence ratio was varied between 0.8 and 1.2 for the fuels used, including methanol, isopropanaol, n-heptane and n-octane. Pyridine and pyrrole were added to n-heptane as nitrogen-containing additives in order to simulate synthetic fuels. Results obtained from the postflame regions using the pure fuels indicate an optimum droplet size in the range of 43 to 58 microns for minimizing NO sub x production. For the fuels examined, the maximum NO sub x reductions relative to the small droplet size limit were about 10 to 20% for lean and 20 to 30% for stoichiometric and rich mixtures. This behavior is attributed to droplet interactions and the transition from diffusive to premixed type of burning. Preflame vaporization controls the gas phase stoichiometry which has a significant effect on the volume of the hot gases surrounding a fuel droplet, where NO sub x is formed.

Sarv, H.↗
NASA NTRS1997

Formation and Combustion of Unconfined Drop Clusters in Microgravity

Single-drop and droplet array studies have become common methods to isolate and investigate the effects of any of the complexities that enter into the drop combustion process. Microgravity environments are required to allow larger drops to be studied while minimizing or eliminating the confounding effects of buoyancy. Based on the results from current isolated drop, drop array, and spray studies funded through the Microgravity Science and Applications Division, it has become clear that even with the effects of buoyancy removed, the extrapolation of results from droplet array studies to spray flames is difficult. The problem occurs because even the simplest spray systems introduce complexities of multi-disperse drop sizes and drop-drop interactions, coupled with more complicated fluid dynamics. Not only do these features make the interpretation of experimental data difficult, they also make the problem very difficult to analyze computationally. Group combustion models, in which the interaction between droplets is treated on a statistical manner, have become a popular method to investigate the behavior of large numbers of interacting droplets, particularly through the work of Ryan et al. and Bellan and co-workers. While these models idealize the actual spray systems to a point where they can be treated computationally, the experimental analogy to these models is difficult to achieve because it requires the formation and Combustion of drop clusters without the effects of buoyancy. Therefore, even though these models have provided useful and insightful information, the verification of the results by direct comparison with experimental data is still lacking.

Liu, S.↗
NASA NTRS1983

Pollutant Formation in Monodisperse Fuel Spray Combustion

The combustion of liquid sprays represents an extremely important class of combustion processes. In the transition region, encompassing droplet sizes in the range of 25-80 micron diameter, the mixing and evaporation processes are both incomplete at the flame front and burning occurs in a combined diffusive and premixed fashion. Under these conditions, the relative importance of heterogeneous and homogeneous effects in dominating the combustion process is switched and gives rise to a number of interesting phenomena. NO (sub x) formation in monodisperse spray combustion was investigated with the following specific objectives: (1) to quantitatively determine the effect of droplet size, number density, etc. on NO sub x formation in monodisperse fuel spray combustion; and (2) to isolate the important physical and chemical phenomena in NO sub x formation in these combustion systems.

Cernansky, N. P.↗
NASA NTRS1974

High pressure combustion of liquid fuels

Measurements were made of the burning rates and liquid surface temperatures for a number of alcohol and n-paraffin fuels under natural and forced convection conditions. Porous spheres ranging in size from 0.64-1.9 cm O.D. were emloyed to simulate the fuel droplets. The natural convection cold gas tests considered the combustion in air of methanol, ethanol, propanol-1, n-pentane, n-heptane, and n-decane droplets at pressures up to 78 atmospheres. The pressure levels of the natural convection tests were high enough so that near critical combustion was observed for methanol and ethanol vaporization rates and liquid surface temperature measurements were made of droplets burning in a simulated combustion chamber environment. Ambient oxygen molar concentrations included 13%, 9.5% and pure evaporation. Fuels used in the forced convection atmospheric tests included those listed above for the natural convection tests. The ambient gas temperature ranged from 600 to 1500 K and the Reynolds number varied from 30 to 300. The high pressure forced convection tests employed ethanol and n-heptane as fuels over a pressure range of one to 40 atmospheres. The ambient gas temperature was 1145 K for the two combustion cases and 1255 K for the evaporation case.

Canada, G. S.↗
NASA NTRS1989

Evolution Of Cenospheres

Microscopy reveals changes in structure during combustion. Experiments performed to trace evolution of structures of droplets of burning fuel oil. Many droplets burn incompletely, forming cenospheres. Knowledge of structure at various stages of combustion process contributes to efforts to design equipment to burn cenospheres.

