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The Nucleosynthetic Heritage of Bennu

The OSIRIS-REx mission sampled the B-type asteroid Bennu and delivered 121.6 g of material to Earth in September 2023. Nucleosynthetic isotope variations are powerful tracers that can be used to establish relationships between different meteorite groups and the returned samples. They can also constrain the samples’ nucleosynthetic heritage, as well as mixing and reservoir formation in the protoplanetary disk. Nucleosynthetic variations reflect the heterogeneous distribution of isotopically distinct dust in the disk, and as such, they provide evidence for the formation of meteorite parent bodies from isotopically distinct dust reservoirs. They are thus also a means to identify exogenous clasts in Bennu materials. Here, we report Ti and Fe isotope data obtained from Bennu samples and carbonaceous chondrites. We also present Ti isotope data for hand-picked matrix from CV and CR chondrites. An isotopic dataset was obtained on aggregate sample OREX-803015-100 consisting of particles typically <500 μm; therefore, its composition represents an average for Bennu materials. A 20.66 mg aliquot was dissolved at Washington University, St. Louis. From this, 5 mg was analysed for Ti and Fe isotopes on a NeptunePlus MC-ICPMS at ETH Zurich; data from a separate aliquot, analysed at Lawrence Livermore National Laboratory, are reported in a companion abstract. Our results demonstrate a close relationship of Bennu to CI and Ryugu samples and therefore a formation outside the snowline, as hypothesized by the mission. Furthermore, the 50 Ti data from the CV and CR matrix fall consistently below the CI and Bennu values, indicating the presence of a uniform matrix mixed with ⁓0.1–0.7% of refractory inclusions in CIs and Bennu.

M. Schönbächler↗

Bulk Elemental Composition of Aggregate Material From Asteroid Bennu

On September 24, 2023, NASA’s OSIRIS-REx mission returned pristine carbonaceous material from asteroid Bennu. One key aspect required to understand this returned material is to establish its bulk chemical composition. This is primarily due to each chondrite group having a distinct elemental composition, which is important both as a classification tool and for establishing the connections between the different chondrite groups. As the carbonaceous and non-carbonaceous chondrites are thought to have formed in the inner and outer protoplanetary disk, respectively, measuring the bulk elemental composition of Bennu material will help test the mission hypothesis that “Bennu's parent body formed beyond the snow line by accretion of material in the protoplanetary disk”. In addition, two further mission hypotheses — paraphrased as Bennu’s bulk elemental composition reflects that of its parent asteroid and is similar to the composition of the Sun and Bennu’s dominant lithologies are comparable in composition to the most aqueously altered carbonaceous chondrites — can be directly tested by bulk elemental analyses. Elemental analyses were undertaken on sample OREX-803015-0, a 20.66 mg aggregate sourced from inside the sample collector. All analyses were conducted using an iCAP Q ICP-MS. Overall, all 54 elements analyzed for the Bennu aggregate sample show similar abundances to those of the average CI chondrite, and thus the solar photosphere composition and some of the most aqueously altered carbonaceous chondrites. The elemental data also show that Bennu is indeed a carbonaceous asteroid that formed beyond the snow line by accretion of material in the protoplanetary disk. This Bennu aggregate sample appears similar in elemental composition to samples of asteroid Ryugu, yet without the small refractory element enrichments seen in Ryugu.

P Koefoed↗

Connecting Community Scientific Hypotheses to Mars Sample Science

The proposed Mars Sample Return (MSR) program seeks to bring back to Earth a set of specially curated samples from the surface of Mars. The first segment of the MSR program is presently under-way; the Mars 2020 rover Perseverance has, to date, collected 24 samples of martian rock, regolith, and at-mosphere within Jezero crater. Its geologically diverse rock sample set can provide insight into the time evolu-tion of the Jezero environment, including the possible preservation of ancient biosignatures. Presently, a cache of 10 samples has been deposited in the Three Forks region on the floor of Jezero crater. These sam-ples, deemed scientifically return worthy by the Mars science community [1], are intended as a contingency sample set, as Perseverance has subsequently obtained more samples, and is therefore storing a more compre-hensive and scientifically valuable set of samples that will grow as the rover ascends to the rim of Jezero crater. The return of samples from Mars has been identi-fied as the highest priority planetary mission in the past three National Academies Decadal Surveys [2-4]. Sub-stantial work has gone into establishing science objec-tives for an MSR program, an overall framework for sample retrieval and analysis, and the expected impact on future Mars science and exploration (e.g., [5]). These objectives have been established at a relatively high level, e.g., “Interpret the primary geologic pro-cesses and history that formed the martian geologic rec-ord, with an emphasis on the role of water.” (Objective 1 in [5]) and are designed to encapsulate the broad sci-entific priorities of, and lay the groundwork for, inves-tigation strategies and measurements to be conducted by a future MSR program. It is from this overarching framework that the Connecting Community Scientific Hypotheses to Mars Sample Science workshop (‘The Workshop’) was conceived, with the purpose of distil-ling these high-level scientific objectives into discrete, testable hypotheses across a range of scientific disci-plines. The output of the workshop is meant to be a ‘hy-pothesis document’ serving as a starting point for cata-loging and condensing specific hypotheses for consid-eration by the scientific community. The template for this approach is based on the “driving hypotheses” de-veloped by the OSIRIS-REx team as part of their Sam-ple Analysis Plan [6].

