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Progress on Computational Modeling of Water-Based NSTF (FY2021)

This report documents the FY21 progress and achievements made in the computational analyses of the water-based NSTF. Both system-level and high-fidelity Computational Fluid Dynamics (CFD) analyses were performed to gain a complete understanding of the complex flow and heat transfer phenomena in natural convection systems. The progress on the waterbased NSTF experimental testing is summarized in a companion report (ANL-ART-230). As a continuation of progress from previous years, in FY21 the RELAP5 model of the NSTF was first updated to include a representative heated cavity that incorporated convection and conduction means of heat transfer. Two different cavity models were developed, one that models the radiation heat exchange among all surfaces in one enclosure (Cavity Model 1), and another that employs multiple radiation enclosures with each considering the surfaces at one axial level (Cavity Model 2). This updated RELAP5 deck was benchmarked with single-phase test data to tune form loss coefficients of the elbows and tees, along with heat transfer coefficients within the cavity and off the external insulation panels. This tuned model was then found to accurately predict fluid temperatures within 2.5% and both system and riser flow rates within 6% during single-phase, steady-state simulations. For transient simulations, there is a slight over prediction of the flow rate, fluid temperatures, and heater temperatures during the heat-up period, which indicate that the transient heat loss may be underestimated. Following, the capabilities of RELAP5-3D were examined, which feature a conduction enclosure model that is not present in the current version of RELAP5-MOD3.3 used for all previous NSTF simulations. As an initial comparison of the two codes, single-phase simulations were run that used similar input decks. The results indicate that the single-phase flow predicted by the two codes was very similar, however RELAP5-3D appears to predict a higher system flow during the two-phase transient when compared to the flow rates predicted by RELAP5-MOD3.3. Furthermore, RELAP5-3D run did not capture the density wave oscillations or geysering phenomena, which are large oscillation flow instabilities observed in the experimental facility. To further the prediction capabilities for capturing two-phase instabilities, Options 55, 57, 58, 61, which are implemented by default in RELAP5-MOD3.3 but not in RELAP5-3D, were investigated. When enabling Option 61, RELAP5-3D agrees well with MOD3.3 in predicting the total system flow, while other options have negligible effect on the predicted total system flow by RELAP5-3D. However, none of these options enables RELAP5-3D to produce the same flow instabilities. For future steps, efforts are currently underway to investigate RELAP5-3D’s different behavior in predicting low-pressure two-phase instabilities. STAR-CCM+ was used to perform CFD analysis of the water-based test facility and provide simulation results for comparisons to experimental data. Efforts first focused on describing the characteristics of flow within the heated cavity. A study was performed on whether possible leakage flow between the two sides of the cavity could substantially impact and explain the results. An additional second assumption was examined which defined adiabatic side walls, so physical insulation structures were added to the models to allow conduction across this outer insulation. The results suggest that potential porosity of the insulation could be a major factor in the temperature distribution within the cavity and should be considered in any studies where it is desirable to know the cavity wall temperatures to higher accuracy.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Photoluminescence in Tagging: A Glowing Review

This literature review explores the options of using photoluminescence for tagging uranium fuel and zirconium cladding in order to easily and quickly associate interdicted material to its facility of origin or pathway after loss of institutional control. Photoluminescence is the spontaneous emission of radiation by a substance when excited by interaction with light. The source of photoluminescence can be from organic, inorganic, and organometallic compounds. Each luminophore, or compound responsible for luminescent properties, has individual strengths and weaknesses, depending on the intended use. Many factors can affect the brightness, lifetime, color, and detectability of luminophores, such as humidity, temperature, oxygen availability, noise from radiation–induced luminescence, and the presence of quenching substances like iron. Application of luminescent compound to the surface of an item can be done using paint, dye, thin film, thick film, or electrochemical coating. Several of the application techniques may have secondary functions such as corrosion resistance and detection, heat resistance, protective properties, and more. When considering cladding, there are various successful studies on the application of luminescent coatings on zirconium. However, significant research will be necessary to explore which luminophore and which application technique would best fit the intended use. In order to proceed with this research, a baseline of the natural luminescence of the intended base material (nuclear fuel or cladding) is necessary. While there may be issues with background noise, quenching from the environment, quenching from the substrate, signal to noise weakness, etc. the multitude of options may make photoluminescent tagging an option. In summary, this review has demonstrated that photoluminescence is a potential option to tag nuclear fuel and cladding, but additional paper–studies, testing, and research is required to understand the compatibility of luminescent tags in nuclear reactor environments, manufacturability, and detectability.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Proposed Risk-Informed Regulatory Framework for Approval of Microreactor Transportation Packages

