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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

Field intercomparison of a novel optical sensor for formaldehyde quantification

A one-week in situ intercomparison campaign was completed on the Rice University campus for measuring HCHO using three different techniques, including a novel optical sensor based on difference frequency generation (DFG) operating at room temperature. Two chemical derivatization methods, 2,4-dinitrophenylhydrazine (DNPH) and o-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine (PFBHA), were deployed during the daylight hours for three- to four-hour time-integrated samples. A real-time optical sensor based on laser absorption spectroscopy was operated simultaneously, including nighttime hours. This tunable spectroscopic source based on difference frequency mixing of two fiber-amplified diode lasers in periodically poled LiNb03 (PPLN) was operated at 3.5315 micrometers (2831.64 cm 1) to access a strong HCHO ro-vibrational transition free of interferences from other species. The results showed a bias of -1.7 and -1.2 ppbv and a gross error of 2.6 and 1.5 ppbv for DNPH and PFBHA measurements, respectively, compared with DFG measurements. These results validate the DFG sensor for time-resolved measurements of HCHO in urban areas.

NASA Discipline Life Sciences Technologies↗

A Physically Based Algorithm for Non-Blackbody Correction of Cloud-Top Temperature and Application to Convection Study

Cloud-top temperature (CTT) is an important parameter for convective clouds and is usually different from the 11-micrometers brightness temperature due to non-blackbody effects. This paper presents an algorithm for estimating convective CTT by using simultaneous passive [Moderate Resolution Imaging Spectroradiometer (MODIS)] and active [CloudSat 1 Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO)] measurements of clouds to correct for the non-blackbody effect. To do this, a weighting function of the MODIS 11-micrometers band is explicitly calculated by feeding cloud hydrometer profiles from CloudSat and CALIPSO retrievals and temperature and humidity profiles based on ECMWF analyses into a radiation transfer model.Among 16 837 tropical deep convective clouds observed by CloudSat in 2008, the averaged effective emission level (EEL) of the 11-mm channel is located at optical depth; approximately 0.72, with a standard deviation of 0.3. The distance between the EEL and cloud-top height determined by CloudSat is shown to be related to a parameter called cloud-top fuzziness (CTF), defined as the vertical separation between 230 and 10 dBZ of CloudSat radar reflectivity. On the basis of these findings a relationship is then developed between the CTF and the difference between MODIS 11-micrometers brightness temperature and physical CTT, the latter being the non-blackbody correction of CTT. Correction of the non-blackbody effect of CTT is applied to analyze convective cloud-top buoyancy. With this correction, about 70% of the convective cores observed by CloudSat in the height range of 6-10 km have positive buoyancy near cloud top, meaning clouds are still growing vertically, although their final fate cannot be determined by snapshot observations.

Physical Algorithm↗

Ground truth data for test sites (SL-4)

Field measurements performed simultaneous with Skylab overpass in order to provide comparative calibration and performance evaluation measurements for the EREP sensors are presented. Wavelength region covered include: solar radiation (400 to 1300 nanometer), and thermal radiation (8 to 14 micrometer). Measurements consisted of general conditions and near surface meteorology, atmospheric temperature and humidity vs altitude, the thermal brightness temperature, total and diffuse solar radiation, direct solar radiation (subsequently analyzed for optical depth/transmittance), and target reflectivity/radiance. The particular instruments used are discussed along with analyses performed. Detailed instrument operation, calibrations, techniques, and errors are given.

Source record↗

Discovery of natural gain amplification in the 10-micrometer carbon dioxide laser bands on Mars - A natural laser

Fully resolved intensity profiles of various lines in the carbon dioxide band at 10.4 micrometers have been measured on Mars with an infrared heterodyne spectrometer. Analysis of the line shapes shows that the Mars atmosphere exhibits positive gain in these lines. The detection of natural optical gain amplification enables identification of these lines as a definite natural laser.