Michael A Mischna↗

Development of Advanced Ablative Carbon Phenolic TPS for Future NASA Missions and Commercial Space

Phenolic Impregnated Carbon Ablator (PICA) is a low-density carbon phenolic ablator that has been used as the planetary entry heatshield for several NASA missions since the late 90’s. Its low density and efficient performance characteristics have proven effective for use from Discovery to Flagship class missions, from Sample Return missions such as Stardust, OSIRIS-REx to large Mars lander missions such as MSL and Mars 2020. Continued development of a mass efficient, compliant version of PICA that use a carbon felt as the substrate will be presented. The felt based versions of PICA known as Conformal PICA (C-PICA) is comparable in terms of peak heat-flux capabilities compared to standard PICA. Additionally, a novel all felt PICA-Flex offers further reductions in density, with higher thermal protection efficiency resulting in additional mass savings beyond C-PICA. Furthermore, the compliant nature of these materials allows for application without Strain Isolation Pad to a wide variety of substrates, making attractive for commercial low earth orbit missions as well as NASA’s aerocapture missions to Ice Giants. NASA is currently working with several commercial partners (Varda and Inversion Space) to Technology Transfer C/S-PICA variants for commercial LEO missions. Preliminary thermal and mechanical tests have been conducted comparing the performance of Conformal and Soft-PICA and PICA-Flex materials.

Flexible Ablative TPS↗

Transmission Electron Microscopy of Carbonaceous Matter in Bennu Aggregate Samples

Preliminary analyses of regolith samples from asteroid Bennu show high bulk carbon abundances (~4.7 wt.%). The organic matter is readily apparent in scanning electron microscopy (SEM), transmission electron microscopy (TEM), and NanoSIMS observations. A major objective of the OSIRIS-REx mission is to understand the nature and origin of the pre-biotic organic matter inventory in Bennu samples. Here we report on TEM studies of indigenous organic matter in Bennu aggregate samples.

L P Keller↗

Hydrogen Isotopic Composition of Hydrous Minerals in Particles From Bennu

On September 24, 2023, NASA’s OSIRIS-REx mission delivered to Earth ~121 g of pristine carbonaceous regolith from asteroid Bennu. A first series of mineralogical observations and chemical/isotopic analyses of Bennu aggregate samples (fine to coarse particles up to a few mm) revealed that this material resembles the most chemically primitive chondrites and the samples returned by the JAXA’s Hayabusa2 mission from the carbonaceous asteroid Ryugu. Laboratory studies have confirmed the story gleaned from the spacecraft encounter that Bennu’s rock fragments underwent extensive aqueous alteration and are predominantly composed of hydrated minerals (serpentine, smectite) and other secondary minerals (e.g., magnetite, carbonates). The secondary phases were likely formed under the presence of liquid water on Bennu’s parent asteroid. The isotopic compositions of hydrous minerals and secondary phases can increase our understanding of the source and distribution of water and volatile elements in the protoplanetary disk [e.g., 5-8]. However, direct estimates of the hydrogen isotopic ratios (D/H) in hydrous minerals cannot be obtained easily in primitive rocks due to the difficulty in estimating the organic matter (OM) contribution to the whole H budget. In order to obtain hints on the initial constituents of Bennu’s parent asteroid and to test if Bennu's parent asteroid have formed beyond the snow line (hypothesis 4 of [9]), we measured the D/H and C/H ratios in chondritic matrices by secondary ion mass spectrometry (SIMS) and obtain information on the D/H ratio of water retained in the hydrated minerals. The method also gives clues on the hydrogen isotope variability among different Bennu rock fragments made available for measurement.

