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Investigation into Cloud Computing for More Robust Automated Bulk Image Geoprocessing

Geospatial resource assessments frequently require timely geospatial data processing that involves large multivariate remote sensing data sets. In particular, for disasters, response requires rapid access to large data volumes, substantial storage space and high performance processing capability. The processing and distribution of this data into usable information products requires a processing pipeline that can efficiently manage the required storage, computing utilities, and data handling requirements. In recent years, with the availability of cloud computing technology, cloud processing platforms have made available a powerful new computing infrastructure resource that can meet this need. To assess the utility of this resource, this project investigates cloud computing platforms for bulk, automated geoprocessing capabilities with respect to data handling and application development requirements. This presentation is of work being conducted by Applied Sciences Program Office at NASA-Stennis Space Center. A prototypical set of image manipulation and transformation processes that incorporate sample Unmanned Airborne System data were developed to create value-added products and tested for implementation on the "cloud". This project outlines the steps involved in creating and testing of open source software developed process code on a local prototype platform, and then transitioning this code with associated environment requirements into an analogous, but memory and processor enhanced cloud platform. A data processing cloud was used to store both standard digital camera panchromatic and multi-band image data, which were subsequently subjected to standard image processing functions such as NDVI (Normalized Difference Vegetation Index), NDMI (Normalized Difference Moisture Index), band stacking, reprojection, and other similar type data processes. Cloud infrastructure service providers were evaluated by taking these locally tested processing functions, and then applying them to a given cloud-enabled infrastructure to assesses and compare environment setup options and enabled technologies. This project reviews findings that were observed when cloud platforms were evaluated for bulk geoprocessing capabilities based on data handling and application development requirements.

Brown, Richard B.↗

Deep Drilling and Sampling via the Wireline Auto-Gopher Driven by Piezoelectric Percussive Actuator and EM Rotary Motor

The ability to penetrate subsurfaces and perform sample acquisition at depths of meters is critical for future NASA in-situ exploration missions to bodies in the solar system, including Mars and Europa. A corer/sampler was developed with the goal of acquiring pristine samples by reaching depths on Mars beyond the oxidized and sterilized zone. To developed rotary-hammering coring drill, called Auto-Gopher, employs a piezoelectric actuated percussive mechanism for breaking formations and an electric motor rotates the bit to remove the powdered cuttings. This sampler is a wireline mechanism that is incorporated with an inchworm mechanism allowing thru cyclic coring and core removal to reach great depths. The penetration rate is being optimized by simultaneously activating the percussive and rotary motions of the Auto-Gopher. The percussive mechanism is based on the Ultrasonic/Sonic Drill/Corer (USDC) mechanism that is driven by piezoelectric stack and that was demonstrated to require low axial preload. The Auto-Gopher has been produced taking into account the a lessons learned from the development of the Ultrasonic/Sonic Gopher that was designed as a percussive ice drill and was demonstrated in Antarctica in 2005 to reach about 2 meters deep. A field demonstration of the Auto-Gopher is currently being planned with objective of reaching as deep as 3 to 5 meters in tufa subsurface.

Auto-Gopher↗

A CFD Analysis of Hydrogen Leakage During On-Pad Purge in the ORION/ARES I Shared Volume

A common open volume is created by the stacking of the Orion vehicle onto the Ares I Upper Stage. Called the Shared Volume, both vehicles contribute to its gas, fluid, and thermal environment. One of these environments is related to hazardous hydrogen gas. While both vehicles use inert purge gas to mitigate any hazardous gas buildup, there are concerns that hydrogen gas may still accumulate and that the Ares I Hazardous Gas Detection System will not be sufficient for monitoring the integrated volume. This Computational Fluid Dynamics (CFD) analysis has been performed to examine these topics. Results of the analysis conclude that the Ares I Hazardous Gas Detection System will be able to sample the vent effluent containing the highest hydrogen concentrations. A second conclusion is that hydrogen does not accumulate under the Orion Service Module (SM) avionics ring as diffusion and purge flow mixing sufficiently dilute the hydrogen to safe concentrations. Finally the hydrogen concentrations within the Orion SM engine nozzle may slightly exceed the 1 percent volume fraction when the entire worse case maximum full leak is directed vertically into the engine nozzle.