Kwack, Eug Y.↗
NASA NTRS1989

NOx formation from the combustion of monodisperse n-heptane sprays doped with fuel-nitrogen additives

A series of experiments with simulated synthetic fuels were conducted in order to investigate the effect of droplet size on the conversion of fuel-nitrogen to NOx. Pyridine and pyrrole were added to n-heptane as nitrogen-containing additives and burned as monodisperse fuel droplets under various operating conditions in a spray combustion facility. The experimental results indicate that under stoichiometric and fuel-rich conditions, reducing the droplet size increases the efficiency of fuel-N conversion to NOx. This observation is associated with improved oxidation of the pyrolysis fragments of the additive by better oxygen penetration through the droplet flame zone. The dominant reactions by which fuel-N is transformed to NOx were also considered analytically by a premixed laminar flame code. The calculations are compared to the small droplet size results.

Sarv, Hamid↗
NASA NTRS1994

Ignition and combustion characteristics of metallized propellants, phase 2

Experimental and analytical investigations focusing on aluminum/hydrocarbon gel droplet secondary atomization and its effects on gel-fueled rocket engine performance are being conducted. A single laser sheet sizing/velocimetry diagnostic technique, which should eliminate sizing bias in the data collection process, has been designed and constructed to overcome limitations of the two-color forward-scatter technique used in previous work. Calibration of this system is in progress and the data acquisition/validation code is being written. Narrow-band measurements of radiant emission, discussed in previous reports, will be used to determine if aluminum ignition has occurred in a gel droplet. A one-dimensional model of a gel-fueled rocket combustion chamber, described in earlier reports, has been exercised in conjunction with a two-dimensional, two-phase nozzle code to predict the performance of an aluminum/hydrocarbon fueled engine. Estimated secondary atomization effects on propellant burnout distance, condensed particle radiation losses to the chamber walls, and nozzle two phase flow losses are also investigated. Calculations indicate that only modest secondary atomization is required to significantly reduce propellant burnout distances, aluminum oxide residual size, and radiation heat losses. Radiation losses equal to approximately 2-13 percent of the energy released during combustion were estimated, depending on secondary atomization intensity. A two-dimensional, two-phase nozzle code was employed to estimate radiation and nozzle two phase flow effects on overall engine performance. Radiation losses yielded a one percent decrease in engine Isp. Results also indicate that secondary atomization may have less effect on two-phase losses than it does on propellant burnout distance and no effect if oxide particle coagulation and shear induced droplet breakup govern oxide particle size. Engine Isp was found to decrease from 337.4 to 293.7 seconds as gel aluminum mass loading was varied from 0-70 wt percent. Engine Isp efficiencies, accounting for radiation and two phase flow effects, on the order of 0.946 were calculated for a 60 wt percent gel, assuming a fragmentation ratio of five.

Mueller, D. C.↗
NASA NTRS2001

Comustion of HAN-Based Monopropellant Droplets in Reduced Gravity

Hydroxylammonium nitrate (HAN) is a major constituent in a class of liquid monopropellants that have many attractive characteristics and which display phenomena that differ significantly from other liquid monopropellants. They are composed primarily of HAN, H2O and a fuel species, often triethanolammonium nitrate (TEAN). HAN-based propellants have attracted attention as liquid gun propellants, and are attractive for NASA spacecraft propulsion applications. A representative propellant is XM46. This mixture is 60.8% HAN, 19.2% TEAN and 20% H2O by weight. Other HAN-based propellant mixtures are also of interest. For example, methanol and glycine have been investigated as potential fuel species for HAN-based monopropellants for thruster applications. In the present research, experimental and theoretical studies are performed on combustion of HAN-based monopropellant droplets. The fuel species considered are TEAN, methanol and glycine. Droplets initially in the mm size range are studied at pressures up to 30 atm. These pressures are applicable to spacecraft thruster applications. The droplets are placed in environments with various amounts of Ar, N2, O2, NO2 and N2O. Reduced gravity is employed to enable observations of burning rates and flame structures to be made without the complicating effects of buoyant and forced convection. Normal gravity experiments are also performed in this research program. The experiment goals are to provide accurate fundamental data on deflagration rates, gasphase temperature profiles, transient gas-phase flame behaviors, the onset of bubbling in droplets at lower pressures, and the low-pressure deflagration limit. Theoretical studies are performed to provide rational models of deflagration mechanisms of HAN-based liquid propellants. Besides advancing fundamental knowledge, this research should aid in applications (e.g., spacecraft thrusters and liquid propellant guns) of this unique class of monopropellants.