L Piani↗

Noble Gases in Samples Returned From Asteroids Ryugu and Bennu

Introduction: The asteroid sample return missions, JAXA’s Hayabusa2 [1] and NASA’s OSIRIS-REx [2], fromC-rich asteroids Ryugu and Bennu offer unique opportunities to sample pristine early solar system material, unaffected by terrestrial weathering and contamination, and with a known geological context. The comparison with most primi-tive members of carbonaceous –and inner solar system ordinary and enstatite– chondrite classes allows us to (i) assess the variation (or the lack of thereof) of the distribution of the most volatile elements throughout the entire early solar system, (ii) determine the effects of parent body thermal and aqueous alteration, and (iii) learn about the dynamic evolution and history of the various parent bodies, as sampled by both return missions and meteorite delivery. Here we will present noble gas data obtained from newly received particles from Ryugu and Bennu. Samples & Analysis: We received nine particles allocated by JAXA, with masses of 0.5-1.7 mg mass: four col-lected during Hayabusa2’s first touchdown (chamber A) and five from a small artificial crater (chamber C). We received three particles from Bennu of 0.07, 0.89 and 0.94 mg mass (OREX-800032-102/3/4). All particles were processed, allocated, weighed, and transferred into our UHV sample chamber within pure N2, to prevent any contact with air. We examined all He-Xe isotopes with our custom-built mass spectrometer “Albatros” ([3,4]). Gases were extracted individually from each particle by melting induced by a 1064 μm Nd:YAG IR laser in 2–4 heating steps. Large amounts of water and other reactive volatiles were released, consistent with the presence of abundant volatiles from both Ryugu and Bennu. Residues of Ryugu particles remaining after lasering, subsequently exposed to air, were additionally extracted in a crucible to verify complete gas extraction. Only the particle that still showed a “crystalline” structure after lasering contained detectable Ryugu noble gases, whereas all other particles turned immediately into glassy spheres by laser heating and lacked any gas. Results & Discussion: Ryugu and Bennu matter contains noble gases similar to the most pristine, unheated aqueously altered meteorites, e.g., CM or CI chondrites [5,6]. Remarkably, all four chamber A samples that originated from Ryugu’s surface show solar wind (SW) Ne (trapped (20Ne/22Ne)tr ~12–13), whereas all five chamber C samples do not ((20Ne/22Ne)tr ~9.0–10.7 consistent with the presence of non-solar trapped Ne components such as Q and HL). This demonstrates that JAXA’s sampling strategy succeeded: Chamber C samples analyzed in this work originated from areas shielded from SW, slightly below the surface, that was sampled after the impactor excavated material. The three Bennu particles populate the same range as the Ryugu particles in Ne isotope space with one particle containing SW suggesting that it was part of the uppermost surface layer of Bennu during sampling, while Ne in the smallest sample can be explained best by mixing Ne from presolar diamonds and SiC or graphite, and that in the third one by mixing of, e.g., Q and HL. Using cosmic ray production rates given by [7] yields preliminary exposure ages for Ryugu particles in the same range as determined in [7]. There is, as expected, also no systematic difference between samples from chambers A and C because both sample sets were likely collected within the uppermost layer of Ryugu, which were not shielded from cosmic rays. The concentration of cosmogenic (cos) Ne in the Bennu particle, where Necos was resolvable, is in the same range as found for Ryugu, suggesting roughly similar exposure time to cosmic rays for 5–8 Ma for all particles examined here. The Xe isotopic compositions of all particles are consistent with those of phase Q, with small additions of Xe-HL from presolar diamonds and excess 129Xe* from short-lived 129I decay. The comparably high 129Xe*/129XeQ ratio is similar in all samples, suggesting similar initial I concentrations and closure to Xe loss –or the incorporation of a well-mixed Xe reservoir. The Bennu material was in brief contact with air in the capsule, after atmospheric entry and before storage in pure N2 in a clean room. Both, the –most diagnostic– Xe isotopes and the Ar/Xe vs. Kr/Xe systematics prove that the noble gases are not affected by terrestrial contamination, in contrast to many CI, CY, and CM chondrites found on Earth [5,6], illustrating the importance of sample return. He-Xe concentrations in all particles unaffected bySW are comparable to but at the upper end of ranges reported [5-7]. In accordance with the strong aqueous alteration experienced on the parent bodies of Ryugu and Bennu [1,2], all samples lack the Ar-rich and water-susceptible noble gas components found in less aqueously altered CMs or CRs [e.g., 5,8] and all COs.

