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Scaling Exponents of Turbulent Static Pressure Structure Function in the Inertial Subrange

The measured variations in the turbulent static pressure structure function D pp (r) with scale $r$ in the roughness sublayer above a subarctic forest are empirically shown to exhibit exponents that are smaller than $r$ 4/3 predicted for the inertial subrange (ISR). Three hypotheses are offered to explain these deviations. The first is based on conventional intermittency correction to the averaged turbulent kinetic energy dissipation rate, the second is based on shearing introducing deviations from locally isotropic state that must be sensed by both velocity and pressure structure functions, and the third is based on large and inertial scale pressure interactions that persist at values of $r$ within the resolvable ISR. The third hypothesis is shown to yield superior results, which allows a new formulation for D pp (r) to be derived that accommodates such finite interactions.

structure function↗

Variations in the Peak Position of the 6.2 micron Interstellar Emission Feature: A Tracer of N in the Interstellar Polycyclic Aromatic Hydrocarbon Population

This paper presents the results of an investigation of the molecular characteristics that underlie the observed peak position and profile of the nominal 6.2 micron interstellar emission band generally attributed to the CC stretching vibrations of polycyclic aromatic hydrocarbons (PAHs). It begins with a summary of recent experimental and theoretical studies ofthe spectroscopic properties of large (>30 carbon atoms) PAH cations as they relate to this aspect of the astrophysical problem. It then continues with an examination of the spectroscopic properties of a number of PAH variants within the context of the interstellar 6.2 micron emission, beginning with a class of compounds known as polycyclic aromatic nitrogen heterocycles (PANHs; PAHs with one or more nitrogen atoms substituted into their carbon skeleton). In this regard, we summarize the results of recent relevant experimental studies involving a limited set of small PANHs and their cations and then report the results of a comprehensive computational study that extends that work to larger PANH cations including many nitrogen-substituted variants of coronene(+) (C24H12(+)), ovalene(+) (C32H14(+)), circumcoronene(+) (C54H18(+)), and circum-circumcoronene(+) (C96H24(+)). Finally, we report the results of more focused computational studies of selected representatives from a number of other classes of PAH variants that share one or more of the key attributes of the PANH species studied. These alternative classes of PAH variants include (1) oxygen- and silicon-substituted PAH cations; (2) PAH-metal ion complexes (metallocenes) involving the cosmically abundant elements magnesium and iron; and (3) large, asymmetric PAH cations. Overall, the studies reported here demonstrate that increasing PAH size alone is insuEcient to account for the position of the shortest wavelength interstellar 6.2 micron emission bands, as had been suggested by earlier studies. On the other hand, this work reveals that substitution of one or more nitrogen atoms within the interior of the carbon skeleton of a PAH cation induces a significant blueshift in the position of the dominant CC stretching feature of these compounds that is suf6cient to account for the position of the interstellar bands. Subsequent studies of the effects of substitution by other heteroatoms (O and Si), metal ion complexation (Fe(+), Mg(+), and Mg(2+)), and molecular symmetry variation-all of which fail to reproduce the blueshift observed in the PANH cations-indicate that N appears to be unique in its ability to accommodate the position of the interstellar 6.2 micron bands while simultaneously satisfying the other constraints of the astrophysical problem. This result implies that the peak position of the interstellar feature near 6.2 micron traces the degree of nitrogen substitution in the population, that most of the PAHs responsible for the interstellar IR emission features incorporate nitrogen within their aromatic networks, and that a lower limit of 1%-2% of the cosmic nitrogen is sequestered within the interstellar PAH population. Finally, in view of the ubiquity and abundance of interstellar PAHs and the permanent dipoles and distinctive electronic structures of these nitrogen-substituted variants, this work impacts a wide range of observational phenomena outside of the infrared region of the spectrum including the forest of unidentified molecular rotational features and the anomalous Galactic foreground emission in the microwave, and the diffuse interstellar bands (DIBs) and other structure in the interstellar extinction curve in the ulhviolet/visible. These astrophysical ramifications are discussed, and the dipole moments and rotational constants are tabulated to facilitate further investigations of the astrophysical role of nitrogen-substituted aromatic compounds.

