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At least 343 records · Page 19

Photoelectrochemical etching of silicon carbide (SiC) and its characterization

Silicon carbide (SiC) is an attractive semiconductor material for high speed, high density, and high temperature device applications due to its wide bandgap (2.2-3.2 eV), high thermal conductivity, and high breakdown electric field (4 x 10(exp 6) V/cm). An instrumental process in the fabrication of semiconductor devices is the ability to etch in a highly controlled and selective manner for direct patterning techniques. A novel technique in etching using electrochemistry is described. This procedure involves the ultraviolet (UV) lamp-assisted photoelectrochemical etching of n-type 3C- and 6H-SiC to enhance the processing capability of device structures in SiC. While under UV illumination, the samples are anodically biased in an HF based aqueous solution since SiC has photoconductive properties. In order for this method to be effective, the UV light must be able to enhance the production of holes in the SiC during the etching process thus providing larger currents with light from the photocurrents generated than those currents with no light. Otherwise dark methods would be used as in the case of p-type 3C-SiC. Experiments have shown that the I/V characteristics of the SiC-electrolyte interface reveal a minimum etch voltage of 3 V and 4 V for n- and p-type 3C-SiC, respectively. Hence it is possible for etch-stops to occur. Etch rates calculated have been as high as 0.67 micrometer/min for p-type, 1.4 micrometer/min for n-type, and 1.1 micrometer/min for pn layer. On n-type 3C- SiC, an oxide formation is present where after etching a yellowish layer corresponds to a low Si/C ratio and a white layer corresponds to a high Si/C ratio. P-type 3C-SiC shows a grayish layer. Additionally, n-type 6H-SiC shows a brown layer with a minimum etch voltage of 3 V.

Collins, D. M.↗

The Relationship Between X-Rays and Relativistic Jets

We present recent multiwaveband observations centered on X-ray monitoring of blazars and the radio galaxy 3C 120 with the RXTE satellite, In 3C 120, we observed four X-ray dips, each followed by ejections of superluminal radio knots down the jet. This behavior, similar to that of the microquasar GRS 1915+105, is interpreted as infall of a piece of the inner accretion disk causing ejection of energy into the relativistic jet. The X-ray emission from the quasars PKS 1510-089, 3C 279, and 3C 273 is highly variable on timescales as short as approximately 1 day. Over 2 years, X-ray flares in PKS 1510-089 occurred about 2 weeks after radio outbursts, which can be explained by light-travel delays. In 3C 279 the X-ray and optical variations are usually well correlated, with very little, if any, time delay. We conclude that the X-ray and optical emission from blazars occurs near the radio core rather than close to the black hole.