Mumma, M. J.↗

Measurement of the nighttime infrared luminosity of Spacelab 1 in the H- and K-bands

Infrared measurements of the Spacelab 1, Space Transportation System 9, were made from the Maui Optical Station tracking facility using a sensitive photometer n two infrared bands, the H-band centered at a wavelength of 1.6 microns and the K-band centered at 2.3 micrometers. The objective was to measure radiation from the vicinity of the Shuttle arising from interaction of Shuttle surfaces with atmospheric particles. It was necessary to include the Shuttle itself in the field of view of the photometer. The integrated brightness of the entire Shuttle at a distance of 400 km was found to be equivalent to that of a star of magnitude +6.6 or 1.6 microns; it was much fainter in the visible. Most of the emission at 1.6 microns appears to be attributable to the Shuttle glow phenomenon. It is hundreds of times brighter than the zodiacal background. The radiation at 2.3 microns can be accounted for primarily by diffusely scattered thermal radiation from Earth's surface.

Witteborn, F. C.↗

Micro-Mechanical Voltage Tunable Fabry-Perot Filters Formed in (111) Silicon

The MEMS (Micro-Electro-Mechanical-Systems) technology is quickly evolving as a viable means to combine micro-mechanical and micro-optical elements on the same chip. One MEMS technology that has recently gained attention by the research community is the micro-mechanical Fabry-Perot optical filter. A MEMS based Fabry-Perot consists of a vertically integrated structure composed of two mirrors separated by an air gap. Wavelength tuning is achieved by applying a bias between the two mirrors resulting in an attractive electrostatic force which pulls the mirrors closer. In this work, we present a new micro-mechanical Fabry-Perot structure which is simple to fabricate and is integratable with low cost silicon photodetectors and transistors. The structure consists of a movable gold coated oxide cantilever for the top mirror and a stationary Au/Ni plated silicon bottom mirror. The fabrication process is single mask level, self aligned, and requires only one grown or deposited layer. Undercutting of the oxide cantilever is carried out by a combination of RIE and anisotropic KOH etching of the (111) silicon substrate. Metallization of the mirrors is provided by thermal evaporation and electroplating. The optical and electrical characteristics of the fabricated devices were studied and show promissing results. A wavelength shift of 120nm with 53V applied bias was demonstrated by one device geometry using 6.27 micrometer air gap. The finesse of the structure was 2.4. Modulation bandwidths ranging from 91KHz to greater than 920KHz were also observed. Theoretical calculations show that if mirror reflectivity, smoothness, and parallelism are improved, a finesse of 30 is attainable. The predictions also suggest that a reduction of the air gap to 1 micrometer results in an increased wavelength tuning range of 175 nm with a CMOS compatible 4.75V.

Patterson, James D.↗

Observations of Aircraft Dissipation Trails from GOES

Two cases of distrails (aircraft dissipation trails) with associated fall streak clouds were analyzed using multispectral geostationary satellite data. One distrail was observed on 23 July 2000 in a single cloud layer over southeastern Virginia and the Chesapeake Bay. Another set of trails developed on 6 January 2000 at the top of multilayer clouds off the coasts of Georgia and South Carolina. The distrails on both days formed in optically thin, midlevel stratified clouds with cloud-top heights between 7.6 and 9.1 km. The distrail features remained intact and easily visible from satellite images for 1-2 h in spite of winds near 50 km at cloud level. The width of the distrails spread as far as 20 km within 90 min or less. Differences between the optical properties of the clouds surrounding the trails and those of the fall streak particles inside the distrails allowed for easy identification of the fall streak clouds in either the 3.9-micrometer brightness temperature imagery, or the 10.7-micrometer - 12.0-micrometer brightness temperature difference. Although the three-channel infrared retrieval was better at retrieving cloud properties in the multilayer cloud case, two independent remote sensing retrievals of both distrail cases showed that the fall streaks had larger particle sizes than the clouds outside of the trails.

Duda, David P.↗

Laboratory Spectra of Mixtures of CH4, C2H6, and CH3OH

Infrared spectroscopy is commonly used as a tool for identifying the composition of objects in the Solar System and beyond. Using laboratory spectra, optical constants can be calculated and used to create model spectra for comparison to spectra obtained from infrared telescopes. In this study, the optical constants of mixtures of simple organics, including CH4, C2H6, and CH3OH were calculated from 15 to 70 K, in the frequency range of 9000-500 cm(sup -1) (1.1-20 micrometers), at a spectral resolution of 1 cm(sup -1).