Hudgins, Douglas M.↗

Regional mapping of forest canopy water content and biomass using AIRSAR images over BOREAS study area

In recent years, monitoring vegetation biomass over various climate zones has become the primary focus of several studies interested in assessing the role of the ecosystem responses to climate change and human activities. Airborne and spaceborne Synthetic Aperture Radar (SAR) systems provide a useful tool to directly estimate biomass due to its sensitivity to structural and moisture characteristics of vegetation canopies. Even though the sensitivity of SAR data to total aboveground biomass has been successfully demonstrated in many controlled experiments over boreal forests and forest plantations, so far, no biomass estimation algorithm has been developed. This is mainly due to the fact that the SAR data, even at lowest frequency (P-band) saturates at biomass levels of about 200 tons/ha, and the structure and moisture information in the SAR signal forces the estimation algorithm to be forest type dependent. In this paper, we discuss the development of a hybrid forest biomass algorithm which uses a SAR derived land cover map in conjunction with a forest backscatter model and an inversion algorithm to estimate forest canopy water content. It is shown that unlike the direct biomass estimation from SAR data, the estimation of water content does not depend on the seasonal and/or environmental conditions. The total aboveground biomass can then be derived from canopy water content for each type of forest by incorporating other ecological information. Preliminary results from this technique over several boreal forest stands indicate that (1) the forest biomass can be estimated with reasonable accuracy, and (2) the saturation level of the SAR signal can be enhanced by separating the crown and trunk biomass in the inversion algorithm. We have used the JPL AIRSAR data over BOREAS southern study area to test the algorithm and to generate regional scale water content and biomass maps. The results are compared with ground data and the sources of errors are discussed. Several SAR images in synoptic modes are used to generate the parameter maps. The maps are then combined to generate mosaic maps over the BOREAS modeling grid.

Saatchi, Sasan↗

X-ray Absorption Spectroscopy and Neutron Scattering Data, Mineral Incubation Experiment, Walker Branch Watershed, TN (2020 - 2021)

Iron (Fe) (oxyhydr)oxides are well-recognized contributors to soil carbon (C) storage, but the effects of manganese (Mn) oxides on carbon storage and transformation are relatively unexplored. Here, the relative capacities of Fe and Mn oxides to bind and stabilize soil organic C were directly compared using an in-situ incubation experiment. Quartz sands coated with either poorly crystalline Mn(III/IV) oxides or Fe(III) oxides, or left uncoated, were buried in a temperate forest soil for up to one year. This data package contains processed data outputs of carbon near edge x-ray absorption fine structure spectroscopy (C NEXAFS), iron and manganese x-ray absorption near edge structure spectroscopy (XANES), and small angle neutron scattering (SANS) data collected for initial oxide-coated and uncoated quartz sands and for those buried in the temperate forest soil for 365 days.

Energy (eV)↗

Decadal-Scale Vegetation Change Driven by Salinity at Leading Edge of Rising Sea Level

As sea levels rise, low-lying coastal forests increasingly are subject to stressors such as inundation and saltwater exposure. At long timescales (for example, centuries), the extent of inundation and saltwater exposure will increase; however, on a decadal timescale, the role of these drivers may differ in both magnitude and direction. To investigate the drivers of decadal-scale vegetation change, we measured the changes in five metrics of vegetation composition and structure between 2003/2004 and 2016/ 2017 at 98 plots distributed across a vegetation gradient from coastal forest to brackish marshes (< 0.5–18 ppt). We used elevation as a proxy of inundation vulnerability and soil sodium concentration as a proxy of saltwater exposure, and we investigated relationships between these two variables and the change in vegetation conditions between the two sampling periods. Soil sodium concentration was a significant predictor of vegetation change for all five vegetation metrics, whereas the effect of elevation was not significant for any of the metrics. The one site that was affected by wildfire twice during the duration of the study shifted almost completely from forest to marsh with limited regeneration ofwoody vegetation observed in 2016/ 2017. Our results show that salinization in our system is a more important driver of vegetation change than inundation potential. Furthermore, the effects of drought-induced salinization could be amplified by the elevated risk of wildfire during droughts. Forecasting the response of coastal wetlands to rising sea levels will require a better understanding of the individual and combined effects of salinity, droughts, and wildfires on vegetation.

