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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Synthesis, antibiotic structure–activity relationships, and cellulose dissolution studies of new room-temperature ionic liquids derived from lignin

Ionic liquids (ILs) are promising pretreatment solvents for lignocellulosic biomass, but are largely prepared from petroleum precursors. Benzaldehydes from depolymerized lignin, such as vanillin, syringaldehyde, and 4-methoxy benzaldehyde, represent renewable feedstocks for the synthesis of ionic liquids. We herein report syntheses of novel lignin-derived ionic liquids, with extended N -alkyl chains, and examine their melting points, cellulose dissolution capacities, and toxicity profiles against Daphnia magna and E. coli strain 1A1. The latter organism has been engineered to produce isoprenol, a drop-in biofuel and precursor for commodity chemicals. The new N,N -diethyl and N,N -dipropyl methyl benzylammonium ILs were liquids at room temperature, showing 75–100 °C decreased melting points as compared to their N,N,N -trimethyl benzylammonium analog. Extension of N -alkyl chains also increased antibacterial activity threefold, while ionic liquids prepared from vanillin showed 2- to 4-fold lower toxicity as compared to those prepared from syringaldehyde and 4-methoxybenzaldehyde. The trend of antibacterial activity for anions of lignin-derived ILs was found to be methanesulfonate < acetate < hydroxide. Microcrystalline cellulose dissolution, from 2 to 4 wt% after 20 min at 100 °C, was observed in all new ILs using light microscopy and IR spectroscopy. Ionic liquids prepared from H-, S- and G-lignin oxidation products provided differential cytotoxic activity against E. coli and D. magna , suggesting these compounds could be tailored for application specificity within a biorefinery.

09 BIOMASS FUELS↗

A Tandem Electrolysis Process for Multi-Carbon Chemical Production from Carbon Dioxide (Final Technical Report)

a two-step CO 2 electroreduction process for selective production of acetate and ethylene was successfully developed at the kW-scale. The CO 2 and CO electrolyzers were first investigated individually on the Watt-scale to achieve high current densities and more durable operation by using a reinforced GDL. High CO 2 conversion was obtained in the first CO 2 electrolyzer to produce a CO-dominant gas stream with minimal CO 2 , and highly pure acetate stream was produced in the second CO electrolyzer by using NiFe anode, which promoted alcohol oxidation to carboxylates. The two-step process operated stably for 200 h with acetate and ethylene as the major C 2+ products. Degradation mechanism study revealed that the flooding and the salt formation in the GDL is likely the biggest contributor to the performance degradation for both CO 2 and CO electrolyzers. A 1,000 cm 2 CO electrolyzer stack was then designed, fabricated, and operated up to a total current of 300 A along with a 500 cm 2 CO 2 electrolyzer stack which was operated up to a total current of 100 A. The CO electrolyzer stack demonstrated good stability at 300 A for at least 125 h at a carbon selectivity >96%. The impact of CO 2 , O 2 , N 2 , SO x , and NO x gas impurities on the CO electrolyzer stack was studied and a relatively high resistance to these contaminants was demonstrated. Electroreduction of CO 2 into acetic acid was also demonstrated to be environmentally favorable when compared to the traditional production of acetic acid when powered by renewable electricity. Additionally, electricity cost was identified as the primary source of cost sensitivity indicating substantial economic improvements could be achieved by continuing to drive down the cost of renewable electricity. Overall, the presented approach demonstrates the feasibility of the two-step electrochemical CO 2 reduction process for the effective production of C 2+ products at the kW-scale which should inspire future scaling efforts accelerating commercialization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Decarbonization of the power sector with CCS: Case study in two regions in the U.S. and lessons for Latin America

This work consists of estimates of potential changes in the total systems cost (TSC) of two RTOs of the United States (U.S.), MISO-N and SPP RTO West, under the traditional decarbonization pathway of replacement of fossil-power plants with variable renewable energy (VRE) and the less traditional pathway of retrofitting fossil fuel units with carbon capture and storage (CCS). Although the power mixes of MISO-N and SPP RTO West are particular to these regions, results can apply to other regions, including Latin American countries that are planning to decarbonize their power sectors. This case study serves to highlight lessons on differences in technology costs between these two pathways, as well as the cost associated with decarbonization rates close to 100%.

