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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

MISSE Thermal Control Materials with Comparison to Previous Flight Experiments

Many different passive thermal control materials were flown as part of the Materials on International Space Station Experiment (MISSE), including inorganic coatings, anodized aluminum, and multi-layer insulation materials. These and other material samples were exposed to the low Earth orbital environment of atomic oxygen, ultraviolet radiation, thermal cycling, and hard vacuum, though atomic oxygen exposure was limited for some samples. Materials flown on MISSE-1 and MISSE-2 were exposed to the space environment for nearly four years. Materials flown on MISSE-3, MISSE-4, and MISSE-5 were exposed to the space environment for one year. Solar absorptance, infrared emittance, and mass measurements indicate the durability of these materials to withstand the space environment. Effects of short duration versus long duration exposure on ISS are explored, as well as comparable data from previous flight experiments, such as the Passive Optical Sample Assembly (POSA), Optical Properties Monitor (OPM), and Long Duration Exposure Facility (LDEF).

Finckenor, Miria↗

Development of a plasma sprayed ceramic gas path seal for high pressure turbine applications

The plasma sprayed graded layered yittria stabilized zirconia (ZrO2)/metal(CoCrAlY) seal system for gas turbine blade tip applications up to 1589 K (2400 F) seal temperatures was studied. Abradability, erosion, and thermal fatigue characteristics of the graded layered system were evaluated by rig tests. Satisfactory abradability and erosion resistance was demonstrated. Encouraging thermal fatigue tolerance was shown. Initial properties for the plasma sprayed materials in the graded, layered seal system was obtained, and thermal stress analyses were performed. Sprayed residual stresses were determined. Thermal stability of the sprayed layer materials was evaluated at estimated maximum operating temperatures in each layer. Anisotropic behavior in the layer thickness direction was demonstrated by all layers. Residual stresses and thermal stability effects were not included in the analyses. Analytical results correlated reasonably well with results of the thermal fatigue tests. Analytical application of the seal system to a typical gas turbine engine application predicted performance similar to rig specimen thermal fatigue performance. A model for predicting crack propagation in the sprayed ZrO2/CoCrAlY seal system was proposed, and recommendations for improving thermal fatigue resistance were made. Seal system layer thicknesses were analytically optimized to minimize thermal stresses in the abradability specimen during thermal fatigue testing. Rig tests on the optimized seal configuration demonstrated some improvement in thermal fatigue characteristics.

Shiembob, L. T.↗

Improving impact resistance of ceramic materials by energy absorbing surface layers

Energy absorbing surface layers were used to improve the impact resistance of silicon nitride and silicon carbide ceramics. Low elastic modulus materials were used. In some cases, the low elastic modulus was achieved using materials that form localized microcracks as a result of thermal expansion anisotropy, thermal expansion differences between phases, or phase transformations. In other cases, semi-vitreous or vitreous materials were used. Substantial improvements in impact resistance were observed at room and elevated temperatures.

Kirchner, H. P.↗

Deployable Debris Shields For Space Station

Multilayer shields made of lightweight sheet materials deployed from proposed Space Station Freedom for additional protection against orbiting debris. Deployment mechanism attached at each location on exterior where extra protection needed. Equipment withdraws layer of material from storage in manner similar to unfurling sail or extending window shade. Number of layers deployed depends on required degree of protection, and could be as large as five.

Christiansen, Eric L.↗

Three dimensional finite element analysis of layered fiber-reinforced composite materials

A three-dimensional finite element analysis was performed for a biaxially loaded composite laminate (with a centered hole) consisting of several fiber-reinforced composite layers each with a specified fiber orientation. The detailed stress distribution around the hole was determined. Also, the locations of initial damage zones due to different failure mechanisms were indicated.