Henner Busemann↗

Genetic Relationships and the Nucleosynthetic Heritage of the Asteroid Bennu

The OSIRIS-REx sample return mission visited the B-type asteroid Bennu and delivered 121.6 gof pristine material to Earth in September 2023. Genetic links between this pristine material and different meteorite groups can be determined using nucleosynthetic isotope variations. These variations reflect the heterogeneous distribution of isotopically distinct dust from different stellar environments within the protoplanetary disk. They can therefore be used to constrain different formation locations of parent asteroids [e.g., 1]. In addition, isotope variations are powerful tracers to establish the nucleosynthetic heritage of returned samples [e.g., 2] and to evaluate mixing and reservoir formation within the disk. Here we present nucleosynthetic Ti and Fe isotope data for samples from Bennu and several carbonaceous chondrites. We also report the Ti isotope composition of hand-picked matrix fractions from CR and CV meteorites.

M Rüfenacht↗

Organic Matter and Nanoglobules in Bennu Samples Revealed By Coordinated UV Fluorescence, SEM-EDX, and Two-Step Laser Mass Spectrometry

Carbonaceous meteorites are derived from asteroids, although specific parent bodies are generally unknown. However, on September 24, 2023, NASA’s Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission delivered regolith from the carbonaceous B-type asteroid (101955) Bennu, enabling coordinated laboratory analysis of pristine samples, with a well characterized geological context, from an asteroid of known provenance. One of primary mission goals [1] was the identification and characterization of primordial organic matter present in the returned samples. We report results from the coordinated analyses of Bennu samples using UV fluorescence, two-step laser mass spectrometry (μ-L2MS) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX).

Asteroid Bennu↗

Investigating Material Behavior in Atmospheric Entry Conditions: Arc-Jet Testing Insights from Meteorite Ablation to High-Temperature Coatings.

Arc-jet testing is an indispensable tool in elucidating the complex interactions materials undergo when subjected to the extreme thermal and mechanical stresses of atmospheric entry. By replicating these harsh conditions, arc-jets enable researchers to explore critical phenomena such as ablation, melting, and spallation, generating invaluable data that informs the development of sophisticated, physics-based models. These models are pivotal not only in predicting material performance for spacecraft re-entry systems but also in assessing the threat posed by celestial bodies as they encounter Earth’s atmosphere. One of the leading facilities for such investigations is the Hypersonic Materials Environmental Test System (HyMETS) at NASA’s Langley Research Center. A pioneering test campaign conducted at HyMETS focused on unraveling the ablation mechanisms of an ordinary chondrite meteorite (Tamdakht H5) and a terrestrial analog (basalt). These studies unveiled distinct material behaviors: Tamdakht demonstrated a remarkably stable melt flow, with mass loss primarily driven by the volatilization of elements such as iron and sodium, whereas basalt exhibited more aggressive surface degradation due to the rapid decomposition of hydrated minerals, culminating in significant spallation and surface material ejection. Beyond meteorite analysis, HyMETS has also been integral in the exploration of advanced Thermal Protection Systems (TPS) such as Phenolic Impregnated Carbon Ablator (PICA), a material with extensive flight heritage in missions like Stardust, Mars Science Laboratory, Mars 2020, and Osiris-REx. PICA, when coated with NuSil CV-1144-0—a polysiloxane resin designed to prevent particle shedding—undergoes a remarkable transformation upon heating. The resin pyrolyzes to form a thin, oxidation-resistant silicon oxycarbide layer that profoundly influences the material’s thermal response through a sophisticated four-stage process. Initially, the silicon oxycarbide acts as a formidable barrier, impeding reactive interactions with the PICA char and effectively suppressing surface temperature rise and material recession. However, as the heating persists, the protective layer decomposes via carbothermal reduction, exposing the underlying char, which in turn leads to a dramatic spike in surface temperature and accelerated material erosion. In the final stage, equilibrium is reached, with recession rates aligning with those of the virgin material. This intricate understanding of PICA-NuSil behavior under extreme conditions offers valuable insights, enhancing material response models and advancing the development of next-generation TPS for space exploration.

Chemistry↗

Current Status of Martian Moons eXploration (MMX) Contamination Control and Curation Activity