Microreactors are very small nuclear reactors with a power output of about 20 megawatts electric or less that are designed to be factory-built, modular in nature, and highly portable. These compact reactors will be small enough to be transported by truck or even air and could help solve energy challenges in a number of areas, ranging from remote commercial or residential locations to military bases. Pacific Northwest National Laboratory is tasked to develop and evaluate transportation licensing options for microreactors. The work is funded by the National Reactor Innovation Center a National Department of Energy program led by Idaho National Laboratory for the Office of Nuclear Energy Research and Development which support demonstration of microreactor technology. Key transportation steps include the (1) initial movement of high-assay low enriched uranium fresh fuel, (2) transportation of an intact, but never-operated microreactor, and (3) transportation of an intact, previously-operated microreactor. The deliverables on the project consists of a documentation of applicable regulations and regulatory authority for transportation. The objective of this report is to propose a risk-informed regulatory framework for the licensing of the transportation of microreactors, including the transportation of irradiated nuclear fuel that is assumed to be an integral component of the microreactor transportation package. The framework lays out a viable regulatory pathway, including decision points for regulatory options and the supporting technical evaluations for those options in phases from near to long term. This report includes discussion of the (1) general microreactor design concepts including representative microreactor source terms, (2) options for regulatory approval of microreactor transportation based on current regulation and historical precedence, (3) regulatory basis for including risk information in microreactor transportation licensing activities, and (4) description of a risk-informed regulatory framework.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Proposed Risk-Informed Regulatory Framework for Approval of Microreactor Transportation Packages

Microreactors are very small nuclear reactors with a power output of about 20 megawatts electric or less that are designed to be factory-built, modular in nature, and highly portable. These compact reactors will be small enough to be transported by truck or even air and could help solve energy challenges in a number of areas, ranging from remote commercial or residential locations to military bases. Pacific Northwest National Laboratory is tasked to develop and evaluate transportation licensing options for microreactors. The work is funded by the National Reactor Innovation Center a National Department of Energy program led by Idaho National Laboratory for the Office of Nuclear Energy Research and Development which support demonstration of microreactor technology. Key transportation steps include the (1) initial movement of high-assay low enriched uranium fresh fuel, (2) transportation of an intact, but never-operated microreactor, and (3) transportation of an intact, previously-operated microreactor. The deliverables on the project consists of a documentation of applicable regulations and regulatory authority for transportation. The objective of this report is to propose a risk-informed regulatory framework for the licensing of the transportation of microreactors, including the transportation of irradiated nuclear fuel that is assumed to be an integral component of the microreactor transportation package. The framework lays out a viable regulatory pathway, including decision points for regulatory options and the supporting technical evaluations for those options in phases from near to long term. This report includes discussion of the (1) general microreactor design concepts including representative microreactor source terms, (2) options for regulatory approval of microreactor transportation based on current regulation and historical precedence, (3) regulatory basis for including risk information in microreactor transportation licensing activities, and (4) description of a risk-informed regulatory framework.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

LAMP-PSR Scoping Studies Report

This report summarizes work performed from July – September 2023, performing an initial evaluation for the LANSCE Proton Storage Ring upgrade option “B.” The studies identified potential pathsforward, performing initial beam dynamics studies, and surveying various technology options different aspects of the upgrade. Taken together, the studies provide an “early look” at the feasibility, challenges and alternative methods for pursuing Option “B,” and give guidance towards more detailed design concept development needed as work progresses. Generally speaking, no major obstacles were identified in pursuing the Option “B” PSR upgrade path in terms of the machine physics or overall system architecture. Several areas of concern have been identified; we note that these primarily center on technology choice and must be addressed regardless of the upgrade path selected, and none of the concerns are considered insurmountable.

