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DOE OSTI2024

Bounding Pressure and Flammability Evaluations of Aluminum-Clad Spent Nuclear Fuel Department of Energy Standard Canisters

This paper presents bounding pressure and flammability evaluations for DOE Standard Canister loaded with DOE-managed aluminum-clad spent nuclear fuel (ASNF). The objective of these evaluations is to gain confidence in the safety and feasibility of possible loading configurations for extended (>50 years) periods of dry storage, with particular focus on the dry storage canister pressures and potential for formation of a flammable atmosphere. The primary concern about the extended dry storage of ASNF is radiolytic gas generation. The aluminum cladding of these materials tends to corrode, and these corrosion products—typically aluminum oxides, such as boehmite, bayerite, or gibbsite—could carry water. This makes ASNF dry storage canisters difficult to dry. The gamma radiation field in dry storage environments could cause a radiolytic breakdown of residual water, forming chemical species such as molecular hydrogen (H2). The release of these species could increase the canister pressure and lead to the generation of a flammable canister atmosphere. The bounding evaluations presented within this study surmise conservative, but credible, conditions and processes. This includes the assumption of a full breakdown of a large quantity of free, physisorbed, and chemisorbed water (bound in a trihydrate, i.e., Al2O3 • 3H2O, layer). The considered dry storage configurations include a ~3 m (10 ft) long, ~46 cm (18 in) diameter (10 x 18) DOE Standard Canister loaded with 32 Advanced Test Reactor (ATR) ASNF elements, and a ~3 m (10 ft) long, ~61 cm (24 in) (10 x 24) diameter DOE Standard Canister loaded with 40 ATR ASNF elements. While the results of this study indicate the possibility of atmospheric hydrogen concentrations above the lower flammability limit, insufficient concentrations of oxygen will prevent the formation of flammable atmospheres. The maximum credible pressures remain well within the structural limits of the DOE Standard Canister.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2021

Institutional and Policy Landscape for Solar-Plus-Storage Deployment by Electric Cooperatives

As co-location with battery storage has become a significant solar project-design trend across the United States, policies at all levels have started to adjust. Generally, these policies address battery storage development in major, urban markets, served by large investor-owned utilities (IOUs). Yet all kinds of utilities nationwide are seeking ways to tap into the fast-growing battery storage market, and they are all stakeholders in the federal, state, and local policies that impact the storage market's development. The electric cooperative sector, which includes some 830 distribution utilities and 63 generating and transmission (G&T) utilities across a mostly rural landscape, is no exception. It is impacted by federal, state, and local government policy requirements and incentives, as well as by policies that are controlled by the sector's own institutions. The objective of this paper is to identify and discuss the various policy and institutional factors that are relevant to the electric cooperative sector, and especially to local, distribution-level electric cooperatives (co-ops) that may be interested in procuring energy storage. Given this, the paper is largely written from the local co-op perspective. It also may be useful to wholesale G&T cooperatives. Other parties that may find the paper useful include storage developers, who are often unfamiliar with co-ops; local and state policymakers addressing policy options for this sector, and local renewable or storage stakeholders, who wish to understand the policy landscape affecting their local utility. Although co-op energy storage programs may tap customer-side batteries, this examination is focused on utility-side "front of the meter" projects and the policy issues they raise.

14 SOLAR ENERGY↗

DOE OSTI2023

Efficient Hydraulic-to-electric Energy Conversion for PCM-based Ocean Thermal Gradient Energy System to Power Uncrewed Underwater Vehicles

Since the 2000, there have been numerous investigations into electrical energy storage types that use ocean thermal-to-electricity conversion techniques. Field tests have demonstrated that this technology is feasible for UUVs with long-term missions of over 3,000 km per deployment. Nonetheless, the energy generated by this method is not sufficient to meet the energy requirements of Unscrewed Underwater Vehicles (UUVs). The objective of this study is to design a highly effective ocean thermal gradient energy system to support long-term missions of a UUV. To enhance the performance of the thermal gradient energy system, we have developed a hybrid type (buoyancy regulation and electrical storage). Phase Change Material (PCM)-based energy harvesting system to facilitate efficient UUV operations. A prototype of the hydraulic-to-electric conversion system was implemented, and experimental findings indicate that the hybrid system successfully delivers hydraulic energy for buoyancy change and improved efficiency of hydraulic-to-electric energy conversion, demonstrating its potential as a promising technology for supporting long-term UUV missions.