Lee, J. D.↗

Inorganic Water Repellent Coatings for Thermal Protection Insulation on an Aerospace Vehicle

The objective of this research was two-fold: first, to identify and test inorganic water-repellent materials that would be hydrophobic even after thermal cycling to temperatures above 600 C and, second, to develop a model that would link hydrophobicity of a material to the chemical properties of its constituent atoms. Four different materials were selected for detailed experimental study, namely, boron nitride, talc, molybdenite, and pyrophyllite, all of which have a layered structure made up of ionic/covalent bonds within the layers but with van der Waals bonds between the layers. The materials tested could be considered hydrophobic for a nonporous surface but none of the observed contact angles exceeded the necessary 90 degrees required for water repellency of porous materials. Boron nitride and talc were observed to retain their water-repellency when heated in air to temperatures that did not exceed 800 C, and molybdenite was found to be retain its hydrophobicity when heated to temperatures up to 600 C. For these three materials, oxidation and decomposition were identified to be the main cause for the breakdown of water repellency after repeated thermal cycling. Pyrophyllite shows the maximum promise as a potential water-repellent inorganic material, which, when treated initially at 900 C, retained its shape and remained hydrophobic for two thermal cycles where the maximum retreatment temperature is 900 C. A model was developed for predicting materials that might exhibit hydrophobicity by linking two chemical properties, namely, that the constituent ions of the compound belong to the soft acid-base category and that the fractional ionic character of the bonds be less than about 20 percent.

Fuerstenau, D. W.↗

Inorganic Water Repellent Coatings for Thermal Protection Insulation on an Aerospace Vehicle

The objective of this research was two-fold: first, to identify and test inorganic water-repellent materials that would be hydrophobic even after thermal cycling to temperatures above 600 C and, second, to develop a model that would link hydrophobicity of a material to the chemical properties of its constituent atoms. Four different materials were selected for detailed experimental study, namely, boron nitride, talc, molybdenite, and pyrophyllite, all of which have a layered structure made up of ionic/covalent bonds within the layers but with van der Waals bonds between the layers. The materials tested could be considered hydrophobic for a nonporous surface but none of the observed contact angles exceeded the necessary 90 degrees required for water repellency of porous materials. Boron nitride and talc were observed to retain their water-repellency when heated in air to temperatures that did not exceed 800 C, and molybdenite was found to be retain its hydrophobicity when heated to temperatures up to 600 C. For these three materials, oxidation and decomposition were identified to be the main cause for the breakdown of water repellency after repeated thermal cycling. Pyrophyllite shows the maximum promise as a potential water-repellent inorganic material, which, when treated initially at 900 C, retained its shape and remained hydrophobic for two thermal cycles where the maximum retreatment temperature is 900 C. A model was developed for predicting materials that might exhibit hydrophobicity by linking two chemical properties, namely, that the constituent ions of the compound belong to the soft acid-base category and that the fractional ionic character of the bonds be less than about 20 percent.

Fuerstenau, D. W.↗

Solar energy apparatus with apertured shield

A protective apertured shield for use about an inlet to a solar apparatus which includesd a cavity receiver for absorbing concentrated solar energy. A rigid support truss assembly is fixed to the periphery of the inlet and projects radially inwardly therefrom to define a generally central aperture area through which solar radiation can pass into the cavity receiver. A non-structural, laminated blanket is spread over the rigid support truss in such a manner as to define an outer surface area and an inner surface area diverging radially outwardly from the central aperture area toward the periphery of the inlet. The outer surface area faces away from the inlet and the inner surface area faces toward the cavity receiver. The laminated blanket includes at least one layer of material, such as ceramic fiber fabric, having high infra-red emittance and low solar absorption properties, and another layer, such as metallic foil, of low infra-red emittance properties.

Collings, Roger J.↗

Planar varactor frequency multiplier devices with blocking barrier

The invention relates to planar varactor frequency multiplier devices with a heterojunction blocking barrier for near millimeter wave radiation of moderate power from a fundamental input wave. The space charge limitation of the submillimeter frequency multiplier devices of the BIN(sup +) type is overcome by a diode structure comprising an n(sup +) doped layer of semiconductor material functioning as a low resistance back contact, a layer of semiconductor material with n-type doping functioning as a drift region grown on the back contact layer, a delta doping sheet forming a positive charge at the interface of the drift region layer with a barrier layer, and a surface metal contact. The layers thus formed on an n(sup +) doped layer may be divided into two isolated back-to-back BNN(sup +) diodes by separately depositing two surface metal contacts. By repeating the sequence of the drift region layer and the barrier layer with the delta doping sheet at the interfaces between the drift and barrier layers, a plurality of stacked diodes is formed. The novelty of the invention resides in providing n-type semiconductor material for the drift region in a GaAs/AlGaAs structure, and in stacking a plurality of such BNN(sup +) diodes stacked for greater output power with and connected back-to-back with the n(sup +) GaAs layer as an internal back contact and separate metal contact over an AlGaAs barrier layer on top of each stack.