Taillie, Paul J.↗

Calibration and Validation of Landsat Tree Cover in the Taiga-Tundra Ecotone

Monitoring current forest characteristics in the taiga-tundra ecotone (TTE) at multiple scales is critical for understanding its vulnerability to structural changes. A 30 m spatial resolution Landsat-based tree canopy cover map has been calibrated and validated in the TTE with reference tree cover data from airborne LiDAR and high resolution spaceborne images across the full range of boreal forest tree cover. This domain-specific calibration model used estimates of forest height to determine reference forest cover that best matched Landsat estimates. The model removed the systematic under-estimation of tree canopy cover greater than 80% and indicated that Landsat estimates of tree canopy cover more closely matched canopies at least 2 m in height rather than 5 m. The validation improved estimates of uncertainty in tree canopy cover in discontinuous TTE forests for three temporal epochs (2000, 2005, and 2010) by reducing systematic errors, leading to increases in tree canopy cover uncertainty. Average pixel-level uncertainties in tree canopy cover were 29.0%, 27.1% and 31.1% for the 2000, 2005 and 2010 epochs, respectively. Maps from these calibrated data improve the uncertainty associated with Landsat tree canopy cover estimates in the discontinuous forests of the circumpolar TTE.

Montesano, Paul Mannix↗

Relating the temporal change observed by AIRSAR to surface and canopy properties of mixed conifer and hardwood forests of northern Michigan

The mixed hardwood and conifer forests of northern Michigan were overflown by a 3-frequency airborne imaging radar in Apr. and Jul. 1990. A set of 10 x 10 km test sites near the University of Michigan Biological Station at Douglas Lake and within the Hiawatha National Forest in the upper peninsula of Michigan contained training stands representing the various forest species typical of forest communities across the ecotone between the coniferous boreal forest and mid-latitude hardwood and coniferous forests. The polarimetric radar data were externally calibrated to allow interdate comparisons. The Apr. flight was prior to bud-break of deciduous species and patchy snowcover was present. The Jul. flights occurred during and 2 days after heavy rain showers, and provide a unique opportunity to examine the differences in radar backscatter attributable to intercepted precipitation. Analyses show that there are significant changes in backscattering between biophysically dissimilar forest stands on any given date and also between dates for a given forest stand. These differences in backscattering can be related to moisture properties of the forest floor and the overlying canopy and also to the quantity and organizational structure of the above-ground biomass.

Dobson, M. Craig↗

Theorizing Land Cover and Land Use Change: The Peasant Economy of Colonization in the Amazon Basin

This paper addresses deforestation processes in the Amazon basin. It deploys a methodology combining remote sensing and survey-based fieldwork to examine, with regression analysis, the impact household structure and economic circumstances on deforestation decisions made by colonist farmers in the forest frontiers of Brazil. Unlike most previous regression-based studies, the methodology implemented analyzes behavior at the level of the individual property. The regressions correct for endogenous relationships between key variables, and spatial autocorrelation, as necessary. Variables used in the analysis are specified, in part, by a theoretical development integrating the Chayanovian concept of the peasant household with spatial considerations stemming from von Thuenen. The results from the empirical model indicate that demographic characteristics of households, as well as market factors, affect deforestation in the Amazon. Thus, statistical results from studies that do not include household-scale information may be subject to error. From a policy perspective, the results suggest that environmental policies in the Amazon based on market incentives to small farmers may not be as effective as hoped, given the importance of household factors in catalyzing the demand for land. The paper concludes by noting that household decisions regarding land use and deforestation are not independent of broader social circumstances, and that a full understanding of Amazonian deforestation will require insight into why poor families find it necessary to settle the frontier in the first place.