Martian Moons eXploration (MMX) is a sample return mission from the Martian moon Phobos. The MMX spacecraft is scheduled to launch in 2026 and return to Earth in 2031. The main science goals of MMX are “to reveal the origin of the Martian moons and make progress in the understanding of planetary system formation and material transport in the solar system, and to observe processes that impact the circumplanetary and surface environments of Mars”. MMX has two sampling systems: coring (C)-sampler and pneumatic (P)-sampler and plans to bring back >10 g of Phobos sample. The retuned sample in the sample capsule will be transferred to the curation facility in ISAS/JAXA for sample curation and subsequent sample analysis. Contamination control of the sample return mission requires special care to prevent terrestrial contamination to the spacecraft, which would ruin the scientific value of the returned sample. Retaining the pristineness of the retuned sample is an important task of the MMX Curation and Sampler Science teams. The basis of the contamination control is (1) to minimize and understand the nature and amount of contaminants, (2) to perform contamination assessment and evaluate the effect of contaminants in the spacecraft on the retuned sample, (3) to employ a contamination knowledge (CK) material coupon in the spacecraft to identify the contaminants in the returned samples. In the MMX contamination control plan, the allowable contamination level for each contaminant is carefully defined. They are mostly set to be 1/1000 of the expected amount of each material in the returned sample and are divided into two main categories: organic and inorganic. The allowable atmospheric leakage rate to the sample container is also defined. The allowable contamination level of the organic materials is based on the composition of carbonaceous chondrites. The target contaminants are amino acids, aliphatic and aromatic hydrocarbons, carboxylic acids, etc. In case of the inorganic materials, the target contaminants are important elements to permit distinguishing the origin of the Martian moon by nucleosynthetic isotope anomalies (Cr, Ti, and Mo) and to reveal the evolution of the Martian moon by chronology (Hf, W, U, Pb, Rb, Sr, Sm, and Nd). The key instrument of contamination control in the sample return mission is the sampler system. The C-sampler has been developed by JAXA and the P-sampler was provided by Honeybee/NASA. In MMX, materials used in the two samplers (C- and P- sampler) were carefully selected to avoid potential contamination from the design stage of the system. The individual parts of the C-sampler FM (Flight Model) were thoroughly cleaned at the curation facility in ISAS/JAXA by the full-course cleaning procedure, which is an ultrasonic cleaning with organic solvents and ultrapure water in several steps. The equivalent level of cleaning was also carried out on the P-Samper FM as well by Honeybee Robotics in the USA. Now, MMX is in the critical phase for contamination control called ATLO: Assembly, Test, and Launch Operations. During the ATLO phase, sampler FM is constantly purged with nitrogen gas and maintained at positive pressure to prevent environmental contamination. The surrounding environments of the sampler FM are also simultaneously monitored using the CK Monitoring Coupon Set, which consists of several witness materials such as a glass petri dish, sapphire glass disk, and carbon adhesive tape (Figure 1). The detailed environmental assessment of each clean room used for the assembly and test of the sampler FM has also been conducted. This assessment includes microbial analysis, which was performed for OSIRIS-REx. Regarding the sample recovery and sample curation, we have started the designing of Sample Container Disassembling Instrument for the sample recovery from the sample container and the MMX curation chamber for sample curation. The curation protocol for the Phobos returned sample has also been discussed by the MMX Sample Analysis Working Team (SAWT). The MMX curation protocol consists of three phases: (1) quick analysis, (2) pre-basic characterization, and (3) basic characterization. (1) is extraction of the sample gas from the sample container and analysis by mass spectrometry, (2) is observation in bulk level, and (3) is observation in grain level and allocation of the sample aliquots. In parallel with the curation protocol, the returned sample undergoes preliminary examination for scientific investigations to achieve science goals. In addition, the CK witness plates made of sapphire glass are on board the sampler system. The CK witness plates will be recovered from the sampler system and analyzed by SAWT for the assessment of in-flight contamination.

Haruna Sugahara↗

TPS Technology Status on Enabling New Frontiers Sample Return Missions from Moon, Asteroids and Comets and Probe Missions to Saturn and Uranus

STMD and SMD investment in TPS technology development such as Heatshield for Extreme Entry Environment (HEEET), 3-D woven Mid-Density Carbon Phenolic (3MDCP) and Conformal PICA over the past decade in response the the Decadal Committee Recommendation (2012). 3MDCP, a variant of HEEET, is baselined as the TPS for MSR, HEEET is enabling the Rocket Lab mission to Venus and Conformal PICA enabled VARDA as the heat shield TPS for their sample return capsule Winnebago-1. In the meantime, PICA, the TPS that enabled Stardust and OSIRIS-REx has atrophied. While these are success stories, upcoming NF-5/6 AO is anticipated to have multiple proposals that may be more demanding for sample return missions from Moon, Asteroids and Comets, and in addition probe missions to Saturn and UOP . This poster will address the state-of-the-art TPS for NF-5/6 in-situ and sample return missions, and for the UOP flagship mission. The poster will focus on steps that need to be taken to both advance and sustain NASA developed TPS and be ready to enable NF-5/6 and Flagship missions.

