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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Identification and Testing of Electric Vehicle Fast Charger Cybersecurity Mitigations

Fast-charging infrastructure for electric vehicles (EVs) is needed to enable and achieve the national goals of transitioning the vehicle fleet toward more electrification. Idaho National Laboratory, Oak Ridge National Laboratory, and the National Renewable Energy Laboratory (NREL) have jointly worked to identify, evaluate, and mitigate potential cyber-related consequences associated with fast charger systems. NREL contributed by considering cyberattack scenarios and consequences associated with integrating distributed energy resources (DERs) at fast-charging stations. The dynamic nature of fast-charger load profiles would encourage site operators to incorporate solar for energy cost reduction and energy storage for peak demand cost management at future charging facilities with multiple fast chargers at a site. These energy resources would be monitored and coordinated via a site energy management controller with data exchange between devices and local power metering infrastructure; thus, networking between devices and the design of the system becomes important in the overall cybersecurity posture. In addition, component vendors and system operators might have remote interfaces to any of these systems. It is therefore important to understand the breadth of the cyberattack surface and potential strategies to mitigate impacts. This project has focused on components and protocols expected to be found within a local charging site that includes multiple chargers and DER resources. Our methods and results are summarized in this final report.

42 ENGINEERING↗
DOE OSTI2026

Integrative SP3 Workflow for Multi-PTM Proteomics Profiling (TZ-DP0)

The goal of the experiment was to demonstrate that the optimized multiplexed multi-PTM profiling workflow can comprehensively and quantitatively capture dynamic changes in protein abundance, cysteine oxidation, phosphorylation, and acetylation in cytokine-induced inflammatory stress in mouse pancreatic ß-cells. Global proteomic, redox proteomic, phosphoproteomic, and acetylomic were data collected from mouse Beta-TC-6 pancreatic Beta-cells, untreated (mock) and cytokine-treated Beta-cells at 4, 8, and 24 hours with 4 biological replicates. Samples were digested with trypsin and Lys-C, then analyzed by LC-MS/MS. Data were searched with MS-GF+, MASIC, and MaxQuant using PNNL's DMS processing pipeline.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2013

THE M87 BLACK HOLE MASS FROM GAS-DYNAMICAL MODELS OF SPACE TELESCOPE IMAGING SPECTROGRAPH OBSERVATIONS

The supermassive black hole of M87 is one of the most massive black holes known and has been the subject of several stellar and gas-dynamical mass measurements; however, the most recent revision to the stellar-dynamical black hole mass measurement is a factor of about two larger than the previous gas-dynamical determinations. Here, we apply comprehensive gas-dynamical models that include the propagation of emission-line profiles through the telescope and spectrograph optics to new Space Telescope Imaging Spectrograph observations from the Hubble Space Telescope. Unlike the previous gas-dynamical studies of M87, we map out the complete kinematic structure of the emission-line disk within {approx}40 pc from the nucleus, and find that a small amount of velocity dispersion internal to the gas disk is required to match the observed line widths. We examine a scenario in which the intrinsic velocity dispersion provides dynamical support to the disk, and determine that the inferred black hole mass increases by only 6%. Incorporating this effect into the error budget, we ultimately measure a mass of M{sub BH}= (3.5{sup +0.9}{sub -0.7}) Multiplication-Sign 10{sup 9} M{sub sun} (68% confidence). Our gas-dynamical black hole mass continues to differ from the most recent stellar-dynamical mass by a factor of two, underscoring the need for carrying out more cross-checks between the two main black hole mass measurement methods.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Dynamic Subgrid Turbulence Modeling for Shallow Cumulus Convection Simulations beyond LES Resolutions