Caldas, Marcellus↗

NASA's Hydrogen Outpost: The Rocket Systems Area at Plum Brook Station

"There was pretty much a general knowledge about hydrogen and its capabilities," recalled former researcher Robert Graham. "The question was, could you use it in a rocket engine? Do we have the technology to handle it? How will it cool? Will it produce so much heat release that we can't cool the engine? These were the questions that we had to address." The National Aeronautics and Space Administration's (NASA) Glenn Research Center, referred to historically as the Lewis Research Center, made a concerted effort to answer these and related questions in the 1950s and 1960s. The center played a critical role transforming hydrogen's theoretical potential into a flight-ready propellant. Since then NASA has utilized liquid hydrogen to send humans and robots to the Moon, propel dozens of spacecraft across the universe, orbit scores of satellite systems, and power 135 space shuttle flights. Rocket pioneers had recognized hydrogen's potential early on, but its extremely low boiling temperature and low density made it impracticable as a fuel. The Lewis laboratory first demonstrated that liquid hydrogen could be safely utilized in rocket and aircraft propulsion systems, then perfected techniques to store, pump, and cleanly burn the fuel, as well as use it to cool the engine. The Rocket Systems Area at Lewis's remote testing area, Plum Brook Station, played a little known, but important role in the center's hydrogen research efforts. This publication focuses on the activities at the Rocket Systems Area, but it also discusses hydrogen's role in NASA's space program and Lewis's overall hydrogen work. The Rocket Systems Area included nine physically modest test sites and three test stands dedicated to liquid-hydrogen-related research. In 1962 Cleveland Plain Dealer reporter Karl Abram claimed, "The rocket facility looks more like a petroleum refinery. Its test rigs sprout pipes, valves and tanks. During the night test runs, excess hydrogen is burned from special stacks in the best Oklahoma oil field tradition." Besides the Rocket Systems Area, Plum Brook Station also included a nuclear test reactor, a large vacuum tank, a hypersonic wind tunnel, and a full-scale upper-stage rocket stand. The Rocket Systems Area operated from 1961 until NASA shut down all of Plum Brook in 1974. The center reopened Plum Brook in the late 1980s and continues to use several test facilities. The Rocket Systems Area, however, was not restored. Today Plum Brook resembles a nature preserve more than an oil refinery. Lush fields and forests separate the large test facilities. Until recently, the abandoned Rocket Systems Area structures and equipment were visible amongst the greenery. These space-age ruins, particularly the three towers, stood as silent sentinels over the sparsely populated reservation. Few knew the story of these mysterious facilities when NASA removed them in the late 2000s.

Rocket Systems↗

Satellite-Based Evidence for Shrub and Graminoid Tundra Expansion in Northern Quebec from 1986-2010

Global vegetation models predict rapid poleward migration of tundra and boreal forest vegetation in response to climate warming. Local plot and air-photo studies have documented recent changes in high-latitude vegetation composition and structure, consistent with warming trends. To bridge these two scales of inference, we analyzed a 24-year (1986-2010) Landsat time series in a latitudinal transect across the boreal forest-tundra biome boundary in northern Quebec province, Canada. This region has experienced rapid warming during both winter and summer months during the last forty years. Using a per-pixel (30 m) trend analysis, 30% of the observable (cloud-free) land area experienced a significant (p < 0.05) positive trend in the Normalized Difference Vegetation Index (NDVI). However, greening trends were not evenly split among cover types. Low shrub and graminoid tundra contributed preferentially to the greening trend, while forested areas were less likely to show significant trends in NDVI. These trends reflect increasing leaf area, rather than an increase in growing season length, because Landsat data were restricted to peak-summer conditions. The average NDVI trend (0.007/yr) corresponds to a leaf-area index (LAI) increase of ~0.6 based on the regional relationship between LAI and NDVI from the Moderate Resolution Spectroradiometer (MODIS). Across the entire transect, the area-averaged LAI increase was ~0.2 during 1986-2010. A higher area-averaged LAI change (~0.3) within the shrub-tundra portion of the transect represents a 20-60% relative increase in LAI during the last two decades. Our Landsat-based analysis subdivides the overall high-latitude greening trend into changes in peak-summer greenness by cover type. Different responses within and among shrub, graminoid, and tree-dominated cover types in this study indicate important fine-scale heterogeneity in vegetation growth. Although our findings are consistent with community shifts in low-biomass vegetation types over multi-decadal time scales, the response in tundra and forest ecosystems to recent warming was not uniform.

