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At least 343 records · Page 19

Oligomerization reactions of deoxyribonucleotides on montmorillonite clay - The effect of mononucleotide structure on phosphodiester bond formation

The formation of oligomers from deoxynucleotides, catalyzed by Na(+)-montmorillonite, was investigated with special attention given to the effect of the monomer structure on the phosphodiester bond formation. It was found that adenine deoxynucleotides bind more strongly to montmorillonite than do the corresponding ribonucleotides and thymidine nucleotides. Tetramers of 2-prime-dpA were detected in the reaction of 2-prime-d-5-prime-AMP with a water-soluble carbodiimide EDAC in the presence of Na(+)-montmorillonite, illustrating the possible role of minerals in the formation of biopolymers on the primitive earth.

Ferris, James P.↗

Limits on the density of neutral gas within 100 parsecs from observations of the soft X-ray background

Observations are presented in two soft X-ray bands, the Be band (0.077-0.111 keV) and the B-prime (0.105-0.188 keV), for nine directions in the sky. The ratio of count rates in these two bands remains constant as the rates vary by a factor of three, even though the effective interstellar absorption cross sections in the bands differ by a factor of about 3.5. For a model in which the bulk of the observed soft X-ray emission originates in a uniform low-density region surrounding the sun, the constant ratio between the band rates places an upper limit on the amount of neutral material that can be homogeneously mixed with the X-ray-emitting gas. The 2 sigma upper limit on the H I column density over an average path through the local emitting region is 6.6 x 10 to the 18th/sq cm. If the average path length is about 100 pc, then clouds similar to the one in which the sun is embedded could still have a filling factor as large as 25 percent.

Juda, M.↗

The effect of nonlinearities on the dynamic response of a large Shuttle payload

The STS Centaur was designed to be a high energy upper stage for use with the Space Shuttle. Two versions were designed and under development when the program was cancelled. The first version, designated G-prime, was designed for planetary missions. The second version, designated G, was designed to place spacecraft in geosynchronous orbit. As a part of the STS Centaur finite-element model verification effort, test articles of both versions were subjected to a series of static tests. In addition the Centaur G-prime test article was subjected to a series of dynamic tests including a modal survey. Both the static and dynamic tests showed that nonlinearities existed in the Centaur and its support system. The support system included flight-like latches. The nonlinearities were particularly apparent in tests that loaded the forward support structure of the Centaur. These test results were used to aid in the development of two improved finite-element models. The first was a linear model, while the second contained nonlinear elements at the boundaries. Results from both models were compared with the transient response obtained from a step-relaxation or twang test. The linear model was able to accurately match the low frequency response found in the test data. However, only the nonlinear model was able to match higher frequency response that was present in some of the test data. In addition the nonlinear model was able to predict other nonlinear behavior such as the dynamic 'jump' that occurs in systems with nonlinear stiffness.

Sullivan, Timothy L.↗

Optimizing bioenergy sorghum productivity and nutrient removal in Illinois: Impact of nitrogen fertilization under diverse marginal conditions

Bioenergy sorghum (Sorghum bicolor L. Moench) is a promising crop for contributing to the United States bioenergy supply. However, the varying limitations of the marginal lands targeted for its cultivation present a management challenge. This two-year study aimed to investigate how the limitations associated with marginal cropland impact the effects of nitrogen fertilization on the yield of bioenergy sorghum and the uptake of 11 macro- (N, P, K, Ca, Mg, and S) and micronutrients (Fe, Mn, Zn, Cu, and B). The study contrasted prime cropland in central Illinois (Urbana) with three marginal cropland sites in southern (Ewing) and central Illinois (Fairbury and Pesotum). These marginal cropland sites are characterized by varying limitations, including low soil fertility (P and K limitations), leaching and erosion, and flooding, respectively. Four nitrogen rates (0, 56, 112, and 168 kg N ha –1 ) were tested under eight environments. The average yields and ranges of sorghum biomass were 20.2 (17.0–23.2) Mg ha –1 in Urbana, 18.1 (13.1–19.8) Mg ha –1 in Ewing, 13.8 (9.0–17.3) Mg ha –1 in Fairbury, and 23.3 (14.6–33.0) Mg ha –1 in Pesotum. Optimal N rates were 56 N in Pesotum and 112 N in Urbana, Ewing, and Fairbury. Tissue macronutrient contents in Urbana were generally higher than in the marginal croplands, while micronutrient contents did not show discernible trends. Increasing N rate generally correlated with the macronutrient removal except in Ewing. Comparable sorghum biomass yields were observed between prime and marginal croplands (averaging 18.3 Mg ha –1 ), but optimal N rates varied between 56 N and 112 N. This suggests that yield gaps can be narrowed by applying the optimal N rates for the respective locations. However, increased removals of macronutrients, especially P and K, with increasing yields indicate the need to revise fertilizer recommendations, particularly for soils deficient in these nutrients.

