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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18

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NASA NTRS1991

An XPS study of the stability of Fomblin Z25 on the native oxide of aluminum

Thin films of Fomblin Z25, a perfluoropolyalkylether lubricant, were vapor deposited onto clean, oxidized aluminum and sapphire surfaces, and their behavior at different temperatures was studied using x ray photoelectron spectroscopy (XPS) and thermal desorption spectroscopy (TDS). It was found that the interfacial fluid molecules decompose on the native oxide at room temperature, and continue to decompose at elevated temperatures, as previous studies had shown to occur on clean metal. TDS indicated that different degradation mechanisms were operative for clean and oxidized aluminum. On sapphire substrates, no reaction was observed at room temperature. Our conclusion is that the native oxide of aluminum is neither passive nor protective towards Fomblin Z25. At high temperatures (150 C) degradation of the polymer on sapphire produced a debris layer at the interface with a chemical composition similar to the one formed on aluminum oxide. Rubbing a Fomblin film on a single crystal sapphire also induced the decomposition of the lubricant in contact with the interface and the formulation of a debris layer.

Herrera-Fierro, Pilar↗

NASA NTRS1992

X-ray photoelectron spectroscopy study of the stability of Fomblin Z25 on the native oxide of aluminum

Thin films of Fomblin Z25, a perfluoropolyalkylether lubricant, were vapor deposited onto clean, oxidized aluminum, and onto sapphire surfaces, and their behavior at different temperatures was studied using X-ray photoelectron spectroscopy and temperature desorption spectroscopy (TDS). The interfacial fluid molecules decompose on the native oxide at room temperature, and continue to decompose at elevated temperatures, as previous studies had shown to occur on the clean metal. TDS indicated that different degradation mechanisms were operative for clean and oxidized aluminum. On sapphire substrates, no reaction was observed at room temperature. The native oxide of aluminum is neither passive nor protective towards Fomblin Z25. At higher temperatures (150 C), degradation of the polymer on sapphire produced a debris layer at the interface with a chemical composition similar to the one formed on aluminum oxide. Rubbing a Fomblin film on a single crystal sapphire also induced the decomposition of the lubricant in contact with the interface and the formation of a debris layer.

Herrera-Fierro, Pilar↗

NASA NTRS1995

(abstract) A Polarimetric Model for Effects of Brine Infiltrated Snow Cover and Frost Flowers on Sea Ice Backscatter

A polarimetric scattering model is developed to study effects of snow cover and frost flowers with brine infiltration on thin sea ice. Leads containing thin sea ice in the Artic icepack are important to heat exchange with the atmosphere and salt flux into the upper ocean. Surface characteristics of thin sea ice in leads are dominated by the formation of frost flowers with high salinity. In many cases, the thin sea ice layer is covered by snow, which wicks up brine from sea ice due to capillary force. Snow and frost flowers have a significant impact on polarimetric signatures of thin ice, which needs to be studied for accessing the retrieval of geophysical parameters such as ice thickness. Frost flowers or snow layer is modeled with a heterogeneous mixture consisting of randomly oriented ellipsoids and brine infiltration in an air background. Ice crystals are characterized with three different axial lengths to depict the nonspherical shape. Under the covering multispecies medium, the columinar sea-ice layer is an inhomogeneous anisotropic medium composed of ellipsoidal brine inclusions preferentially oriented in the vertical direction in an ice background. The underlying medium is homogeneous sea water. This configuration is described with layered inhomogeneous media containing multiple species of scatterers. The species are allowed to have different size, shape, and permittivity. The strong permittivity fluctuation theory is extended to account for the multispecies in the derivation of effective permittivities with distributions of scatterer orientations characterized by Eulerian rotation angles. Polarimetric backscattering coefficients are obtained consistently with the same physical description used in the effective permittivity calculation. The mulitspecies model allows the inclusion of high-permittivity species to study effects of brine infiltrated snow cover and frost flowers on thin ice. The results suggest that the frost cover with a rough interface significantly increases the backscatter from thin saline ice and the polarimetric signature becomes closer to the isotropic characteristics. The snow cover also modifies polarimetric signatures of thin sea ice depending on the snow mixture and the interface condition.