Mastrapa, Rachel↗

Dense cores in dark clouds - Young embedded stars at 2 micrometers

Twenty-five visually opaque regions which contain strong sources of NH3 (1,1) line emission (dense cores) have been surveyed for evidence of associated stars at two microns. Five such stars have been found, of which three - in B5, L1489, and L1582 - are optically invisible and probably embedded in their associated cores. The stars in B5 and L1489 have 2-100 micron spectra and luminosity similar to those of HL Tau, a very young T Tauri star. These stars probably formed in the cores where they are now seen. These results tend to confirm earlier suggestions that low-mass stars form in dense cores.

Benson, P. J.↗

Pointing Reference Scheme for Free-Space Optical Communications Systems

A scheme is proposed for referencing the propagation direction of the transmit laser signal in pointing a free-space optical communications terminal. This recently developed scheme enables the use of low-cost, commercial silicon-based sensors for tracking the direction of the transmit laser, regardless of the transmit wavelength. Compared with previous methods, the scheme offers some advantages of less mechanical and optical complexity and avoids expensive and exotic sensor technologies. In free-space optical communications, the transmit beam must be accurately pointed toward the receiver in order to maintain the communication link. The current approaches to achieve this function call for part of the transmit beam to be split off and projected onto an optical sensor used to infer the pointed direction. This requires that the optical sensor be sensitive to the wavelength of the transmit laser. If a different transmit wavelength is desired, for example to obtain a source capable of higher data rates, this can become quite impractical because of the unavailability or inefficiency of sensors at these wavelengths. The innovation proposed here decouples this requirement by allowing any transmit wavelength to be used with any sensor. We have applied this idea to a particular system that transmits at the standard telecommunication wavelength of 1,550 nm and uses a silicon-based sensor, sensitive from 0.5 to 1.0 micrometers, to determine the pointing direction. The scheme shown in the figure involves integrating a low-power 980-nm reference or boresight laser beam coupled to the 1,550-nm transmit beam via a wavelength-division-multiplexed fiber coupler. Both of these signals propagate through the optical fiber where they achieve an extremely high level of co-alignment before they are launched into the telescope. The telescope uses a dichroic beam splitter to reflect the 980- nm beam onto the silicon image sensor (a quad detector, charge-coupled device, or active-pixel-sensor array) while the 1,550- nm signal beam is transmitted through the optical assembly toward the remotely located receiver. Since the 980-nm reference signal originates from the same single-mode fiber-coupled source as the transmit signal, its position on the sensor is used to accurately determine the propagation direction of the transmit signal. The optics are considerably simpler in the proposed scheme due to the use of a single aperture for transmitting and receiving. Moreover, the issue of mechanical misalignment does not arise because the reference signal and transmitted laser beams are inherently co-aligned. The beam quality of the 980-nm reference signal used for tracking is required to be circularly symmetric and stable at the tracking-plane sensor array in order to minimize error in the centroiding algorithm of the pointing system. However, since the transmit signal is delivered through a fiber that supports a single mode at 1,550 nm, propagation of higher order 980-nm modes is possible. Preliminary analysis shows that the overall mode profile is dominated by the fundamental mode, giving a near symmetric profile. The instability of the mode was also measured and found to be negligible in comparison to the other error contributions in the centroid position on the sensor array.

Wright, Malcolm↗

15 meter multiple mirror telescope design study

Taking as a starting point the existing Multiple Mirror Telescope (MMT), a concept for a larger and more advanced instrument has been developed. It makes use of four 7.5-m diameter paraboloidal glass primaries of the honeycomb sandwich type being developed by the University of Arizona. These are mounted quite close together in a square configuration, with their axes coaligned. Separate optical configurations are provided, for optical and infrared applications. To minimze telescope emissivity in the thermal infrared at the combined focus, all the beam combining and streering optics that follow the tertiary mirrors are enclosed in a large central dewar and cooled with liquid nitrogen. The diffraction-limited resolution at the combined focus of 0.11 arcsec at 10 micrometers wavelength is equivalent to that of a 20.5 meter filled aperture. Diffraction-limited resolution should be routinely achievable at 10 and 20 micrometers, if active correction of large-scale wavefront errors is implemented.