43 PARTICLE ACCELERATORS↗

Survey of Uranium Nitride and Mixed Oxide Fuels for Microreactor Applications

Different fuel systems are being proposed for use in microreactors including TRISO fuel and metallic U-Zr based fuel. TRISO fuel is considered the main fuel option for most of the industry teams. Given the need for compact size core and potential for long fuel life of a microreactor, high density fuels such as metallic and nitride fuels are potential options. Of interest here is the uranium nitride (UN) option, which can allow for higher fissile material content and higher thermal conductivity compared to conventional uranium oxide fuel, and also has higher melting temperature compared to metallic fuel. Meanwhile, the current availability is limited for high assay low enriched uranium (HALEU) that is needed for high density fuels, which motivates the consideration of using Pu as a potential replacement for HALEU until adequate production capacity is in place. Current Pu availability is mainly attributed to the inventory of excess weapons Pu rather than through reprocessing of spent nuclear fuel. This inventory of excess Pu can be used in both metallic and oxide fuel systems to replace HALEU. Of interest here, the oxide form, that is the mixed oxide form of PuO 2 and UO 2 (MOX). In this report, the options of using UN or MOX, in both pellet and TRISO fuel forms, in microreactors are evaluated in relation to their properties, fuel performance and irradiation data, as well as fabrication. Gaps related to those areas are identified for both fuel systems, to guide future activities by DOE programs such as the advanced fuels campaign (AFC), to enable their use in microreactors.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Bench-Scale Electrolytic Dissolution of Quarter-Scale FCA Cans

In 2016, the Savannah River National Laboratory (SRNL) led, in support of and under sponsorship of the Department of Energy’s National Nuclear Security Administration (DOE/NNSA) Office of Material Management and Minimization (M3), the removal and transfer of the plutonium based Fast Critical Assembly (FCA) fuel from the Japan Atomic Energy Agency (JAEA) Tokai facility to the Savannah River Site (SRS). The team also included JAEA, multiple organizations in Savannah River Nuclear Solutions (SRNS), International Nuclear Services, and many other entities. The FCA fuel removal project completion was a key deliverable for M3 to the 2016 Nuclear Security Summit and constituted the largest inventory of weapons-usable plutonium removed under the nonproliferation program. The FCA materials consist of thousands of stainless steel (SS) clad plates and hundreds of SS clad rods. The FCA fuel elements were packaged in a carrier can and stored at SRS pending disposition of the fuel. Following an assessment of candidate disposition options, SRNS identified electrolytic dissolution (ED) as the most promising disposition option for the FCA plates and their preferred option was endorsed by DOE. This option entails electrochemically dissolving the entire FCA carrier can with fuel elements and was based on bench-scale laboratory testing and historical work on processing SS-clad and zirconium-clad uranium-based fuel in the H-Canyon electrolytic dissolver (last operated in 1980). The FCA plate consists of a plutonium-aluminum metal alloy core hermitically sealed in SS cladding.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Energy Transitions Initiative Partnership Project: Alaska Longline Fishermen’s Association Alternative Fuels Review

This report provides information about additional options in electrifying the Alaska Longline Fishermen’s Association (ALFA) fishing fleet. Currently, the Energy Transitions Initiative Partnership Project is prioritizing electric hybrid and battery electric options for retrofit of select fishing vessels in the fleet. However, there are other options for reducing carbon emissions among the fleet, namely hydrogen, ammonia, and biofuels. The use of these alternative fuels may be an option for the fleet in the future as ALFA addresses its vulnerabilities. A literature review of available resources on these fuels was conducted to provide information on several topics associated with implementation of these technologies, including current applications, commercially available power modules, necessary components, infrastructure, and safety codes and standards. An additional aspect that this report investigates is general sizing and refueling schedule based on operating records of multiple ships in the fleet.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Energy Transitions Initiative Partnership Project: Alaska Longline Fishermen’s Association Alternative Fuels Review

This report provides information about additional options in electrifying the Alaska Longline Fishermen’s Association (ALFA) fishing fleet. Currently, the Energy Transitions Initiative Partnership Project is prioritizing electric hybrid and battery electric options for retrofit of select fishing vessels in the fleet. However, there are other options for reducing carbon emissions among the fleet, namely hydrogen, ammonia, and biofuels. The use of these alternative fuels may be an option for the fleet in the future as ALFA addresses its vulnerabilities. A literature review of available resources on these fuels was conducted to provide information on several topics associated with implementation of these technologies, including current applications, commercially available power modules, necessary components, infrastructure, and safety codes and standards. An additional aspect that this report investigates is general sizing and refueling schedule based on operating records of multiple ships in the fleet.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Power Technologies for Rail Decarbonization Workshop: Summary Report

