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NASA NTRS1991

Characterization of magneto-optical media

Amorphous rare earth-transition metal (RE-TM) alloys and compositionally modulated TM/TM films were characterized in terms of their magnetic, magneto-optic, and galvanomagnetic properties. The loop tracer, vibrating sample magnetometer (VSM), and Rutherford Backscattering (RBS) facility were used to characterize and analyze the various properties of these magneto-optical storage media. Kerr effect, ellipticity, coercivity, and anisotropy at various temperatures, magnetoresistance, and resistivity are among the properties measured in Co/Pt films, Co/Pd films, and TbFeCo films.

Hajjar, Roger A.↗

NASA NTRS1980

Determination of the complex refractive index and size distribution of atmospheric particulates from bistatic-monostatic lidar and solar radiometer measurements

A method is presented for inferring both the size distribution and the complex refractive index of atmospheric particulates from combined bistatic-monostatic lidar and solar radiometer observations. The basic input measurements are spectral optical depths at several visible and near-infrared wavelengths as obtained with a solar radiometer and backscatter and angular scatter coefficients as obtained from a biostatic-monostatic lidar. The spectral optical depth measurements obtained from the radiometer are mathematically inverted to infer a columnar particulate size distribution. Advantage is taken of the fact that the shape of the size distribution obtained by inverting the particulate optical depth is relatively insensitive to the particle refractive index assumed in the inversion. Bistatic-monostatic angular scatter and backscatter lidar data are then processed to extract an optimum value for the particle refractive index subject to the constraint that the shape of the particulate size distribution be the same as that inferred from the solar radiometer data. Specifically, the scattering parameters obtained from the bistatic-monostatic lidar data are compared with corresponding theoretical computations made for various assumed refractive index values. That value which yields best agreement, in a weighted least squares sense, is selected as the optimal refractive index estimate. The results of this procedure applied to a set of simulated measurements as well as to measurements collected on two separate days are presented and discussed.

Reagan, J. A.↗

NASA NTRS2008

Demonstration of Aerosol Property Profiling by Multi-wavelength Lidar Under Varying Relative Humidity Conditions

The feasibility of using a multi-wavelength Mie-Raman lidar based on a tripled Nd:YAG laser for profiling aerosol physical parameters in the planetary boundary layer (PBL) under varying conditions of relative humidity (RH) is studied. The lidar quantifies three aerosol backscattering and two extinction coefficients and from these optical data the particle parameters such as concentration, size and complex refractive index are retrieved through inversion with regularization. The column-integrated, lidar-derived parameters are compared with results from the AERONET sun photometer. The lidar and sun photometer agree well in the characterization of the fine mode parameters, however the lidar shows less sensitivity to coarse mode. The lidar results reveal a strong dependence of particle properties on RH. The height regions with enhanced RH are characterized by an increase of backscattering and extinction coefficient and a decrease in the Angstrom exponent coinciding with an increase in the particle size. We present data selection techniques useful for selecting cases that can support the calculation of hygroscopic growth parameters using lidar. Hygroscopic growth factors calculated using these techniques agree with expectations despite the lack of co-located radiosonde data. Despite this limitation, the results demonstrate the potential of multi-wavelength Raman lidar technique for study of aerosol humidification process.

Whiteman, D.N.↗

NASA NTRS2012

Optical Characterisation of Suspended Particles in the Mackenzie River Plume (Canadian Arctic Ocean) and Implications for Ocean Colour Remote Sensing