Ajmani, Kumud↗

The use of tethered satellites for the collection of cosmic dust and the sampling of man made orbital debris far from the space station

The use of a tethered subsatellite employed downward into the earth's upper atmosphere to an altitude of about 110 km above the earth would eliminate the orbital contamination problem while at the same time affording a measure of atmospheric braking to reduce the velocities of many particles to where they may be captured intact or nearly so with properly designed collectors. The same technique could also be used to monitor the flux of all types of man-made orbital debris out to a distance of more than a hundred kilometers in any direction from the space station. In this way the build up of any debris belt orbiting earth could be determined. The actual collecting elements used for both purposes could be of several different materials and designs so as to optimize the collection of different types of particles with different densities. Stacks of foils, films, plastics, and foams, as well as simple capture cells would be mounted in clusters around the outside of a tethered satellite and protected by iris covers until the tethered had been fully deployed. If the orientation history of the satellite were known the direction of the incoming material could be infered. A chief advantage in deploying such tethered collectors from the Space Station instead of from the shuttle is the ability to maintain deployment of the tether for days instead of hours resulting in much greater yields of intact particles and impact debris.

Corso, G. J.↗

In-situ hydrogen microstructural characterization of Si heterojunction passivation: Addressing V OC degradation and mitigation pathways

Si heterojunction (SHJ) solar cells have demonstrated record efficiency >27%, approaching the theoretical limit of ≈ 29%, primarily due to best surface/interface defect passivation provided by deposited thin layers of hydrogenated amorphous silicon (a-Si:H). Such excellent surface/interface passivation reduces recombination loss and result in >100 mV improvement of cell open circuit voltage (V OC ) to ≈ 750 mV, thus the cell efficiency. However, fielded SHJ modules exhibit loss of V OC and hence efficiency over time in years, presumably due to degradation related to a-Si:H layers. This adversely affects the technology’s market acceptance, and levelized cost of energy (LCOE). It is hypothesized that the origin of a-Si:H degradation is somehow related to the presence of weak Si–Si bonds and hydrogen in a-Si:H films. The objective of this project is to test this hypothesis by directly measuring chemical and structural changes occurring within SHJ component layers and solar cells. This is achieved by developing an innovative in-situ Fourier transform infrared (FTIR) spectrometry apparatus to monitor hydrogen microstructural changes occurring within amorphous silicon and decipher hydrogen evolution kinetics over time when samples are exposed to heat and/or light stress. These in-situ measured hydrogen microstructural changes are correlated to the changes in effective minority carrier lifetime (τ eff ), implied V OC (iV OC ), surface recombination velocity (S), and cell V OC . These mechanistic understandings will provide critical guidance to mitigate the V OC -driven degradation of SHJ solar cell performance. Passivation optimization and degradation analysis of individual SHJ component structures were achieved through systematic deposition of three symmetric structures and the completed SHJ solar cell structure. The three symmetric structures used were intrinsic a-Si:H [(i)a-Si:H] layers in a bilayer structure, intrinsic and p-type doped stacked layers [(i-p)a-Si:H] representing the front heterojunction in the SHJ cell, and intrinsic and n-typed doped stacked layers [(i-n)a-Si:H] representing the back-side back surface field (BSF) in the SHJ cell. State-of-the-art passivation qualities are demonstrated by a champion iV OC of 740 mV for the (i)a-Si:H layers, and the (i-n)a-Si:H symmetric structure. A 725 mV iV OC is observed for the (i-p)a-Si:H symmetric structure. These symmetric passivated SHJ component structures were subsequently subjected to different accelerated lifetime (ALT) stressors to identify which conditions contribute the most to iV OC degradation. Degradation of the thin (10 nm) (i)a-Si:H passivation layers without any additional overlying layers is minimal; complexity of this study arises due to unavoidable surface oxidation of (i)a-Si:H layer during most of the stress application, which is likely irrelevant for a full SHJ cell configuration with overlying protective layers. The iV OC degradation of symmetric structures is found to occur primarily at the (i-p)a-Si:H passivation stack under dark heat stress with associated hydrogen loss from the (p)a-Si:H layer. An activation energy for increase in S (defect creation) of 0.65 eV can be correlated to the activation energy of ≈ 0.4 eV for hydrogen loss from the (i-p)a-Si:H stack. This also suggests the presence of weakly bonded hydrogen in the (p)a-Si:H films, which effuses out of the film stack at such low activation energy. When light and heat stress are applied together, similar hydrogen loss from (i-p)a-Si:H stack is observed, however, does not appreciably degrade iV OC or increase S. This is an important result and departure from direct correlation between hydrogen loss and defect creation. This perhaps indicates additional defect chemistries or annealing that might be occurring in the presence of light requiring further detailed defect measurements. The full SHJ cell structure used for this project is depicted in Fig.1(d). SHJ cells with an initial V OC ≈ 700 mV were fabricated and subjected to similar ALT stress conditions. Cell V OC is found to degrade the most under dark heat stress and is confirmed by observed hydrogen migration out of the (i-p)a-Si:H stack. However, hydrogen cannot escape from the cell stack, it accumulates near the (p)a-Si:H/ITO contact interface, where ITO acts as a barrier preventing hydrogen loss. Furthermore, light-heat combined stress does not degrade V OC appreciably, confirming the occurrence of a defect annealing process.