Argonne National Laboratory organized the Power Technologies for Rail Decarbonization Workshop for the U.S. Department of Energy (DOE) Vehicle Technologies Office. The workshop offered an inclusive venue for different stakeholders to convey their perspective on challenges and opportunities in decarbonizing the rail sector. The first day of the workshop focused on (1) rail decarbonization efforts in the DOE and collaboration opportunities, (2) technology pathways to decarbonize rail, and (3) prime mover and low-carbon options for rail. The second day was devoted to (1) prime mover and zero-carbon options for rail, and (2) rail logistics, infrastructure, and safety. Each day raised challenges and solutions through presentations from national leaders and discussions among panel members and the audience. Through this engagement with different stakeholders, we will produce a cross-disciplinary recommendation for the role of government agencies to contribute meaningful research to address current technology gaps. The workshop included up 139 active participants and featured keynote speakers and panelists from Association of American Railroads, Progress Rail Locomotive, Wabtec, Burlington Northern Santa Fe Railroad, Amtrak, Caterpillar, Cummins, Renewable Energy Group-Chevron, DOE’s Bioenergy Technologies Office, California Air Resources Board, Federal Railroad Administration and multiple DOE national laboratories. This summary report presents highlights from participant discussions covering the topics of technology pathways to decarbonize rail, prime mover and low-carbon options, prime mover and zero-carbon options, as well as rail logistics, infrastructure, and safety. The variety of input gathered from the stakeholder attendees is vital, as it helps inform DOE on rail decarbonization challenges and opportunities. Stakeholder feedback is balanced against DOE strategic directions and priorities with consideration of the roles of government and industry.

33 ADVANCED PROPULSION SYSTEMS↗

Potential Supply Chain and Cost Reduction Strategies for Advanced Nuclear Reactors

This milestone represents a level of effort to provide recommendations for a supply chain plan and establish relationships between advanced reactor companies and large companies in the oil & gas and chemical industries. It represents a starting point to develop the plan with options, general equipment lists, and rough associated cost estimates of major equipment and the associated systems needed. This effort will provide an opportunity to leverage the experience that oil & gas and chemicals companies possess in large capital equipment procurement, modularization, acquisition and installation. Potential supply chain solutions will be discussed and preliminary options for worldwide manufacturers will be elucidated. The goal of this effort will be to leverage the years of accumulated experience in the oil & gas and chemical industries in the area of capital equipment acquisition to understand the potential supply chain options and to reduce potential acquisition costs by optimizing the supply chain options for advanced nuclear reactor modularization, manufacturing and acquisition.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Electric Utility Distribution Costs: Scoping Study on Trends, Drivers, and Possible Response Strategies [Slides]

This scoping study synthesizes information that will help stakeholders understand the scope, scale, and drivers of recent increases in investor-owned utility (IOU) expenditures on local distribution power grids, while providing regulators and other decision-makers with potential strategies to keep electricity bills down. The study includes five distinct components. Drawing first on data from FERC Form 1, it summarizes key trends in past and recent IOU distribution costs. Next, through a review of a sample of distribution-system plans, it characterizes material drivers of planned distribution expenditures. Ultimately, regulators must approve cost recovery for IOU expenditures, including those for the distribution system. The study therefore also: examines trends in utility requests and regulatory approvals related to changes in retail rates and return on equity; identifies areas where utility shareholder and customer incentives may be misaligned; and develops a menu of options that state regulators might consider to optimize distribution system expenditures. Some of the key findings include: - IOU distribution spending at a national level has grown by 6%/yr since 2014 in real dollar terms, 4x faster than in the prior 20 years and consisting mostly of capital (not operating) expenditure. - On a per-kWh basis, increases in IOU distribution costs since 2014 represent over 30% of the overall national-average increase in retail electricity rates. - Regional spending growth has ranged from 2-8%/yr, with larger estimated rate impacts in CAISO, then NYISO & ISO-NE, and then the Southeast, MISO & PJM (see figure). - Some utilities are planning for significantly increased distribution system spending. Planned spending on managing the existing system (asset replacement, safety & reliability, and resilience are all important drivers) exceeds that for capacity expansion. - IOU rate increase requests ($18 billion in 2025) and public utility commission (PUC) approval levels (average of 64% of requested amounts from 2021-2025) have recently hit multi-decadal highs. - PUCs in New England and the Southeast have recently approved a greater fraction of rate requests (>75%, on average) than in ther regions, while PUCs in California and the Southeast have generally authorized higher equity returns than in other regions. - Regulators have many tools to tackle potential misalignments between utility and customer interests and, more specifically, to optimize and reduce distribution costs. Shorter-term options include those related to return on equity, capital structure, depreciation, trackers, construction work in progress, and securitization. Longer-term options include performance-based regulation and a wide variety of planning-related requirements. All options embed important tradeoffs.

