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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

Non-catalytic pyrolysis of associated gas to zero CO 2 hydrogen and high value carbon black

The overall objective of this work is to perform a pre-Front End Engineering Design (pre-FEED) study of the conversion of associated gas produced at an active oil pad of a Bakken oil field producer, to high value carbon black and hydrogen using the Microwave Plasma Pyrolysis of Associated Gas (MPP-AG) process developed by H Quest Vanguard, Inc (HQV). The University of North Dakota’s Center for Process Engineering Research (CPER) collaborated with HQV to complete a design and techno-economic analysis for the MPP-AG deployed at an active Bakken well site flaring an average of 54,000 standard cubic feet per day of AG. The proposed design consists of: • A Microwave Pyrolysis Unit (MPU) which consists of H Quest’s proprietary MPP technology • A patent-pending Gas Conditioning Unit (GCU) designed by the University of North Dakota to condition intermittent and variable flow gas prior to pyrolysis. • An auxiliary unit running on the associated gas to power the GCU and MPU in an “island mode” configuration.

03 NATURAL GAS↗

Microwave signatures from a reconnecting plasma pinch, with application to loop flares

A calculation is made of microwave signature of a cylindrical plasma pinch undergoing magnetic reconnection, a process which occurs in many astrophysical situations, such as solar flares. Depending on the viewing angle and the average energy of the accelerated electrons, the microwaves from this betatron-like source show various amounts of circular polarization. The degree of polarization is shown to be frequency dependent, and the sense of polarization is sometimes reversed. The power spectrum is predicted to have several interesting properties, which can be compared with high-resolution measurements.

Mok, Y.↗

Assessment of the Impact of Spatial Heterogeneity on Microwave Satellite Soil Moisture Periodic Error

An accurate temporal and spatial characterization of errors is required for the efficient processing, evaluation, and assimilation of remotely-sensed surface soil moisture retrievals. However, empirical evidence exists that passive microwave soil moisture retrievals are prone to periodic artifacts which may complicate their application in data assimilation systems (which commonly treat observational errors as being temporally white). In this paper, the link between such temporally-periodic errors and spatial land surface heterogeneity is examined. Both the synthetic experiment and site-specified cases reveal that, when combined with strong spatial heterogeneity, temporal periodicity in satellite sampling patterns (associated with exact repeat intervals of the polar-orbiting satellites) can lead to spurious high frequency spectral peaks in soil moisture retrievals. In addition, the global distribution of the most prominent and consistent 8-day spectral peak in the Advanced Microwave Scanning Radiometer - Earth Observing System soil moisture retrievals is revealed via a peak detection method. Three spatial heterogeneity indicators - based on microwave brightness temperature, land cover types, and long-term averaged vegetation index - are proposed to characterize the degree to which the variability of land surface is capable of inducing periodic error into satellite-based soil moisture retrievals. Regions demonstrating 8-day periodic errors are generally consistent with those exhibiting relatively higher heterogeneity indicators. This implies a causal relationship between spatial land surface heterogeneity and temporal periodic error in remotely-sensed surface soil moisture retrievals.

Fangni Lei↗

Resolution of defects by microwave holography.

Basic techniques for microwave holography are considered, giving attention to ways of approaching the problem, swept frequency depth resolution, optical processing of swept frequency data, B-scans with optical processing, and the side-looking radar principle. Aspects of image formation with Vander Lugt filters are discussed together with holograms for Vander Lugt filter imaging. It is shown that a single basic scanning operation with microwaves can produce records for optical processing to provide any of the common readouts used in flaw detection.