Climate change significantly impacts Arctic shelf regions in terms of air temperature, ultraviolet radiation, melting of sea ice, precipitation, thawing of permafrost and coastal erosion. Direct consequences have been observed on the increasing Arctic river flow and a large amount of organic carbon sequestered in soils at high latitudes since the last glacial maximum can be expected to be delivered to the Arctic Ocean during the coming decade. Monitoring the fluxes and fate of this terrigenous organic carbon is problematic in such sparsely populated regions unless remote sensing techniques can be developed and proved to be operational. The main objective of this study is to develop an ocean colour algorithm to operationally monitor dynamics of suspended particulate matter (SPM) on the Mackenzie River continental shelf (Canadian Arctic Ocean) using satellite imagery. The water optical properties are documented across the study area and related to concentrations of SPM and particulate organic carbon (POC). Robust SPM and POC : SPM proxies are identified, such as the light backscattering and attenuation coefficients, and relationships are established between these optical and biogeochemical parameters. Following a semi-analytical approach, a regional SPM quantification relationship is obtained for the inversion of the water reflectance signal into SPM concentration. This relationship is reproduced based on independent field optical measurements. It is successfully applied to a selection of MODIS satellite data which allow estimating fluxes at the river mouth and monitoring the extension and dynamics of the Mackenzie River surface plume in 2009, 2010 and 2011. Good agreement is obtained with field observations representative of the whole water column in the river delta zone where terrigenous SPM is mainly constrained (out of short periods of maximum river outflow). Most of the seaward export of SPM is observed to occur within the west side of the river mouth. Future work will require the validation of the developed SPM regional algorithm based on match-ups with field measurements, then the routine application to ocean colour satellite data in order to better estimate the fluxes and fate of SPM and POC delivered by the Mackenzie River to the Arctic Ocean.

Mackenzie River plume↗

NASA NTRS1998

Tropospheric Wind Profile Measurements with a Direct Detection Doppler Lidar

Research has established the importance of global tropospheric wind measurements for large scale improvements in numerical weather prediction. In addition, global wind measurements provide data that are fundamental to the understanding and prediction of global climate change. These tasks are closely linked with the goals of the NASA Earth Science Enterprise and Global Climate Change programs. NASA Goddard has been actively involved in the development of direct detection Doppler lidar methods and technologies to meet the wind observing needs of the atmospheric science community. In this paper we describe a recently developed prototype wind lidar system using a direct detection Doppler technique for measuring wind profiles from the surface through the troposphere. This system uses a pulsed ND:YAG laser operating at 1064 nm as the transmitter. The laser pulse is directed to the atmosphere using a 40 cm diameter scan mirror. The portion of the laser energy backscattered from aerosols and molecules is collected by a 40 cm diameter telescope and coupled via fiber optics into the Doppler receiver. Single photon counting APD's are used to detect the atmospheric backscattered signal. The principle element of the receiver is a dual bandpass tunable Fabry Perot etalon which analyzes the Doppler shift of the incoming laser signal using the double edge technique. The double edge technique uses two high resolution optical filters having bandpasses offset relative to one another such that the 'edge' of the first filter's transmission function crosses that of the second at the half power point. The outgoing laser frequency is located approximately at the crossover point. Due to the opposite going slopes of the edges, a Doppler shift in the atmospheric backscattered laser frequency produces a positive change in signal for one filter and a negative change in the second filter. Taking the ratio of the two edge channel signals yields a result which is directly proportional to the component of the wind along the line-of-sight of the laser. Measuring the radial wind in several directions provides sufficient information to determine the true wind speed and direction. The lidar has operated from our laboratory at Goddard since June, 1997. Wind profiles have been obtained to altitudes of 12 km with a vertical resolution of 330 in. Vector wind data are obtained by rotating the scan mirror to measure line-of-sight wind profiles for at least two azimuth angles at an elevation angle of 45 degrees. The precision of the data as determined from the standard deviation of multiple independent lidar profiles is in the range of 1 to 3 m/sec up to 10 km. Good agreement is obtained when the lidar data are compared with the upper air rawinsonde soundings taken at Dulles airport. Examples of the wind lidar data will be presented along with a description of the instrument and future developments.