McManus, K. M.↗

Symmetry in polarimetric remote sensing

Relationships among polarimetric backscattering coefficients are derived from the viewpoint of symmetry groups. For both reciprocal and non-reciprocal media, symmetry encountered in remote sensing due to reflection, rotation, azimuthal, and centrical symmetry groups is considered. The derived properties are general and valid to all scattering mechanisms, including volume and surface scatterings and their interactions, in a given symmetrical configuration. The scattering coefficients calculated from theoretical models for layer random media and rough surfaces are shown to obey the symmetry relations. Use of symmetry properties in remote sensing of structural and environmental responses of scattering media is also discussed. Orientations of spheroidal scatterers described by spherical, uniform, planophile, plagiothile, erectophile, and extremophile distributions are considered to derive their polarimetric backscattering characteristics. These distributions can be identified from the observed scattering coefficients by comparison with theoretical symmetry calculations. A new parameter is then defined to study scattering structures in geophysical media. Observations from polarimetric data acquired by the Jet Propulsion Laboratory airborne synthetic aperture radar over forests, sea ice, and sea surface are presented. Experimental evidences of the symmetry relationships are shown and their use in polarimetric remote sensing is illustrated. For forests, the coniferous forest in Mt. Shasta area (California) and mixed forest near Presque Isle (Maine) exhibit characteristics of the centrical symmetry at C-band. For sea ice in the Beaufort Sea, multi-year sea ice has a cross-polarized ratio e close to e(sub 0), calculated from symmetry, due to the randomness in the scattering structure. First-year sea ice has e much smaller than e(sub 0) due to the preferential alignment of the columnar structure of the ice. From polarimetric data of a sea surface in the Bering Sea, it is observed that e and e(sub 0) are increasing with incident angle and e is greater than e(sub 0) at L-band because of the directional feature of sea surface waves. Symmetry properties of geophysical media can also be used to calibrate polarimetric radars.

Nghiem, S. V.↗

Polarimetric Remote Sensing of Geophysical Medium Structures

Polarimetric remote sensing of structures in geophysical media is studied in this paper based on their symmetry properties. Orientations of spheroidal scatterers described by spherical, uniform, planophile, plagiothile, erectophile, and extremophile distributions are considered to derive their polarimetric backscattering characteristics. These distributions can be identified from the observed scattering coefficients by comparison with theoretical symmetry calculations. A new parameter is defined to study scattering structures in geophysical media. Experimental observations from polarimetric data acquired by the Jet Propulsion Laboratory airborne synthetic aperture radar over forests, sea ice, and sea surface are presented to illustrate the use of symmetry properties. For forests, the coniferous forest in Mount Shasta area and mixed forests neir Presque Isle show evidence of the centrical symmetry at C band. In sea ice from the Beaufort Sea, multiyear sea ice has a cross-polarized ratio e close to e(sub 0), calculated from symmetry, due to the randomness in the scattering structure. For first-year sea ice, e is much smaller than e(sub 0) as a result of preferential alignment of the columnar structure of the ice. From polarimetric data of a sea surface in the Bering sea, it is observed that e and e(sub 0) are increasing with incident angle and e is greater than e(sub 0) at L band because of the directional feature of sea surface waves. Use of symmetry properties of geophysical media for polarimetric radar calibration is also suggested.

