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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Processing study of a high temperature adhesive

An adhesive-bonding process cycle study was performed for a polyimidesulphone. The high molecular weight, linear aromatic system possesses properties which make it attractive as a processable, low-cost material for elevated temperature applications. The results of a study to better understand the parameters that affect the adhesive properties of the polymer for titanium alloy adherends are presented. These include the tape preparation, the use of a primer and press and simulated autoclave processing conditions. The polymer was characterized using Fourier transform infrared spectroscopy, glass transition temperature determination, flow measurements, and weight loss measurements. The lap shear strength of the adhesive was used to evaluate the effects of the bonding process variations.

Progar, D. J.↗
NASA NTRS1985

Boron cosmochemistry

The abundances of boron, silicon, sulfur, and sodium were determined in 50 pieces of 28 chondritic meteorites. Boron abundances are found to define compositionally distinct domains within type C2M carbonaceous chondrites and petrologic type 5 and 6 ordinary chondrites. These domains may manifest the redistribution of boron within meteorites in response to low-temperature hydrous processes in C2M chondrites and high-temperature metamorphic processes in high petrologic type ordinary chondrites. Assuming that the redistribution was limited to regions comparable in size to the mass of the available meteorites, the boron abundance in unaltered material is determined. The depletion factors for boron in chondritic subgroups correlate with those for sulfur in the same subgroups. This correlation indicates that boron, like sulfur, is a moderately volatile element with a condensation temperature between 400 and 900 K.

Curtis, D. B.↗
NASA NTRS2013

High Temperature Boost (HTB) Power Processing Unit (PPU) Formulation Study

This technical memorandum is to summarize the Formulation Study conducted during fiscal year 2012 on the High Temperature Boost (HTB) Power Processing Unit (PPU). The effort is authorized and supported by the Game Changing Technology Division, NASA Office of the Chief Technologist. NASA center participation during the formulation includes LaRC, KSC and JPL. The Formulation Study continues into fiscal year 2013. The formulation study has focused on the power processing unit. The team has proposed a modular, power scalable, and new technology enabled High Temperature Boost (HTB) PPU, which has 5-10X improvement in PPU specific power/mass and over 30% in-space solar electric system mass saving.

Chen, Yuan↗
NASA NTRS1997

Factors Influencing Residual Stresses in Yttria Stabilized Zirconia Thermal Barrier Coatings

To improve gas turbine and diesel engine performance using thermal barrier coatings (TBC's) requires an understanding of the factors that influence the in-service behavior of thermal barrier coatings. One of the many factors related to coating performance is the state of stress in the coating. The total stress state is composed of the stresses due to the in-service loading history and the residual stresses. Residual stresses have been shown to affect TBC life, the bond strength of thermal spray coatings, and the fatigue life of tungsten carbide coatings. Residual stresses are first introduced in TBC's by the spraying process due to elevated temperatures during processing and the difference in coefficients of thermal expansion of the top coat, bond coat, and substrate. Later, the residual stresses can be changed by the in-service temperature history due to a number of time and temperature dependent mechanisms, such as oxidation, creep, and sintering. Silica content has also been shown to affect sintering and the cyclic life of thermal barrier coatings. Thus, it is important to understand how the spraying process, the in-service thermal cycles, and the silica content can create and alter residual stresses in thermal barrier coatings.

McGrann, Roy T. R.↗
NASA NTRS1997

Computational Modeling in Structural Materials Processing

High temperature materials such as silicon carbide, a variety of nitrides, and ceramic matrix composites find use in aerospace, automotive, machine tool industries and in high speed civil transport applications. Chemical vapor deposition (CVD) is widely used in processing such structural materials. Variations of CVD include deposition on substrates, coating of fibers, inside cavities and on complex objects, and infiltration within preforms called chemical vapor infiltration (CVI). Our current knowledge of the process mechanisms, ability to optimize processes, and scale-up for large scale manufacturing is limited. In this regard, computational modeling of the processes is valuable since a validated model can be used as a design tool. The effort is similar to traditional chemically reacting flow modeling with emphasis on multicomponent diffusion, thermal diffusion, large sets of homogeneous reactions, and surface chemistry. In the case of CVI, models for pore infiltration are needed. In the present talk, examples of SiC nitride, and Boron deposition from the author's past work will be used to illustrate the utility of computational process modeling.