Cribbs, R. W.↗

Microwave-Assisted Reactive CO 2 Capture with the SrCO 3 -Graphite System

This study details the initial development of a microwave heat-driven reactive CO 2 capture (RCC) process using the SrO/SrCO 3 cycle and graphitic carbon to absorb ppm-levels of CO 2 from humidified room temperature air and selectively convert it into CO. By combining first-principles density functional theory (DFT) simulations with thermogravimetric analysis (TGA) and X-ray diffraction (XRD) verification, it is demonstrated that SrO spontaneously absorbs moisture to generate Sr(OH) 2 followed by Sr(OH) 2 *1H 2 O, which then can spontaneously react with atmospheric levels of CO 2 to form SrCO 3 . The resulting SrCO 3 can then react with solid carbon at elevated temperatures to selectively produce CO and regenerate SrO. Graphitic carbon is an excellent microwave absorber that can quickly generate temperatures approaching 1000 °C and then cool to room temperature within minutes, potentially allowing for integration with intermittent electricity. It is shown that using microwaves to selectively heat a mixture of graphitic carbon and SrCO 3 produced CO with 85 ± 3% selectivity and stable performance over ten cycles. The rapid heating for release and room temperature CO 2 uptake processes appeared to prevent performance loss from particle sintering typically observed with traditional thermal systems. In conclusion, these results demonstrate a new RCC approach that adds to the growing number of potential technologies available for converting CO 2 to useful chemicals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Heating And Positioning In A Microwave Cavity

Two reports describe theoretical and experimental studies of microwave dielectrophoretic positioning of spherical sample of lossy dielectric material in microwave resonant cavity and heating of positioned sphere by electro-magnetic field. Studies part of continuing effort to develop techniques for containerless processing of materials in microgravity. Previous studies in this series described in "Microwave Dielectrophoretic Levitation in Microgravity" (NPO-18824).

Jackson, Henry W.↗

Initial Processing of Infrared Spectral Data

The Atmospheric Infrared Spectrometer (AIRS) Science Processing System is a collection of computer programs, denoted product generation executives (PGEs), for processing the readings of the AIRS suite of infrared and microwave instruments orbiting the Earth aboard NASA's Aqua spacecraft. Following from level 0 (representing raw AIRS data), the PGEs and their data products are denoted by alphanumeric labels (1A, 1B, and 2) that signify the successive stages of processing. Once level-0 data have been received, the level-1A PGEs begin processing, performing such basic housekeeping tasks as ensuring that all the Level-0 data are present and ordering the data according to observation times. The level-1A PGEs then perform geolocation-refinement calculations and conversions of raw data numbers to engineering units. Finally, the level-1A data are grouped into packages, denoted granules, each of which contain the data from a six-minute observation period. The granules are forwarded, along with calibration data, to the Level-1B PGEs for processing into calibrated, geolocated radiance products. The Level-2 PGEs, which are not yet operational, are intended to process the level-1B data into temperature and humidity profiles, and other geophysical properties.

De Picciotto, Solomon↗

On the Characterization and Mitigation of Noise in Space-borne Microwave Sounding Instruments

Space-borne microwave sounding instruments have become vital data sources for weather prediction and climate change studies. Among the various radiometer configurations, the total power microwave radiometer is particularly appealing for current and future operational satellites due to its superior sensitivity and simple design. However, its performance is vulnerable to degradation caused by receiver gain fluctuations, electronic 1/f noise, and other time varying receiver characteristics. For Numerical Weather Prediction (NWP) users, 1/f noise introduces inter-channel correlations, complicating the assimilation of affected observations and reducing their accuracy. Addressing this noise issue in ground data processing system is essential to enhance the utility of microwave sounding data. This paper focuses on the characterization and mitigation of noise in current and future microwave sounding instruments, with particular emphasis on the impact of 1/f noise. Various methods are applied to quantitatively characterize noise features in both frequency and time domains. Additionally, the influence of calibration parameters on 1/f noise are analyzed. Based on these findings, we propose a mitigation algorithm for reducing noise during the on-orbit calibration of microwave sounding instruments, aiming to improve the quality of retrieved data for operational use.

calibration↗

Microwave ice prevention

The concept of using microwave energy to provide aircraft ice protection, specifically an anti-icing system, and the feasibility of such a system are discussed. In a microwave anti-icing system impinging supercooled water droplets are heated to above freezing by the resonant absorption of microwave energy located upstream of the aircraft. This process is inherently more efficient than existing anti-icing devices due to the saving of the latent heat of fusion (a substantial 334 joules/gm (80 cal/gm)) and the fact that only the droplets are heated, thereby reducing convective losses to the air.