Nghiem, S. V.↗

Performance Prediction of High‐Entropy Perovskites La 0.8 Sr 0.2 Mn x Co y Fe z O 3 with Automated High‐Throughput Characterization of Combinatorial Libraries and Machine Learning

Perovskite oxides form a large family of materials with applications across various fields, owing to their structural and chemical flexibility. Efficient exploration of this extensive compositional space is now achievable through automated high-throughput experimentation combined with machine learning. In this study, we investigate the composition–structure–performance relationships of high-entropy La 0.8 Sr 0.2 Mn x Co y Fe z O 3±𝞭 perovskite oxides (0 < x, y, z <1; x+y+z≈1) for application as oxygen electrodes in Solid Oxide Cells. Following the deposition of a continuous compositional map using thin-film combinatorial pulsed laser deposition, compositional, structural, and performance properties are characterized using six different techniques with mapping capabilities. Random forests effectively model electrochemical performance, consistently identifying Fe-rich oxides as optimal compounds with the lowest area-specific resistance values for oxygen electrodes at 700 °C. Additionally, the models identify a statistical correlation between oxygen sublattice distortion—derived from spectral analysis of Raman-active modes—and enhanced performance.

high entropy oxides↗

Cosmic structure strikes back: The elimination of vector-mediated nonstandard interaction models as a mechanism for sterile neutrino dark matter production

We revisit sterile neutrino production enabled by nonstandard interactions (NSIs) among active neutrinos mediated by new bosons. We focus on vector mediators, including neutrinophilic, gauged 𝐿 𝜇 −𝐿 𝜏 , and 𝐵−𝐿 realizations, that modify in-medium dispersion and scattering, thereby altering the active-sterile conversion history. Building on a novel production framework with NSI thermal potentials and collision integrals, we compute nonthermal phase-space distributions across sterile neutrino mixing and NSI parameters and map each point to an equivalent thermal warm dark matter particle mass 𝑚 th via linear theory transfer function fitting with the cosmological structure formation Boltzmann solver. This enables a direct reinterpretation of state-of-the-art structure formation limits from Milky Way satellites, strong lensing, and the Lyman-𝛼 forest. These limits, in conjunction with x-ray decay searches, as well as results from a wide variety of particle physics experiments allow for a more complete examination of these models. We find that these vector-mediated models are ruled out when the full combination of current constraints, listed above, are taken into account. NSI scalar-mediated models and models with low reheating temperatures remain viable.

cosmology↗

Analysis of ERTS-1 imagery and its application to evaluation of Wyoming's natural resources

The author has identified the following significant results. A summary of the significant results of the studies completed during the July-August, 1973 period includes: (1) ERTS-1 image brightness contrasts can be related to important contrasts in rangeland and forest vegetation communities of the Laramie Basin. (2) Stereoscopic viewing is essential for correct structural interpretation in outcrop patterns in some areas. (3) Complex fracture patterns which may have exerted a controlling influence on intrusive activity in the Absaroka Mountains can be mapped from ERTS. (4) Volcanic lithologies of the Yellowstone region are often differentiated on the basis of their textures, and cannot be successfully mapped by photogeologic interpretation of ERTS-1 imagery. Ground spectral readings confirm a general lack of contrast between these lithologies in the four ERTS-1 MSS bands. (5) Major dune fields can be recognized and defined from ERTS-1 image interpretations and recognition of differences in stabilizing plant communities (some of which may be mappable from ERTS-1) yields information about migration history of the dune fields.

Marrs, R. W.↗

The 2013 FLEX-US Airborne Campaign at the Parker Tract Loblolly Pine Plantation in North Carolina, USA

The first European Space Agency (ESA) and NASA collaboration in an airborne campaign to support ESA's FLuorescence EXplorer (FLEX) mission was conducted in North Carolina, USA during September-October 2013 (FLEX-US 2013) at the Parker Tract Loblolly Pine (LP) Plantation (Plymouth, NC, USA). This campaign combined two unique airborne instrument packages to obtain simultaneous observations of solar-induced fluorescence (SIF), LiDAR-based canopy structural information, visible through shortwave infrared (VSWIR) reflectance spectra, and surface temperature, to advance vegetation studies of carbon cycle dynamics and ecosystem health. We obtained statistically significant results for fluorescence, canopy temperature, and tower fluxes from data collected at four times of day over two consecutive autumn days across an age class chronosequence. Both the red fluorescence (F685) and far-red fluorescence (F740) radiances had highest values at mid-day, but their fluorescence yields exhibited different diurnal responses across LP age classes. The diurnal trends for F685 varied with forest canopy temperature difference (canopy minus air), having a stronger daily amplitude change for young vs. old canopies. The Photochemical Reflectance Index (PRI) was positively correlated with this temperature variable over the diurnal cycle. Tower measurements from mature loblolly stand showed the red/far-red fluorescence ratio was linearly related to canopy light use efficiency (LUE) over the diurnal cycle, but performed even better for the combined morning/afternoon (without midday) observations. This study demonstrates the importance of diurnal observations for interpretation of fluorescence dynamics, the need for red fluorescence to understand canopy physiological processes, and the benefits of combining fluorescence, reflectance, and structure information to clarify canopy function versus structure characteristics for a coniferous forest.

