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At least 325 records · Page 18

Extension of Clad Damage Propagation Model for Fission Gas Dispersal and Two-Phase Flow Effects in MOOSE SubChannel Module

This report presents an extension of the Clad Damage Propagation (CDAP) model implemented in the MOOSE SubChannel Module (SCM) to capture post-failure fission-gas dispersal and two-phase flow effects in sodium-cooled fast reactor assemblies. The extended model tracks discharged gas axially and radially, computes channel-averaged flow quality and void fraction using a Lockhart–Martinelli framework, evaluates two-phase frictional pressure-drop multipliers, determines inlet mass-flow degradation under fixed core pressures, and applies an intensified-void-based heat-transfer degradation to affected fuel pins. Radial plume expansion is parameterized using mineral-oil jet experiments mapped to sodium conditions via Reynolds–Weber similarity. Implementation details are documented, along with the new methods and user inputs needed to control plume mapping and two-phase behavior. Demonstration simulations for 19- and 37-pin bundles show that breach size and inlet velocity strongly influence propagation potential: small breaches (≤0.5 mm) produce limited degradation while larger breaches (~1 mm) can drive oscillatory temperature spikes and enhanced failure propagation, especially at higher velocities. These results demonstrate that the extended CDAP model provides a more complete framework for quantifying cladding damage propagation and evaluating propagation potential in transient scenarios. The approach remains computationally efficient, consistent with subchannel-level analysis, yet incorporates sufficient physics to bridge localized post-failure effects with bundle- and assembly-scale degradation.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

CO 2 -Responsive Fracturing Fluids for Enhanced Geothermal Systems (Final Report)

Our group has recently developed StimuFrac, a non-toxic stimuli-responsive fracturing fluid consisting of a CO 2 -reactive polymer which has shown at the lab-scale to consistently fracture rock cores at significantly lower net pressures in a range of representative geothermal pressure/temperature conditions. However, until now the mechanism/s responsible for more effective fracturing, of critical importance to optimize fracturing performance as well as strategize injection methodologies for field deployment, was not understood. In this document, we report (1) on the two main mechanisms responsible for fracturing rock at lower net pressures with StimuFrac; (2) the phase behavior of StimuFrac/CO 2 under geothermal wellbore conditions; and (3) based on high-temperature true triaxial stimulations, detailed evidence that StimuFrac/CO 2 is the best performing stimulation fluid under EGS T/P conditions as compared to water, waterless CO 2 , and CO 2 /water fracturing fluids. This is because i) it requires significantly lower volumes of CO 2 due to its reduced leak off into the formation by the crosslinked polymer solution; ii) large fractures can be generated reproducibly at both low and high CO 2 injection flow rates, and iii) the reversible (previously reported) viscosity increase of StimuFrac could be beneficial to transport proppants when they become available for EGS. These results were particularly evident for hot nearly dry rock as well as partially and nearly fully water-saturated granitic rock. GTO requires StimuFrac to be evaluated in fully water-saturated rock to determine whether the above-described performance applies under these conditions. Since (1) GTO considers there is no enough evidence for Sa different StimuFrac formulation to work below 90C (where full water-saturation in an open system is possible) and (2) no polyaxial loading frame larger than a few centimeters that can do hydraulic fracturing tests while maintaining the rock sample fully saturated with water at 200 C exists; PNNL concludes that the only way to determine if StimuFrac represents an advanced fracturing fluid alternative for EGS, is to perform a stimulation in an actual EGS reservoir.

15 GEOTHERMAL ENERGY↗

Chiral, Topological, and Knotted Colloids in Liquid Crystals

The geometric shape, symmetry, and topology of colloidal particles often allow for controlling colloidal phase behavior and physical properties of these soft matter systems. In liquid crystalline dispersions, colloidal particles with low symmetry and nontrivial topology of surface confinement are of particular interest, including surfaces shaped as handlebodies, spirals, knots, multi-component links, and so on. These types of colloidal surfaces induce topologically nontrivial three-dimensional director field configurations and topological defects. Director switching by electric fields, laser tweezing of defects, and local photo-thermal melting of the liquid crystal host medium promote transformations among many stable and metastable particle-induced director configurations that can be revealed by means of direct label-free three-dimensional nonlinear optical imaging. The interplay between topologies of colloidal surfaces, director fields, and defects is found to show a number of unexpected features, such as knotting and linking of line defects, often uniquely arising from the nonpolar nature of the nematic director field. This review article highlights fascinating examples of new physical behavior arising from the interplay of nematic molecular order and both chiral symmetry and topology of colloidal inclusions within the nematic host. Furthermore, the article concludes with a brief discussion of how these findings may lay the groundwork for new types of topology-dictated self-assembly in soft condensed matter leading to novel mesostructured composite materials, as well as for experimental insights into the pure-math aspects of low-dimensional topology.