Hansman, R. J., Jr.↗

Solar flare precursors

Recent progress in the study of flare precursors and onset is reviewed. New theoretical results on filament formation and erution are presented, including especially the dynamical effects of magnetic fields. Ample evidence is found that energetic processes are already at work in the onset phase, a few minutes before the rapid rise of the hard-radiation impulse. In particular, the prevalence of soft and hard X-ray preheating (to less than 100 million K) is detailed, along with a connection to the launch of coronal mass ejections. A possible interpretation of the empirical time profiles near onset is that 'preheating' signifies that the flare has slowly started, and the transition to the impulsive stage then represents a change of phase in the flare-instability process. Finally, the problem of the interpretation of microwave preflare data is delineated.

Van Hoven, G.↗

Remote sensing of global snowpack energy and mass balance: In-situ measurements on the snow of interior and Arctic Alaska

Observations led to a study of the physical properties of snow and the processes which operate on it. These observations included microwave brightness temperatures in interior Alaska which revealed: (1) up to three times more variability from one cell (1/2 degree latitude x 1/2 degree longitude) to the next in winter than in summer (5 to 15 K in winter and about 5 K in summer); (2) the overall range of temperature from week to week is about seven times greater in winter than in summer; (3) the microwave brightness temperature is about 25 K less than air temperature during summer but 35 to 60 K less during winter; and (4) the presence of snow cover appears to contribute to increasing the difference between air temperature and brightness temperature. The role of irregular substrate under the snow in enhancing convection has been studied with particular attention to variations in snow cover on water surfaces and in forested regions. LANDSAT imagery has been obtained to prepare a classification of ground surface types of the area. The extreme conditions of the 1988 to 1989 winter are discussed with respect to comparing the microwave data sets from 1985, and before, up to the present. The use of the Mt. Wrangell area as aerial photogrammetric controls for glacier measurements is given attention.

Benson, Carl S.↗

Plasma reactor waste management systems

The University of North Dakota is developing a plasma reactor system for use in closed-loop processing that includes biological, materials, manufacturing, and waste processing. Direct-current, high-frequency, or microwave discharges will be used to produce plasmas for the treatment of materials. The plasma reactors offer several advantages over other systems, including low operating temperatures, low operating pressures, mechanical simplicity, and relatively safe operation. Human fecal material, sunflowers, oats, soybeans, and plastic were oxidized in a batch plasma reactor. Over 98 percent of the organic material was converted to gaseous products. The solids were then analyzed and a large amount of water and acid-soluble materials were detected. These materials could possibly be used as nutrients for biological systems.

Ness, Robert O., Jr.↗

In Situ Resource Utilization (ISRU) Experiments for Mars Exploration

In situ resource utilization can best be described as living off the land. In our case the land is the planet Mars. ISRU is based on the idea that some fraction of the consumables, life support and propellant materials do not have to be flown from earth. Rather, they can be manufactured or extracted from resources already present on Mars. The primary resources on Mars are the atmosphere, polar caps and regolith. The atmosphere of Mars is mostly carbon dioxide as shown in the table below. The proportion of oxygen on the other hand is quite small. Still, there is quite a bit of oxygen in the Martian atmosphere, but it is unfortunately tied up with carbon. Thus, one of the goals of ISRU is the separation of breathable oxygen from the carbon dioxide. Several means of separation have been proposed. We have begun experiments on another approach for production of oxygen with carbon monoxide as a useful by product. Our work on a CO2 separator is described later in this report. Regolith melting is another means of obtaining materials. Two materials of interest are iron and silicon. Iron oxide is plentiful on Mars and is of obvious importance for structural components. Silicon is the foundation of solid state devices. Power generation on Mars may be accomplished using silicon solar cells. There is discussion of the feasibility of in situ production of solar cells. This would require a means of extracting silicon from the regolith. We have conducted several experiments concerning melting and glassification of the Mars soil simulant. Other summer faculty fellows have tried various means of processing the stimulant material. These include furnace melting, microwave melting and laser ablation. We have conducted several furnace melting experiments in both air and carbon dioxide environments. We have also carried out experiments to test spark melting in a carbon dioxide atmosphere. These experiments suggest the possibility of using arc melting in a reducing atmosphere. It is important to keep in mind that we are working with a soil stimulant. Any simulant, no matter how chemically similar it is to Martian regolith, may differ in mineralogy. The underlying assumption in this work is that once a glass is formed, any differences between simulant and regolith are unimportant. The exact means of forming the glass do, however, depend on the mineralogy of the regolith. A sample return mission is required to help answer these questions.