Lieneweg, Udo↗

A Proposed Landing Site for the 2001 Lander in a Hematite-Rich Region in Sinus Meridiani

The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has identified an accumulation of crystalline hematite (alpha-Fe2O3) that covers an area with very sharp boundaries approximately 350 by 350-750 km in size centered near 2 S latitude between 0 and 5 W longitude (Sinus Meridiani). The depth and shape of the hematite fundamental bands in the TES spectra show that the hematite is relatively coarse grained (> 5-10 microns). The spectrally-derived areal abundance of hematite varies with particle size from approx. 10% for particles > 30 microns in diameter to 40-60% for unpacked 10 micron powders. The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter < 5-10 microns), red, crystalline hematite considered, on the basis of visible and near-IR data, to be a minor spectral component in Martian bright regions. A map of the hematite index has been constructed using TES data from 11 orbits, including the six in which hematite was detected and five orbits that passed nearby that showed no evidence of hematite. The boundaries of the hematite-rich region are sharp at spatial scales of about 10 km. Within this region there are spatial variations in spectral band depth of a factor of two to three. At the present time the hematite-rich region has not been completely mapped. However, by using the bounding orbits to the east and west in which hematite was not detected, we can establish that this region covers an area that is between 350 and 750 km in length and over -350 km in width (1.2 x 10(exp 5) to 2.6 x 10(exp 5 sq km). The hematite-rich surface discovered by TES closely corresponds with smooth-surfaced unit ('sm') that appears to be the surface of a layered sequence. The presence of small mesas superposed on 'sm' and the degraded nature of the small impact craters suggests that material has been removed from this unit. These layered materials do not appear to be primary volcanic products (i.e., lava flows) because there are no associated lava flow lobes, fronts or pressure ridges; there are no fissures or calderae, nor any other features that can be interpreted as volcanic within 'sm'. Bowl-shaped depressions in 'sm' and the remnant mesas on top of a portion of this unit suggest that deflation has removed material that was once above the present surface of 'sm'. The most likely cause of the deflation is wind, which suggests that the layered materials are relatively friable. In summary, Sinus Meridiani hematite is closely associated with a smooth, layered, friable surface that is interpreted to be sedimentary in origin.

Christensen, Philip R.↗

Lithiation Induced Phases in 1T'-MoTe 2 Nanoflakes

Multiple polytypes of MoTe 2 with distinct structures and intriguing electronic properties can be accessed by various physical and chemical approaches. Here, in this study, we report electrochemical lithium (Li) intercalation into 1T'-MoTe 2 nanoflakes, leading to the discovery of two previously unreported lithiated phases. Distinguished by their structural differences from the pristine 1T' phase, these distinct phases were characterized using in situ polarization Raman spectroscopy and in situ single-crystal X-ray diffraction. The lithiated phases exhibit increasing resistivity with decreasing temperature, and their carrier densities are two to 4 orders of magnitude smaller than the metallic 1T' phase, as probed through in situ Hall measurements. The discovery of these gapped phases in initially metallic 1T'-MoTe 2 underscores electrochemical intercalation as a potent tool for tuning the phase stability and electron density in two-dimensional (2D) materials.

36 MATERIALS SCIENCE↗

Shielding from space radiations

This Progress Report covering the period of December 1, 1992 to June 1, 1993 presents the development of an analytical solution to the heavy ion transport equation in terms of Green's function formalism. The mathematical development results are recasted into a highly efficient computer code for space applications. The efficiency of this algorithm is accomplished by a nonperturbative technique of extending the Green's function over the solution domain. The code may also be applied to accelerator boundary conditions to allow code validation in laboratory experiments. Results from the isotopic version of the code with 59 isotopes present for a single layer target material, for the case of an iron beam projectile at 600 MeV/nucleon in water is presented. A listing of the single layer isotopic version of the code is included.