14 SOLAR ENERGY↗

Charged particle LET-spectra measurements aboard LDEF

The linear energy transfer (LET) spectra of charged particles was measured in the 5 to 250 keV/micron (water) interval with CR-39 and in the 500 to 1500 keV/micron (water) interval with polycarbonate plastic nuclear track detectors (PNTDs) under different shielding depths in the P0006 experiment. The optimal processing conditions were determined for both PNTDs in relation to the relatively high track densities due to the long term exposure in space. The total track density was measured over the selected samples, and tracks in coincidence on the facing surfaces of two detector sheets were selected for measuring at the same position on each sheet. The short range (SR) and Galactic Cosmic Ray (GCR) components were measured separately with CR-39 PNTDs and the integral dose and dose rate spectra of charged particles were also determined. The high LET portion of the LET spectra was measured with polycarbonate PNTDs with high statistical accuracy. This is a unique result of this exposure due to the low flux of these types of particles for typical spaceflight durations. The directional dependence of the charged particles at the position of the P0006 experiment was also studied by four small side stacks which surrounded the main stack and by analyzing the dip angle and polar angle distributions of the measured SR and GCR particle tracks in the main stack.

Csige, I.↗

Sedimentology and Stratigraphy of the Lower Delta Sequence, Jezero Crater, Mars.

In April 2022, the Mars 2020 Perseverance rover arrived at the base of the ancient delta in Jezero crater after completing the first year of its mission exploring and sampling aqueously altered igneous rocks of the present-day crater floor. Perseverance then spent ~200 sols exploring the lower ~25 m of rock exposed within the eastern scarp of the Jezero delta, a sedimentary sequence informally named the ‘Shenandoah’ formation. This study describes the sedimentology and stratigraphy of the Shenandoah formation explored by Perseverance at two sections—'Cape Nukshak’ and ‘Hawksbill Gap’—including a description, interpretation, and depositional framework for the facies that comprise it.