09 BIOMASS FUELS↗

Data for Optimizing Bioenergy Sorghum Productivity and Nutrient Removal in Illinois: Impact of Nitrogen Fertilization Under Diverse Marginal Conditions

Bioenergy sorghum ( Sorghum bicolor L. Moench) is a promising crop for contributing to the United States bioenergy supply. However, the varying limitations of the marginal lands targeted for its cultivation present a management challenge. This two-year study aimed to investigate how the limitations associated with marginal cropland impact the effects of nitrogen fertilization on the yield of bioenergy sorghum and the uptake of 11 macro- (N, P, K, Ca, Mg, and S) and micronutrients (Fe, Mn, Zn, Cu, and B). The study contrasted prime cropland in central Illinois (Urbana) with three marginal cropland sites in southern (Ewing) and central Illinois (Fairbury and Pesotum). These marginal cropland sites are characterized by varying limitations, including low soil fertility (P and K limitations), leaching and erosion, and flooding, respectively. Four nitrogen rates (0, 56, 112, and 168 kg N ha−1) were tested under eight environments. The average yields and ranges of sorghum biomass were 20.2 (17.0–23.2) Mg ha−1 in Urbana, 18.1 (13.1–19.8) Mg ha−1 in Ewing, 13.8 (9.0–17.3) Mg ha−1 in Fairbury, and 23.3 (14.6–33.0) Mg ha−1 in Pesotum. Optimal N rates were 56 N in Pesotum and 112 N in Urbana, Ewing, and Fairbury. Tissue macronutrient contents in Urbana were generally higher than in the marginal croplands, while micronutrient contents did not show discernible trends. Increasing N rate generally correlated with the macronutrient removal except in Ewing. Comparable sorghum biomass yields were observed between prime and marginal croplands (averaging 18.3 Mg ha−1), but optimal N rates varied between 56 N and 112 N. This suggests that yield gaps can be narrowed by applying the optimal N rates for the respective locations. However, increased removals of macronutrients, especially P and K, with increasing yields indicate the need to revise fertilizer recommendations, particularly for soils deficient in these nutrients. Our study suggests that while sorghum production on marginal cropland is feasible, N management needs to be adapted to the unique limitations associated with various types of marginal cropland.

Biomass Analytics↗

Experimental and analytical characterization of triaxially braided textile composites

There were two components, experimental and analytical, to this investigation of triaxially braided textile composite materials. The experimental portion of the study centered on measuring the materials' longitudinal and transverse tensile moduli, Poisson's ratio, and strengths. The identification of the damage mechanisms exhibited by these materials was also a prime objective of the experimental investigation. The analytical portion of the investigation utilized the Textile Composites Analysis (TECA) model to predict modulus and strength. The analytical and experimental results were compared to assess the effectiveness of the analysis. The figures contained in this paper reflect the presentation made at the conference. They may be divided into four sections: a definition of the material system tested; followed by a series of figures summarizing the experimental results (these figures contain results of a Moire interferometry study of the strain distribution in the material, examples and descriptions of the types of damage encountered in these materials, and a summary of the measured properties); a description of the TECA model follows the experimental results (this includes a series of predicted results and a comparison with measured values); and finally, a brief summary completes the paper.