Shaw, B. D.↗
NASA NTRS1972

Investigation of critical burning of fuel droplets

Fuel droplets were simulated by porous spheres having diameters in the range 0.63 to 1.9 cm and combustion tests were conducted at pressures up to 78 atm in a quiescent cold air environment. Measurements were made of the burning rate and liquid surface temperature during steady combustion. A high pressure flat flame burner apparatus is under development in order to allow testing of high pressure droplet burning in a combustion gas environment. Work was continued on the high pressure strand combustion characteristics of liquid fuels, with the major emphasis on hydrazine. Data was obtained on the burning rate and liquid surface temperatures at pressures in the range 7 to 500 psia. The response of a burning liquid monopropellant to imposed pressure oscillations is being investigated.

Allison, C. B.↗
NASA NTRSDate not supplied

Comparison of Non-Combusting Spray Fields in a Model Combustor using Shadowgraphy

Droplet sizes were measured using shadowgraphy in the spray issuing from the center element of the baseline configuration of the NASA 7-element lean direct injector (LDI) array. Each LDI element consisted of a 60 degree clockwise axial air swirler, converging-diverging venturi, and a pressure-swirl atomizer positioned with its tip at the venturi throat. The non-combusting measurements were conducted using water spray in a 3-inch diameter research combustor operating at pressure of 5 bar and air inlet temperature of 700 K. At these inlet conditions, three air flow rates were used, producing reference velocities of 7.6, 15.2, and 22.9 m/s. Only the center nozzle was used. At each reference velocity, water flow rates were adjusted to simulate a common equivalence. Data were collected at a frame rate of 15 Hz over a range of positions near the LDI dump plane, and downstream, along the combustor centerline. Velocity measurements were achieved by use of a dual head Nd:YAG laser and frame transfer PIV camera. Droplet size and velocity, mass and number density, and volume fraction are compared at these inlet conditions to determine the effect of nozzle pressure drop on the measured properties.

lean direct injection↗
NASA NTRSDate not supplied

Comparison of Non-Combusting Spray Fields in a Model Combustor using Shadowgraphy

Droplet sizes were measured using shadowgraphy in the spray issuing from the center element of the baseline configuration of the NASA 7-element lean direct injector (LDI) array. Each LDI element consisted of a 60 degree clockwise axial air swirler, converging-diverging venturi, and a pressure-swirl atomizer positioned with its tip at the venturi throat. The non-combusting measurements were conducted using water spray in a 3-inch diameter research combustor operating at pressure of 5 bar and air inlet temperature of 700 K. At these inlet conditions, three air flow rates were used, producing reference velocities of 7.6, 15.2, and 22.9 m/s. Only the center nozzle was used. At each reference velocity, water flow rates were adjusted to simulate a common equivalence. Data were collected at a frame rate of 15 Hz over a range of positions near the LDI dump plane, and downstream, along the combustor centerline. Velocity measurements were achieved by use of a dual head Nd:YAG laser and frame transfer PIV camera. Droplet size and velocity, mass and number density, and volume fraction are compared at these inlet conditions to determine the effect of nozzle pressure drop on the measured properties.

lean direct injection↗
NASA NTRS1990

Supercritical microgravity droplet vaporization

Supercritical droplet vaporization is an important issue in many combustion systems, such as liquid fueled rockets and compression-ignition (diesel) engines. In order to study the details of droplet behavior at these conditions, an experiment was designed to provide a gas phase environment which is above the critical pressure and critical temperature of a single liquid droplet. In general, the droplet begins as a cold droplet in the hot, high pressure environment. In order to eliminate disruptions to the droplet by convective motion in the gas, forced and natural convection gas motion are required to be small. Implementation of this requirement for forced convection is straightforward, while reduction of natural convection is achieved by reduction in the g-level for the experiment. The resulting experiment consists of a rig which can stably position a droplet without restraint in a high-pressure, high temperature gas field in microgravity. The microgravity field is currently achieved by dropping the device in the NASA Lewis 2.2 second drop tower. The performance of the experimental device and results to date are presented.

Hartfield, J.↗
NASA NTRS1985

Liquid rocket combustor computer code development

The Advanced Rocket Injector/Combustor Code (ARICC) that has been developed to model the complete chemical/fluid/thermal processes occurring inside rocket combustion chambers are highlighted. The code, derived from the CONCHAS-SPRAY code originally developed at Los Alamos National Laboratory incorporates powerful features such as the ability to model complex injector combustion chamber geometries, Lagrangian tracking of droplets, full chemical equilibrium and kinetic reactions for multiple species, a fractional volume of fluid (VOF) description of liquid jet injection in addition to the gaseous phase fluid dynamics, and turbulent mass, energy, and momentum transport. Atomization and droplet dynamic models from earlier generation codes are transplated into the present code. Currently, ARICC is specialized for liquid oxygen/hydrogen propellants, although other fuel/oxidizer pairs can be easily substituted.

Liang, P. Y.↗