thin sea ice radar backscatter frost flowers snow ↗

NASA NTRS1978

Catalysts for electrochemical generation of oxygen

Single crystal surfaces of platinum and gold and transition metal oxides of the spinel type were studied to find more effective catalysts for the electrolytic evolution of oxygen and to understand the mechanism and kinetics for the electrocatalysis in relation to the surface electronic and lattice properties of the catalyst. The single crystal studies involve the use of low energy electron diffraction (LEED) and Auger electron spectroscopy as complementary tools to the electrochemical measurements. Modifications to the transfer system and to the thin-layer electrochemical cell used to facilitate the transfer between the ultrahigh vacuum environment of the electron surface physics equipment and the electrochemical environment with a minimal possibility of changes in the surface structure, are described. The electrosorption underpotential deposition of Pb onto the Au(111), (100) and (110) single crystal surfaces with the thin-layer cell-LEED-Auger system is discussed as well as the synthesis of spinels for oxygen evolution studies.

Hagans, P.↗

NASA NTRS1992

Imperfect fractional crystallization of the lunar magma ocean and formation of the lunar mantle: A realistic chemical approach

It is generally considered that lunar mare basalts were generated by the melting of a cumulate mantle formed in an early Moon-wide magma ocean or magmasphere. However, the nature and chemistry of this cumulate mantle and the logistics of its origin have remained elusive. Extensive studies of terrestrial layered mafic intrusions over the past sixty years have emphasized the imperfection of fractional crystallization and attendant crystal-crystal and crystal-liquid separation in a convecting magma chamber. These separations were similarly inefficient during evolution of the lunar magmasphere, allowing for the trapping of interstitial melt and entrainment of a small proportion of less-dense plagioclase into the more-dense mafic cumulate mush. Indeed, petrography of lunar highlands samples demonstrates this well for anorthosites (with 1-10 percent olivine). Therefore, we propose a 'realistic' model for the evolution of the lunar mantle, which takes these observations into consideration, by the imperfect fractional crystallization of an early lunar magma ocean.

Snyder, Gregory A.↗

NASA NTRS1974

Epitaxial growth of 6H silicon carbide in the temperature range 1320 C to 1390 C

High-quality epitaxial layers of 6H SiC have been grown on 6H SiC substrates with the grown direction perpendicular to the crystal c-axis. The growth was by chemical vapor deposition from methyltrichlorosilane (CH3SiCl3) in hydrogen at temperatures in the range of 1320 to 1390 C. Epitaxial layers up to 80 microns thick were grown at rates of 0.4 microns/min. Attempts at growth on the (0001) plane of 6H SiC substrates under similar conditions resulted in polycrystalline cubic SiC layers. Optical and X-ray diffraction techniques were used to characterize the grown layers.

Will, H. A.↗

NASA NTRS1979

Layered synthetic microstructures - Properties and applications in X-ray astronomy

Refinements in vacuum deposition technology have made it possible to produce structures in which two materials are arranged in alternating layers of uniform thickness and as thin as 5 A. Such structures act as Bragg diffractors or 'artificial crystals' for X-rays, as well as they may be regarded as multilayer interference coatings. A dynamical theory is used to show how the properties of layered synthetic microstructures are dependent on the layer materials and thicknesses and how these properties can be tailored to specific applications. Laboratory results at various X-ray wavelengths are presented. In particular, specific X-ray astronomy applications in spectroscopy, imaging, polarimetry and laboratory calibration are discussed.