Gentry, Bruce M.↗

NASA NTRSDate not supplied

Airborne High Spectral Resolution Lidar Measurements of Aerosol Distributions and Properties During the NASA CAMP2Ex Mission

The NASA Clouds, Aerosols and Monsoon Processes-Philippines Experiment (CAMP2Ex) occurred during August-October, 2019,primarily over the ocean near the Philippines, including the ocean west of Luzon. CAMP2Ex attempts to characterize the role of anthropogenic and natural aerosol particles in modulating warm and mixed-phase precipitation in the maritime continent during the Southwest Monsoon. This mission is also examining relationships between spatial heterogeneity in the aerosol and cloud fields and radiative heating rates and studying the effects of aerosol concentration and composition on the microphysical properties of shallow cumulus and cumulus congestus clouds. Critical to the successful investigation of these objectives is profiling of aerosol, cloud and meteorological properties throughout the atmospheric column. For the CAMP2Ex experiment, we deployed the second generation NASA Langley airborne High Spectral Resolution Lidar (HSRL-2) on the NASA P-3 aircraft to obtain profile measurements of aerosol and thin cloud extinction and optical thickness via the HSRL technique at 355 and 532 nm, and of backscatter and depolarization at 355, 532, and 1064 nm. The HSRL technique allows for the independent measurement of extinction and backscatter without the need to assume modeled lidar ratios. Additional HSRL-2 data products include aerosol type, mixed layer depth, and range-resolved aerosol microphysical parameters. The HSRL measurements reveal the temporal, spatial, and vertical variability of aerosol optical properties over these locations. The HSRL-2 measured these backscatter, extinction, and depolarization profiles during all nineteen science flights and the transit flights to and from the aircraft operations base at Clark International Airport.In this presentation, we use these HSRL-2 measurements to show the horizontal and vertical distributions of aerosols in the CAMP2Ex operational area as well as provide insight into the optical and physical characteristics of these aerosols. We also discuss how these aerosols are distributed within and above the mixed layer.

aerosol↗

DOE OSTI2024

Distributed Optical Fiber Sensor Systems: Application to Natural Gas Pipeline Monitoring

Distributed fiber optic sensing is a cutting-edge technology that has found extensive applications in the monitoring of pipelines. Considering the low backscattering level of standard single-mode fiber as fiber under test, a Rayleigh enhanced optical fiber embedded within the tight-buffered cable is demonstrated in field testing. We analyzed the increased backscattering fiber cable's vibration performance to the conventional single-mode telecom fiber using a custom-built Φ-OTDR interrogator system. Thereafter, using a 4-inch steel pipeline with a flow rate of 5, 10, 15, and 20 ft/s and a fixed pressure level of 1000 psi, we field-tested the sensor system for monitoring natural gas pipeline acoustic vibrations. We also field tested Brillouin optical time domain analysis (BOTDA) system for pipeline hoop strain monitoring under various pressure conditions. The pilot-scale testing results presented in this study suggested that pipeline operators can accurately perform flow monitoring, leak detection, and pressure monitoring for pipeline integrity monitoring.

Lalam, Nageswara↗

NASA NTRS2005

Bio-Optics of the Chesapeake Bay from Measurements and Radiative Transfer Calculations

We combined detailed bio-optical measurements and radiative transfer (RT) modeling to perform an optical closure experiment for optically complex and biologically productive Chesapeake Bay waters. We used this experiment to evaluate certain assumptions commonly used when modeling bio-optical processes, and to investigate the relative importance of several optical characteristics needed to accurately model and interpret remote sensing ocean-color observations in these Case 2 waters. Direct measurements were made of the magnitude, variability, and spectral characteristics of backscattering and absorption that are critical for accurate parameterizations in satellite bio-optical algorithms and underwater RT simulations. We found that the ratio of backscattering to total scattering in the mid-mesohaline Chesapeake Bay varied considerably depending on particulate loading, distance from land, and mixing processes, and had an average value of 0.0128 at 530 nm. Incorporating information on the magnitude, variability, and spectral characteristics of particulate backscattering into the RT model, rather than using a volume scattering function commonly assumed for turbid waters, was critical to obtaining agreement between RT calculations and measured radiometric quantities. In situ measurements of absorption coefficients need to be corrected for systematic overestimation due to scattering errors, and this correction commonly employs the assumption that absorption by particulate matter at near infrared wavelengths is zero.