chlorophyll fluorescence; diurnal responses; red S↗

The Characteristic Dimension of Lyman-Alpha Forest Clouds Toward Q0957+561

Far-ultraviolet spectra of the gravitational lens components Q0957+561 A and B were obtained with the Hubble Space Telescope Faint Object Spectrograph to investigate the characteristic dimension of Lyman-alpha forest clouds in the direction of the quasar. If one makes the usual assumption that the absorbing structures are spherical clouds with a single radius, that radius can be found analytically from the ratio of Lyman-alpha lines in only one line of sight to the number in both. A simple power series approximation to this solution, accurate everywhere to better than 1%, will be presented. Absorption lines in Q0957+561 having equivalent width greater than 0.3 A in the observer's frame not previously identified as interstellar lines, metal lines, or higher order Lyman lines were taken to be Ly-alpha forest lines. The existence of each line in this consistently selected set was then verified by its presence in two archival FOS spectra with approximately 1.5 times higher signal to noise than our spectra. Ly-alpha forest lines appear at 41 distinct wavelengths in the spectra of the two images. One absorption line in the spectrum of image A has no counterpart in the spectrum of image B, and one line in image B has no counterpart in image A. Based on the separation of the lines of sight over the redshift range searched for Ly-alpha forest lines, the density of the absorbing clouds in the direction of Q0957+561 must change significantly over a radius R = 160 (+120, -70) h (sup -1) (sub 50) kpc (H (sub 0) 50 h (sub 50) km s (sup -1) kpc (sup -1), q (sub 0) = 1/2). The 95% confidence interval on R extends from (50 950) h (sup -1) (sub 50) kpc.

Dolan, J. F.↗

Monolayer Films of Binary Metal Oxide Nanoparticles for Carbon Nanotube Synthesis

Binary metal oxide nanoparticles (biMO-NPs) combining transition and main-group metals with well-organized atomic architectures have unique potential as robust and economical heterogeneous catalysts. Herein, metal oxide nanoparticles (CoAlxOy) using cobalt and aluminum were synthesized, and their structure, morphology, and chemical composition were investigated using various characterization techniques. The biMO-NPs, which had a Gaussian-type size distribution (∼6 nm), were assembled on plain silicon substrates modified chemically with linker molecules bearing suitable end groups. Surface analysis revealed an ordered, uniform, close-packed arrangement of biMO-NPs forming a monolayer architecture with nanoscale thickness (∼12 nm), high surface uniformity, and negligible defects. The nanoparticle monolayer film (NP-MF) was employed as a catalyst to grow carbon nanotube (CNT) forests via the thermal chemical vapor deposition (CVD) method, similar to those grown from catalyst thin films deposited by physical vapor deposition. Structural characterization confirmed the growth of a dense, uniform, high-quality vertically aligned carbon nanotube (VA-CNT) forest with a length of ∼125 µm, which is comparable to the VA-CNTs grown from expensive thin films. Thus, CNT growth was successfully catalyzed by the biMO-NPs, highlighting a simple and inexpensive alternative for catalyst deposition. In this innovative wet-chemistry approach, the catalyst and catalyst support are combined within a single nanoparticle before NP-MF assembly. Interestingly, this approach provides a scalable and cost-effective pathway for CNT growth, eliminating the need for expensive thin deposition techniques.

Regmi, Bishow [University of Cincinnati]↗