Todd White↗

The Nature of Space Weathering in Samples From Asteroid (162173) Ryugu Revealed By Coordinated Analysis

Space weathering, driven primarily by micrometeorite bombardment and solar wind ion irradiation, alters the morphology, microstructure, and chemistry of the surface regolith on airless bodies. The accumulation of microstructural and chemical space weathering features, including melt deposits, amorphous rims, and nanophase iron-bearing particles (npFe), are associated with alterations of the spectral properties of the regolith. In particular, space weathering changes the spectral slope and reflectance of surface materials, and causes the attenuation of characteristic absorption bands in the visible to near-infrared wave-lengths, as well as a shift towards longer wavelengths of the Christiansen feature (CF)in thermal infrared spectra. Previous studies of space weathering characteristics have focused on siliceous bodies like the Moon and S-type asteroid Itokawa. However, observations of asteroid Ryugu by the JAXA Hayabusa2 spacecraft and subsequent analyses of returned samples revealed carbonaceous and hydrated materials. These samples provided our first opportunity to constrain the effects of space weathering processes on primitive, C-type asteroids. Analyses of returned samples to understand the space weathering of carbonaceous materials are important for accurately interpreting remote sensing observations of carbonaceous asteroids. In addition, the analysis of Hayabusa2 samples from Ryugu paved the way for the analysis of samples from the asteroid Bennu, re-turned by the NASA OSIRIS-REx mission. As space weathering impacts the microstructure, chemistry, and spectral characteristics of asteroidal surfaces, here we report the results of a coordinated analytical study of the micro-and nano-scale signatures of space weathering in samples returned from Ryugu.

L E Melendez↗

An Overview of Experiments and Modeling of Polysiloxane-Coated Thermal Protection Systems for Missions to Mars, Titan, and Beyond.

Phenolic Impregnated Carbon Ablator (PICA) gained heritage during the historic Stardust mission, where it successfully returned samples from a comet’s tail and has since been instrumental in delivering payloads to the surface of Mars [1-3]. Most recently, PICA enabled the safe return of samples collected from asteroid Bennu as part of the OSIRIS-REx mission. This rich legacy underscores PICA’s critical role in allowing NASA’s most ambitious exploration missions. However, the friable nature of its phenolic phase presents challenges during handling and pre-launch activities. To mitigate this issue, PICA is coated with a polysiloxane resin system, which serves to suppress particulate dispersion and thereby safeguard spacecraft components. A comprehensive understanding of the polysiloxane resin’s behavior is imperative, as it profoundly shapes the material response of PICA during atmospheric entry by influencing its thermal and oxidative stability. This influence extends to thermocouple plugs embedded within thermal protection systems. These plugs have demonstrated their significance in missions such as Mars Science Laboratory (MSL) and Mars 2020, where the MEDLI and MEDLI2 instrumentation suites delivered in-valuable insights into the performance of thermal protection systems during entry into the Martian atmosphere [4]. Looking ahead, missions such as Dragonfly, set to descend into Titan’s dense atmosphere, aim to leverage advanced sensor technologies to further refine our understanding of thermal protection response [5]. Moreover, thermocouple plugs play an essential role in validating cutting-edge material response models, such as those pioneered under NASA’s Entry Systems Modeling Project (ESM), designed, in-part, to predict the operational integrity of thermal protection systems under the extreme stresses of atmospheric entry. To achieve these modeling goals, ground-based experiments are crucial to provide the foundational data necessary for developing and refining these predictive tools. To this end, an extensive test campaign was conducted at the Hypersonic Materials Environmental Test System (HyMETS) to investigate the high-temperature behavior of the polysiloxane resin in an air environment [6]. These experiments revealed critical phenomena, including the formation of a silicon oxycarbide layer that enhances oxidation resistance, moderates surface temperatures, and alters in-depth thermal response. Building on these findings, subsequent tests were designed to simulate atmospheric entry conditions in reactive gases, such as CO2 and N2, to mimic the environments of Mars and Titan, respectively, as well as non-reactive gases representing the atmospheres of the Ice Giants (Neptune and Uranus). A heating rate dependent decomposition mechanism has been identified for the polysiloxane resin under oxidizing conditions (Fig. 1). In the initial stage, the resin and the underlying thermal protection system undergo pyrolysis, rapidly generating a thin amorphous silicon oxycarbide interwoven with carbonaceous char and residual fibers from PICA. During the second stage, the nascent oxide layer establishes a robust, oxidation-resistant thermal barrier coating, which significantly impedes heat transfer to the underlying carbonaceous char, resulting in a stagnation of the surface temperature. A key factor contributing to this thermal resistance is the low recombination efficiency of atomic oxygen (γ), which further diminishes the heat load on the material’s interior layers [7]. Moreover, as the surface temperature stagnates, the silicon oxycarbide phase separates into distinct regions of silica and free graphite. Ultimately, when the heat flux reaches a critical threshold, a third stage is triggered, leading to the breakdown of the coating through carbothermal reduction, exposing the underlying char layer. This exposure leads to a dramatic surface temperature spike, driven by highly exothermic reactions between atomic oxygen and the char layer, further accelerating material degradation. A detailed mass and heat transfer model of PICA coated with polysiloxane resin was implemented in the Porous material Analysis Toolbox based on OpenFOAM, PATO [8]. The initial stage was considered negligible in this model because the resin decomposition occurs rapidly within a thin surface layer. Instead, the coating was directly considered as an oxygen-resistant thermal barrier coating. For the second stage, the thin amorphous silicon oxycarbide was treated as a pure silica surface to simplify the thermochemical behavior. The model ac-counts for surface equilibrium processes using representative elements of the coating-environment system. For the third stage, specific boundary conditions were developed to estimate the onset and progression of the coating removal. Two-dimensional material response simulations were conducted to compare uncoated and coated PICA using boundary conditions calibrated with HyMETS data. Fig. 2 illustrates that the simulations closely align with experimental data, successfully reproducing measured temperature profiles. This work will include the latest advancements in the coating model, including the calibration of recombination of atomic oxygen at the surface during the second phase. These simulated results will be further validated against additional CO2 data points from HyMETS, reinforcing the models’ predictive capabilities. These mechanisms and their effects on thermal protection systems, including thermochemical behavior and thermocouple probe performance in extreme environments, provide crucial insights for optimizing spacecraft designs that safeguard scientific payload and ensure mission success in future planetary exploration endeavors.