Pena-Cabra, Ivonne A.↗

Analysis of AC-DC Converters for Grid-tied High Temperature Steam Electrolysis Systems

Grid-tied HTSE systems have the prospects to produce clean hydrogen enabling power and broad energy systems decarbonization. Most commercially available power electronic converter systems (PECS) are designed for batteries, solar PVs, wind, and other well-established renewable energy resources. Standards (such as IEEE 1547, UL 1741, CA Rule-21, HI Rule-14) exist for PECS used for renewable energy systems such as battery storage and solar PVs. However, those that consider the dynamic behavior of HTSEs and that can be used for large-scale H2 systems are yet to be developed. This paper investigates the performance of these PECS for the HTSE application that are set up at the Idaho National Laboratory for hydrogen production testing, research and development. In particular, the performance analysis of two grid-tied PECS (A and B) is conducted for a 100 kW solid oxide HTSE system. System A consists of 6 units of 30kW MOSFET-switched bidirectional AC-DC rectifier while system B has a single unit of 150kW thyristor-switched ACDC rectifier. Both systems are connected to the HTSE stacks via a DC-DC converter. Different operational conditions of the HTSE system are tested to analyze the dynamic response of the HTSE’s PECS. The experimental results show the need to develop advanced control strategies for PECS that incorporates the dynamics of HTSE systems for improved performance.

08 - HYDROGEN↗

Analysis of AC-DC Converters for Grid-tied High Temperature Steam Electrolysis Systems

Grid-tied HTSE systems have the prospects to produce clean hydrogen enabling power and broad energy systems decarbonization. Most commercially available power electronic converter systems (PECS) are designed for batteries, solar PVs, wind, and other well-established renewable energy resources. Standards (such as IEEE 1547, UL 1741, CA Rule-21, HI Rule14) exist for PECS used for renewable energy systems such as battery storage and solar PVs. However, those that consider the dynamic behavior of HTSEs and that can be used for large-scale H2 systems are yet to be developed. This paper investigates the performance of these PECS for the HTSE application that are set up at the Idaho National Laboratory for hydrogen production testing, research and development. In particular, the performance analysis of two grid-tied PECS (A and B) is conducted for a 100 kW solid oxide HTSE system. System A consists of 6 units of 30kW MOSFET-switched bidirectional AC-DC rectifier while system B has a single unit of 150kW thyristor-switched AC-DC rectifier. Both systems are connected to the HTSE stacks via a DC-DC converter. Different operational conditions of the HTSE system are tested to analyze the dynamic response of the HTSE’s PECS. The experimental results show the need to develop advanced control strategies for PECS that incorporates the dynamics of HTSE systems for improved performance.

High temperature steam electrolysis↗

Floating solar panels on reservoirs impact phytoplankton populations: A modelling experiment

Floating solar photovoltaic (FPV) deployments are increasing globally as the switch to renewable energy intensifies, representing a considerable water surface transformation. FPV installations can potentially impact aquatic ecosystem function, either positively or negatively. However, these impacts are poorly resolved given the challenges of collecting empirical data for field or modelling experiments. In particular, there is limited evidence on the response of phytoplankton to changes in water body thermal dynamics and light climate with FPV. Given the importance of understanding phytoplankton biomass and species composition for managing ecosystem services, we use an uncertainty estimation approach to simulate the effect of FPV coverage and array siting location on a UK reservoir. FPV coverage was modified in 10% increments from a baseline with 0% coverage to 100% coverage for three different FPV array siting locations based on reservoir circulation patterns. Results showed that FPV coverage significantly impacted thermal properties, resulting in highly variable impacts on phytoplankton biomass and species composition. The impacts on phytoplankton were often dependent on array siting location as well as surface coverage. Changes to phytoplankton species composition were offset by the decrease in phytoplankton biomass associated with increasing FPV coverage. We identified that similar phytoplankton biomass reductions could be achieved with less FPV coverage by deploying the FPV array on the water body's faster-flowing area than the central or slower flowing areas. The difference in response dependent on siting location could be used to tailor phytoplankton management in water bodies. Simulation of water body-FPV interactions efficiently using an uncertainty approach is an essential tool to rapidly develop understanding and ultimately inform FPV developers and water body managers looking to minimise negative impacts and maximise co-benefits.