24 POWER TRANSMISSION AND DISTRIBUTION↗

High Harmonic Generation Seeding Echo-Enabled Harmonic Generation toward a Storage Ring-Based Tender and Hard X-ray-Free Electron Laser

To align with the global trend of integrating synchrotron light source (SLS) and free electron laser (FEL) facilities on one site, in line with examples such as SPring-8 and SACLA in Japan and ELETTRA and FERMI in Italy, we actively explore FEL options leveraging the ultralow-emittance electron beam of the NSLS-II upgrade. These options show promising potential for synergy with storage ring (SR) operations, thereby significantly enhancing our facility’s capabilities. Echo-enabled harmonic generation (EEHG) is well-suited to SR-based FELs, and has already been demonstrated with the capability of generating extremely narrow bandwidth as well as high brightness, realized using diffraction-limited short pulses in transverse planes and Fourier transform-limited bandwidth in the soft X-ray spectrum. However, regarding a conventional EEHG scheme, the combination of the shortest seed laser wavelength (256 nm) and highest harmonic (200) sets the short wavelength limit to λ = 1.28 nm. To further extend the short wavelength limit down to the tender and hard X-ray region, a vital option is to shorten the seed laser wavelength. Thanks to recent advances in high harmonic generation (HHG), packing 10 9 photons at one harmonic within a few-femtosecond pulse could turn such a novel HHG source into an ideal seeding for EEHG. Thus, compared to the cascaded EEHG, the HHG seeding option could not only lower the cost, but also free the SR space for accommodating more user beamlines. Moreover, to mitigate the SASE background noise on the sample and detector, we combine the HHG seeding EEHG with the crab cavity short pulse scheme for maximum benefit.

36 MATERIALS SCIENCE↗

Siting Analysis of a Solar-Nuclear-Desalination Integrated Energy System

Nuclear power is typically deployed as a baseload generator. Increased penetration of variable renewables motivates combining nuclear and renewable technologies into Integrated Energy Systems (IES) to improve dispatchability, component synergies and, through cogeneration, address multiple markets. However, combining multiple energy resources heavily depends on the proper selection of each system’s location and design limitations. In this paper, co-siting options for IES that couple nuclear and concentrating solar power (CSP) with thermal desalination are investigated. A comprehensive siting analysis is performed that utilizes global information survey data to determine possible co-siting options for nuclear and solar thermal generation in the United States. Viable co-siting options are distributed across the Southwestern U.S., with the greatest concentration of siting options in the southern Great Plains, although siting with higher solar direct normal irradiance is possible in other states such as Arizona and New Mexico. Brackish water desalination is also attractive across the southwest U.S. due to high water stress, but for brackish water desalination reverse osmosis (an electricity driven process) is most cost- and energy-efficient, which does not require co-siting with the thermal generator. The most attractive state for nuclear and thermal desalination (which is more attractive when using seawater) is Texas, although other areas may become attractive as water stress increases over the coming decades. Co-siting of all CSP and thermal desalination is challenging as attractive CSP sites are not coastal.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

FINAL TECHNICAL AND ECONOMIC FEASIBILITY STUDY ON THE APPLICATION OF A HEAT INTEGRATED POST-COMBUSTION CO2 CAPTURE SYSTEM WITH HITACHI ADVANCED SOLVENT INTO EXISTING COAL-FIRED POWER PLANT