Active Oxidation↗

Phosphate Textural Diversity in CI Chondrites and C-Type Asteroids

Introduction: Apatite, Ca 5 (PO 4 ) 3 (CL/F/OH-), is a ubiquitous phosphate found throughout the solar system, including the most primitive solids, CI-chondrites [1,2] and related samples of carbonaceous asteroids Ryugu [3] and Bennu [4], returned by JAXA’s Hayabusa2 and NASA’s OSIRIS-REx missions, respectively. Apatite in these primitive solids is found as individual grains or mineral clusters and has been inferred to form from the hydrothermal sequence during cooling of their respective parent body or bodies. To better understand the formation history and reworking of these early phosphates we have undertaken a highly coordinated study of phosphate microstructures, geochemistry and U/Pb geochronology from a suite of CI meteorites and carbonaceous asteroid samples. These data have identified novel phosphate microstructures and complex relationships across a suite of apatite grains from the early solar system, indicating multiple episodes of growth and modification on the CI parent body(ies). Methods: Samples of CI chondrites, Alais, Ivuna, Orgueil, Oued Chebeika 002, Yamato (Y) 82162, Y980115, Y980134, and two chips of Hayabusa2 Ryugu particles (A0262 and C0263) have been acquired for analysis. The bulk texture of the samples were first scanned by X-ray Computed Tomography (XCT) using the Nikon XT H 320 within the XFACT facility at NASA JSC or the Xradia 620 Versa at the UTCT facility. Based on the identification of petrofabrics or features of interest from the XCT data, samples were chipped, oriented, potted in epoxy and thick sections were prepared. After anhydrously polishing the samples with silicon carbide and dry diamond powder down to 1 µm, the samples were ion polished using a Hitachi ArBlade. Energy dispersive Xray spectrometry (EDS) maps were collected to ID phosphates of interest using a JEOL 7900F SEM. The internal microstructures of identified phosphates were then mapped by electron backscatter diffraction (EBSD) using the JEOL 7900F. Based on the EDS and EBSD data, domains of interest were targeted for quantitative chemical analyses using a JEOL 8530 EPMA. Subsequently, in situ U-Pb and 207 Pb/ 206 Pb ages will be collected using a Cameca ims1290 secondary ion mass spectrometer at UCLA across a range of microstructures. Results: Apatite grains are ubiquitous throughout the CI chondrites and carbonaceous asteroid materials, found as individual grains, disseminated clusters or grain aggregates. Apatite grains are associated with serpentine, magnet-ite, and/or carbonate. Of particular interest, we have identified individual and aggregate polycrystalline grains ex-hibiting an internal ‘honeycomb’ texture (Fig. 1). Some of these grains appear overprinted by subsequent alteration while others remain unaltered. Apatite halogen sites are dominated by the missing component, assumed to be OH, and F, comparable to published values from Bennu, Ryugu and CM-chondrites [3-5]. However, the Yamato CI-like meteorites show a broader range of Cl values, and one grain from Alais is dominated by CL. Summary: Apatite growth features indicate a protracted and complex growth history, consistent with precipitation from an evolving fluid system. The ‘honeycomb’ texture identified in some CI meteorites is, to the best of our knowledge, the first report of such a microstructure in meteoritic phosphate. The microtextures and zoning will guide subsequent age analyses, to better constrain the formation and reworking of phosphate in CI(-like) materials. Acknowledgments: We thank the National Institute of Polar Research, Japan for samples of Y82162, 980115 and 980134 meteorites, ASU’s Buseck Center for Meteorite Studies for samples of Ivuna and Alais meteorites, and JAXA curation for chips of Ryugu material. This work was funded by NASA ROSES LARS grant 24-LARS24-0014. References: [1] Morlok et al., 2016, GCA 70:5371-5394. [2] Alfin g et al., 2019, Geochemistry 79:125532. [3] Nakamura et al. (2022) Science 379:1-15. [4] Seifert et al. (2026) MAPS 61:504-521. [5] Piralla et al. (2021) MAPS 56:809-828.