Marscher, A. P.↗

Search for the NΔ resonance in the 𝛾𝑑 → 𝑑𝜋 +𝜋 − reaction

A dibaryon which is an object with baryon number B = 2 has been studied for a long time. Dyson and Xuong classified non-strangeness dibaryon states based on SU(6) symmetries in 1960?s. In the framework, the deuteron is classified as one of the sextet states of dibaryons. Although dibaryon have been an interesting subject of research for a long time, most of the experimental studies up to the early 2000?s were unsuccessful. The CELCIUS/WASA collaboration reported this state via the double-pionic fusion reaction (?= ! 3c0c0) in 2009. Thereafter, the WASA-at-COSY collaboration revealed properties of the isoscaler resonance state via the ?= ! 3c0c0 reaction in 2011. The dibaryon resonance state with isospin ? = 0 and spin ( = 3 thought to be a ?03 which was predicted by Dyson and Xuong at 2.35 GeV?22 with a configuration of ??. The reported mass and width of that state were 2?37 GeV?22 and 0?07 GeV?22, espectively. The mass was ?0?08 GeV?22 smaller than that of 2?, the width was narrower than that of single ?. This surprising result made dibaryon study come back into the limelight. ?12 is one of the dibaryon states classified by Dyson and Xuong with isospin ? = 1, spin ( = 2. This state can be regarded as an s-wave #? resonance. ?12 is an interesting state from the point of view of the possibilities of existence as an internal structure of ?03 and contribution to many-body effects in nuclei. Though there were some experimental clues and theoretical studies of this state, it was unclear whether the obtained experimental results represented a real resonance or not due to the difficulty of separation from kinematical effects. Very recently, the FOREST group at Tohoku University reported a photoproduced isovector dibaryon state at mass of 2.14 GeV?22 in the 3c0 invariant mass spectra of the W3 ! 3c0c0 reaction. The most probable ?% configuration was 2¸ although they didn?t exclude the possibility of ?% = 1¸ or 3?. They separated the dibaryon production process from conventional pion production process for the first time using angular distribution of deuteron. We investigated the W3 ! 3c¸c? reaction for study of a possible #? dibaryon state using a deuterium target at the Research Center for Electron Photon Science, Tohoku University, Japan. In the experiment, ?3 ? 1012 tagged photon beam at energies ranging from 0.8 to 1.1 GeV was impinged to the liquid deuterium target (?520 mg?cm2) and the charged particles in the final state: deuteron, c¸, and c?, were detected by a magnetic spectrometer with a large solid angle named NKS2. NKS2 had capabilities of reconstructing momentum of charged particles, multi-track analysis, and ??c separation. We performed two different analyses named 2-track analysis and 3-track analysis. The 2-track (3-track) analysis was for events in which two (three) particles of 3c¸c? in the final state, including deuteron, were detected by NKS2. In the 3-track and 2-track analysis, ?2000? ?15000 events were identified as the W3 ! 3c¸c? reaction events, respectively. The 2-track analysis with higher statistics was mainly used to derive the cross sections, and the 3-track analysis was used to check the consistency of the 2-track analysis. In this thesis, we have shown the total cross section, the differential cross sections of the W3 ! 3c¸c? reaction in the region of jC j ¡ 0?15 GeV2. This is the world?s first measurement of this reaction in this energy region. Dibaryon resonance structures were observed below the #? threshold in the differential cross section of the invariant mass of 3c?. The mass and width of the structure were consistent with these of ?12 measured by the W3 ! 3c0c0 reaction. The mechanism of the production process was discussed based on the angular distribution of emitted deuteron.

Toyama, Yuichi↗

Balancing moisture and oxygen can match the crystallization dynamics of inert halide perovskite processing

Understanding crystallization in ambient environments is essential for scaling the fabrication of halide perovskite solar cells. Antisolvent-free perovskite deposition offers improved compatibility with high-throughput processing but introduces distinct crystallization dynamics relative to the more ubiquitous use of antisolvents in lab-scale perovskite fabrication. These dynamics are driven by interactions between solutes, solvent and the deposition environment. Using in situ wide-angle X-ray scattering during spin-coating and annealing, we demonstrate how relative humidity (RH) and oxygen, can be tuned to drive polytype evolution during ambient crystallization of formamidinium lead iodide to match that of inert synthesis and achieve comparable film and device quality. In an inert (N 2 ) environment, we find that perovskite films follow a well-established 2H → 3C phase transformation with a short period of coexistence of the 4H and 6H phase during heating. During crystallization in dry air (RH 0%), the added presence of oxygen leads to the dominance of 4H intermediate for an extended duration, establishing a 2H → 4H → 3C pathway. Introducing low humidity (RH 10%) suppresses the 4H phase to a short-lived intermediate above 100 °C, facilitating a more direct transition to the desired 3C phase and almost replicating the crystallization behavior observed under inert conditions. Interestingly, films crystallized under RH 10% show a lower onset temperature for the perovskite 3C phase than under N 2 . At higher humidity (RH 40%), the strong interaction of oxygen and moisture with iodoplumbates appears to stabilize higher order polytypes (4H and 6H). Devices fabricated under RH 10% achieve higher efficiency and enhanced stability compared to those produced under inert atmosphere. These findings provide mechanistic insight into crystallization pathways in different environments and provide a framework to transfer processes from inert to ambient conditions. The results highlight the critical role of controlled humidity in tuning antisolvent-free perovskite crystallization for scalable processing.

Hossain, Maimur [Univ. of California, San Diego, C↗

Mg and native defects in cubic silicon carbide from first principles

The diffusion of Mg defects in 3C-SiC is studied using the density functional theory. Mg has the highest burn-in rate as a transmutant in 3C-SiC when it is placed in high-energy neutron irradiation environment of a fusion reactor. The presence and evolution of transmutant defects impact thermal and mechanical properties of this important structural material. This study is focused on understanding the structure, stability, and evolution of Mg defects and the interaction of Mg with native defects in 3C-SiC. Our calculations of diffusion coefficients for different Mg defects suggest that Mg is likely to diffuse faster in pristine 3C-SiC than in the damaged one, in agreement with earlier experimental observations.