A scale-dependent dynamic Smagorinsky model is implemented in the Met Office/NERC Cloud (MONC) model using two averaging flavors, along Lagrangian pathlines and local moving averages. The dynamic approaches were compared against the conventional Smagorinsky–Lilly scheme in simulating the diurnal cycle of shallow cumulus convection. The simulations spanned from the LES to the near-gray-zone and gray-zone resolutions and revealed the adaptability of the dynamic model across the scales and different stability regimes. The dynamic model can produce a scale- and stability-dependent profile of the subfilter turbulence length scale across the chosen resolution range. At gray-zone resolutions the adaptive length scales can better represent the early precloud boundary layer leading to temperature and moisture profiles closer to the LES compared to the standard Smagorinsky. As a result, the initialization and general representation of the cloud field in the dynamic model is in good agreement with the LES. In contrast, the standard Smagorinsky produces a less well-mixed boundary layer, which fails to ventilate moisture from the boundary layer, resulting in the delayed spinup of the cloud layer. Moreover, strong downgradient diffusion controls the turbulent transport of scalars in the cloud layer. However, the dynamic approaches rely on the resolved field to account for nonlocal transports, leading to overenergetic structures when the boundary layer is fully developed and the Lagrangian model is used. Introducing the local averaging version of the model or adopting a new Lagrangian time scale provides stronger dissipation without significantly affecting model behavior.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Simulating Dynamic Roots in the Energy Exascale Earth System Land Model

Abstract Roots are important contributors to plant development, functioning to provide nutrients and water for plant growth. However, roots and their functions are often simplified in Earth system models, which limit the feedback of root foraging strategy on plant productivity, and their impacts on the carbon cycle. The goal of this study is to introduce a new method to resolve the vertical structure of roots over time. The method allows plasticity of rooting depth distribution under nonuniform profiles of water and nitrogen, which influences aboveground dynamics. The dynamic root model optimizes root distribution for both water and nitrogen uptake but gives priority to plant water demands. I implement this new method in the Energy Exascale Earth System model. The resulting root distribution maintains agreement with observations in most ecosystems and marginally improves the gross primary productivity estimated by the model, compared to satellite observations. Increases in gross primary productivity are simulated in desert and boreal ecosystems. However, the model does not capture deep roots in the dry tropics, and therefore, productivity losses are observed in parts of the Amazon and the African savannah. I discuss details of the model algorithm, along with some sensitivity studies that shed light on the model behavior in water‐limited ecosystems. The study shows that additional model processes, such as climate dependent root depth, root hydraulics, root form and function, and better nitrogen uptake, should be considered to improve the root water uptake in the Energy Exascale Earth System Land Model (ELM).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Effect of asymmetric concentration profile on thermal conductivity in Ge/SiGe superlattices

The effect of the chemical composition in Si/Ge-based superlattices on their thermal conductivity has been investigated using molecular dynamics simulations. Simulation cells of Ge/SiGe superlattices have been generated with different concentration profiles such that the Si concentration follows a step-like, a tooth-saw, a Gaussian, and a gamma-type function in direction of the heat flux. The step-like and tooth-saw profiles mimic ideally sharp interfaces, whereas Gaussian and gamma-type profiles are smooth functions imitating atomic diffusion at the interface as obtained experimentally. Symmetry effects have been investigated comparing the symmetric profiles of the step-like and the Gaussian function to the asymmetric profiles of the tooth-saw and the gamma-type function. At longer sample length and similar degree of interdiffusion, the thermal conductivity is found to be lower in asymmetric profiles. Furthermore, it is found that with smooth concentration profiles where atomic diffusion at the interface takes place the thermal conductivity is higher compared to systems with atomically sharp concentration profiles.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2014

nSQUID arrays as conveyers of quantum information

We have considered the quantum dynamics of an array of nSQUIDs—two-junction SQUIDs with negative mutual inductance between their two arms. Effective dual-rail structure of the array creates additional internal degree of freedom for the fluxons in the array, which can be used to encode and transport quantum information. Physically, this degree of freedom is represented by electromagnetic excitations localized on the fluxon. We have calculated the spatial profile and frequency spectrum of these excitations. Their dynamics can be reduced to two quantum states, so that each fluxon moving through the array carries with it a qubit of information. Coherence properties of such a propagating qubit in the nSQUID array are characterized by the dynamic suppression of the low-frequency decoherence due to the motion-induced spreading of the noise spectral density to a larger frequency interval.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2014

Temporal dynamics of fibrolytic and methanogenic rumen microorganisms during in situ incubation of switchgrass determined by 16S rRNA gene profiling