14 SOLAR ENERGY↗

FY24 LLNL Laboratory Directed Research and Development (LDRD) Project Accomplishments

Large duration energy storage is the key to couple renewable energy generation with power supply. This project aimed to advance the durability of a low-cost and eco-friendly flow battery technology based on iron chemistry to speed up the technology readiness level rapidly and radically. A novel device which is called “an artificial kidney” was innovated through disruptive research to integrate with the flow battery for rebalancing capacity. Key results at 50 cm2 scale demonstrates that artificial kidney enabled retaining the storage capacity of the flow battery over 100 cycles. Comparison of outcome of this work showing 0% capacity degradation to the state-of-the-art technology corroborates that this novel system is a game changing innovation.

99 GENERAL AND MISCELLANEOUS↗

Nondimensional convection numbers modeling thermally stratified storage tanks: Richardson's number and hot-water tanks

Thermally stratified storage tank studies have spanned over 50 years to increase the thermal storage efficiency and accurate prediction of the outlet temperature particularly for solar applications. The studies have reviewed and modeled the jet and plume flow phenomena inside the tank due to the inlet mixing and stratification level. Kelvin–Helmholtz and Rayleigh–Taylor instabilities are the major drivers of the mixing in these tanks. Momentum jets deflecting off walls at the bottom of the tank also create significant mixing. Reviewing Richardson models shows that the categorization was based on the range of Reynolds numbers at the inlet. Unfortunately, the use of superficial velocity in calculating the Richardson number results in critical values in the literature ranging from below 0.25 to 100. The most used length scale associated with these flows is an inertial scale based on the tank height or diameter although the mixing can occur at a relatively smaller scale. The various inlet devices and a large span of flow rates experienced in thermally stratified storage tanks requisite the use of the Reynolds number in combination with a convection number for accurate one dimensional models that predict performance over the long-term. The evaluation of peak shifting of electric loads leveraging renewable sources for applications, including residential hot-water tanks, commercial water tanks, and large-scale chilled water storage tanks, require these models. Finally, this paper is focused on establishing the significance of the convection numbers in conjunction with the Reynolds number for modeling the thermal stratification in storage tanks.

14 SOLAR ENERGY↗

Decarbonization of the power sector with CCS: Case study in two regions in the U.S. and lessons for Latin America

This paper estimates potential changes in the total systems cost (TSC) of two RTOs of the United States (U.S.), MISO-N and SPP RTO West, under the traditional decarbonization pathway of replacement of fossil-power plants with variable renewable energy (VRE) and the less traditional pathway of retrofitting fossil fuel units with carbon capture and storage (CCS). Although the power mixes of MISO-N and SPP RTO West are particular to those regions, the results can apply to other regions, including Latin American countries that are planning to decarbonize their power sectors. This case study serves to highlight lessons on the difference of technology costs between these two pathways, as well as the cost associated with decarbonization rates close to 100%.