36 MATERIALS SCIENCE↗

Attraction and Longevity of 2- and 3-Component Food Cone Lures for the Caribbean Fruit Fly, Anastrepha suspensa (Diptera: Tephritidae)

Abstract The Caribbean fruit fly, Anastrepha suspensa (Loew) (Diptera: Tephritidae), is a quarantine pest of Citrus spp. and a production pest of guava and other specialty fruits in Florida. Effective monitoring lures and traps are needed for early pest detection and timely initiation of control measures. As part of a continued effort to identify attractive synthetic lures for the Caribbean fruit fly, we conducted field tests in Homestead, Florida to compare the efficacy and longevity of commercial 2- and 3-component cone lures (2C [ammonium acetate and putrescine], 3C [ammonium acetate, putrescine, and trimethylamine]), the current standards used by regulatory agencies, versus the traditional liquid protein bait consisting of hydrolyzed torula yeast and borax as a positive control. Additional lures were also field-aged and periodically brought into the laboratory to quantify residual chemical contents. Traps baited with the torula yeast-borax mixture captured the highest mean number of A. suspensa, and traps baited with the commercial 2C lures captured more flies than the 3C lures. Traps baited with torula yeast-borax also captured the highest number of nontarget Diptera. Captures with all three treatments were significantly biased toward females. Attractiveness of the 2C lure began to drop after 6–8 wk, and the 3C lure after 5–6 wk. Overall, these data suggest that the 2C cone lure is more attractive to A. suspensa than the 3C cone lure under field conditions in south Florida, and that the 2C lures are attractive for up to 8 wk.

Entomology↗

Bypassing the yellow phase for extremely stable formamidinium lead iodide perovskite solar cells

INTRODUCTION Formamidinium lead iodide (FAPI) emerged as an ideal material for single-junction perovskite solar cells owing to its near optimal bandgap of 1.45 to 1.5 eV and outstanding thermal stability. However, the photoactive cubic α-phase (3C-FAPI) of FAPI is structurally unstable and undergoes a reconstructive phase transition to the nonperovskite yellow hexagonal δ-phase (2H-FAPI) at ambient temperature. The phase reconstruction from 3C-FAPI to 2H-FAPI could be prevented by alloying methylammonium (MA) or Cs or both at the A-site and Br at the halide site, but this limits long-term durability owing to phase segregation or materials instability. Addressing these challenges requires a rational design strategy to stabilize 3C-FAPI by restricting lattice reconstruction without compromising thermal stability. RATIONALE Two main strategies have emerged to improve the phase stability and film quality of FAPI. Here, the first is a lattice-templating approach, which enables the slow formation of perovskite but it eventually degrades through the formation of yellow phases. The second approach, which has been widely explored, involves additive engineering, using alkyl ammonium halide or mostly chloride-based additives, which provide better control over the crystallization route. However, the FAPI films fabricated using these additives are often alloyed and compromise long-term stability. Moreover, the exact role of Cl has been unclear and speculative, specifically when Cl-based additives are used. Even after using a high additive concentration, the incorporation of Cl in perovskite lattice is rare. RESULTS Guided by synergistic modeling and experimental studies, we developed a coadditive strategy using 15 mol % FACl and 0.5 mol % BA 2 PbI 4 perovskites in combination (where BA is butylammonium) to enable a highly oriented (100) Cl-doped FAPI film with exceptional durability. Synchrotron-based in situ wide-angle x-ray scattering revealed a favorable transition for the coadditive-treated FAPI (FAPI-CA) to the corner-sharing 3C black phase through a progressive transformation through the 2H, 4H, 6H, and 8H phases. Moreover, solid-state 35 Cl nuclear magnetic resonance (NMR) revealed Cl incorporation in the perovskite lattice and, as predicted by modeling, indicated that Cl plays a key role in altering the energetics of both the formation and degradation pathways. The Cl-doped perovskite can completely bypass the expected and energetically favorable degradation pathway via the yellow phase or the 2H-PbI 2 phase. Instead, it undergoes degradation only upon exposure to harsh conditions such as 15-sun illumination and 90°C through the energetically uphill 3R-PbI 2 phase path. A p-i-n device fabricated with FAPI-CA film demonstrated a power conversion efficiency (PCE) of 25.1% with an average of 24.1% (40 devices). The notable film stability translated to other devices and retained 98% of its initial PCE under open-circuit conditions at 85° ± 5°C for 1200 hours. CONCLUSION Our study highlights the decisive role of chloride in regulating both the formation and degradation pathways. This regulation is critical for creating a perovskite film with commercially relevant durability.