The rumen microbial ecosystem is known for its biomass-degrading and methane-producing phenotype. Fermentation of recalcitrant plant material, comprised of a multitude of interwoven fibers, necessitates the synergistic activity of diverse microbial taxonomic groups that inhabit the anaerobic rumen ecosystem. Although interspecies hydrogen (H2) transfer, a process during which bacterially generated H2 is transferred to methanogenic Archaea, has obtained significant attention over the last decades, the temporal variation of the different taxa involved in in situ biomass-degradation, H2 transfer and the methanogenesis process remains to be established. Here we investigated the temporal succession of microbial taxa and its effect on fiber composition during rumen incubation using 16S rRNA amplicon sequencing. Switchgrass filled nylon bags were placed in the rumen of a cannulated cow and collected at nine time points for DNA extraction and 16S pyrotag profiling. The microbial community colonizing the air-dried and non-incubated (0 h) switchgrass was dominated by members of the Bacilli (recruiting 63% of the pyrotag reads). During in situ incubation of the switchgrass, two major shifts in the community composition were observed: Bacilli were replaced within 30 min by members belonging to the Bacteroidia and Clostridia, which recruited 34 and 25% of the 16S rRNA reads generated, respectively. A second significant shift was observed after 16 h of rumen incubation, when members of the Spirochaetes and Fibrobacteria classes became more abundant in the fiber-adherent community. During the first 30 min of rumen incubation ~13% of the switchgrass dry matter was degraded, whereas little biomass degradation appeared to have occurred between 30 min and 4 h after the switchgrass was placed in the rumen. Interestingly, methanogenic members of the Euryarchaeota (i.e., Methanobacteria) increased up to 3-fold during this period of reduced biomass-degradation, with peak abundance just before rates of dry matter degradation increased again. We hypothesize that during this period microbial-mediated fibrolysis was temporarily inhibited until H2 was metabolized into CH4 by methanogens. Collectively, our results demonstrate the importance of inter-species interactions for the biomass-degrading and methane-producing phenotype of the rumen microbiome—both microbially facilitated processes with global significance.

interspecies H2 transfer↗
DOE OSTI2020

How accurately can we detect the splashback radius of dark matter haloes and its correlation with accretion rate?

ABSTRACT The splashback radius (Rsp) of dark matter haloes has recently been detected using weak gravitational lensing and cross-correlations with galaxies. However, different methods have been used to measure Rsp and to assess the significance of its detection. In this paper, we use simulations to study the precision and accuracy to which we can detect the splashback radius with 3D density, 3D subhalo, and weak lensing profiles. We study how well various methods and tracers recover Rsp by comparing it with the value measured directly from particle dynamics. We show that estimates of Rsp from density and subhalo profiles correspond to different percentiles of the underlying Rsp distribution of particle orbits. At low accretion rates, a second caustic appears and can bias results. Finally, we show that upcoming lensing surveys may be able to constrain the Rsp–Γdyn relation directly.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Avalanches driven by pressure gradients in a magnetized plasma

The results are presented for a basic heat transport experiment involving an off-axis heat source in which avalanche events occur. The configuration consists of a long, hollow, cylindrical region of elevated electron temperature embedded in a colder plasma, and far from the device walls [Van Compernolle et al. Phys. Rev. E 91, 031102(R) (2015)]. The avalanche events are identified as sudden rearrangements of the pressure profile following the growth of fluctuations from ambient noise. The intermittent collapses of the plasma pressure profile are associated with unstable drift-Alfvén waves and exhibit both radial and poloidal dynamics. After each collapse, the plasma enters a quiescent phase in which the pressure profile slowly recovers and steepens until a threshold is exceeded, and the process repeats. The use of reference probes as time markers allows for the visualization of the 2D spatio-temporal evolution of the avalanche events. Avalanches are observed only for a limited combination of heating powers and magnetic fields. At higher heating powers, the system transits from the avalanche regime into a regime dominated by sustained drift-Alfvén wave activity. Here, this manuscript focuses on new results that illustrate the individual contributions to the avalanche process from density and temperature gradients in the presence of zero-order, sheared flows.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