Meyyappan, Meyya↗
NASA NTRS1987

Addition polymers from 1,4,5,8-tetrahydro-1,4;5,8-diepoxyanthracene and Bis-dienes: Processable resins for high temperature application

1,4,5,8-Tetrahydro-1,4;5,8-diepoxyanthracene reacts with various anthracene endcapped polyimide oligomers to form Diels-Alder cycloaddition copolymers. The polymers are soluble in common organic solvents, and have molecular weights of approximately 21,000 to 32,000. Interestingly, these resins appear to be more stable in air then in nitrogen. This is shown to be due to a unique dehydration (loss of water ranges from 2 to 5 percent) at temperatures of 390 to 400 C to give thermo-oxidatively stable pentiptycene units along the polymer backbone. Because of their high softening points and good thermo-oxidative stability, the polymers have potential as processible, matrix resins for high temperature composite applications.

Meador, Mary Ann B.↗
NASA NTRS1984

The B2 aluminides as alternative materials

The potential of the B2 aluminides as structural material alternatives for the strategic element containing superalloys currently used in gas turbine engines is being explored with emphasis on the equiatomic Fe and Ni aluminides. Although Co is a strategic material, the equiatomic Co aluminide is also being studied to gain a more complete understanding of these fourth period intermetallics. Research focuses on initial processing techniques such as ingot melting, power metallurgy, and rapid solidification with and without additional thermomechanical processing; high temperature deformation - primarily compressive creep; compositional effects within the binary B2 aluminides; third-element alloying addition effects on high temperature strength and oxidation resistance, and near room temperature ductility as influenced by processing, alloying, and grain size. Various programs now underway are reviewed and some highlights of research results are presented.

Stephens, J. R.↗
NASA NTRS1985

The B2 aluminides as alternative materials

The potential of the B2 aluminides as structural material alternatives for the strategic element containing superalloys currently used in gas turbine engines is being explored with emphasis on the equiatomic Fe and Ni aluminides. Although Co is a strategic material, the equiatomic Co aluminide is also being studied to gain a more complete understanding of these fourth period intermetallics. Research focuses on initial processing techniques such as ingot melting, power metallurgy, and rapid solidification with and without additional thermomechanical processing; high temperature deformation primarily compressive creep; compositional effects within the binary B2 aluminides; third-element alloying addition effects on high temperature strength and oxidation resistance, and near room temperature ductility as influenced by processing, alloying, and grain size. Various programs now underway are reviewed and some highlights of research results are presented.

Stephens, J. R.↗
NASA NTRS1984

Containerless-Processing Module

High-temperature, containerless-processing module positions and melts molten glass or metal without contact with container wall. Fluid masses manipulated, stirred, and controlled by acoustic forces. Module provides photographic monitoring and transfer of solidified specimens to storage bins.

Wang, T. G.↗
NASA NTRS1985

Study of photon emission by electron capture during solar nuclei acceleration, 1: Temperature-dependent cross section for charge changing processes

The study of charge changing cross sections of fast ions colliding with matter provides the fundamental basis for the analysis of the charge states produced in such interactions. Given the high degree of complexity of the phenomena, there is no theoretical treatment able to give a comprehensive description. In fact, the involved processes are very dependent on the basic parameters of the projectile, such as velocity charge state, and atomic number, and on the target parameters, the physical state (molecular, atomic or ionized matter) and density. The target velocity, may have also incidence on the process, through the temperature of the traversed medium. In addition, multiple electron transfer in single collisions intrincates more the phenomena. Though, in simplified cases, such as protons moving through atomic hydrogen, considerable agreement has been obtained between theory and experiments However, in general the available theoretical approaches have only limited validity in restricted regions of the basic parameters. Since most measurements of charge changing cross sections are performed in atomic matter at ambient temperature, models are commonly based on the assumption of targets at rest, however at Astrophysical scales, temperature displays a wide range in atomic and ionized matter. Therefore, due to the lack of experimental data , an attempt is made here to quantify temperature dependent cross sections on basis to somewhat arbitrary, but physically reasonable assumptions.