Masters, John E.↗

Remote sounding of surface radiative fluxes in cirrus cloudy conditions

It has been long recognized that radiation and radiation perturbations play a critical role in the climate system. Surface radiative fluxes are useful parameters for monitoring global change, for understanding of the effects of clouds on the radiation field, and for improving parameterization of surface sensible and latent heat fluxes. Monitoring of the radiation budget at the top of the atmosphere has been one of the prime satellite programs for the last 30 years. However, monitoring radiative fluxes at the surface over the globe from space cannot be performed in a direct way at the present time. In particular, since clouds are the prime regulators of the radiative fluxes, uncertainties in the retrieved cloud parameters, which are inputs to radiative transfer models, can introduce significant errors in the computed radiative fluxes. Thus, remote sounding of surface radiative fluxes in cloudy conditions requires the development of both satellite cloud retrieval scheme and radiation models. In this paper, we present results of computed surface radiative fluxes in cirrus cloudy conditions using a cirrus cloud retrieval scheme and a detailed radiative transfer program. Comparisons have been made between the computed surface radiative fluxes and the ground-based radiometer measurements obtained during FIRE-II-IFO, which was carried out near Coffeyville, Kansas, during November and December, 1991.

Ou, S. C.↗

Resist! : Sustaining forest carbon sequestration and wood production after insect disturbance

Disturbances from insect pests threaten ecologically and economically important goods and services supplied by forests, including wood production and carbon sequestration. We highlight the factors that influence these services’ resistance, a term quantifying the initial response to disturbance. Insects inflict damage through a range of mechanisms, prompting distinct plant physiological responses that scale to influence ecosystem processes and, with time, goods and services. The degree and timing of tree mortality and defoliation affect the amount of residual vegetation available to support compensatory wood production and influence carbon sequestration by changing rates of detritus-fueled decomposition. Compounding, or sequential, insect attacks may prime a forest for additional disturbance, further eroding wood production and carbon sequestration. Forest management practices that promote biological and structural diversity, and augment or retain limiting biological and nutrient resources, may buffer against the effects of insect pests on wood production and carbon sequestration.

Gough, Christopher M. [Virginia Commonwealth Univ.↗

Effect of inlet disturbances on fan inlet noise during a static test

Measurements of fan rotor inlet noise taken during static test situations are at variance with aircraft engine flight data. In particular, static tests generally yield a significantly higher tone at blade passage frequency than that measured during flight. To explain this discrepancy, the extent of the influence of inlet ground vortices and large-scale inlet turbulence on the forward-radiated fan noise measured at a static test facility was investigated. While such inlet disturbances were generated intentionally in an anechoic test chamber, far-field acoustic measurements and inlet flow-field hot-film mappings of a fan rotor were obtained. Experimental results indicate that the acoustic effect of such disturbances appears to be less severe for supersonic than for subsonic tip speeds. Further, a reverse flow that occurs on the exterior cowl in static test facilities appears to be an additional prime candidate for creating inlet disturbances and causing variance between flight and static acoustic data.

Bekofske, K. L.↗

Fan inlet disturbances and their effect on static acoustic data

There is evidence that measurements of fan-rotor inlet noise taken during static test situations are at variance with aircraft engine flight data. In particular, static tests generally yield a significantly higher tone at blade passing frequency than that measured during flight. An experimental program was carried out to investigate this discrepancy. Inlet ground vortices and large-scale inlet turbulence were generated intentionally in an anechoic test chamber. Far-field acoustic measurements and inlet flow field hot film mappings of a fan rotor were then carried out to study the influence of such inlet disturbances at a static test facility. Experimental results indicate that the acoustic effect of such disturbances appears to be less severe for supersonic than for subsonic tip speeds. Further, a reverse flow that occurs on the exterior cowl in static test facilities appears to be an additional prime candidate for creating inlet disturbances and causing variance between flight and static acoustic data.