Pena-Cabra, Ivonne A.↗

Proceedings of the 2021 Airborne Wind Energy Workshop

On March 2-3, 2021, the National Renewable Energy Laboratory (NREL) conducted a virtual workshop to evaluate the status, potential development, and technical viability of AWE systems as a source of energy in the United States. Stakeholder input provided at the workshop will contribute to the report to Congress. This report summarizes key workshop findings, current technology research and development activities in the United States, and opportunities and potential modes of collaboration and coordination for future technology research and development activities. The workshop focused on U.S. stakeholders in AWE, with approximately 100 experts and industry stakeholders from AWE technology developers, operators, engineering firms, consultants, government, national laboratories, and university researchers. The workshop began with an explanation from DOE's Wind Energy Technologies Office (WETO) Technology Manager, Ben Hallissy, of the context and purpose of the workshop, including a request from Congress that the U.S. Department of Energy (DOE) deliver a "report on the potential for, and technical viability of, airborne wind energy systems to provide a significant source of energy in the United States, including a summary of research, development, demonstration, and commercialization needs, including an estimate of Federal funding requirements, to further examine and validate the technical and economic viability of airborne wind energy concepts over the 10-year period." The workshop began with brief introductions from attendees who explained their interest in AWE. Nicolas El Hayek of Planair summarized the proceedings from the AWE workshop held in September 2020 by the International Energy Agency (IEA) Wind Task 11. This was followed by a presentation by Roland Schmehl of TU-Delft summarizing European AWE R&D efforts. Chris Vermillion of North Carolina State University and Jason Jonkman of NREL presented an overview of U.S. R&D efforts. Then five panelists discussed AWE markets, sizes of AWE systems, challenges, and opportunities. Panelists included: Cristina Archer, professor at the College of Earth, Ocean, and Environment and associate director at the Center for Research in Wind (CReW) at the University of Delaware; Stephan Brabeck, chief technology officer at SkySails; Thierry Delahave, innovation and technology development lead at Saipem; Rob Creighton, founder and chief executive officer at WindLift; and David Schaefer, founder and chief executive officer at eWind Solutions. The second day of the workshop began with a brief overview of five key topics that are crucial to enabling AWE in the United States. These topics range from estimates of the U.S. wind resource, technical generation potential, economic analysis, environmental challenges, status of current technology and R&D activities, and needed activities to enable commercialization of AWE. This set the stage for a robust discussion in breakout groups where individuals could offer their opinions on the potential opportunities for AWE in the United States. The following topics were discussed in the breakout groups: resource potential and energy output, technical potential, social and environmental impacts, and permitting, techno-economic analysis and markets, technology assessment and upscaling and demonstration and commercialization needs. The second day concluded with reports by the NREL research team, communicating the key themes and outcomes from each of the breakout group discussions.

17 WIND ENERGY↗

Final Scientific Technical Report for "Microgrid RD&D and Testing of PIDC and PWD Systems"

Alstom Grid Inc’s (ALSTOM Grid) Research Design and Development (RD&D) project, “Microgrid RD&D and Testing for PIDC and PWD” was conducted in partnership with Philadelphia Industrial Development Corporation (PIDC) in its role as owner’s representative and manager of a vibrant commercial and industrial community, involving critical loads in one of the nation’s largest unregulated, non-military electric distribution systems. PIDC needed to develop solutions to address the planned considerable growth in Distributed Energy Resources (DER) Combined Heat Plan (CHP), Renewables, Distributed Generation (DG), Demand Response (DR) and Storage. In supporting the corporate objective, PIDC needed a new class of control systems for achieving enhanced energy resilience of their critical infrastructure operation during adverse conditions together with carbon emission reduction and optimization of the overall system operation economics through system energy efficiency during normal and emergency operating conditions. Additionally, PIDC anticipated the need to support a new class of commercial agreements with tenants, such as those for Urban Outfitters, for guaranteed one hundred percent (100%) grid resilience and electric power supply in case of utility outage conditions. The project was designed to address the challenges for the commercial & industrial (C&I) communities. But more importantly, the project included development of scalable and replicable solutions intended to target a multitude of the nation’s electric distribution communities. The project researched and developed a fully comprehensive prototype consisting of microgrid operation and control functions including islanding, synchronization and reconnection, protection, voltage, frequency, and power quality management, dispatch, and system resiliency. The project provided the foundation required to significantly enhance the overall national objectives set by the DOE for energy resilience, emission reduction and system energy efficiency improvement, including protection of critical infrastructure and public resources.