Deng, Zhiqun↗

DOE OSTI2021

Technology Evaluation of the Yotta SolarLEAF: A Panel-Based Thermally Managed Battery Module

In 2019, the United States installed 13.3 gigawatts of solar energy production capacity. This demand for solar will continually increase as the phasing out of fossil fuels continue. As the demand for solar energy grows, so does the demand to store this generated energy. It is projected that by 2035 the global demand for stationary energy storage will reach the terawatt scale. So, scalable solutions with suitable thermal management systems are required to meet future demand. Yotta Solar has developed an ESS system, the Yotta LEAF, that provides solar energy storage without increasing the footprint of solar arrays. This is particularly useful in applications with limited space (e.g., building roof) and where large scale batteries require strong requirements for fire suppression systems. As part of the Wells Fargo Innovation Incubator (IN2), the National Renewable Energy Laboratory (NREL) has conducted a third-party technology validation of Yotta's alpha prototype. The report includes the objectives, technology description, methodology, and results from experiments conducted at the Thermal Transfer Facility (TTF) at NREL.

14 SOLAR ENERGY↗

DOE OSTI2020

Spatiotemporal variations of albedo in managed agricultural landscapes: inferences to global warming impacts (GWI)

Albedo can be used to quantify ecosystem and landscape contributions to local and global climate. Such contributions are conventionally expressed as radiative forcing (RF) and global warming impact (GWI). We contextualize our results within landscape carbon production and storage to highlight the importance of changes in albedo for landscape GWI from multiple causes, including net ecosystem production (NEP) and greenhouse gas (GHG) emissions. Objective To examine the spatiotemporal changes in albedo (Δα) in contrasting managed landscapes through calculations of albedo-induced RF (RF Δα ) and GWI (GWI Δα ) under different climatic conditions. Methods We selected five contrasting landscapes within the Kalamazoo River watershed in southern Michigan USA as proof of concept. The daily MCD43A3 MODIS (V006) product was used to analyze the inter- and intra-annual variations of growing season albedo. In addition, the variations of RF Δα and GWI Δα were computed based on landscape composition and climate. Results The RF Δα (-5.6 W m -2 ) and GWI Δα (-1.3 CO 2eq ha -1 year -1 ) were high in forest-dominated landscapes, indicating cooling effects and CO 2eq mitigation impacts similar to crops. The CO 2eq mitigation of cropland-dominated landscapes was on average 52% stronger than forest-dominated landscapes. In the landscape with the highest proportion of forest, under dry and wet conditions CO 2eq mitigation was reduced by up to 24% and ~ 30%, respectively; in one cropland-dominated landscape wet conditions reduced CO 2eq mitigation by 23%. Conclusions Findings demonstrate that quantifying spatiotemporal changes in albedo in managed landscapes and under different climatic conditions is essential to understand how landscape modification affects RF Δα and GWI Δα and thereby contributes to ecosystem-level GWI.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

Evaluating methods to reduce duration of near-threshold fatigue crack growth rate measurements for low-alloy steels in hydrogen gas

Measurement of the near-threshold fatigue crack growth rate (da/dN) vs. stress-intensity factor range (∆K) relationship in hydrogen gas is essential for maximizing the calculated design fatigue life of high-pressure hydrogen storage vessels. However, such measurements are rarely performed, since the low cyclic loading frequencies applied in standard practice lead to prohibitively protracted test durations. The objective of this study was to demonstrate two means for reducing test durations when measuring near-threshold da/dN vs. ΔK relationships under decreasing ΔK for low-alloy pressure vessel steels in hydrogen gas: 1) imposing steeper K-gradients relative to the recommended limits in standards such as ASTM E647, and 2) increasing cyclic loading frequency relative to typical values applied during fatigue crack growth testing of low-alloy steels in hydrogen gas. Recognizing that steeper K-gradients could amplify loading-history effects, test methods employing this approach were designed to mitigate such effects by either maintaining constant K max or gradually increasing the K-gradient as the threshold was approached. Although the varying K-gradient method was vulnerable to loading-history effects in the form of plasticity-induced crack closure, particularly at lower stress ratio (R) and higher starting K max values, these effects could be compensated by applying the adjusted compliance ratio (ACR) method. Here, it was demonstrated that steeper K-gradients in concert with increased cyclic loading frequency reduced the duration of near-threshold fatigue crack growth tests in hydrogen gas by more than 99% relative to standard practices.