A prototype scintillator real‐time beam monitor for ultra‐high dose rate radiotherapy

Background: FLASH Radiotherapy (RT) is an emergent cancer RT modality where an entire therapeutic dose is delivered at more than 1000 times higher dose rate than conventional RT. For clinical trials to be conducted safely, a precise and fast beam monitor that can generate out-of-tolerance beam interrupts is required. This paper describes the overall concept and provides results from a prototype ultra-fast, scintillator-based beam monitor for both proton and electron beam FLASH applications. Purpose: A FLASH Beam Scintillator Monitor (FBSM) is being developed that employs a novel proprietary scintillator material. The FBSM has capabilities that conventional RT detector technologies are unable to simultaneously provide: (1) large area coverage; (2) a low mass profile; (3) a linear response over a broad dynamic range; (4) radiation hardness; (5) real-time analysis to provide an IEC-compliant fast beam-interrupt signal based on true two-dimensional beam imaging, radiation dosimetry and excellent spatial resolution. Methods: The FBSM uses a proprietary low mass, less than 0.5 mm water equivalent, non-hygroscopic, radiation tolerant scintillator material (designated HM: hybrid material) that is viewed by high frame rate CMOS cameras. Folded optics using mirrors enable a thin monitor profile of ∼10 cm. A field programmable gate array (FPGA) data acquisition system generates real-time analysis on a time scale appropriate to the FLASH RT beam modality: 100–1000 Hz for pulsed electrons and 10–20 kHz for quasi-continuous scanning proton pencil beams. An ion beam monitor served as the initial development platform for this work and was tested in low energy heavy-ion beams ( 86 Kr +26 and protons). A prototype FBSM was fabricated and then tested in various radiation beams that included FLASH level dose per pulse electron beams, and a hospital RT clinic with electron beams. Results: Results presented in this report include image quality, response linearity, radiation hardness, spatial resolution, and real-time data processing. Furthermore, the HM scintillator was found to be highly radiation damage resistant. It exhibited a small 0.025%/kGy signal decrease from a 216 kGy cumulative dose resulting from continuous exposure for 15 min at a FLASH compatible dose rate of 237 Gy/s. Measurements of the signal amplitude versus beam fluence demonstrate linear response of the FBSM at FLASH compatible dose rates of >40 Gy/s. Comparison with commercial Gafchromic film indicates that the FBSM produces a high resolution 2D beam image and can reproduce a nearly identical beam profile, including primary beam tails. The spatial resolution was measured at 35–40 µm. Tests of the firmware beta version show successful operation at 20 000 Hz frame rate or 50 µs/frame, where the real-time analysis of the beam parameters is achieved in less than 1 µs. Conclusions: The FBSM is designed to provide real-time beam profile monitoring over a large active area without significantly degrading the beam quality. A prototype device has been staged in particle beams at currents of single particles up to FLASH level dose rates, using both continuous ion beams and pulsed electron beams. Using a novel scintillator, beam profiling has been demonstrated for currents extending from single particles to 10 nA currents. Radiation damage is minimal and even under FLASH conditions would require ≥50 kGy of accumulated exposure in a single spot to result in a 1% decrease in signal output. Beam imaging is comparable to radiochromic films, and provides immediate images without hours of processing. Real-time data processing, taking less than 50 µs (combined data transfer and analysis times), has been implemented in firmware for 20 kHz frame rates for continuous proton beams.

2D beam imaging↗
DOE OSTI2015

ONE PLANE FOR ALL: MASSIVE STAR-FORMING AND QUIESCENT GALAXIES LIE ON THE SAME MASS FUNDAMENTAL PLANE AT z ∼ 0 AND z ∼ 0.7