14 SOLAR ENERGY↗

Techno-economic Analysis and Life-Cycle Analysis of Renewable Diesel Fuels Produced with Waste Feedstocks

Wet waste feedstocks represent an important category of resources that could be utilized to produce biofuels. Diversion of the wet waste resources from going through conventional waste management practices to utilization as feedstocks for energy production also benefits from avoided cost and pollutant emissions of waste management and disposal. This study investigates the economic and environmental implications of producing bio-blendstocks for mixing controlled compression ignition (MCCI) engines from two waste-to-fuel pathways: hydroprocessed esters and fatty acids (HEFA) from yellow grease, and swine manure hydrothermal liquefaction (HTL) followed by biocrude upgrading. Detailed process models were developed for both pathways, which informed the techno-economic analysis (TEA) and life-cycle analysis (LCA). Conventional swine manure management practice was also modeled in detail as the business-as-usual (BAU) scenario for the swine manure HTL pathway. The estimated minimum fuel selling prices (MFSP) were $4.47/gasoline gallon equivalent (GGE) and $3.57/GGE for the yellow grease to HEFA and swine manure HTL pathways, respectively. The life-cycle greenhouse gas (GHG) emissions of the two pathways were 11.2 and -33.3 g CO2e/MJ, respectively, for the yellow grease to HEFA and swine manure HTL pathways. The credits of avoided emissions from conventional swine manure management were the main reason for the negative GHG emissions of the swine manure HTL pathway. The marginal GHG emissions abatement costs were estimated to be $100 – $253/tonne CO2e and $5 – $103/tonne CO2e for the yellow grease HEFA and swine manure HTL pathways, respectively, for a diesel price ranging between $2.0/GGE and $3.5/GGE. Since the yellow grease HEFA pathway is already commercialized, it can benefit from the $200/tonne carbon credit in the California Low Carbon Fuel Standard (LCFS) market, which could help the yellow grease HEFA pathway to achieve near-zero marginal GHG emissions abatement cost.

renewable diesel, techno economic analysis, life c↗

Big Adaptive Rotor Phase I Final Report

The Big Adaptive Rotor (BAR) project was initiated by the U.S. Department of Energy (DOE) in 2018 with the goal of identifying novel technologies that can enable large (>100 meter [m]) blades for low-specific-power wind turbines. Five distinct tasks were completed to achieve this goal: 1. Assessed the trends, impacts, and value of low-specific-power wind turbines; 2. Developed a wind turbine blade cost-reduction road map study; 3. Completed research-and-development opportunity screening; 4. Performed detailed design and analysis; and, 5. Assessed low-cost carbon fiber. These tasks were completed by the national laboratory team consisting of Sandia National Laboratories (Sandia), the National Renewable Energy Laboratory (NREL), and Lawrence Berkeley National Laboratory.

17 WIND ENERGY↗

Grand Challenges in the Science of Making Torque from Wind: Then and Now

Shifting the electricity supply to renewable sources within the next two decades is the first step in decarbonizing the energy sector, and wind energy will play a central role in enabling this rapid energy transition to clean energy. The international wind energy research community - including NREL researchers - has determined that for wind power to fulfill its expected role as a major global supplier of carbon-free energy, critical challenges around the design, development, and deployment of wind energy must be addressed - quickly. Paul Veers and other NREL researchers joined 100 worldwide wind energy experts in writing a series of 10 articles for publication in Wind Energy Science. With the support and guidance of the European Academy of Wind Energy Publications Committee, the articles synthesize and clarify the most critical wind energy science needs. This presentation introduces the concept of the Grand Challenges and its 10 articles.