Marone, Matt↗

Microwave/Sonic Apparatus Measures Flow and Density in Pipe

An apparatus for measuring the rate of flow and the mass density of a liquid or slurry includes a special section of pipe instrumented with microwave and sonic sensors, and a computer that processes digitized readings taken by the sensors. The apparatus was conceived specifically for monitoring a flow of oil-well-drilling mud, but the basic principles of its design and operation are also applicable to monitoring flows of other liquids and slurries.

Arndt, G. D.↗

Sabatier Reactor System Integration with Microwave Plasma Methane Pyrolysis Post-Processor for Closed-Loop Hydrogen Recovery

The Carbon Dioxide Reduction Assembly (CRA) designed and developed for the International Space Station (ISS) represents the state-of-the-art in carbon dioxide reduction (CDRe) technology. The CRA produces water and methane by reducing carbon dioxide with hydrogen via the Sabatier reaction. The water is recycled to the Oxygen Generation Assembly (OGA) and the methane is vented overboard resulting in a net loss of hydrogen. The proximity to earth and the relative ease of logistics resupply from earth allow for a semi-closed system on ISS. However, long-term manned space flight beyond low earth orbit (LEO) dictates a more thoroughly closed-loop system involving significantly higher recovery of hydrogen, and subsequent recovery of oxygen, to minimize costs associated with logistics resupply beyond LEO. The open-loop ISS system for CDRe can be made closed-loop for follow-on missions by further processing methane to recover hydrogen. For this purpose, a process technology has been developed that employs a microwave-generated plasma to reduce methane to hydrogen and acetylene resulting in 75% theoretical recovery of hydrogen. In 2009, a 1-man equivalent Plasma Pyrolysis Assembly (PPA) was delivered to the National Aeronautics and Space Administration (NASA) for technical evaluation. The PPA has been integrated with a Sabatier Development Unit (SDU). The integrated process configuration incorporates a sorbent bed to eliminate residual carbon dioxide and water vapor in the Sabatier methane product stream before it enters the PPA. This paper provides detailed information on the stand-alone and integrated performance of both the PPA and SDU. Additionally, the integrated test stand design and anticipated future work are discussed.

Abney, Morgan B.↗

The Impact of Standard Semiconductor Fabrication Processes on Polycrystalline Nb Thin Film Surfaces

Polycrystalline Nb thin films are extensively used for microwave kinetic inductance detectors (MKIDs) and superconducting transmission line applications. The microwave and mm-wave loss in these films is impacted, in part, by the presence of surface nitrides and oxides. In this study, glancing incidence x-ray diffraction was used to identify the presence of niobium nitride and niobium monoxide surface layers on Nb thin films which had been exposed to chemicals used in standard photolithographic processing. A method of mitigating the presence of ordered niobium monoxide surface layers is presented. Furthermore, we discuss the possibility of using glancing incidence x-ray diffraction as a non-destructive diagnostic tool for evaluating the quality of Nb thin films used in MKIDs and transmission lines. For a given fabrication process, we have both the X-ray diffraction data of the surface chemistry and a measure of the mm-wave and microwave loss, the latter being made in superconducting resonators.

superconducting films↗

The Impact of Standard Semiconductor Fabrication Processes on Polycrystalline Nb Thin Film Surfaces

Polycrystalline Nb thin films are extensively used for microwave kinetic inductance detectors (MKIDs) and superconducting transmission line applications. The microwave and mm-wave loss in these films is impacted, in part, by the presence of surface nitrides and oxides. In this study, glancing incidence x-ray diffraction was used to identify the presence of niobium nitride and niobium monoxide surface layers on Nb thin films which had been exposed to chemicals used in standard photolithographic processing. A method of mitigating the presence of ordered niobium monoxide surface layers is presented. Furthermore, we discuss the possibility of using glancing incidence x-ray diffraction as a non-destructive diagnostic tool for evaluating the quality of Nb thin films used in MKIDs and transmission lines. For a given fabrication process, we have both the X-ray diffraction data of the surface chemistry and a measure of the mm-wave and microwave loss, the latter being made in superconducting resonators.

superconducting films↗