Underwood, J. H.↗

NASA NTRS1981

High efficiency thin-film GaAs solar cells

The paper demonstrates the feasibility of producing high-efficiency GaAs solar cells with high power-to-weight ratios by organic metallic chemical vapor deposition (OM-CVD) growth of thin epi-layers on suitable substrates. An AM1 conversion efficiency of 18% (14% AM0), or 17% (13% AM0) with a 5% grid coverage is achieved for a single-crystal GaAs n(+)/p cell grown by OM-CVD on a Ge wafer. Thin GaAs epi-layers OM-CVD grown can be fabricated with good crystallographic quality using a Si-substrate on which a thin Ge epi-interlayer is first deposited by CVD from GeH4 and processed for improved surface morphology

Zwerdling, S.↗

NASA NTRS2002

Surface Relaxation in Protein Crystals

Surface X-ray diffraction measurements were performed on (111) growth faces of crystals of the Cellular iron-storage protein horse spleen ferritin. Crystal Trunkation Rods (CTR) were measured. A fit of the measured profile of the CTR revealed a surface roughness of 48 +/- 4.5 A and a top layer spacing contraction of 3.9 +/- 1.5%. In addition to the peak from the CTR, the rocking curves of the crystals displayed unexpected extra peaks. Multiple-scattering is demonstrated to account for them. Future applications of the method could allow the exploration of hydration effects on the growth of protein crystals.

Boutet, S.↗

NASA NTRS1985

Minimizing Convection During Crystal Growth

Buoyant convection during crystal growth from solution minimized in experiment cell using boundary-layer stabilizing configurants such as downward isothermal growth or upward growth into thermal gradient.

Shlichta, P. J.↗

NASA NTRS1999

Blade Heat Transfer Measurements and Prediction in a Transonic Turbine Cascade

Detailed heat transfer measurements and predictions are given for a turbine rotor with 136 deg of turning and an axial chord of 12.7 cm. Data were obtained for inlet Reynolds numbers of 0.5 and 1.0 x 10(exp 6), for isentropic exit Mach numbers of 1.0 and 1.3, and for inlet turbulence intensities of 0.25% and 7.0%. Measurements were made in a linear cascade having a highly three-dimensional flow field resulting from thick inlet boundary layers. The purpose of the work is to provide benchmark quality data for three-dimensional CFD code and model verification. Data were obtained by a steady-state technique using a heated, isothermal blade. Heat fluxes were determined from a calibrated resistance layer in conjunction with a surface temperature measured by calibrated liquid crystals. The results show the effects of strong secondary vortical flows, laminar-to-turbulent transition, shock impingement, and increased inlet turbulence on the surface heat transfer.

Giel, P. W.↗

NASA NTRS1979

Heterojunction semiconductor device

A layer of germanium on a body of P type conductivity single crystal indium phosphide provides a blocking heterojunction. This device will emit light when a suitable voltage is placed thereacross or the device can be used as a photoconductor to generate electrons when light is directed thereon.

Harwylo, Frank Z.↗

NASA NTRS2007

Comparison of CALIPSO-Like, LaRC, and MODIS Retrievals of Ice Cloud Properties over SIRTA in France and Florida during CRYSTAL-FACE