decarbonization↗

Electrification pathways for U.S. passenger vehicles

As electric vehicle (EV) adoption continues to accelerate, we explore the implications of different adoption trajectories that achieve a full transition to EVs by 2050 for U.S. light-duty passenger vehicles (LDVs). Using a vetted transportation system model, we find that achieving 100% EV sales by 2040 would decrease tailpipe greenhouse gases (GHGs) by 90% between 2022 and 2050, leaving about 45 million gasoline vehicles on the road. Achieving 100% sales by 2035, tailpipe emissions decrease 93%, with about 28 million gasoline vehicles on the road in 2050 (9% of stock). Slower EV adoption, reaching 100% sales by 2045, would result in 69 million gasoline vehicles on the road in 2050. Fully electrifying passenger vehicles by 2050 would require a full transition to EVs sales in the 2030s coupled with either changes to mobility, or an accelerated stock turnover in the 2040s with additional 19–30% annual LDV sales.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Gaps in global wildlife trade monitoring leave amphibians vulnerable

As the biodiversity crisis continues, we must redouble efforts to understand and curb pressures pushing species closer to extinction. One major driver is the unsustainable trade of wildlife. Trade in internationally regulated species gains the most research attention, but this only accounts for a minority of traded species and we risk failing to appreciate the scale and impacts of unregulated legal trade. Despite being legal, trade puts pressure on wild species via direct collection, introduced pathogens, and invasive species. Smaller species-rich vertebrates, such as reptiles, fish, and amphibians, may be particularly vulnerable to trading because of gaps in regulations, small distributions, and demand of novel species. Here, we combine data from five sources: online web searches in six languages, Convention on International Trade in Endangered Species (CITES) trade database, Law Enforcement Management Information System (LEMIS) trade inventory, IUCN assessments, and a recent literature review, to characterise the global trade in amphibians, and also map use by purpose including meat, pets, medicinal, and for research. We show that 1215 species are being traded (17% of amphibian species), almost three times previous recorded numbers, 345 are threatened, and 100 Data Deficient or unassessed. Traded species origin hotspots include South America, China, and Central Africa; sources indicate 42% of amphibians are taken from the wild. Newly described species can be rapidly traded (mean time lag of 6.5 years), including threatened and unassessed species. The scale and limited regulation of the amphibian trade, paired with the triptych of connected pressures (collection, pathogens, invasive species), warrants a re-examination of the wildlife trade status quo, application of the precautionary principle in regard to wildlife trade, and a renewed push to achieve global biodiversity goals.

Hughes, Alice C.↗

Evaluating the effect of meso/submesoscale current–wave interactions on wave energy resource characterization at northeast U.S. coast

Wave energy is a promising renewable resource, but accurate assessment is difficult in regions with strong currents due to wave–current interactions (WCI). Here, this study develops a two-way coupled WCI model within the Coupled Ocean Atmosphere Wave Sediment Transport (COAWST) framework at 2 km resolution to improve wave energy characterization along the northeastern U.S. coast, including the Mid-Atlantic Bight and Gulf of Maine. The model integrates WaveWatchIII (WWIII) and the Regional Ocean Modeling System (ROMS) to enhance wave hindcasting by accounting for Doppler-shift, refraction, and nonlinear energy exchanges. Validation against buoy and satellite observations confirms model accuracy. Analysis shows that Doppler-shifting can alter wave power density by over 20%, while strong current gradients and shear distort wave crests via focusing/defocusing and stretching/squeezing, modifying wave direction and frequency. These processes together can induce wave power fluctuations of up to 40% on synoptic scales. Applying a 2.5 MW Ocean Energy Converter power matrix shows that WCI may change harvested energy by up to 100% in shallow-waters and 60% in deep-waters. These results underscore the importance of incorporating nonlinear WCI for reliable wave climate predictions and resource assessments in energetic coastal regions.

doppler-shift↗

Understanding Multifamily Energy Use in the Colorado Mountains: Building Stock Segmentation for Retrofit Planning

This report is an addendum to a publication series that focuses on approximately 100 different local geographies, or "clusters". This addendum expands the report series to include large multifamily building characteristics as well as energy and emission data for each local geography. The intention of this addendum is to help policymakers at the city, county, and state levels better understand building energy use and emissions in large multifamily buildings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