Garai, Rabindranath [Rice Univ., Houston, TX (Unit↗

The small-scale structure of radio galaxies and quasi-stellar sources at 3.8 centimeters.

Observation of fringes from 31 compact radio sources, including eight known or suspected galaxies and 20 known or suspected QSSs, by using the Goldstack interferometer at lambda = 3.8 cm (d/lambda = 10 to the 8th power). Fringe visibility curves were obtained for nine sources showing structure on a scale of .001 sec of arc, and simple models are fitted to the data. Results for 3C 273 and 3C 279 are compared with data taken by Knight et al. (1971) at an earlier epoch. The apparent changes in brightness distribution of 3C 273 and 3C 279 are difficult to explain.

Cohen, M. H.↗

A high declination search at 8 GHz for compact radio sources

With the Haystack-NRAO interferometer (baseline length of 20 million wavelengths at 3.8 cm) 37 sources were observed whose declinations were above 50 deg. Seven of these sources have compact cores with diameters smaller than 5 milliarcsec and with correlated flux densities greater than about 0.5 Jy; the remaining sources have no cores with flux densities above about 0.3 Jy, the sensitivity limit of the interferometer. Two of the sources with detected compact cores, 4C 67.05 and 3C 418, were also observed with longer-baseline interferometers; the diameter of the core of 4C 67.05 was estimated to be smaller than 1 milliarcsec and that of 3C 418 to be smaller than 0.4 milliarcsec. All diameter estimates were based on an assumed circular Gaussian distribution of radio brightness and refer to the contour with brightness density e to the -1/2 power times that of the center. Positions for the detected sources were also obtained from the interferometric data, the uncertainty in these coordinate estimates ranging from 0.04 to 0.6 arcsec. The compact core detected in 3C 390.3 was found to lie near the center of this extended (approximately 4 arcmin in diameter) double radio source and to be coincident to within 1 arcsec with an N galaxy previously identified with 3C 390.3.

Wittels, J. J.↗

The hydrogen line spectra of narrow-line radio galaxies

The results of the first detection of Ly-alpha in a narrow-line radio galaxy are reported. Nearly simultaneous optical and UV observations of 3C 192 and 3C 223 allow the measurement of both Balmer and Lyman decrements. These line ratios are approximate functions of the interstellar reddening and of a parameter which is proportional to the amount of H I collisional excitation present. The reddening of 3C 192 is slightly larger than that due to the Galaxy, although 3C 223 may have a larger value. Both galaxies have intrinsic Balmer and Lyman decrements which are significantly steeper than case B, suggesting that the gas is photoionized by a fairly hard X-ray continuum. The deduced values of L-alpha/H-beta and H-alpha/H-beta compare favorably with predictions of recent models.

Ferland, G. J.↗

Ultraviolet and optical spectra of broadline radio galaxies

Near-simultaneous ultraviolet and optical spectra of three broadline radio galaxies (3C 382, 3C 445, and PKS 2349-014) have been obtained, and the emission lines of Ly-alpha, H-beta, and H-alpha have been deconvolved into narrow and broad components; published fluxes for 3C 390.3 are also included in this study. Although the broad Ly-alpha/H-beta ratios in these objects cover a large range (1.2-22.3), there is no evidence that these ratios are intrinsically different from those of Seyfert 1 galaxies or quasars. Thus, in general, the higher H-alpha/H-beta ratios in these broadline radio galaxies cannot entirely be due to additional reddening of the broadline region. However, in the specific case of 3C 445, there is evidence that the nonstellar continuum and broadline region are highly reddened.