Tzortziou, Maria↗

NASA NTRS2019

3+2+X: What Is the Most Useful Depolarization Input for Inverting Lidar Measurements of Non-Spherical Particles to Microphysical Properties?

The typical multiwavelength aerosol lidar data set for inversion of optical to microphysical parameters is composed of three backscatter coefficients (β ) at 355, 532, and 1064 nm and two extinction coefficients (α ) at 355 and 532 nm. This data combination is referred to as 3β +2α or 3+2 data set. This set of data is sufficient for retrieving some important microphysical particle parameters if the particles have spherical shape. Here, we investigate the effect of including the particle linear depolarization ratio (δ) as a third input parameter to the inversion of lidar data. The inversion algorithm is generally not used if measurements show values of δ that exceed 0.10 at 532 nm, i.e. in the presence of non-spherical particles such as desert dust, volcanic ash, and under special circumstances biomass-burning smoke.We use experimental data collected with instruments that are capable of measuring δ at all three lidar wavelengths with an inversion routine that uses the theory of light scattering by randomly oriented spheroids to replicate scattering properties of non-spherical particles. This is the first systematic test of the effect of using all theoretically possible combinations of δ taken at 355, 532, and 1064 nm as input in the lidar data inversion. We find that depolarization information at least at one wavelength already provides useful information in the in version of optical data that describe light-scattering by nonspherical particles. However, any choice of δ(λ) will give lower values of the single-scattering albedo than the traditional 3+2 data set. We find that input data sets that include 355 give a non-spherical fraction that closely resembles the dust ratio we obtain from using β(532) and δ(532) in a methodology applied in aerosol-type separation. The use of 355 in data sets of two or three reduces the fraction of non-spherical particles that is retrieved when using δ(532) and δ(1064). Use of the latter two without accounting for 355 generally leads to high fractions of non-spherical particles that we consider not trustworthy. The use of three δ(λ) instead of two δ(λ) including the constraint that one of these is measured at 355 nm does not provide any advantage over using 3+2+δ(355). Because of the technical challenges involved with accurately measuring δ(1064) we conclude that — depending on measurement capability — the future standard input for inversion using spheroid kernels might be 3+2+δ(355) or 3+2+δ(355)+δ(532).

Tesche, M.↗

NASA NTRS1998

Airborne lidar observations of smoke haze during SCAR-B 1995

The Smoke, Clouds, Aerosol, and Radiation Brazil(SCAR-B) field campaign was conducted to study the effects that widespread and persistent biomass burning have upon radiative and chemical processes in the atmosphere. The radiative transfer characteristics of the atmosphere are altered by the introduction of particulate and gaseous materials which are the products of the combustion of vegetative material at ground level. These substances are transported and distributed horizontally and vertically by atmospheric dynamical processes which may be perturbed by the heat energy from the fires. As the pollutants disperse, their physical and chemical properties change substantially. A complete description of the effects of smoke requires that the evolution back to the natural situation be fully examined. A most important component of smoke haze investigation is finding its vertical and horizontal distribution in relation to the driving factors of dynamics and the related horizontal transport. In this presentation, we employ data from the Cloud Lidar System(CLS), carried aboard the NASA ER-2 aircraft, to provide a unique view of the particulate or aerosol loading produced by fires, especially with regard to the geometrical distribution of the aerosols in the vertical plane. The lidar has the ability to measure aerosol optical properties in a continuous fashion at quite fine vertical and horizontal resolution. The results from the lidar provide measurements that are largely independent of influences that corrupt passive instruments and thus it can serve to corroborate their results. The extended horizontal and vertical range of lidar results can also augment ground based and airborne in situ measurements which have limited horizontal and vertical scope. We present the results of our analysis of CLS observations taken during the SCAR-B field campaign. Observations of the the aerosol optical thickness from the Aerosol Robotic Network(AERONET) of solar photometers are employed in conjunction with CLS data to derive extinction to backscatter ratio values which are used to convert the lidar backscatter coefficient into extinction coefficient. The extinction coefficient is integrated vertically to find aerosol optical thickness along ER-2 flight tracks. We use images of the CLS derived extinction coefficient to depict its horizontal and vertical distribution. Multispectral photometer optical thickness is used to compute the Angstrom exponent. With these, we examine the hypothesis that the values of extinction to backscatter ratio can be related to the Anstrom coefficient since both of these would be a function of the refractive index and size distribution of the aerosols.