K. M. Stack↗

Imaging spectrophotometry of the nuclear outflow of NGC 1068

This observational program (in conjunction with R. B. Tully (IfA, Honolulu), and J. Bland (Rice U., Houston)) aims to constrain the kinematic organization and dominant excitation mechanisms of ionized gas in active galaxies. More generally, researchers are interested in the dynamics of radiative, supersonic flows in the Interstellar Medium (ISM). Imaging Fabry-Perot interferometers and low-noise Charge Coupled Devices (CCDs) are used for complete spatial coverage of the complex gas distribution in circumnuclear narrow-line regions (NLRs). Extranuclear emission line widths in NLRs can exceed 3000 km s(-1), so to avoid inter-order confusion researchers use an etalon of 4000 km s(-1) free spectral range to map (N II) lambda lambda 6548, 6583 and H alpha. To maximize spatial resolution, researchers select nearby active systems independent of luminosity but known to possess interesting morphologies and/or high-velocity extranuclear ionized gas. Monochromatic images Full Width Half Maximum (FWHM) approx. 65 km s(-1) have thus far been obtained in 1 second or better seeing at the U. Hawaii 2.2m, CFH 3.6m, and CTIO 4.0m telescopes. These are stacked into grids of line profiles, of spectrophotometric quality, at sub-arcsecond increments across a 3 second field. To handle the approx. 20,000 to 300,000 useful spectra that arise from a typical night's work, researchers have developed a complete analysis and reduction package for VAX and Sun image workstations. Reduction involves parametrization of approx. 10 to the 8th raw data points to a few maps (e.g., velocities of each kinematic subsystem, continuum-free line fluxes) containing approx. 10 to the 5th pixels. Researchers identify kinematic and structural symmetries by examining these maps and the point to point variations of the synthesized line profiles. The combination of monochromatic images and full spatial sampling of line profiles has allowed them to isolate such symmetries and has led to reliable kinematic deprojections.

Cecil, Gerald↗

Weak Lensing Mass Calibration of the ACT DR5 Galaxy Clusters with the DES Year 3 Weak Lensing Data

We use weak gravitational lensing measurements from Year 3 Dark Energy Survey data to calibrate the masses of 443 galaxy clusters selected via the Sunyaev-Zel'dovich effect from Atacama Cosmology Telescope Data Release 5 maps of the cosmic microwave background. We incorporate redshift and SZ measurements for individual clusters into a hierarchical model for the stacked lensing signals and perform Bayesian analyses to constrain the hydrostatic mass bias of the clusters. Our treatment of systematic uncertainties includes a prescription for measuring and accounting for the weak lensing boost factor, consideration of a miscentering effect, as well as marginalization over uncertainties in the source galaxy photometric redshift distributions and shear calibration. The resultant constraints on the normalization of the mass-observable relation have a precision of approximately 7%, with the mean WL halo mass of M $_{500c}$ = 5.4 × 10$^{14}$ M $_{⊙}$. We measure the bias between the true cluster mass and the mass estimated from the SZ signal based on an X-ray-calibrated scaling relation assuming hydrostatic equilibrium, to be 1 - b = 0.74$^{+0.06}$ $_{-0.05}$ over the full sample. When splitting the clusters into high (z = 0.43-0.70) and low (z = 0.15-0.43) redshift bins, we measure 1 - b = 0.58$^{+0.06}$ $_{-0.05}$ and 0.81$^{+0.08}$ $_{-0.06}$, respectively. When introducing additional freedom in redshift and mass to the hydrostatic bias model, we find that 1 - b decreases with redshift (with the power law of -1.8$^{+0.5}$ $_{-0.6}$, 99.95% confidence), consistent with findings from other recent studies, while we do not find any significant trend in mass. We also demonstrate that our result is robust against various systematics such as a scale cut, priors on baryonic and miscentering parameters, and degree of scatter in mass-observable relation. The weak-lensing mass calibration presented in this study will be a useful tool for using the ACT clusters as probes of astrophysics, and as a step towards using their abundance as a cosmological probe.