Chang, C. Ken↗

Engineered Multifunctional Surfaces for Fluid Handling

Designs incorporating variations in capillary geometry and hydrophilic and/or antibacterial surface properties have been developed that are capable of passive gas/liquid separation and passive water flow. These designs can incorporate capillary grooves and/or surfaces arranged to create linear and circumferential capillary geometry at the micro and macro scale, radial fin configurations, micro holes and patterns, and combinations of the above. The antibacterial property of this design inhibits the growth of bacteria or the development of biofilm. The hydrophilic property reduces the water contact angle with a treated substrate such that water spreads into a thin layer atop the treated surface. These antibacterial and hydrophilic properties applied to a thermally conductive surface, combined with capillary geometry, create a novel heat exchanger capable of condensing water from a humid, two-phase water and gas flow onto the treated heat exchanger surfaces, and passively separating the condensed water from the gas flow in a reduced gravity application. The overall process to generate the antibacterial and hydrophilic properties includes multiple steps to generate the two different surface properties, and can be divided into two major steps. Step 1 uses a magnetron-based sputtering technique to implant the silver atoms into the base material. A layer of silver is built up on top of the base material. Completion of this step provides the antibacterial property. Step 2 uses a cold-plasma technique to generate the hydrophilic surface property on top of the silver layer generated in Step 1. Completion of this step provides the hydrophilic property in addition to the antibacterial property. Thermally conductive materials are fabricated and then treated to create the antibacterial and hydrophilic surface properties. The individual parts are assembled to create a condensing heat exchanger with antibacterial and hydrophilic surface properties and capillary geometry, which is capable of passive phase separation in a reduced gravity application. The plasma processes for creating antibacterial and hydrophilic surface properties are suitable for applications where water is present on an exposed surface for an extended time, such that bacteria or biofilms could form, and where there is a need to manage the water on the surface. The processes are also suitable for applications where only the hydrophilic property is needed. In particular, the processes are applicable to condensing heat exchangers (CHXs), which benefit from the antibacterial properties as well as the hydrophilic properties. Water condensing onto the control surfaces of the CHX will provide the moist conditions necessary for the growth of bacteria and the formation of biofilms. The antibacterial properties of the base layer (silver) will mitigate and prevent the growth of bacteria and formation of biofilms that would otherwise reduce the CHX performance. In addition, the hydrophilic properties reduce the water contact angle and prevent water droplets from bridging between control surfaces. Overall, the hydrophilic properties reduce the pressure drop across the CHX.

Thomas, Chris↗

Pneumatically Actuated Miniature Peristaltic Vacuum Pumps

Pneumatically actuated miniature peristaltic vacuum pumps have been proposed for incorporation into advanced miniature versions of scientific instruments that depend on vacuum for proper operation. These pumps are expected to be capable of reaching vacuum-side pressures in the torr to millitorr range (from .133 down to .0.13 Pa). Vacuum pumps that operate in this range are often denoted roughing pumps. In comparison with previously available roughing pumps, these pumps are expected to be an order of magnitude less massive and less power-hungry. In addition, they would be extremely robust, and would operate with little or no maintenance and without need for oil or other lubricants. Portable mass spectrometers are typical examples of instruments that could incorporate the proposed pumps. In addition, the proposed pumps could be used as roughing pumps in general laboratory applications in which low pumping rates could be tolerated. The proposed pumps could be designed and fabricated in conventionally machined and micromachined versions. A typical micromachined version (see figure) would include a rigid glass, metal, or plastic substrate and two layers of silicone rubber. The bottom silicone layer would contain shallow pump channels covered by silicone arches that could be pushed down pneumatically to block the channels. The bottom silicone layer would be covered with a thin layer of material with very low gas permeability, and would be bonded to the substrate everywhere except in the channel areas. The top silicone layer would be attached to the bottom silicone layer and would contain pneumatic- actuation channels that would lie crosswise to the pump channels. This version is said to be micromachined because the two silicone layers containing the channels would be fabricated by casting silicone rubber on micromachined silicon molds. The pneumatic-actuation channels would be alternately connected to a compressed gas and (depending on pump design) either to atmospheric pressure or to a partial vacuum source. The design would be such that the higher pneumatic pressure would be sufficient to push the silicone arches down onto the substrates, blocking the channels. Thus, by connecting pneumatic- actuation channels to the two pneumatic sources in spatial and temporal alternation, waves of opening and closing, equivalent to peristalsis, could be made to move along the pump channels. A pump according to this concept could be manufactured inexpensively. Pneumatic sources (compressors and partial vacuum sources) similar those needed for actuation are commercially available; they typically have masses of .100 g and power demands of the order of several W. In a design-optimization effort, it should be possible to reduce masses and power demands below even these low levels and to integrate pneumatic sources along with the proposed pumps into miniature units with overall dimensions of no more than a few centimeters per side.