Angel, J. R. P.↗

Remote sensing of cloud, aerosol and water vapor properties from the Moderate Resolution Imaging Spectrometer (MODIS)

The Moderate Resolution Imaging Spectrometer (MODIS) is an Earth-viewing sensor being developed as a facility instrument for the Earth Observing System (EOS) to be launched in the late 1990s. MODIS consists of two separate instruments that scan a swath width sufficient to provide nearly complete global coverage every two days from a polar-orbiting, Sun-synchronous, platform at an altitude of 705 km. Of primary interest for studies of atmospheric physics is the MODIS-N (nadir) instrument which will provide images in 36 spectral bands between 0.415 and 14.235 micrometers with spatial resoulutions of 250 m (2 bands), 500 m (5 bands) and 1000 m (29 bands). These bands have been carefully selected to enable advanced studies of land, ocean and atmosperhic processes. The intent of this lecture is to describe the current status of MODIS-N and its companion instrument MODIS-T (tilt), a tiltable cross-track scanning radiometer with 32 uniformly spaced channels between 0.410 and 0.875 micrometers, and to describe the physical principles behind the development of MODIS for the remote sensing of atmospheric properties. Primary emphasis will be placed on the main atmospheric applications of determining the optical, microphysical and physical properties of clouds and aerosol particles form spectral-reflection and thermal-emission measurements. In addition to cloud and aerosol properties, MODIS-N will be utilized for the determination of the total precipitable water vapor over land and atmospheric stability. The physical principles behind the determination of each of these atmospheric products will be described herein.

King, M. D.↗

Modal Filters for Infrared Interferometry

Modal filters in the approximately equal to 10-micrometer spectral range have been implemented as planar dielectric waveguides in infrared interferometric applications such as searching for Earth-like planets. When looking for a small, dim object ("Earth") in close proximity to a large, bright object ("Sun"), the interferometric technique uses beams from two telescopes combined with a 180 phase shift in order to cancel the light from a brighter object. The interferometer baseline can be adjusted so that, at the same time, the light from the dimmer object arrives at the combiner in phase. This light can be detected and its infrared (IR) optical spectra can be studied. The cancellation of light from the "Sun" to approximately equal to 10(exp 6) is required; this is not possible without special devices-modal filters- that equalize the wavefronts arriving from the two telescopes. Currently, modal filters in the approximately equal to 10-micrometer spectral range are implemented as single- mode fibers. Using semiconductor technology, single-mode waveguides for use as modal filters were fabricated. Two designs were implemented: one using an InGaAs waveguide layer matched to an InP substrate, and one using InAlAs matched to an InP substrate. Photon Design software was used to design the waveguides, with the main feature all designs being single-mode operation in the 10.5- to 17-micrometer spectral range. Preliminary results show that the filter's rejection ratio is 26 dB.

Ksendzov, Alexander↗

SSH-2 measurements of cirrus at 18-28 micrometers from the King Air during FIRE 2

In November of 1991, the First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment (FIRE) Phase II cirrus study took place at Coffeyville, Kansas. The field experiment incorporated instrumentation from surface, aircraft, and satellite to attempt to define the optical, radiative, and microphysical characteristics of these high altitude, predominantly ice clouds. The NCAR King Air research aircraft was outfitted with a variety of radiative and microphysical instrumentation for the FIRE II project. Included for this project was the SSH-2, a 16-channel passive radiometer. The SSH-2 was originally designed as a space-qualified infrared (IR) temperature and water vapor sounder for deployment onboard the Defense Meteorological Satellite Program (DMSP) series of environmental satellites. For this experiment, only those channels associated with the water vapor profiling function have been examined although downwelling radiance measurements were taken at all channels during the project. With supporting information from the aircraft telemetry observations it may be possible to relate these SSH-2 measurements to cloud radiative and microphysical properties. The following sections will describe the spectral characteristics of the instrument, the calibration scheme used to convert the raw measured counts into calibrated radiances, and the case studies that will be covered in this paper. This will be followed by a discussion of the results of this preliminary investigation and a description of future work to be done.