This study compares cirrus particle effective radius retrieved by a CALIPSO-like method with two similar methods using MODIS, MODI Airborne Simulator (MAS), and GOES imagery. The CALIPSO-like method uses lidar measurements coupled with the split-window technique that uses the infrared spectral information contained at the 8.65-micrometer, 11.15-micrometer and 12.05-micrometer bands to infer the microphysical properties of cirrus clouds. The two other methods, sing passive remote sensing at visible and infrared wavelengths, are the operational MODIS cloud products (referred to by its archival product identifier MOD06 for MODIS Terra) and MODIS retrievals performed by the CERES team at LaRC (Langley Research Center) in support of CERES algorithms; the two algorithms will be referred to as MOD06- and LaRC-method, respectively. The three techniques are compared at two different latitudes: (i) the mid-latitude ice clouds study uses 18 days of observations at the Palaiseau ground-based site in France (SIRTA: Site Instrumental de Recherche par Teledetection Atmospherique) including a ground-based 532 nm lidar and the Moderate Resolution Imaging Spectrometer (MODIS) overpasses on the Terra Platform, (ii) the tropical ice clouds study uses 14 different flight legs of observations collected in Florida, during the intensive field experiment CRYSTAL-FACE (Cirrus Regional Study of Tropical Anvils and cirrus Layers-Florida Area Cirrus Experiment), including the airborne Cloud Physics Lidar (CPL) and the MAS. The comparison of the three methods gives consistent results for the particle effective radius and the optical thickness, but discrepancies in cloud detection and altitudes. The study confirms the value of an active remote-sensing method (CALIPSO-like) for the study of sub-visible ice clouds, in both mid-latitudes and tropics. Nevertheless, this method is not reliable in optically very thick tropical ice clouds.

Chiriaco, M.↗

NASA NTRS2002

AFM Studies of Salt Concentration Effects on the (110) Surface Structure of Tetragonal Lysozyme Crystals

Previous high resolution AFM studies of the (110) surface of tetragonal chicken egg white lysozyme crystals had shown that only one of two possible molecular surfaces is present, those constituting the completed 43 helices. These suggested that the crystal growth process was by the solution-phase assembly of the growth units, which then attach to the surface. However, the best fit for the imaged surfaces, vs. those predicted based upon the bulk crystallographic coordinates, were obtained when the packing about the 43 helices was "tightened up", while maintaining the underlying crystallographic unit cell spacing. This results in a widening of the gap between adjacent helices, and the top- most layer(s) may no longer be in contact. We postulated that the tightened packing about the helices is a result of the high salt concentrations in the bulk solution, used to crystallize the protein, driving hydrophobic interactions. Once the crystal surface is sufficiently buried by subsequent growth layers the ratio of salt to protein molecules decreases and the helices relax to their bulk crystallographic coordinates. The crystal surface helix structure is thus a reflection of the solution structure, and the tightness of the packing about the 43 helices would be a function of the bulk salt concentration. AFM images of the (110) surface of tetragonal lysozyme crystals grown under low (2%) and high (5%) NaCl concentrations reveal differences in the packing about the 43 helices consistent with the above proposal.

Pusey, Marc Lee↗

NASA NTRS1982

Use of high L.E.T. radiation to improve adhesion of metals to polytetrafluoroethylene

MgK alpha X-rays (1254 eV) and 2 keV electrons irradiate the surface of polytetrafluoro ethylene (PTFE). The damage is confined to a few tenths of a micron below the surface, and the doses exceed 10 to the eight power rad. X-ray Photoelectron Spectroscopy (XPS) of the irradiated surfaces and mass spectroscopy of the gaseous products of irradiation indicate that the damaged layer is crosslinked or branched PTFE. After either type of irradiation, the surface has enhanced affinity for metals and a lower contact angle with hexadecane. Tape pull tests show that evaporated Ni and Au films adhere better to the irradiated surface. XPS shows the Ni interacts chemically with PTFE forming NiF2 and possibly NiC. However, the gold adhesion and contact angle results indicate that the interaction is, at least in part, chemically nonspecific. Decreased contact angles on FEP Teflon crystallized against gold were attributed to either the presence of a polar oxygen layer or increased physical forces due to greater density. In the case of irradiated PTFE, no oxygen on the surface was observed. The crosslinked structure might, however, have a greater density, thus accounting for the observed increase in adhesion and wettability.