Bekofske, K. L.↗

Independent Orbiter Assessment (IOA): FMEA/CIL assessment

The results of the Independent Orbiter Assessment (IOA) of the Failure Modes and Effects Analysis (FMEA) and Critical Items List (CIL) are presented. Direction was given by the Orbiter and GFE Projects Office to perform the hardware analysis and assessment using the instructions and ground rules defined in NSTS 22206. The IOA analysis features a top-down approach to determine hardware failure modes, criticality, and potential critical items. To preserve independence, the anlaysis was accomplished without reliance upon the results contained within the NASA and prime contractor FMEA/CIL documentation. The assessment process compares the independently derived failure modes and criticality assignments to the proposed NASA Post 51-L FMEA/CIL documentation. When possible, assessment issues are discussed and resolved with the NASA subsystem managers. The assessment results for each subsystem are summarized. The most important Orbiter assessment finding was the previously unknown stuck autopilot push-button criticality 1/1 failure mode, having a worst case effect of loss of crew/vehicle when a microwave landing system is not active.

Saiidi, Mo J.↗

DESI-253.2534+26.8843: A New Einstein Cross Spectroscopically Confirmed with Very Large Telescope/MUSE and Modeled with GIGA-Lens

Gravitational lensing provides unique insights into astrophysics and cosmology, including the determination of galaxy mass profiles and constraining cosmological parameters. We present spectroscopic confirmation and lens modeling of the strong lensing system DESI-253.2534+26.8843, discovered in the Dark Energy Spectroscopic Instrument (DESI) Legacy Imaging Surveys data. This system consists of a massive elliptical galaxy surrounded by four blue images forming an Einstein Cross pattern. We obtained spectroscopic observations of this system using the Multi Unit Spectroscopic Explorer on ESO's Very Large Telescope and confirmed its lensing nature. The main lens, which is the elliptical galaxy, has a redshift of z L1 = 0.636 ± 0.001, while the spectra of the background source images are typical of a starburst galaxy and have a redshift of z s = 2.597 ± 0.001. Additionally, we identified a faint galaxy foreground of one of the lensed images, with a redshift of z L2 = 0.386. We employed the GIGA-Lens modeling code to characterize this system and determined the Einstein radius of the main lens to be ${\theta }_{{\rm{E}}}=2\buildrel{\prime\prime}\over{.} {520}_{-0.031}^{+0.032}$, which corresponds to a velocity dispersion of σ = 379 ± 2 km s –1 . Our study contributes to a growing catalog of this rare kind of strong lensing system and demonstrates the effectiveness of spectroscopic integral field unit observations and advanced modeling techniques in understanding the properties of these systems.

79 ASTRONOMY AND ASTROPHYSICS↗

New aromatic silicon-containing polyamides

The experiments described were aimed at studying systematically the effect of silyl linkages on the thermogravimetric and thermomechanical properties of aromatic polyamides. Specifically, 18 aromatic silicon-containing polyamides were synthesized via interfacial polymerization of six silicon-containing diacid chlorides with 3,3-prime-diaminodiphenylmethane, 3,3-prime-diaminobenzophenone, and 1-(3-prime-aminobenzyl)-4-(3-double prime-aminobenzoyl)benzene. All polyamides were soluble in m-cresol and N,N-dimethylacetamide, and had glass transition temperatures between 178 and 254 C. Thermogravimetric analysis conducted in static air on film specimens showed 5 and 10 percent weight losses between 331 and 400 C and 354 and 440 C, respectively. The potential gain in processability engendered by incorporation of silane substituents was offset in most cases by substantial losses in thermo-oxidative stability.

Pratt, J. R.↗

Experimental study and improved modeling of high-temperature air radiation

Spectral emission measurements were conducted in an atmospheric pressure air plasma. The thermodynamic state of the plasma was determined to be close to local thermodynamic equilibrium (LTE), and the temperature profile was measured. The spectrum emitted by the plasma over the range 2,000 to 8,000 A was recorded and calibrated. This spectrum comprises the major radiating molecular bands and atomic lines in air, and is therefore proposed as a benchmark to test radiative calculations. A comparison of these results with the predictions of the NEQAIR code induced several modeling improvements in the code. In particular, radiative transition probabilities and spectroscopic constants were updated, and additional band systems of NO (NO Delta, Epsilon, Beta prime and Gamma prime) were included. Since the C state from which the NO Delta transition originates is predissociated, a simplified collision-predissociation model for this state was added to the code. These changes are presented, and their effect discussed.