chirality↗

Development of Antimicrobial PLA Composites for Fused Filament Fabrication

In addition to possessing the desirable properties of being a biodegradable and biocompatible polymer fabricated from renewable resources, poly (lactic acid) (PLA) has useful mechanical and thermal attributes that has enabled it to be one of the most widely-used plastics for medicine, manufacturing, and agriculture. Yet, PLA composites have not been heavily explored for use in 3D-printing applications, and the range of feasible materials for the technology is limited, which inhibits its potential growth and industry adoption. In this study, tunable, multifunctional antimicrobial PLA composite filaments for 3D-printing have been fabricated and tested via chemical, thermal, mechanical, and antimicrobial experiments. Thermally stable antimicrobial ceramics, ZnO and TiO2, were used as fillers up to 30 wt%, and poly (ethylene glycol) (PEG) was used as a plasticizer to tune the physical material properties. Results demonstrate that the PLA composite filaments exhibit the thermal phase behaviors and thermal stability suitable for 3D-printing. Additionally, PEG can be used to tune the mechanical properties while not affecting the antimicrobial efficacy that ZnO and TiO2 imbue.

TiO2↗

Chemistry of vaporization of refractory materials

A discussion is given of the principles of physical chemistry important in vaporization studies, notably the concepts of equilibrium, phase behavior, thermodynamics, solid solution, and kinetics. The important factors influencing equilibrium vaporization phenomena are discussed and illustrated. A proper course of a vaporization study consisting of 9 stages is proposed. The important experimental techniques of Knudsen effusion, Langmuir vaporization and mass spectrometry are discussed. The principles, the factors, the course of a study and the experimental techniques and procedures are illustrated by recent work on the Ti-O system.

Gilles, P. W.↗

Explorer 45 observations of the proton ring current

Explorer 45 satellite data on the stormtime proton ring current are reported and analyzed. Storm-associated variations of equatorially mirroring protons, interactions between the ring current and the plasmapause, and storm recovery phase behavior are discussed. Pitch-angle distributions are plotted as a function of proton energy and radial distance, the structure implying domination of pitch-angle diffusion of ring-current protons in the plasmapause region by resonant interactions with ion cyclotron waves during storm recovery. The anisotropic precipitation in the plasmapause region and the more poleward isotropic precipitation observed at low altitudes outside the plasmapause are compared and distinguished.

Lyons, L. R.↗

An experimental evaluation of the application of the Kirchhoff formulation for sound radiation from an oscillating airfoil

The Kirchhoff integral formulation is evaluated for its effectiveness in quantitatively predicting the sound radiated from an oscillating airfoil whose chord length is comparable with the acoustic wavelength. A rigid airfoil section was oscillated at samll amplitude in a medium at rest to produce the sound field. Simultaneous amplitude and phase measurements were made of surface pressure and surface velocity distributions and the acoustic free field. Measured surface pressure and motion are used in applying the theory, and airfoil thickness and contour are taken into account. The result was that the theory overpredicted the sound pressure level by 2 to 5, depending on direction. Differences are also noted in the sound field phase behavior.

Brooks, T. F.↗

Surface tension and contact angles: Molecular origins and associated microstructure

Gradient theory converts the molecular theory of inhomogeneous fluid into nonlinear boundary value problems for density and stress distributions in fluid interfaces, contact line regions, nuclei and microdroplets, and other fluid microstructures. The relationship between the basic patterns of fluid phase behavior and the occurrence and stability of fluid microstructures was clearly established by the theory. All the inputs of the theory have molecular expressions which are computable from simple models. On another level, the theory becomes a phenomenological framework in which the equation of state of homogeneous fluid and sets of influence parameters of inhomogeneous fluids are the inputs and the structures, stress tensions and contact angles of menisci are the outputs. These outputs, which find applications in the science and technology of drops and bubbles, are discussed.

Davis, H. T.↗

Dust streaks on Mars: Colors and photometry

Photometric studies of crater related bright and dark streaks have strongly supported the hypothesis that the bright streaks are excess dust deposits and dark streaks are erosional windows in a partial dust cover. Red-blue (and red-violet) plots show that bright streaks are consistent with mosaics of bright red dust and background material. Here the plains are also consistent with a partial dust cover; the dark streak is the least covered area. Bright and dark streaks both reverse contrast relative to surrounding plains at phase angles over 100 deg in violet filter images. The similar phase behavior of both bright and dark streaks supports the idea that they are both changes in the amount of dust cover. Red-violet plots of bright streaks are most easily explained by mosaics of optically thick dust and plains material. Lengths of bright streaks are independent of their contrasts. This suggests the streak deposition, if in the mosaic patterns indicated above, is a function of available sites of deposition, rather than atmospheric dust loading. Contrasts of dark streaks with plains indicate the plains have fractional dust covers nealy as great as the maximum additional cover in bright streaks. The bright streaks thus store little of the global supply of dust.