Scaling relations between galaxy structures and dynamics have been studied extensively for early- and late-type galaxies, both in the local universe and at high redshifts. The abundant differences between the properties of disky and elliptical, or star-forming and quiescent, galaxies seem to be characteristic of the local universe; such clear distinctions begin to disintegrate as observations of massive galaxies probe higher redshifts. In this paper we investigate the existence of the mass fundamental plane of all massive galaxies (σ ≳ 100 km s{sup –1}). This work includes local galaxies (0.05 < z < 0.07) from the Sloan Digital Sky Survey, in addition to 31 star-forming and 72 quiescent massive galaxies at intermediate redshift (z ∼ 0.7) with absorption-line kinematics from deep Keck-DEIMOS spectra and structural parameters from Hubble Space Telescope imaging. In two-parameter scaling relations, star-forming and quiescent galaxies differ structurally and dynamically. However, we show that massive star-forming and quiescent galaxies lie on nearly the same mass fundamental plane, or the relationship between stellar mass surface density, stellar velocity dispersion, and effective radius. The scatter in this relation (measured about log σ) is low: 0.072 dex (0.055 dex intrinsic) at z ∼ 0 and 0.10 dex (0.08 dex intrinsic) at z ∼ 0.7. This 3D surface is not unique: virial relations, with or without a dependence on luminosity profile shapes, can connect galaxy structures and stellar dynamics with similar scatter. This result builds on the recent finding that mass fundamental plane has been stable for early-type galaxies since z ∼ 2. As we now find that this also holds for star-forming galaxies to z ∼ 0.7, this implies that these scaling relations of galaxies will be minimally susceptible to progenitor biases owing to the evolving stellar populations, structures, and dynamics of galaxies through cosmic time.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

A numerical evaluation of the ambient air temperature in the Electron-Ion Collider tunnel

The Electron-Ion Collider (EIC) is a next-generation collider-accelerator that may require consistent operating temperature conditions for the beams within the accelerator tunnels to maintain stable operation. Variations in ambient temperature within the tunnel can cause thermal expansion of beampipe and component supports and can negatively affect the tunnel equipment, impacting the stability of the beamline. Modifications will be made to the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Laboratory (BNL) to create the EIC, which necessitates a temperature model that addresses these modifications. To approach this problem, the consistency of temperature changes in different tunnel sections was first evaluated by plotting RHIC tunnel temperature data at various times of the day and year. From this data, a tunnel section was selected and a 2D temperature model was created for RHIC, EIC, and EIC with added cooling configurations. Soil temperature data was analyzed to determine the maximum, average, and mode soil temperatures, which were used as boundary conditions in different temperature scenarios. Computational fluid dynamics modeling was used to create 2D temperature profiles for the configurations. From this model, the predicted temperatures indicate that further analysis is required to validate the boundary conditions and benchmark the current conditions to allow the prediction of the tunnel ambient conditions at EIC. This research can be used as a preliminary model to create an EIC tunnel cooling system that will increase the operational stability of the EIC. As a result of my work this summer, I have become familiar with computational fluid dynamics, including creating fluid dynamic simulations using ANSYS Fluent and related software. I have also learned about the project process required for planning large-scale engineering projects.

43 PARTICLE ACCELERATORS↗
DOE OSTI2021

Kinetic Properties of Microbial Exoenzymes Vary With Soil Depth but Have Similar Temperature Sensitivities Through the Soil Profile