Perez-Peraza, J.↗
NASA NTRS1984

Molecular processes in a high temperature shock layer

Models of the shock layer encountered by an Aeroassisted Orbital Transfer Vehicle require as input accurate cross sections and rate constants for the atomic and molecular processes that characterize the shock radiation. From the estimated atomic and molecular densities in the shock layer and the expected residence time of 1 m/s, it can be expected that electron-ion collision processes will be important in the shock model. Electron capture by molecular ions followed by dissociation, e.g., O2(+) + e(-) yields 0 + 0, can be expected to be of major importance since these processes are known to have high rates (e.g., 10 to the -7th power cu/cm/sec) at room temperature. However, there have been no experimental measurements of dissociative recombination (DR) at temperatures ( 12000K) that are expected to characterize the shock layer. Indeed, even at room temperature, it is often difficult to perform experiments that determine the dependence of the translational energy and quantum yields of the product atoms on the electronic and vibrational state of the reactant molecular ions. Presented are ab initio quantum chemical studies of DR for molecular ions that are likely to be important in the atmospheric shock layer.

Guberman, S. L.↗
NASA NTRS2022

Processing Tomato Production Is Expected to Decrease By 2050 Due to the Projected Increase in Temperature

The global processing tomato production is concentrated in a small number of regions where climate change will have a significant impact on the future supply. Process-based tomato models project that the production in the three main producing countries (the United States, Italy, and China, representing 65% of global production) will decrease 6% by 2050, compared to the baseline period of 1980-2009. The predicted reduction in processing tomato production is due to a simulated increase in air temperature. Under an ensemble of projected climate scenarios, California and Italy might not be able to sustain the current levels of processing tomato production due to water resources constraints. Cooler producing regions, such as China and the northern parts of California, stand to improve their competitive advantage. The projected environmental changes indicate that the main growing regions of processing tomatoes might change in the coming decades.

Tomato production↗
NASA NTRS2005

Nickel Base Superalloy Turbine Disk

A low solvus, high refractory alloy having unusually versatile processing mechanical property capabilities for advanced disks and rotors in gas turbine engines. The nickel base superalloy has a composition consisting essentially of, in weight percent, 3.0-4.0 N, 0.02-0.04 B, 0.02-0.05 C, 12.0-14.0 Cr, 19.0-22.0 Co, 2.0-3.5 Mo, greater than 1.0 to 2.1 Nb, 1.3 to 2.1 Ta,3.04.OTi,4.1 to 5.0 W, 0.03-0.06 Zr, and balance essentially Ni and incidental impurities. The superalloy combines ease of processing with high temperature capabilities to be suitable for use in various turbine engine disk, impeller, and shaft applications. The Co and Cr levels of the superalloy can provide low solvus temperature for high processing versatility. The W, Mo, Ta, and Nb refractory element levels of the superalloy can provide sustained strength, creep, and dwell crack growth resistance at high temperatures.

Gabb, Timothy P.↗
NASA NTRS1988

Non-contact temperature measurement requirements for electronic materials processing

The requirements for non-contact temperature measurement capabilities for electronic materials processing in space are assessed. Non-contact methods are probably incapable of sufficient accuracy for the actual absolute measurement of temperatures in most such applications but would be useful for imaging in some applications.

Lehoczky, S. L.↗
NASA NTRS1975

Formation mechanism of a silicon carbide coating for a reinforced carbon-carbon composite

Results are presented for a study to determine the mechanisms involved in a high-temperature pack cementation process which provides a silicon carbide coating on a carbon-carbon composite. The process and materials used are physically and chemically analyzed. Possible reactions are evaluated using the results of these analytical data. The coating is believed to develop in two stages. The first is a liquid controlled phase process in which silicon carbide is formed due to reactions between molten silicon metal and the carbon. The second stage is a vapor transport controlled reaction in which silicon vapors react with the carbon. There is very little volume change associated with the coating process. The original thickness changes by less than 0.7%. This indicates that the coating process is one of reactive penetration. The coating thickness can be increased or decreased by varying the furnace cycle process time and/or temperature to provide a wide range of coating thicknesses.

Rogers, D. C.↗
NASA NTRS1984

Two-Layer Glass Thermal-Control Coating

Optical properties endure high temperatures. Coating has outer scattering layer and inner high emissivity layer. Absorptivity/emissivity ratio less than 0.4. Coating withstands repeated exposure to temperatures in excess of 2,000 degrees F. Coating has industrial uses in solar-energy equipment, high temperature chemical processing systems, laboratory equipment and high temperature instrumentation.

Stewart, D. A.↗