Shin, T. [Carnegie Mellon U.] (ORCID:0000000263895↗

Effect of Lithium Doping on MgO Hydroxylation and Carbonation

Recovery of magnesium from brines can potentially be used to source MgO (periclase) as a CO 2 sorbent or for Mg-based cements. However, it is not clear how common impurities in brines, such as lithium, affect the resulting MgO reactivity. Here, to test the effect of lithium incorporation on MgO reactivity for hydration and carbonation, we combined computational simulations with experiments. Experimentally altered (Mg,Li)O with a low dopant concentration (0.012 ± 0.002% w/w Li) was characterized using synchrotron-based X-ray scattering and high-resolution electron microscopy to measure reaction layer formation on (Mg,Li)O. Single-crystal X-ray diffraction analysis of (Mg,Li)O demonstrates that the incorporation of lithium leads to the formation of oxygen vacancies. The presence of vacancies is likely causing faster hydroxylation rates as predicted by ab initio molecular dynamics simulations. However, the faster hydroxylation rates likely lead to faster passivation of the surface because we observe thinner reaction layers on (Mg,Li)O samples both over short time periods (30 days) and over long time periods (28 years). After 28 years, the reaction layer on the (Mg,Li)O sample was less than one-third of the thickness of that of the pure MgO sample. In addition, over 30 days, reaction layers on (Mg,Li)O samples primarily formed at steps rather than on terraces, in contrast to our previous observations on MgO. Based on our results, naturally occurring impurities in MgO modify its reactivity even at very low concentrations and need to be considered for accurate reaction rate prediction for application of MgO as a CO 2 sorbent or in cements.

MgO↗

H I Depletion Begins Well Beyond the Virial Radius: A FAST Stacking Study of 36 Galaxy Clusters to 5 × R 200

Abstract We present a stacking study of the neutral atomic hydrogen (H i ) content in and around 36 local galaxy clusters at z < 0.07, using a combination of the FAST All Sky H i survey (FASHI) and the extensive spectroscopic catalog mainly from the Dark Energy Spectroscopic Instrument (DESI). We employ spectral stacking techniques to probe the average H i mass and HI-to-stellar mass ratio ( M HI / M * ) for member galaxies down to stellar masses of M * ∼ 10 9 M ⊙ , spanning a projected cluster-centric distance of up to 5 R 200 . Our analysis reveals a pronounced environmental effect; both M HI and M HI / M * decrease steadily toward the cluster center, dropping by ∼0.5 dex on average from the outskirts to the core. Crucially, we find that M HI / M * of galaxies remain lower than the field galaxies even at the 5 R 200 . This provides direct, statistical evidence for substantial gas stripping and preprocessing in the cluster outskirts, likely occurring in infalling groups and large-scale filaments. By further splitting the sample by g − r color, we show that the H i deficiency persists at fixed galaxy color; even the bluest cluster members exhibit ∼0.5 dex lower M HI / M * than field galaxies of similar color, reflecting environmental effects on the cold gas reservoir prior to full optical transformation. The total H i mass within clusters and their outskirts agrees broadly with predictions from cosmological simulations. Our results underscore the critical role of the extended cluster environment in quenching galaxies by depleting their cold gas reservoirs well before they enter the dense cluster core.

Cheng, Cheng [Chinese Academy of Sciences South Am↗

The effect of hydrogen on the deformation behavior of a single crystal nickel-base superalloy

The effect of hydrogen on the tensile deformation behavior of PWA 1480 is presented. Tensile tests were interrupted at different plastic strain levels to observe the development of the dislocation structure. Transmission electron microscopy (TEM) foils were cut perpendicular to the tensile axis to allow the deformation of both phases to be simultaneously observed as well as parallel to zone axes (III) to show the superdislocations on their slip planes. Similar to other nickel-base superalloys, hydrogen was detrimental to the room temperature tensile properties of PWA 1480. There was little effect on strength, however the material was severely embrittled. Even without hydrogen, the elongation-to-failure was only approximately 3 percent. The tensile fracture surface was made up primarily of ductile voids with regions of cleavage fracture. These cleavage facets are the eutectic (gamma') in the microstructure. It was shown by quantitative fractography that hydrogen embrittles the eutectic (gamma') and causes the crack path to seek out and fracture through the eutectic (gamma'). There was two to three times the amount of cleavage on the fracture surface of the hydrogen-charged samples than on the surface of the uncharged samples. The effect of hydrogen can also be seen in the dislocation structure. There is a marked tendency for dislocation trapping in the gamma matrix with and without hydrogen at all plastic strain levels. Without hydrogen there is a high dislocation density in the gamma matrix leading to strain exhaustion in this region and failure through the matrix. The dislocation structure at failure with hydrogen is slightly different. The TEM foils cut parallel to zone axes (III) showed dislocations wrapping around gamma precipitates. Zone axes (001) foils show that there is a lower dislocation density in the gamma matrix which can be linked to the effects of hydrogen on the fracture behavior. The primary activity in the gamma precipitates is in the form of superlattice intrinsic stacking faults (SISFs). These faults have also been reported in other ordered alloys and superalloys.