Thomas, P.↗

Mars - Subsurface properties from observed longitudinal variation of the 3.5-mm brightness temperature

Extensive 3.5-mm measurements are reported which show a variation in the brightness temperature of Mars, with the Central Meridian Longitude that is generally in phase with the variation at 2.8 cm and is opposite in sign from the variations at 20 microns. It is pointed out that the phase result is not unexpected, since 3.5 mm is longer than the wavelength at which the phase behavior is expected to change. The result that the 3.5-mm rotation curve amplitude is larger than the amplitudes at both 20 microns and 2.8 cm, however, is unexpected. This result, it is noted, can be explained as a consequence of subsurface scattering from rocks smaller than 1.5 cm in radius. A correlation of subsurface scatterers with the location of the high-thermal inertial regions would be consistent with the hypothesis that rock abundance predominates in determining the thermal inertia.

Epstein, E. E.↗

'Dust' streaks on Mars

Global mapping and photometry of selected areas on Mars are used to investigate the nature of bright and dark wind streaks that extend from topographic obstacles. Occurrence of both bright and dark streaks is strongly latitude dependent and is only weakly correlated with surface properties such as albedo and thermal inertia. Data on the colors, albedos, and phase behavior of streaks are consistent with models of bright streaks as mosaics of plains materials and brighter, redder dust. Less than 20 percent of the ground need be covered by the optically thick dust in the brightest parts of the streaks; the amount of dust in optically thick layers could be as little as 0.001 g/sq cm. Dark streaks can be interpreted as erosional windows in a patchy dust cover. The model of dust deposition in optically thick patches is sedimentologically different from scenarios involving the deposition of ubiquitous, optically thin layers. It has the advantage that large amounts of dust can be deposited without affecting regional albedos.

Thomas, P.↗

Studies of Model Immiscible Systems

The objectives are to use model transparent monotectics to obtain fundamental information applicable to two-phase systems in general, to apply this understanding to materials of interest in the Microgravity Science and Applications program, and to interpret results of flight experimental involving monotectic alloys. A number of model immiscible systems are in use to study various aspects of two-phase behavior within the miscibility gap and during solidification. Particle growth, coalescence and particle motions are under investigation using a holographic microscopy system. The system is capable of working with particle densities up to 10 to the 7th power particles/cubic centimeters through a 100 micron depth and can resolve particles of the order of 2 to 3 micron in diameter throughout the entire cell volume. Particle size, distribution changes with respect to time and temperature are observable from sequential holograms. Initial experiments using diethylene glycol/ethyl salicylate (DEG/ES) have demonstrated the usefulness of the technique. The thermal system controls temperature to at least plus or minus 0.001 K over the course of an experiment. A time-lapse film, made from holograms, of a succinonitrile/water solution shows particle size and number distribution changes with time under isothermal conditions. The observations are consistent with Ostwald ripening theory.

Frazier, D. O.↗

Optical and UV spectroscopy of the peculiar RS CVn system, RT Lacertae

Spectra in the H-alpha and H-beta regions of the peculiar double-lined RS CVn binary, RT Lacertae, were obtained in the fall of 1984. Limited International Ultraviolet Explorer (IUE) long wavelength low and high resolution spectra were obtained concurrently. The ground based spectra have shown an asymmetry with orbital phase in the H-alpha profile. The H-beta profiles were consistent with the same effect. One hemisphere showed excess emission and the other excess absorption, with a broad Gaussian emission component superposed upon the excess H-alpha line. An improved radial velocity curve, giving a better determined mass ratio and geometry was derived. This combined with the radii implied by the rotational broadening of the spectra, showed one component to be 80 to 90% filling the equilibrium Roche surface. The two-faced nature is, therfore, very likely due to mass transfer from the contact component impacting upon its companion. Low resolution ultraviolet data showed that the supposed cooler component is bluer than its companion. High resolution ultraviolet data taken during secondary eclipse showed Mg II emission strength which decreased more slowly than the area visible. The phase behavior of the low resolution data support the former situation, indicating traditional chromospheric activity.