CI chondrites↗

Evidence of an Extended Period of Aqueous Alteration on the Bennu Parent Body Revealed By I-Xe Analyses

NASA’s OSIRIS-REx mission delivered to Earth 121.6 g of regolith material from asteroid Bennu on 24th September 2023. We report multi-step laser pyrolysis xenon isotopic analysis to investigate the I-Xe system in individual particles separated from aggregate material (a mixture of small particles of undefined lithology). The high sensitivity of the RELAX mass spectrometer allows us to observe small excesses of individual isotopes and separate out different components, which may not be possible using a conventional noble gas mass spectrometer. The temperature resolution of RELAX is sufficient to seek an I-Xe isochron from step heating analysis of a sample mass <100 μg, which can contribute to our understanding of the nature and timing of aqueous alteration on Bennu’s parent body. We also aim to better estimate and understand the iodine concentration of CI chondrite-like material.

S A Crowther↗

Adaptive Curation at NASA Johnson Space Center: Preparing for Artemis Samples by Leveraging Proven Practices and Innovative Solution

The proper curation of returned astromaterial samples is essential to ensure that high-quality scientific investigations can be conducted for decades, enabling future generations to address evolving research questions. The Astromaterials Acquisition and Curation Office at NASA Johnson Space Center (hereafter JSC Curation) is responsible for curating all of NASA’s extraterrestrial samples. Under the governing document, NASA Procedural Requirement (NPR) 7100.5 “Curation of Extraterrestrial Materials”, JSC Curation is charged with “The curation of all extraterrestrial material under NASA control, including future NASA missions.” The Directive goes on to define Curation as including “...documentation, preservation, preparation, and distribution of samples for research, education, and public outreach.” JSC Curation has a long-standing legacy of curating extraterrestrial materials, including but not limited to Apollo and Luna lunar samples, Genesis solar wind samples, Stardust comet samples, asteroid samples (Hayabusa1, Hayabusa2, and OSIRIS-REx), and Antarctic Meteorite samples from a variety of parent bodies. Building on this foundation, the Artemis program introduces new challenges and opportunities for sample curation, requiring both the application of proven practices and the development of innovative solutions. The Artemis Collection will be curated using established protocols refined through decades of experience with Apollo and subsequent sample collections, including but not limited to the utilization of cleanrooms, custom nitrogen gloveboxes, specialized storage containers and tools; all of which have strict material utilization and prohibition requirements. These practices provide a robust framework for contamination control, documentation, and long-term preservation. However, Artemis samples may present unique scientific and operational requirements, including enhanced contamination control measures (relative to Apollo) driven by evolving science objectives. To meet these needs, JSC Curation is actively developing new technologies and protocols that extend beyond traditional approaches, ensuring that the integrity of samples is maintained under increasingly stringent standards. One critical area of innovation is the development of cold sample curation capabilities. Certain Artemis samples, particularly those from Permanently Shadowed Regions (PSRs) and cold environments, are expected to contain ices and volatile components that require preservation and handling at sub-zero or even cryogenic temperatures. JSC Curation is leveraging best practices from the cold and cryogenic sample industries, as well as other government agencies and academic experts, to design facilities and handling procedures that maintain sample integrity while enabling scientific access. The goal is to develop capabilities to allow researchers to investigate volatiles and other temperature-sensitive materials while minimizing chemical and physical alterations from their returned state. In summary, adaptive curation at JSC combines the reliability of proven methodologies with forward-looking innovations to meet the scientific and operational demands of Artemis. Through enhanced contamination control, advanced cold curation capabilities, and an understanding of known and evolving future science priorities, NASA is preparing to maximize the scientific return from Artemis samples and preserve their value for generations of researchers.

Andrea D Harrington↗