Walston, W. S.↗

Strength, deformation, and the fcc–hcp phase transition in condensed Kr and Xe to the 100 GPa pressure range

The rare gas solids exhibit systematic differences in crystal structure, phase transition conditions, bond strength, and other physical properties. The physical properties of heavy rare gas solids krypton and xenon are modified by the martensitic phase transition from face-centered cubic to hexagonal close packed structure over a broad pressure range. Crystal structure, strength, and plastic deformation of krypton and xenon have been investigated at 300 K using compression in the diamond-anvil cell with synchrotron angle-dispersive x-ray diffraction and complementary ruby fluorescence spectroscopy for Xe. Stacking faults indicative of the fcc–hcp phase transition are observed at pressures at and above 1.23 ± 0.05 and 1.9 ± 0.6 GPa in Kr and Xe, respectively. The transition remains incomplete in both solids to pressures greater than 100 GPa. Strength determined from stress measurements in Pt and ruby standards at pressures up to 111 GPa and complemented by observations of strain and texture measurements obtained by x-ray diffraction in the radial geometry to 100 GPa indicates similar or higher strength than Ar at all conditions, with significant stiffening at 15–20 GPa. Radial diffraction data reveal the persistence of broad highly textured fcc diffraction lines to 101 GPa in Xe, suggesting that the axial measurements may underestimate the metastable persistence of the fcc phase due to biased sampling of hcp crystallites resulting from preferred crystallite orientation. Kr and Xe are compared with He, Ne, and Ar for a systematic understanding of physical properties and phase equilibria of rare gas solids.

Compressive stress↗

Laser Ablation Electrodynamic Ion Funnel for In Situ Mass Spectrometry on Mars

A front-end instrument, the laser ablation ion funnel, was developed, which would ionize rock and soil samples in the ambient Martian atmosphere, and efficiently transport the product ions into a mass spectrometer for in situ analysis. Laser ablation creates elemental ions from a solid with a high-power pulse within ambient Mars atmospheric conditions. Ions are captured and focused with an ion funnel into a mass spectrometer for analysis. The electrodynamic ion funnel consists of a series of axially concentric ring-shaped electrodes whose inside diameters (IDs) decrease over the length of the funnel. DC potentials are applied to each electrode, producing a smooth potential slope along the axial direction. Two radio-frequency (RF) AC potentials, equal in amplitude and 180 out of phase, are applied alternately to the ring electrodes. This creates an effective potential barrier along the inner surface of the electrode stack. Ions entering the funnel drift axially under the influence of the DC potential while being restricted radially by the effective potential barrier created by the applied RF. The net result is to effectively focus the ions as they traverse the length of the funnel.

Johnson, Paul V.↗

In Situ Geologic Context Mapping Transect on the Floor of Jezero Crater From Mars 2020 Perseverance Rover Observations

In situ geologic context mapping based on rover and helicopter observations provides documentation of a nearly continuous record of geology and exposed surface structure over a 120 m-wide corridor along the traverse of the Mars 2020/Perseverance rover. The results record the geologic context of Mars 2020 campaign sites and sample sites, including the local extent of bedrock outcrops, stratigraphy, attitude, and structure from imaging and rover-based remote sensing, and outcrop lithology based on in situ proximity science. Mapping identifies a sequence of igneous lithologies including (a) early mafic, possibly intrusive, rocks; (b) pervasively fractured and deeply altered massive bedrock of undetermined protolith; (c) buried and exhumed lava flows with pahoehoe and aa textures; (d) several varieties of regolith; and (e) small impact craters.