Crenshaw, D. Michael↗

An Interlaminar Tensile Strength Specimen

This paper describes a technique to determine interlaminar tensile strength, sigma(sub 3c), of a fiber reinforced composite material using a curved beam. The specimen was a unidirectional curved beam, bent 90 deg, with straight arms. Attached to each arm was a hinged loading mechanism that was held by the grips of a tension testing machine. Geometry effects of the specimen, including the effects of loading arm length, inner radius, thickness, and width, were studied. The data sets fell into two categories: low strength corresponding to a macroscopic flaw related failure and high strength corresponding to a microscopic flaw related failure. From the data available, the specimen width and loading arm length had little effect on sigma(sub 3c). The inner radius was not expected to have a significant effect on sigma(sub 3c), but this conclusion could not be confirmed because of differences in laminate quality for each curve geometry. The thicker specimens had the lowest value of sigma(sub 3c) because of poor laminate quality.

Martin, Roderick H.↗

Beamed and Unbeamed X-Ray Emission in FR1 Radio Galaxies

The research exploited ROSAT's sensitivity, together with its spatial and spectral resolution, to separate X-ray emission components in the sources. Prior to ROSAT, the dominant X-ray emission mechanism in radio galaxies as a class was unclear, with correlations between the X-ray and radio emission used on one hand to argue for a nuclear origin for the X-rays, and on the other hand for a thermal origin. Our observations (normally between 10 and 25 ks in length) routinely detected the target sources, and demonstrated that both resolved (thermal) and unresolved X-ray emission are typically present. Highlights of our work included two of the first detections of high-power radio galaxies at high redshift, 3C 280 and 3C 220.1. When combined with the work of two other groups, we find that of the 38 radio galaxies at z > 0.6 in the 3CRR sample, 12 were observed in ROSAT pointed observations and 9 were detected with the four most significant detections exhibiting source extent, including 3C 280 and 3C 220.1. Moreover, we discovered extended emission around five 3CRR quasars at redshift greater than about 0.4, one of which is at z > 0.6. Unification predicts that the X-ray environments of powerful radio galaxies and quasars should be similar, and our results show that powerful radio sources are finding some of the highest-redshift X-ray clusters known to date, pointing to deep gravitational potential wells early in the Universe.

Worrall, Diana M.↗

Constraints on Particles and Fields from X-Ray Data

We review emission processes for the handful of extragalactic radio sources which produce X-rays from hotspots and knots in radio jets. In almost all cases, the emitting feature shows a large gradient in radio brightness, indicative of the presence of a strong shock. Since both thermal and synchrotron self Compton models face severe difficulties (except for the hotspots of Cygnus A and 3C 295), the most likely explanation is the presence of gamma = 10(exp 7) electrons producing X-ray synchrotron emission. The major problems remaining are why so few features have been detected so far and why has no optical emission been detected in some cases. While a somewhat unique situation exists for 3C 390.3, serious problems remain for Pictor A, 3C 120, and the quasar jets in 3C 273 and PKS 0637.

Harris, D. E.↗

Continued RXTE Observations of Three Blazars

This project continued (during Cycle 3 of the RXTE mission) weekly observations of the quasars PKS 1510-089 and 3C 454.3 and the BL Lac object OJ 287. The data were analyzed by the PI and his graduate student. In the middle of Cycle 3, the PI changed the mode of observation of 3C 454.3, based on a report from another astronomer that observations with the Rosat satellite had found a strong confusing X-ray source about 45 arcmin away. The RXTE observations, in which the flux was measured while pointing directly at 3C 454.3 and then 15' from 3C 454.3, in the direction away from the confusing source. The flux decreased considerably, and so it appears that nearly all the X-ray flux measured by RXTE comes from the confusing source rather than the quasar. OJ 287 was detected only at one epoch of the Cycle 3 observations. This corresponded to a particularly quiet period for this source, when its flux at other wavebands was also low. From the single epoch of detection, no conclusions can be drawn concerning the general nature of the X-ray emission from this object. In contrast to the other two sources, the results of the observations of PKS 1510-089, when combined with data from cycles 3 and 4, are very interesting. The RXTE (2.4-20 keV) abd 14.5 GHz University of Michigan Radio Astronomy Observatory (UMRAO) light curves through the end of RXTE Cycle 4 are shown for PKS 1510-089. Visual inspection reveals an obvious correlation between the X-ray and 14.5 GHz light curves. While this is as expected in the SSC model in a source with simultaneous mm-wave (the photons thought to be scattered to X-ray energies) and cm-wave variations, the X-ray spectrum is flat ("energy" spectral index alpha = 0.2-0.5, where F (sub v) proportional to v (sup - alpha)) compared with the mm-wave synchrotron spectrum (alpha approximately equal to 0.8). The PI is currently engaged in theoretical work to determine whether this is possible for an SSC model.