Feldman, Sabrina↗

Structure and superconductivity in (Bi(0.35)Cu(0.65))Sr2YCu2O7 and related materials

The recently reported (Bi/Cu)Sr2YCu2O7 phase has been studied by time of flight powder neutron diffraction. The proposed 1212 structure has been confirmed and refinements have shown the oxygen in the (Bi/Cu)O layer is displaced by 0.78 A from the ideal (1/2,1/2,0) site (P4/mmm space group) along /100/. Bond Valence Sum calculations have suggested oxidation states of Bi(5+) and Cu(2+) for the cations in the (Bi/Cu)O layers. The material is non-superconducting and all attempts to induce superconductivity have been unsuccessful. Work on the related material (Ce/Cu)Sr2YCu2O7 has shown the ideal Ce content to be 0.5 Ce per formula unit. The introduction of Ba (10%) onto the Sr site dramatically increases phase stability and also induces superconductivity (62 K).

Jennings, R. A.↗

Solid-state non-volatile electronically programmable reversible variable resistance device

A solid-state variable resistance device (10) whose resistance can be repeatedly altered by a control signal over a wide range, and which will remain stable after the signal is removed, is formed on an insulated layer (14), supported on a substrate (12) and comprises a set of electrodes (16a, 16b) connected by a layer (18) of material, which changes from an insulator to a conductor upon the injection of ions, covered by a layer (22) of material with insulating properties which permit the passage of ions, overlaid by an ion donor material (20). The ion donor material is overlaid by an insulating layer (24) upon which is deposited a control gate (26) located above the contacts. In a preferred embodiment, the variable resistance material comprises WO.sub.3, the ion donor layer comprises Cr.sub.2 O.sub.3, and the layers sandwiching the ion donor layer comprise silicon monoxide. When a voltage is applied to the gate, the resistance between the electrode contacts changes, decreasing with positive voltage and increasing with negative voltage.

Ramesham, Rajeshuni↗

A Study to Analyze the Permeation of High Density Gases and Propellant Vapors Through Single Layer Teflon or Teflon Structure Materials and Laminations

This report contains the results of a fifteen month analytical and experimental study of the leakage rate of the pressurant gases (N2, He) and the propellant vapors (N2O4,N2H4) through bladder structures consisting of two layers of Teflon separated by a metallic foil diffusion barrier containing microscopic or larger holes. Results were obtained for the steady state leakage rate through circular holes and long rectangular openings in the barrier for arbitrary thicknesses of the two Teflon layers. The effect of hole shape and relative hole position on the leakage rate were studied. The transient problem was analyzed and it was shown that steady state calculations are adequate for estimating the leakage rate. A computer program entitled "Diffusion Analyzer Program" was developed to calculate the leakage rate, both transient and steady state. Finally, the analytical results were compared to experimentally determined values of the leakage rate through a model laminated bladder structure. The results of the analysis are in good agreement with experiment. The experimental effort (Part II of the Bladder Permeation Program) measured the solubility, diffusion coefficient and permeability of helium, nitrogen and nitrogen tetroxide vapor through Teflon TFE and FEP membranes. Data were obtained in the temperature range of 25 to 100 C at pressures ranging from near vacuum to about 20 atmospheres. Results of the experimental effort were compared with the limited data previously reported. As a verification to the applicability of results to actual bladder systems, counter diffusion tests were performed with a laminated sample containing aluminum foil with a selected group of holes.

Johnson, R. L.↗

Multishock Shield Against Meteoroids And Debris

Two documents discuss "multi-shock shielding" concept, according to which multiple spaced, very thin layers of material protects spacecraft against impacts by meteoroids, orbiting debris, or other projectiles traveling at hypervelocities. According to concept, incoming projectile broken up upon impact on first (outermost) layer, and fragments further broken up by subsequent layers. At each successive surface, impact pressure heats fragments, eventually melting and/or vaporizing them.

Cour-Palais, Burton G.↗