Mars 2020↗

Sampling of Jezero Crater Máaz Formation By Mars 2020 Perseverance Rover

Collection of samples that could be returned to Earth from the floor of Jezero crater is a major goal of the Mars 2020 mission. Laboratory analyses of these will expand exploration of Jezero, a Noachian crater on Mars characterized by a delta–lake system with high potential for habitability. The samples will also be used to test current ideas about the early planetary evolution of Mars. The Perseverance rover has collected samples from two members of the Máaz formation, mapped in orbital images as the Crater floor fractured rough unit by [1]. Type localities of the Roubion and Rochette members have been targeted and abraded prior to sample collection. Here we summarize these sampling activities and the potential of sampling the Chal member of Máaz. A similar summary for samples collected from the Séítah formation is described in Hickman-Lewis et al. (this meeting).

Mars 2020↗

Mass Spectra Deconvolution of Gaseous Mixtures Containing Volatile Organic Compounds

The Spacecraft Atmosphere Monitor (S.A.M.) analyzes all gaseous pollutants in the 1-150Th mass-to-charge range based on their positive-ion mass spectra. Of particular interest is the Trace Gas Analysis (TGA) mode of operation in which S.A.M detects minute amounts of volatile organic compounds (VOC). Pollutant component of the ambient air is sampled on demand in twenty full mass spectra per second. All spectra is accumulated in two-second intervals by an on-board Field Programmable Gate Arrays (FPGA) unit. Mass spectra represents the number of detected fragment ions in a given mass-to-charge ratio channel. Electron impact ionization of neutral molecules results in creation of numerous fragment ions and most of organic compounds will contribute several identical fragments. Despite the presence of these molecular isobars, we developed the deconvolution algorithm capable of identifying target species based on their characteristic fragmentation patterns. We investigate the efficiency of deconvolution algorithm as a function of mass resolution with which mass spectrum is acquired. Higher the mass resolution, better the chances are to distinguish between stereoisomers using their fragmentation propensities, but also results in higher data volumes to be processed by a set of small footprint software stacks hosted by an on-board computer. Finding the balance between deconvolution accuracy and generated data volume under time constrains and limited computing resources is the main topic of this study.

Darrach, M.↗

The Cosmic History of Hot Gas Cooling and Radio AGN Activity in Massive Early-Type Galaxies

We study the X-ray properties of 393 optically selected early-type galaxies (ETGs) over the redshift range of z approx equals 0.0-1.2 in the Chandra Deep Fields. To measure the average X-ray properties of the ETG population, we use X-ray stacking analyses with a subset of 158 passive ETGs (148 of which were individually undetected in X-ray). This ETG subset was constructed to span the redshift ranges of z = 0.1-1.2 in the approx equals 4 Ms CDF-S and approx equals 2 Ms CDF-N and z = 0.1-0.6 in the approx equals 250 ks E-CDF-S where the contribution from individually undetected AGNs is expected to be negligible in our stacking. We find that 55 of the ETGs are detected individually in the X-rays, and 12 of these galaxies have properties consistent with being passive hot-gas dominated systems (i.e., systems not dominated by an X-ray bright Active Galactic Nucleus; AGN). On the basis of our analyses, we find little evolution in the mean 0.5-2 keY to B-band luminosity ratio (L(sub x) /L(sub Beta) varies as [1 +z]) since z approx equals 1.2, implying that some heating mechanism prevents the gas from cooling in these systems. We consider that feedback from radio-mode AGN activity could be responsible for heating the gas. We select radio AGNs in the ETG population using their far-infrared/radio flux ratio. Our radio observations allow us to constrain the duty cycle history of radio AGN activity in our ETG sample. We estimate that if scaling relations between radio and mechanical power hold out to z approx equals 1.2 for the ETG population being studied here, the average mechanical power from AGN activity is a factor of approx equals1.4 -- 2.6 times larger than the average radiative cooling power from hot gas over the redshift range z approx equals 0-1.2. The excess of inferred AGN mechanical power from these ETGs is consistent with that found in the local Universe for similar types of galaxies.

Danielson, A. L. R.↗