Huenemoerder, D. P.↗

Dynamics of Bridgman-Stockbarger growth of non-dilute binary alloys

The coupling between heat and mass transfer in the Bridgman-Stockbarger growth of nondilute crystals induces growth rate transients that are longer than those caused by heat transfer alone. The dynamics of the diffusion-controlled growth for thermophysical properties representative of Pb(1-x)Sn(x)Te and Hg(1-x)Cd(x)Te are computed from a one-dimensional solidification model which includes melt-crystal phase behavior. Results show that the growth rate response to a step change in pull rate for both systems differs from the exponential decay observed for dilute alloys and that growth rates cannot be inferred from axial segregation data in nondilute systems due to the dependence of the segregation coefficient on composition.

Bourret, E. D.↗

The atmospheric heat source over the Tibetan plateau May-August 1979

Estimates of the time and space variability of the atmospheric heat source over Tibet are presented for the summer of 1979. These estimates rely on new data from the People's Republic of China allowing a better assessment of the surface heat fluxes, and on new satellite data from Nimbus-7 giving the radiation balance at the top of the atmosphere. The estimates of the atmospheric heat source turned out to be considerably smaller than those provided earlier in the literature, mainly because of different assumptions of the drag coefficient. The atmospheric heat source over Tibet is mainly modulated by the release of latent heat. Over the southeastern and southwestern plateau regions the heat source appears to be in phase with the precipitation yield of the Indian summer monsoon, whereas central Tibet reveals an out-of-phase behavior. Over western Tibet there appears to be hardly any net import of moisture from outside the region, whereas the maintenance of the hydrological cycle over eastern Tibet requires moisture flux convergence from outside the region of up to 40 percent of the mean rainfall, in agreement with what is known about the surface hydrology of Tibet.

Chen, L.↗

Optical and UV spectroscopy of the peculiar RS CVn system RT Lacertae

H-alpha and H-beta spectra of the peculiar double-lined RS CVn binary RT Lacertae have been obtained using the IUE, together with a ground-based coude-feed telescope at KPNO. The ground-based spectra show an asymmetry related to the orbital phase in the H-alpha profile. H-beta profiles showed excess emission in one hemisphere and excess absorption in the other, with a broad Gaussian emission component superposed on the excess H-alpha line. A radial velocity curve was derived to estimate the mass ratio and geometry of the system. It is shown that the component of RT Lac fills 80-90 percent of the equilibrium Roche surface. Low-resolution ultraviolet data show that the supposed cooler component is bluer than its companion, suggesting evidence of a scattering shell or a cloud produced by the splash of a gas stream. The phase behavior of the low resolution ultraviolet data support the conclusion that RT Lac is a mass transfer system and that mass transfer is the primary cause of its activity.

Huenemoerder, D. P.↗

Recent research on magnetospheric wave-particle interactions

Highlights of recent Stanford University VLF research in the Antarctic include new observations of wave-induced particle precipitation and controlled experiments on nonlinear wave growth phenomena. Higher-than-expected levels of burst precipitation have been discovered inside the plasmasphere, near L = 2, using subionospheric signal perturbations called 'Trimpi events'. Studies of burst precipitation have been extended to the region poleward of the plasmapause using the Siple transmitter signal as a waveguide probe. Experiments on the 'coherent wave instability', using the amplitude and frequency modulation capability of the new Siple transmitter, have produced exciting new results. Examples are: (1) better definition of the power threshold for the stimulation of temporal wave growth, (2) generation of strong sidebands by unamplified 'beat' waves and (3) generation of chorus-like elements within a band of simulated hiss. Using a new digital processing technique developed at Stanford, new features of the phase behavior of growing waves have been found. Opportunities for extending these experiments are discussed.

Helliwell, R. A.↗

Mixing-induced fluid destratification and ullage condensation

In many applications, on-orbit storage and transfer of cryogens will require forced mixing to control tank pressure without direct venting to space. During a no-vent transfer or during operation of a thermodynamic vent system in a cryogen storage tank, pressure control is achieved by circulating cool liquid to the liquid-vapor interface to condense some of the ullage vapor. To measure the pressure and temperature response rates in mixing-induced condensation, an experiment has been developed using Freon 11 to simulate the two-phase behavior of a cryogen. A thin layer at the liquid surface is heated to raise the tank pressure, and then a jet mixer is turned on to circulate the liquid, cool the surface, and reduce the pressure. Many nozzle configurations and flow rates are used. Tank pressure and the temperature profiles in the ullage and the liquid are measured. Initial data from this ground test are shown correlated with normal-gravity and drop-tower dye-mixing data. Pressure collapse times are comparable to the dye-mixing times, whereas the times needed for complete thermal mixing are much longer than the dye-mixing times.

Meserole, Jere S.↗