Current knowledge of the mechanisms driving soil organic matter (SOM) turnover and responses to warming is mainly limited to surface soils, although over 50% of global soil carbon is contained in subsoils. Deep soils have different physicochemical properties, nutrient inputs, and microbiomes, which may harbor distinct functional traits and lead to different SOM dynamics and temperature responses. We hypothesized that kinetic and thermal properties of soil exoenzymes, which mediate SOM depolymerization, vary with soil depth, reflecting microbial adaptation to distinct substrate and temperature regimes. We determined the Michaelis-Menten (MM) kinetics of three ubiquitous enzymes involved in carbon (C), nitrogen (N) and phosphorus (P) acquisition at six soil depths down to 90 cm at a temperate forest, and their temperature sensitivity based on Arrhenius/ Q 10 and Macromolecular Rate Theory (MMRT) models over six temperatures between 4–50°C. Maximal enzyme velocity ( V max ) decreased strongly with depth for all enzymes, both on a dry soil mass and a microbial biomass C basis, whereas their affinities increased, indicating adaptation to lower substrate availability. Surprisingly, microbial biomass-specific catalytic efficiencies also decreased with depth, except for the P-acquiring enzyme, indicating distinct nutrient demands at depth relative to microbial abundance. These results suggested that deep soil microbiomes encode enzymes with intrinsically lower turnover and/or produce less enzymes per cell, reflecting distinct life strategies. The relative kinetics between different enzymes also varied with depth, suggesting an increase in relative P demand with depth, or that phosphatases may be involved in C acquisition. V max and catalytic efficiency increased consistently with temperature for all enzymes, leading to overall higher SOM-decomposition potential, but enzyme temperature sensitivity was similar at all depths and between enzymes, based on both Arrhenius/ Q 10 and MMRT models. In a few cases, however, temperature affected differently the kinetic properties of distinct enzymes at discrete depths, suggesting that it may alter the relative depolymerization of different compounds. We show that soil exoenzyme kinetics may reflect intrinsic traits of microbiomes adapted to distinct soil depths, although their temperature sensitivity is remarkably uniform. These results improve our understanding of critical mechanisms underlying SOM dynamics and responses to changing temperatures through the soil profile.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2015

Monolayer-by-monolayer compositional analysis of InAs/InAsSb superlattices with cross-sectional STM

In this paper, we use cross-sectional scanning tunneling microscopy (STM) to reconstruct the monolayer-by-monolayer composition profile across a representative subset of MBE-grown InAs/InAsSb superlattice layers and find that antimony segregation frustrates the intended compositional discontinuities across both antimonide-on-arsenide and arsenide-on-antimonide heterojunctions. Graded, rather than abrupt, interfaces are formed in either case. We likewise find that the incorporated antimony per superlattice period varies measurably from beginning to end of the multilayer stack. Finally, although the intended antimony discontinuities predict significant discrepancies with respect to the experimentally observed high-resolution x-ray diffraction spectrum, dynamical simulations based on the STM-derived profiles provide an excellent quantitative match to all important aspects of the x-ray data.

36 MATERIALS SCIENCE↗
DOE OSTI2013

ALL SIX PLANETS KNOWN TO ORBIT KEPLER-11 HAVE LOW DENSITIES

The Kepler-11 planetary system contains six transiting planets ranging in size from 1.8 to 4.2 times the radius of Earth. Five of these planets orbit in a tightly packed configuration with periods between 10 and 47 days. We perform a dynamical analysis of the system based upon transit timing variations observed in more than three years of Kepler photometric data. Stellar parameters are derived using a combination of spectral classification and constraints on the star's density derived from transit profiles together with planetary eccentricity vectors provided by our dynamical study. Combining masses of the planets relative to the star from our dynamical study and radii of the planets relative to the star from transit depths together with deduced stellar properties yields measurements of the radii of all six planets, masses of the five inner planets, and an upper bound to the mass of the outermost planet, whose orbital period is 118 days. We find mass-radius combinations for all six planets that imply that substantial fractions of their volumes are occupied by constituents that are less dense than rock. Moreover, we examine the stability of these envelopes against photoevaporation and find that the compositions of at least the inner two planets have likely been significantly sculpted by mass loss. The Kepler-11 system contains the lowest mass exoplanets for which both mass and radius have been measured.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Surface‐Enforced Alignment of Reprogrammable Liquid Crystalline Elastomers

Abstract Liquid crystalline elastomers (LCEs) are stimuli‐responsive materials capable of undergoing large deformations. The thermomechanical response of LCEs is attributable to the coupling of polymer network properties and disruption of order between liquid crystalline mesogens. Complex deformations have been realized in LCEs by either programming the nematic director via surface‐enforced alignment or localized mechanical deformation in materials incorporating dynamic covalent chemistries. Here, the preparation of LCEs via thiol‐Michael addition reaction is reported that are amenable to surface‐enforced alignment. Afforded by the thiol‐Michael addition reaction, dynamic covalent bonds are uniquely incorporated in chemistries subject to surface‐enforce alignment. Accordingly, LCEs prepared with complex director profiles are able to be programmed and reprogrammed by (re)activating the dynamic covalent chemistry to realize distinctive shape transformations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