Laux, Christophe O.↗

The impact of r -process heating on the dynamics of neutron star merger accretion disc winds and their electromagnetic radiation

Neutron star merger accretion discs can launch neutron-rich winds of >10 -2 M⊙. This ejecta is a prime site for r-process nucleosynthesis, which will produce a range of radioactive heavy nuclei. The decay of these nuclei releases enough energy to accelerate portions of the wind by ~0.1c. Here, we investigate the effect of r-process heating on the dynamical evolution of disc winds. We extract the wind from a 3D general relativistic magnetohydrodynamic simulation of a disc from a post-merger system. This is used to create inner boundary conditions for 2D hydrodynamic simulations that continue the original 3D simulation. We perform two such simulations: one that includes the r-process heating, and another one that does not. We follow the hydrodynamic simulations until the winds reach homology (60 s). Using time-dependent multifrequency multidimensional Monte Carlo radiation transport simulations, we then calculate the kilonova light curves from the winds with and without dynamical r-process heating. We find that the r-process heating can substantially alter the velocity distribution of the wind, shifting the mass-weighted median velocity from 0.06c to 0.12c. The inclusion of the dynamical r-process heating makes the light curve brighter and bluer at $\sim 1\, \mathrm{d}$ post-merger. However, the high-velocity tail of the ejecta distribution and the early ($\lesssim 1\, \mathrm{d}$) light curves are largely unaffected.

79 ASTRONOMY AND ASTROPHYSICS↗

Preliminary Results of Cyclical De-Icing of a Gas-Heated Airfoil

An NACA 65(sub 1)-212 airfoil of 8-foot chord was provided with a gas-heated leading edge for investigations of cyclical de-icing. De-icing was accomplished with intermittent heating of airfoil segments that supplied hot gas to chordwise passages in a double-skin construction. Ice removal was facilitated by a spanwise leading-edge parting strip which was continuously heated from the gas-supply duct. Preliminary results demonstrate that satisfactory cyclical ice removal occurs with ratios of cycle time to heat-on period (cycle ratio) from 10 to 26. For minimum runback, efficient ice removal, and minimum total heat input, short heat-on periods of about 15 seconds with heat-off periods of 260 seconds gave the best results. In the range of conditions investigated, the prime variables in the determination of the required heat input for cyclical ice removal were the air temperature and the cycle ratio; heat-off period, liquid water content, airspeed, and angle of attack had only secondary effects on heat input rate.

Gray, V. H.↗

The Astro-1 mission

The Astro-1 mission was to be launched in March 1986 for an effective duration of 7 days, chosen to overlap spacecraft encounters with Halley's Comet, i.e., Vega-2 (on 9 March) and Giotto (on 13/14 March). The ultraviolet instrument complement while not designed with cometary research as the prime objective, was well suited to the study of comets. The opportunity of an extended mission during the time of the spacecraft encounters of Halley's Comet offered an extraordinary opportunity for a synergistic interaction between the intercept spacecraft, the Earth-orbital Astro-1 mission, and ground-based observations. The addition of visual-wavelength, wide-field cameras would enhance the scientific return of the mission. Loss of Challenger cancelled the mission.

Brandt, J. C.↗

Basic characteristics of high-frequency Stark-effect modulation of CO2 lasers.

The molecular Stark effect and its application to the modulation of infrared laser radiation have been investigated both theoretically and experimentally. Using a density matrix approach, a quantum mechanical description of the effect of a time-varying electric field on the absorption coefficient and refractive index of a molecular gas near an absorption line has been formulated. For modulation applications a quantity known as the ?modulation depth' is of prime importance. Theoretical expressions for the frequency dependence of the modulation depth show that the response to the frequency of a time-varying Stark field is separated into a nondispersive and a dispersive region, depending on whether the modulating frequency is less than or greater than the homogeneous absorption linewidth. Experimental results showing nondispersive modulation at frequencies to 30 MHz are presented. In addition it is shown that the response of modulation depth to Stark field amplitude is separated into linear and nonlinear regions, the field at which nonlinearities begin being determined by the absorption spectrum of the molecule being used.

Claspy, P. C.↗