Hart, William D.↗

NASA NTRS1967

Optical radar measurements of the atmosphere

Optical radar investigations of atmosphere, and Mie scattering intensity functions for backscatter

MIE SCATTERING FUNCTION↗

NASA NTRS1993

A Fiber Optic Probe for the Detection of Cataracts

A compact fiber optic probe developed for on-orbit science experiments was used to detect the onset of cataracts, a capability that could eliminate physicians' guesswork and result in new drugs to 'dissolve' or slow down the cataract formation before surgery is necessary. The probe is based upon dynamic light scattering (DLS) principles. It has no moving parts, no apertures, and requires no optical alignment. It is flexible and easy to use. Results are presented for excised but intact human eye lenses. In a clinical setting, the device can be easily incorporated into a slit-lamp apparatus (ophthalmoscope) for complete eye diagnostics. In this set-up, the integrated fiber optic probe, the size of a pencil, delivers a low power cone of laser light into the eye of a patient and guides the light which is backscattered by the protein molecules of the lens through a receiving optical fiber to a photo detector. The non-invasive DLS measurements provide rapid determination of protein crystalline size and its size distribution in the eye lens.

Ansari, Rafat R.↗

DOE OSTI2024

Development of an Attenuated Total Reflectance–Ultraviolet–Visible Probe for the Online Monitoring of Dark Solutions

Optical spectroscopy is a valuable tool for on-line monitoring of a variety of processes. Ultraviolet-visible (UV-vis) spectroscopy in particular, can monitor the concentration of analytes as well as identify speciation and oxidation state. However, it can be difficult to impossible to employ UV-vis based sensors on chemical systems that are very dark (i.e., high optical density) as exceedingly short pathlengths are required (for transmission approaches) or effective means of backscattering are needed (for reflectance approaches). Examples of processes that would benefit significantly from the use of optical sensors and encounter these challenges include used nuclear fuel recycling and molten salts with high concentrations of dissolved uranium. Utilizing an attenuated total reflectance (ATR) UV-vis approach can overcome these challenges and allow for the measurement of solutions orders of magnitude more concentrated than transmission UV-vis. However, determining ideal sensor specifications for varied processes can be time consuming and expensive. Here, in this study, we evaluate the ability for a novel ATR-UV-vis probe to measure very concentrated solutions of Co(II) and Ni(II) nitrate as well as organic dyes (methylene blue, acid red 1, and crystal violet). This sensor design provides a modular method for exploring possible “pathlengths” by altering the exposed ATR fiber length. Also studied were approaches to loading and measuring the sensor cell. These results are compared to a traditional 1 cm cuvette measured by transmission UV-vis. It was found that the ATR-UV-vis probe was capable of measuring solutions 600 times more concentrated than the 1 cm cuvette. Advanced data analysis in the form of multivariate curve resolution (MCR) was used to analyze the speciation of methylene blue over a large concentration range. The application of this novel ATR-UV-vis probe to the interrogation of dark solutions is a promising avenue for use in on-line monitoring of nuclear processes.