Fatigue threshold↗

DOE OSTI2025

Analog Signal Multiplexing System for the Iota Proton Injector

The Fermilab Accelerator Science and Technology (FAST) Facility at FNAL is a dedicated research and development center focused on advancing particle accelerator technologies for future applications worldwide. Currently, a key objective of FAST Operations is to commission the 2.5 MeV IOTA Proton Injector (IPI) and enable proton injection into the Integrable Optics Test Accelerator (IOTA) storage ring. The low and medium-energy sections of the IPI include four frame-style dipole trims and two multi-function correctors with independently controlled coils, requiring readout of 32 analog channels for current and voltage monitoring in total. To reduce cost and optimize rack space within the PLC-based control system, a 32-to-4 analog signal multiplexing system was designed and implemented. This system enables real-time readback of excitation parameters from all magnetic correctors. This paper presents the design, construction, implementation, and performance of the multiplexing system.

MacLean, Daniel R. [Fermilab] (ORCID:0000000210103↗

DOE OSTI2023

Onsite Energy Techno-Economic Analysis Using REopt

Since 2019, the National Renewable Energy Laboratory (NREL) has collaborated with IEDO's Combined Heat and Power (CHP) Deployment Program and the CHP Technical Assistance Partnerships (TAPs) to expand the capabilities of NREL's publicly available REopt® tool for techno-economic analysis of on-site energy. As a result, capabilities to analyze heating and cooling loads and serve those loads with CHP were added to the REopt tool in 2021. Currently, NREL is using REopt to evaluate the economics and feasibility of deploying distributed energy resources at sites of 3-5 manufacturers. The analysis is based on location, site-specific load data, customized utility bill analysis, and other criteria such as resilience needs and decarbonization targets. The objectives of the current effort are to (1) assist manufacturers with analyzing on-site energy options, including CHP, solar photovoltaics (PV), wind, and battery storage, (2) validate the capabilities and use of REopt to provide technical assistance to manufacturers, and (3) publish case studies showcasing the engagement, key takeaways, and lessons learned. Future work is expected to include additional REopt capabilities for evaluating other technologies to reduce scope 1 emissions, such as electrifying process heating loads, using carbon-free fuels, and other clean heat strategies.

ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2024

Real-time hybrid controls of energy storage and load shedding for integrated power and energy systems of ships

This paper presents an original energy management methodology to enhance the resilience of ship power systems. The integration of various energy storage systems (ESS), including battery energy storage systems (BESS) and super-capacitor energy storage systems (SCESS), in modern ship power systems poses challenges in designing an efficient energy management system (EMS). The EMS proposed in this paper aims to achieve multiple objectives. The primary objective is to minimize shed loads, while the secondary objective is to effectively manage different types of ESS. Considering the diverse ramp-rate characteristics of generators, SCESS, and BESS, the proposed EMS exploits these differences to determine an optimal long-term schedule for minimizing shed loads. Furthermore, the proposed EMS balances the state-of-charge (SoC) of ESS and prioritizes the SCESS’s SoC levels to ensure the efficient operation of BESS and SCESS. For better computational efficiency, we introduce the receding horizon optimization method, enabling real-time EMS implementation. Further, a comparison with the fixed horizon optimization (FHO) validates its effectiveness. Simulation studies and results demonstrate that the proposed EMS efficiently manages generators, BESS, and SCESS, ensuring system resilience under generation shortages. Additionally, the proposed methodology significantly reduces the computational burden compared to the FHO technique while maintaining acceptable resilience performance.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2021

