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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The Feasibility of Atomic Layer Deposition of Aluminum Oxide on TATB
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Developing a Pyrolysis Gas Thermal Blocking Model for Reentry Demise
In NASA’s Object Reentry Survival Analysis Tool (ORSAT), aerodynamic drag and aerothermal heating coefficients are computed for each of the free-molecular, continuum, and transitional flow regimes using analytical and semi-analytical methods. These heating coefficients were derived for typical metallic materials that melt and do not have a strong gas-phase contribution to the flow in the boundary layer. Modern satellites typically feature fiber-reinforced polymer (FRP) components, such as solar array booms, facesheets of sandwich panels, or overwraps for composite-overwrapped pressure vessels (COPV). These FRP materials do not behave the same as metals in the reentry environment, but instead will pyrolyze and develop significant volumes of gas into the boundary layer. Accurately predicting the reentry demise of FRP components is critical to assessing the reentry casualty risk for modern spacecraft. Research in recent years has shown that this demisability can depend heavily on how the expulsion of gaseous pyrolysis products through the outer surface of the material affects the heat flux at the surface. The ODPO has been developing a reduced-order model of the effect of pyrolysis gas blowing on the heat flux based on correlations between a blowing factor and a non-dimensional heat flux to be incorporated in the upcoming version 7.3 of the Object Reentry Survivability Analysis Tool (ORSAT). This presentation discusses the progress of this development project and the challenges remaining for generalizing the model across families of FRP materials.
The impact of chemistry on anion migration in bixbyite-structured lanthanide oxides
This manuscript describes atomistic calculations of oxygen vacancy and interstitial migration in bixbyite structured lanthanide oxides. We examine two types of compounds, one in which only one type of lanthanide cation is present and a second class in which two lanthanides are present in a 3:1 ratio as dictated by the symmetry of the bixbyite crystal structure. Using temperature accelerated dynamics and the nudged elastic band method, we quantify the role of chemistry on the energy barriers for the most important pathways for both vacancy and interstitial migration. We then analyze the impact of these variations on the overall diffusivity of each defect, quantifying the contribution of each pathway using the theory of kinosons. We find that vacancy mobility can vary by as much as three orders of magnitude through changes in chemistry at 500 K. Changes in interstitial mobility are more modest but can still vary by an order of magnitude. This points to the ability to tune the mass transport characteristics of these compounds through appropriate choices in chemistry. We have also included supplementary information containing the atomic structures of the relevant pathways.
NestedAE: interpretable nested autoencoders for multi-scale materials characterization
The multi-scale features and latent space are connected by a nested autoencoder.
Interface engineering of lithium metal anodes via atomic and molecular layer deposition
Atomic and molecular layer deposition (ALD and MLD) are two promising tools for practicing interface engineering of lithium metal anodes precisely.
Separator development for a heat sterilizable battery Final summary progress report, 1 May 1966 - 15 Mar. 1967
Development and testing of vivyl polymer separator materials for sterilized silver-zinc secondary battery
Investigation of a Few Noble Metal Oxides with 17 O Solid-State NMR Spectroscopy
Not provided.
Li 2 FeCl 4 as a Cost-Effective and Durable Cathode for Solid-State Li-Ion Batteries
Not provided.
Accelerating and Enhancing Thermodynamic Simulations of Electrochemical Interfaces
Not provided.
A Bayesian method for selecting data points for thermodynamic modeling of off-stoichiometric metal oxides
A novel Bayesian approach significantly accelerates data collection for metal oxide reduction/re-oxidation thermodynamic fitting.
Role of Fe Impurity Reactions in the Electrochemical Properties of MgFeB 2 O 5
Not provided.