Marscher, Alan P.↗

New Insights on the Accretion Disk-Winds Connection in Radio-Loud AGNs from Suzaku

From the spectral analysis of long Suzaku observations of five radio-loud AGNs we have been able to discover the presence of ultra-fast outflows with velocities ,,approx.0.1 c in three of them, namely 3C III, 3C 120 and 3C 390.3. They are consistent with being accretion disk winds/outflows. We also performed a follow-up on 3C III to monitor its outflow on approx.7 days time-scales and detected an anti-correlated variability of a possible relativistic emission line with respect to blue-shifted Fe K features, following a flux increase. This provides the first direct evidence for an accretion disc-wind connection in an AGN. The mass outflow rate of these outflows can be comparable to the accretion rate and their mechanical power can correspond to a significant fraction of the bolometric luminosity and is comparable to their typical jet power. Therefore, they can possibly play a significant role in the expected feedback from AGNs and can give us further clues on the relation between the accretion disk and the formation of winds/jets.

Tombesi, F.↗

Effect of Foot-and-Mouth Disease Virus 2B Viroporin on Expression and Extraction of Mammalian Cell Culture Produced Foot-and-Mouth Disease Virus-like Particles

To improve the production of foot-and-mouth disease (FMD) molecular vaccines, we sought to understand the effects of the FMD virus (FMDV) 2B viroporin in an experimental, plasmid-based, virus-like particle (VLP) vaccine. Inclusion of the FMDV viroporin 2B into the human Adenovirus 5 vectored FMD vaccine enhanced transgene expression despite independent 2B expression negatively affecting cell viability. Evaluating both wildtype 2B and mutants with disrupted viroporin activity, we confirmed that viroporin activity is detrimental to overall transgene expression when expressed independently. However, the incorporation of 2B into an FMD molecular vaccine construct containing a wildtype FMDV 3C protease, a viral encoded protease responsible for processing structural proteins, resulted in enhancement of transgene expression, validating previous observations. This benefit to transgene expression was negated when using the FMDV 3CL127P mutant, which has reduced processing of host cellular proteins, a reversion resulting from 2B viroporin activity. Inclusion of 2B into VLP production constructs also adversely impacted antigen extraction, a possible side effect of 2B-dependent rearrangement of cellular membranes. These results demonstrate that inclusion of 2B enhanced transgene expression when a wildtype 3C protease is present but was detrimental to transgene expression with the 3CL127P mutant. This has implications for future molecular FMD vaccine constructs, which may utilize mutant FMDV 3C proteases.

2B↗

Direct Determination of 3C/4H Silicon Carbide Heterophase Interfaces by Electron Ptychography

Silicon carbide is a technologically relevant material that can exist in various structural polymorphs, each with its own electronic properties. Through the controlled growth of abrupt interfaces between the polymorphs, systems with emergent properties arise from differences in local bonding and stacking sequences. Determining the structure of these interfaces provides important insights into predicting and ultimately controlling their properties. Here, in this study, we use multislice electron ptychography (MEP) to qualitatively and quantitatively analyze interfaces between 3C and 4H silicon carbide in three dimensions. Two distinct interfaces are investigated: a coherent interface between $(1\bar{1}1)$ (3C) and $(0001)$ (4H) , and an incoherent interface between $(1\bar{1}2)$ (3C) and $(1\bar{1}00)$ (4H) . At the coherent interface, MEP enables direct quantification of a sharp boundary with an inclined step, whereas at the incoherent interface, local atomic displacements are determined along dislocation cores. By quantifying the spatial distribution and atomic-scale structure of these interfaces in three dimensions, this study provides insight into the complexity of silicon carbide heteropolytype interfaces, paving the way for theoretical modeling and the development of design rules to achieve desired properties.

heterophase interface↗