TBAA20: Task-Based Algorithms and Applications

The new challenges posed by Exascale system architectures have resulted in difficulty achieving a desired scalability using traditional distributed memory runtimes. Task-based programming models show promise in addressing these challenges, providing application developers with a productive and performant approach to programming on next generation systems. Empirical studies show that task-based models can overcome load balancing issues that are inherent to traditional distributed memory runtimes, and that task-based runtimes perform comparably to those systems when balanced. This panel is designed to explore the advantages of task-based programming models on modern and future HPC systems from an industry, university, and national lab perspective. It aims at gathering application experts and proponents of these models to present concrete and practical examples of using task-based runtimes to overcome the challenges posed by Exascale system architectures. This report describes the objectives, activities, and outcomes of the panel TBAA: Task-Based Algorithms and Applications which was held at the International Conference for High Performance Computing, Networking, Storage, and Analysis (SC 20) on November 18, 2020.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2025

Fossil Energy in the Hydrogen Economy – A Carbon-Water-Energy Nexus Adaptive Evaluation Platform

This project develops tools to evaluate fossil energy within the hydrogen economy. In particular, the project seeks to explore the Carbon-Water-Energy Nexus and develop adaptive evaluation tools. The primary goal of this project was to evaluate fossil-based hydrogen production methods with an emphasis on their sustainability, particularly with respect to carbon emissions and water use. The overall technical objectives that guided this evaluation consisted of 1) technology assessment, which sought to establish a comprehensive baseline of existing and emerging technologies for the generation, transportation, storage, and end use of hydrogen derived from fossil fuels, 2) carbon footprint analysis through quantification and analysis of carbon emissions associated with these hydrogen technologies, and identification of novel strategies and technologies that can effectively mitigate the carbon footprint, 3) water intensity assessment by evaluating the water needs (water-energy nexus) associated with different fossil fuel-based hydrogen technologies and proposing strategies to reduce water use, thus ensuring sustainable resource management, and 4) review of regulatory, policy and economic trends were examined to provide an overview of the factors influencing the adoption and integration of fossil fuel-derived hydrogen technologies into current energy markets. Beyond the technical outcomes, this project contributed to 5) education and workforce development through targeted training and educational opportunities for engineering students, preparing the next generation of professionals with technical, economic, and regulatory expertise in the hydrogen economy. Ultimately, this effort was intended to train the future workforce to provide useful insights to policymakers, industry stakeholders, and the broader energy community to facilitate informed decisions and responsible development within the hydrogen economy.

08 HYDROGEN↗

DOE OSTI2023

A Ceph S3 Object Data Store for HEP

We present a novel data format design that obviates the need for data tiers by storing individual event data products in column objects. The objects are stored and retrieved through Ceph S3 technology, with a layout designed to minimize metadata volume and maximize data processing parallelism. Performance benchmarks of data storage and retrieval are presented.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2023

Grid-Scale Electricity Storage at Lowest Possible Cost Enabled by Pumped Heat Electricity Storage (Final Report)

Grid-scale energy storage technologies that can provide greater than 10 hours of electricity at full power address a critical need for full penetration of renewables on electricity grids worldwide, minimize renewable curtailment, and maximize grid security and reliability. Pumped Heat Energy Storage (PHES) systems can store energy thermally in any location at the low costs necessary for displacing fossil fuels, reducing foreign fuel imports, and reducing emissions to maintain the energy security of the United States. The award allowed Southwest Research Institute® (SwRI®) and Malta, Inc. (Malta) to advance the PHES concept to a proof-of-concept demonstration for a kW-scale system. The project focused on system operation and integration. The main project objectives were: 1. Address first implementation challenges 2. Explore system control strategies and operation 3. Translate lessons learned to the full-scale system Through these objectives the project completes a first demonstration of this technology and reduces the technical risk associated with a full-scale system.