This report contains the results of a techno-economic assessment (TEA) conducted of a heat integrated post-combustion CO2 capture process with Hitachi advanced solvent for retrofit into an existing coal-fired power plant (but treated as greenfield plant on cost analysis). The process has been developed by the University of Kentucky Center for Applied Energy (UK CAER). EPRI was chiefly responsible for this analysis, with significant input from WorleyParsons, Hitachi Power Systems America (Hitachi) and UK CAER. The project also involves the design, fabrication, installation, testing, and analyses of a slipstream facility located at L&GE-KU’s E.W. Brown Generating Station to demonstrate the UK CAER carbon capture system that could utilize heat integration with the main power plant. The design, start-up, and baseline of the pilot system was performed with a generic 30 wt% MEA solvent to obtain data for direct comparison with the DOE/NETL Reference Case followed by testing Hitachi’s proprietary solvent H3-1. In this techno-economic analysis, two cases utilizing the UK CAER process are compared, using different approach temperatures and solvent, against the DOE/NETL Reference Case (Case 10). The results are shown comparing the energy demand for post-combustion CO2 capture and the net higher heating value (HHV) efficiency of the power plant integrated with the post-combustion capture (PCC) plant. A levelized cost of electricity (LCOE) assessment was performed showing the costs of the options presented in the study. The key factors contributing to the reduction of LCOE were identified as CO2 partial pressure increase at the flue gas inlet, thermal integration of the process, and performance of the Hitachi H3-1 solvent. Recent UK CAER process pilot-scale testing data and process simualtion data showed that the packing heights of absorber and stripper columns were significantly oversized in the prelimanary TEA (Task 2 of this project) and thus updated in this final TEA for the H3-1 case only. In addition, the solvent make-up cost for H3-1 was updated based on lattest test results. Finally, a heat integration with the main power plant was applied in this final TEA to increase overall energy effciency for both the MEA and H3-1 cases. Additonal reductions in capital and operational costs are expected but not taken into account here. Shorter columns result in reduced pressure drops, smaller blower head and pump hydraulic head requirements. An increase in overall energy efficiency resuls in a decreased size of the power plant, the CCS and a reduced parasitic steam requirement to the CCS. The net efficiency of the UK CAER integrated PC power plant with CO2 capture changes from 26.2% for the Reference Case 10 plant in 2010 revised DOE/NETL baseline report to 27.6% for the MEA options considered, and 29.1% for the options utilizing the Hitachi advanced solvent. The UK CAER Process + Hitachi case also produces an extra 30.9 MW of generation compared to the UK CAER Process + MEA case and total 60.9 MW more than DOE Case 10. LCOE ($/MWh) values are $172.08/MWh for the MEA option and $157.65/MWh for the Hitachi H3-1 solvent cases considered in comparison to $189.59/MWh in January 2012 dollar for the Reference Case 10. The UK CAER CCS process with MEA case lowers energy consumption for CO2 capture to 1340 Btu/lb-CO2 captured as compared to 1540 Btu/lb-CO2 in the Reference Case 10. The UK CAER CCS process with H3-1 case further lowers energy consumption for CO2 capture to 973 Btu/lb-CO2 captured, for an advantage of 36.8% less energy consumption than Case 10. The study also shows 38.1% less heat rejection associated with the carbon capture system from 3398 MBtu/hr (Case 10) to 2104 MBtu/hr for the UK CAER + MEA system. Heat rejection is reduced to 2464 MBtu/hr in the UK CAER + H3-1 case, for a 27.5 % decrease compared to Case 10. Modeling outputs show that in the UK CAER process, the cooling water that is 2-5°C cooler than conventional cooling tower water can be achieved for ambient conditions common to the midwest and other regions. The results from the techno-economic assessment show that the proposed technology can be investigated further as a viable alternative to conventional CO2 capture technology. The evaluation also shows the effect of the critical parameters on the LCOE, with the main variables being the approach temperature and CO2 partial pressure increase at the flue gas inlet. A summary of the key advantages of the UK CAER Process + H3-1 case for LCOE and other economic factors compared to the DOE Case 10 is as follows: • A lower variable operating cost by $1.56/MWh ($1.08MWh less than the UK CAER Process + MEA Case), a 11.7% reduction compared to the DOE Case 10 • A lower COE by $25.32MWh ($13.94/MWh lower than the UK CAER Process + MEA Case), a 16.9% reduction compared to the DOE Case 10 • A lower LCOE by $31.94/MWh ($17.51/MWh lower than the UK CAER Process + MEA Case), a 16.9% reduction compared to the DOE Case 10 • A lower cost of CO2 captured by $18.65/tonne CO2 ($9.44/tonne CO2 lower than the UK CAER Process + MEA Case), a 30.4% reduction compared to the DOE Case 10 • A lower cost of CO2 avoided by $34.95/tonne CO2 ($18.53 tonne CO2 lower than the UK CAER Process + MEA Case), a 38.7% reduction compared to the DOE Case 10