47 OTHER INSTRUMENTATION↗

NASA NTRS2014

Performance Simulations for a Spaceborne Methane Lidar Mission

Future spaceborne lidar measurements of key anthropogenic greenhouse gases are expected to close current observational gaps particularly over remote, polar, and aerosol-contaminated regions, where actual in situ and passive remote sensing observation techniques have difficulties. For methane, a "Methane Remote Lidar Mission" was proposed by Deutsches Zentrum fuer Luft- und Raumfahrt and Centre National d'Etudes Spatiales in the frame of a German-French climate monitoring initiative. Simulations assess the performance of this mission with the help of Moderate Resolution Imaging Spectroradiometer and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations of the earth's surface albedo and atmospheric optical depth. These are key environmental parameters for integrated path differential absorption lidar which uses the surface backscatter to measure the total atmospheric methane column. Results showthat a lidar with an average optical power of 0.45W at 1.6 μm wavelength and a telescope diameter of 0.55 m, installed on a low Earth orbit platform(506 km), will measure methane columns at precisions of 1.2%, 1.7%, and 2.1% over land, water, and snow or ice surfaces, respectively, for monthly aggregated measurement samples within areas of 50 × 50 km2. Globally, the mean precision for the simulated year 2007 is 1.6%, with a standard deviation of 0.7%. At high latitudes, a lower reflectance due to snow and ice is compensated by denser measurements, owing to the orbital pattern. Over key methane source regions such as densely populated areas, boreal and tropical wetlands, or permafrost, our simulations show that the measurement precision will be between 1 and 2%.

methane↗

NASA NTRS1997

Contribution of Phycoerythrin-Containing Phytoplankton to Remotely Sensed Signals in the Ocean

The purpose of this project was to evaluate the importance of phycoerythrin-containing phytoplankton, in particular coccoid cyanobacteria, to remote sensing. We proposed to estimate cyanobacteria abundance and pigmentation and their relationship to water-column optics. We have estimated the contribution of cyanobacteria to scattering and backscattering in both open ocean (Sargasso Sea) and coastal waters (western coast of North Atlantic and the California Current). Sampling and data processing is performed. Relationship between water column optics and phycoerythrin concentration and algorithms development are being carried out.

Vernet, Maria↗

DOE OSTI2023

Surface grain refinement of casting A380 aluminum alloy by ultrasonic-assisted surface mechanical grinding treatment

A novel surface processing technique, ultrasonic-assisted surface mechnical grinding treatment (U-SMGT), was proposed and applied to modify the surface micriostructure of the casting aluminum alloy (A380). Comprehensive post-process chracterization techniques including 3D profilometry, optical microscope, scanning electric microscopy (SEM), and electron backscatter diffraction (EBSD) were carried out to investigate the surface morphology and microstructure of the processed region (PR). It was found that a surface layer of grain refinement with a thickness of about 50 µm was formed. In the as-received base material (BM), large clusters of dendritic eutectic phase with a size of approximately 20 µm were isolated by α-Al matrix. Nano-indentation tests showed that hardness of the eutectic and α-Al in the as-received BM was 2.15 GPa and 1.2 GPa respectively. After U-SMGT, the large dendritic eutectic phase was broken down into much fine particles with an average size of 0.57 µm. These fine particles were uniformly distributed into the α-Al matrix. Nano-indentation measurement exhibited a hardness of 2.27 GPa within the processed region. The overall high hardness in the processed region is a result of the pinning effect of uniformly distributed fine dendrites and grain refinement of Al-matrix.

36 MATERIALS SCIENCE↗

NASA NTRS1973

Remote sensing of Mare Serenitatis

An examination was made of earth based observations of optical color differences, infrared eclipse temperatures, and radar backscatter for Mare Serenitatis. Information is also included on orbital observations, physical properties of surface types, and correlation of surface types with geologic units. Differences in these remote observations are attributed to variations in chemical and minerological compositions.

Thompson, T. W.↗

NASA NTRS1976

Infrared thermal models for Saturn's ring

Infrared (10 and 20 microns) thermal emission data for Saturn's rings are discussed in terms of simple isothermal radiative transfer models of finite optical thickness. Recent brightness temperature measurements, corresponding to essentially maximum ring tilt, indicate that optical single scattering albedos less than 0.75 are required to provide sufficient heating of the ring material. Reconciliation with analyses of the optical scattering properties of the ring requires the backscattering efficiency to be even higher than for a macroscopic sphere. Historical brightness temperature measurements are used to show that no unique isothermal ring model exists. Instead, a temperature gradient perpendicular to the ring plane appears to be present.

Price, M. J.↗