25 ENERGY STORAGE↗

DOE OSTI2020

Progress on TRANSCEND Theme 1: Integrated Waste Management - 20194

The management of radioactive waste includes mobilisation, processing, packaging, storage, transport and final disposal. Research in the Integrated Waste Management theme of TRANSCEND focuses on underpinning science and engineering in areas of relevance to hazard reduction and decommissioning and the objectives are to: (1) develop new materials for effluent decontamination; (2) demonstrate predictive modelling of sludge/slurry removal, underpinned by experimental data; (3) transform understanding of radiation-driven processes in nuclear waste sludges; and (4) provide underpinning studies to develop innovative processes and wasteform materials. This paper gives overviews of the 16 research projects that will be done over the next 3 years in this theme. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2023

A phased workflow to define permit‐ready locations for large volume CO 2 injection and storage

Abstract To‐date, only two UIC Class VI permits have been issued by the US Environmental Protection Agency. We illustrate a four‐phase workflow to first identify regional storage resources and then down‐select sites to yield permit‐ready locations that can accept and store large volumes of CO 2 . Specific permit requirements should guide objectives and define deliverables of respective workflow phases. In the first phase we used available regional data and screened structure and injection zones to locate resources that match CO 2 volumes planned to be captured. Available data were also used to assess presence and depth of usable groundwater, the key resource being protected via permitting. We then used advanced, closed‐form, analytical solutions (EASiTool) to estimate CO 2 injectivity into each hydrologically connected injection compartment. In the second phase we acquired and conditioned additional wireline logs and leased available seismic datasets. We interpreted the depositional systems from wireline well‐log character and mapped sandbody geometry to interpolate injection and confining‐zone distribution. Using available data, we mapped faults and locations of freshwater and overpressure (or other capacity‐limiting geologic parameters) in more detail. In the third phase, we used the augmented geologic data to develop a static model for the selected area, extracted the areas of highest interest, and generated and ran dynamic (flow) models. In a fourth phase, we reduced major uncertainties identified in earlier phases. Our case study indicates that to complete preparation of a permit application requires (1) improved lithologic characterization information (thicknesses and horizontal and vertical connectivity) and (2) better definition of poorly defined local faults. © 2023 The Authors. Greenhouse Gases: Science and Technology published by Society of Chemical Industry and John Wiley & Sons Ltd.

58 GEOSCIENCES↗

DOE OSTI2021

A hardware-in-the-loop approach for laboratory performance verification of flexible building equipment in a typical commercial building

The overall objective of the project is to develop datasets that measure the holistic load flexibility performance of a suite of commonly-used commercial building HVAC and thermal storage equipment using a hardware-in-the-loop test method. The development of the software side of the hardware-in-the-loop flexible load testbed is summarized in this paper.

Chen, Zhelun↗

DOE OSTI2024

Accelerated Energy Storage Deployment in RELAC Countries

"Renewables in Latin America and the Caribbean" or RELAC is a regional initiative across Latin America and the Caribbean (LAC) that was created at the end of 2019, within the framework of the United Nations Climate Action Summit, with the objective of reaching at least 70% of renewable energy installed capacity, and 80% of the region's total electricity generation from renewables by 2030. 16 countries are members (Barbados, Bolivia, Chile, Colombia, Costa Rica, Dominican Republic, Ecuador, El Salvador, Guatemala, Haiti, Honduras, Nicaragua, Panama, Paraguay, Peru, and Uruguay), and others are in discussions to join. RELAC provides these countries with support in addressing technical and financial needs to increase renewable energy penetration, matchmaking with financial resources to support capacity building needs and implementation of RE expansion plans, and knowledge exchange via peer-learning, and best practices in renewable energy integration to the electrical grid.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2021

Battery Performance, Thermal, and Life Modeling for Southern California Edison (Cooperative Research and Development Final Report)

The objective of this project is to develop battery performance models, thermal models and life models for SCE to use in simulation and analysis of grid services involving energy storage. NREL will fit the models to three separate chemistries using test data provided by SCE. The dataset for each chemistry will include electrical, thermal and aging response to different temperatures and cycling conditions, measured under a variety of cell-level and module-level experiments described in SCE test protocol documents. Once tuned to a test dataset, the battery system model software will provide predictions of battery energy and power loss, and thus cycle and calendar life, for any energy storage grid service power profile of interest to SCE. The automated battery life modeling and simulation tool can also be applied to any other grid battery systems as long as necessary input data is available to accelerate battery model development and battery lifetime analysis.

25 ENERGY STORAGE↗