Griffin, Michael K.↗

Surface Water Quality Data from Beaver-Impacted Streams; Trail Creek and East River, Colorado 2025

This data package contains surface water chemistry measurements collected in 2025 to evaluate how beaver damming and low-tech process-based stream restoration influence water quality and metal mobility in mountainous headwater systems of the Upper Colorado River Basin. Sampling was conducted at Trail Creek (Taylor Park watershed, Colorado), a tributary undergoing restoration through installation of low-tech process-based structures (i.e., beaver dam analogs), and at off-channel beaver ponds within the East River floodplain (East River watershed, Colorado). Samples were collected along longitudinal transects spanning upstream control reaches, beaver-influenced ponded reaches, and downstream segments. Additional samples were collected from near-surface pore waters within a beaver dam seepage face. The dataset includes concentrations of major and trace elements measured by inductively coupled plasma–mass spectrometry (ICP-MS) and inductively coupled plasma–optical emission spectrometry (ICP-OES), major anions measured by ion chromatography (IC), and dissolved organic carbon (DOC; reported as non-purgeable organic carbon, NPOC). Samples were size-fractionated at 0.45 micrometers (µm), 0.22 µm, and 0.02 µm to distinguish particulate (>0.45 µm), colloidal (0.22–0.02 µm), and dissolved (<0.02 µm) fractions. The data package consists of comma-separated value (.csv) files containing tabulated chemical concentration data, sample metadata (site identifiers, geographic coordinates, sampling dates, fraction type), and quality control flags. All files are provided in open, non-proprietary formats that can be accessed using standard data analysis software such as Microsoft Excel, R, Python, MATLAB, or other programs capable of reading .csv files. Units, detection limits, and analytical methods are documented in accompanying metadata files. The dataset is designed to support analyses of (1) how beaver impoundment and restoration structures alter elemental partitioning and transport, (2) the role of iron and organic carbon in mediating trace metal mobility, and (3) reach-scale changes in water quality across restoration gradients. This work was supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231. Part of this work was performed at SLAC Accelerator Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-76SF00515.

Anions↗

Discovery of natural gain amplification in the 10 muon m CO2 laser bands on Mars: The first definite natural laser

Fully resolved intensity profiles of various lines in the CO2 bands at 9.4 micrometers and 10.4 micrometers were measured on Mars using an infrared heterodyne spectrometer. Analysis of the line shapes shows that the Mars atmosphere exhibits positive gain on these lines, providing the first definite detection of natural optical gain amplification and enabling identification of these lines as the first definite natural laser ever discovered.

Mumma, M.↗

KNbO3 single crystal growth by the radio frequency heating Czochralski method

A radio frequency heating Czochralski technique to obtain single crystal KNbO3 is first presented. The technological parameters of KNbO3 crystal growth by the Czochralski technique and its pulling conditions were studied in detail. The experiments on second harmonic generation using 1.06 micrometer Nd:YAG laser in KNbO3 have been conducted. The second harmonic efficiency for upconversion of KNbO3 is found to be as high as that of NaBa2Nb5O15. An automatic scanning measurement for the optical homogeneity of KNbO crystal is also described. KNbO3 is revealed to be a potentially useful nonlinear material for optical device applications.

Wang, W.↗

Making Rectangular Apertures In Silicon

Conventional silicon micromachining techniques produce micrometer-sized rectangular apertures. Used to define source and detector openings for measurements of images and scattered light in visible, ultraviolet, and soft x-ray wavelength regions, and as general-purpose optical slits or slit arrays. Rectangular microscopic apertures replace circular pinholes made by puncturing foils with needles or by drilling foils with intense, highly-focused laser beams. Precise photolithography yields apertures of superior geometry.

Leviton, Douglas B.↗