Bhown, Abhoyjit S.↗

Renewable Thermal Hybridization Framework for Industrial Process Heat Applications

Renewable thermal energy systems (RTES) could be hybridized with different renewable options (e.g., flat plate collectors (FPCs) with parabolic collectors), or combined with existing heat supplies (e.g., fossil fuels), to give options for targeted solar IPH applications, industrial decarbonization and the reduction of fuel consumption. Buildings and industrial thermal energy applications require different temperature ranges, quantities, and rates of thermal energy, and as such require flexible, cost competitive solutions, able to provide heat over various temperature ranges. Hybrid solutions and thermal energy storage (TES) will be important for the dispatch of heat at optimal times needed by the demand side of the buildings and industrial applications. A variety of tools and platforms, such as the System Advisor Model (SAM), can provide hourly thermal yield simulations from single renewable energy (RE) technology options, including FPCs or CSP for solar IPH. We have investigated a variety of approaches to hybrid system modeling for RTES at different temperatures or combinations of technologies and developed an initial framework. The hybridization framework starts by creating a heat stream and raising the temperature of that heat stream by various combinations of RE technologies and other sources such as fossil fuels, new fuels or electric heating in multiple stages, with options for TES and/or waste heat recovery (WHR).

43 PARTICLE ACCELERATORS↗

EERC Final Topical Report – Findings on Subtask 3.2 – Produced Water Management Through Geologic Homogenization, Conditions, and Reuse