Wheeler, D. R.↗

NASA NTRS2023

The CHROMA Cloud-Top Pressure Retrieval Algorithm for the Plankton, Aerosol, Cloud, Ocean Ecosystem (PACE) Satellite Mission

This paper provides the theoretical basis and simulated retrievals for the Cloud Height Retrieval from O2 Molecular Absorption (CHROMA) algorithm. Simulations are performed for the Ocean Color Instrument (OCI), which is the primary payload on the forthcoming NASA Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission, and the Ocean Land Colour Instrument (OLCI) currently flying on the Sentinel 3 satellites. CHROMA is a Bayesian approach which simultaneously retrieves cloud optical thickness (COT), cloud-top pressure and height (CTP and CTH respectively), and (with a significant prior constraint) surface albedo. Simulated retrievals suggest that the sensor and algorithm should be able to meet the PACE mission goal for CTP error, which is ±60 mb for 65 % of opaque (COT ≥3) single-layer clouds on global average. CHROMA will provide pixel-level uncertainty estimates, which are demonstrated to have skill at telling low-error situations from high-error ones. CTP uncertainty estimates are well-calibrated in magnitude, although COT uncertainty is overestimated relative to observed errors. OLCI performance is found to be slightly better than OCI overall, demonstrating that it is a suitable proxy for the latter in advance of PACE's launch. CTP error is only weakly sensitive to correct cloud phase identification or assumed ice crystal habit/roughness. As with other similar algorithms, for simulated retrievals of multi-layer systems consisting of optically thin cirrus clouds above liquid clouds, retrieved height tends to be underestimated because the satellite signal is dominated by the optically thicker lower layer. Total (liquid plus ice) COT also becomes underestimated in these situations. However, retrieved CTP becomes closer to that of the upper ice layer for ice COT ≈3 or higher.

PACE↗

NASA NTRS1996

Characterization of zinc selenide single crystals

ZnSe single crystals of high quality and low impurity levels are desired for use as substrates in optoelectronic devices. This is especially true when the device requires the formation of homoepitaxial layers. While ZnSe is commercially available, it is at present extremely expensive due to the difficulty of growing single crystal boules with low impurity content and the resultant low yields. Many researchers have found it necessary to heat treat the crystals in liquid Zn in order to remove the impurities, lower the resistivity and activate the photoluminescence at room temperature. The physical vapor transport method (PVT) has been successfully used at MSFC to grow many single crystals of II-VI semiconducting materials including ZnSe. The main goal at NASA has been to try to establish the effect of gravity on the growth parameters. To this effect, crystals have been grown vertically upwards or horizontally. Both (111) and (110) oriented ZnSe crystals have been obtained via unseeded PVT growth. Preliminary characterization of the horizontally grown crystals has revealed that Cu is a major impurity and that the low temperature photoluminescence spectra is dominated by the copper peak. The ratio of the copper peak to the free exciton peak is being used to determine variations in composition throughout the crystal. It was the intent of this project to map the copper composition of various crystals via photoluminescence first, then measure their electrical resistivity and capacitance as a function of frequency before proceeding with a heat treatment designed to remove the copper impurities. However, equipment difficulties with the photoluminescence set up, having to establish a procedure for measuring the electrical properties of the as-grown crystals and time limitations made us re-evaluate the project goals. Vertically grown samples designated as ZnSe-25 were chosen to be measured electrically since they were not expected to show as much variation in their composition through their cross-section as the horizontally grown samples.

Gerhardt, Rosario A.↗

NASA NTRS1980

An experimental investigation of convection in a fluid that exhibits phase change

Convection flows were systematically observed in a layer of fluid between two isothermal horizontal boundaries. The working fluid was a nematic liquid crystal, which exhibits a liquid-liquid phase change at which latent heat is released and the density changed. In addition to ordinary Rayleigh-Benard convection when either phase is present alone, there exist two types of convective motions initiated by the unstable density difference. When a thin layer of heavy fluid is present near the top boundary, hexagons with downgoing centers exist with no imposed thermal gradient. When a thin layer of light fluid is brought on near the lower boundary, the hexagons have upshooting centers. In both cases, the motions are kept going once they are initiated by the instability due to release of latent heat. Relation of the results to applicable theories is discussed.

Fitzjarrald, D. E.↗