The Energy & Environmental Research Center (EERC) was awarded a contract by the North Dakota Industrial Commission (NDIC) Oil and Gas Research Program (NDIC No. G-051-101) to conduct a study on the recycling of water used in oil and gas operations, also known as produced water, from oil- and gas-producing regions of North Dakota as directed by Section 19 of North Dakota House Bill 1014. This final report provides a compilation of results of the study, which include regulatory, scientific, technological, and feasibility methods and considerations associated with North Dakota produced water management. The report provides a synopsis of this project’s previously submitted produced water assessment report entitled “Produced Water Management and Recycling Options in North Dakota” (Energy & Environmental Research Center, 2020), with updated values provided as appropriate. The report provides the results from the investigation of a novel produced water management strategy, referred to as geologic homogenization, conditioning, and reuse (GHCR), which aims to use a subsurface geologic formation as a natural medium for managing produced water recycling and reuse. Water management is a significant technical and economic challenge for sustainable oil and gas production, and water volumes are intrinsically linked to oil production volumes. North Dakota oil production rose to over 1.5 million barrels (MMbbl)/day in 2019, and despite a downturn in oil price in early 2020, North Dakota oil production has recovered to 1.1 MMbbl/day as of August 2021. Bakken petroleum system development between 2008 and 2020 has resulted in a nearly fourfold increase in produced water volumes to 642 MMbbl/yr in 2020 after peaking at 740 MMbbl/yr in 2019 and a fivefold increase in saltwater disposal (SWD) volumes to 565 MMbbl/yr in 2020 after a peak of 682 MMbbl/yr in 2019. Produced water and SWD volumes are forecasted to double by 2030. SWD is the primary method of produced water management used in North Dakota, with approximately 95% of the SWD volume occurring through subsurface injection into sandstones of the Dakota Group (Dakota). Localized pressurization of the Dakota resulting from SWD and projected increases in produced water volumes could impact the economics of North Dakota oil production. As a result, there is an emerging need to pursue alternative produced water management approaches, including recycling and reuse. While produced water recycling is not yet widespread, commercial operators are making strides in overcoming the technical challenges of using high salinity produced water in completion operations (Marathon Oil, 2020). As water management continues to be a key focal point in companies’ environmental, social, and governance (ESG) initiatives, focus on water management, including recycling, will likely continue to increase. Laboratory column testing, field sample collection, geologic modeling and numerical simulation, and techno-economic analysis all indicate that GHCR could feasibly be implemented as a potential water management option. Laboratory column testing and field sample collection indicate that the Inyan Kara sandstone and native formation fluid are capable of homogenizing with the Bakken produced water to a point where the fluid composition appears to stabilize. Extracting that stabilized fluid could be considered homogeneous and capable of providing individual batches of hydraulic fracturing fluid. Numerical simulation results indicate that extraction of fluids from the Inyan Kara in a GHCR implementation scenario is capable of reducing formation pressure, which would help ease localized pressurization of the Inyan Kara and extend the available capacity for nearby existing SWD wells. Economic analysis indicates that there are scenarios where GHCR implementation can be a competitive or even lower-cost option than a conventional water management approach. Site-specific conditions will dictate the economic potential of GHCR, but potentially attractive sites for GHCR implementation will be those that are located above a pressurized zone of the Inyan Kara, need six or more Bakken infill wells, and face high costs for conventional SWD and/or freshwater. Based on the regulatory review, drilling into the Inyan Kara for SWD and to harness as a source water for industrial use have precedent in North Dakota, and a workable regulatory solution for GHCR seems likely. However, restrictions in the state regarding surface storage and transport of produced fluids may limit some activities, which will affect how GHCR could ultimately be implemented. In summary, this study reveals pursuing GHCR can be a viable approach to water management in North Dakota. The GHCR concept addresses some of the challenges that hinder the more traditional approaches to recycling in the industry. Furthermore, an assessment of the current landscape of water management within the state reveals the ongoing trend of increasing volumes of produced water and SWD. Projections reveal that the volumes of produced water that need to be managed are expected to double over the next decade (Energy & Environmental Research Center, 2020). With the continued development of the Bakken and continuing driving factors related to ESG initiatives, implementing a practice such as GHCR is a feasible approach to adding recycling of produced water to industry within the state. This subtask was cofunded through the EERC–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FE0024233. Nonfederal funding was provided by the North Dakota Industrial Commission Oil and Gas Research Program. References Energy & Environmental Research Center, 2020, Produced water management and recycling options in North Dakota: Final Report for North Dakota Legislative Management Energy Development and Transmission Committee and North Dakota Industrial Commission. Marathon Oil, 2020, Sustainability report: https://cdn.sanity.io/files/ghcnw9z2/website/ 91744eb6ef8fbe59505a911c6b8d2e8dd9a537fa.pdf?dl (accessed November 2021).

02 PETROLEUM↗

Risk-Informed Approach for Regulatory Approval of Microreactor Transport

Pacific Northwest National Laboratory (PNNL) is addressing the challenges associated with safe transport of microreactors including the development and evaluation of regulatory options. PNNL developed a risk-informed regulatory framework for the licensing of the transportation of microreactors in which irradiated nuclear fuel is part microreactor transportation package. The framework lays out a viable regulatory pathway, including decision points for regulatory options and the supporting technical evaluations for those options in phases from near to long term. A microreactor and its contents will likely not be able to meet all the federal regulatory requirements as a Type B or fissile material transportation package under 10 CFR Part 71 (“Packaging and Transportation of Radioactive Material”). However, the regulatory framework developed by PNNL lays out a viable risk-informed licensing options that are safe and feasible. Risk assessment such as probabilistic risk assessment (PRA) can be used to show comparable safety to that provided by a Type B or fissile material package for surface transport. The framework includes guidance on applicable regulations and discusses historical precedence in using risk information for transportation licensing. The framework includes guidance for performing a microreactor transportation PRA, use and development of risk evaluation criteria, and factors such of defense-in-depth and safety margin concepts. Key advantages of using the approach are (1) increasing the likelihood of successfully obtaining regulatory transportation package approval, (2) informing the design on the relative risk significance of microreactor containment and shielding, and (3) informing the need for transportation compensatory measures. This paper focuses on two primary elements of the framework which are development of a transportation PRA for microreactor packages and development of the risk acceptance guidelines to assess the results of the PRA for regulatory decision-making.

microreactor, micro nuclear power plant, MNPP, ris↗