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At least 343 records · Page 19

Modular Processing of Flare Gas for Carbon Nanoproducts

This project demonstrated the technical viability and economic promise of a modular system for converting flared natural gas into valuable carbon nanoproducts (CNPs) through catalytic chemical vapor deposition (CVD). All major project milestones were successfully completed, including reactor design and commissioning, catalyst development, process optimization, technoeconomic analysis, and application testing in concrete systems. The overarching goal was to create a scalable, field-deployable process that valorizes stranded methane by producing high-value carbon materials for use in cementitious composites. At the lab scale, the team designed and built a fluidized bed reactor optimized for use with silica fume-supported nickel catalysts synthesized via atomic layer deposition (ALD). A statistically designed sintering study enabled precise tuning of nickel nanoparticle size, identifying the influence of oxygen partial pressure, time, and temperature on catalyst morphology and performance. These insights allowed the team to target catalyst conditions that maximize carbon nanofilament growth. Subsequent CVD experiments achieved up to 31.8 wt% carbon deposition under optimized conditions, with TEM confirming the presence of nanofilament structures and sustained hydrogen evolution during reaction. Reactor upgrades and empirical fluidization studies supported the development of reliable, repeatable experimental protocols. The modular pilot-scale skid reactor was fully constructed, instrumented, and commissioned. Capable of operating at 675–800°C and pressures up to 290 psig, the system was designed for continuous operation at a carbon production rate of 1 kg/hr. Initial demonstration runs confirmed solids handling, thermal control, and system leak-tightness, although a critical reactor component (the downfeed tube) was inadvertently omitted during final assembly. This omission limited gas–solid contact and prevented meaningful carbon deposition during pilot-scale CVD runs. Nonetheless, the system operated safely under design conditions, and the root cause of performance limitations was clearly identified. Complementary work on UHPC formulations demonstrated that small additions of carbon nanoproducts, including those derived from flare gas, can significantly enhance mechanical performance while preserving workability. A comprehensive study of CNF dispersion techniques and mix design optimization led to a clear protocol for integrating these nanomaterials into concrete. Incorporation of CNPs improved flexural toughness and reduced porosity, supporting their use in high-performance infrastructure applications. A technoeconomic analysis (TEA) confirmed that this process can produce CNP-loaded catalyst material at a levelized cost below $\$$7/kg across a range of catalyst loadings and reaction yields. With estimated market values for the carbon composite product ranging from $\$$14 to over $\$$60/kg, and the ability to blend CNPs into concrete at sub-percent levels with less than 10% added cost, the system presents a compelling economic case. While additional engineering work is needed to optimize fluidization and heat transfer at scale, this project establishes a strong foundation for commercial development. The process is not only technically sound but also economically promising, representing a viable pathway for flare gas mitigation through modular carbon nanomaterial production.

03 NATURAL GAS↗

Response of space shuttle insulation panels to acoustic noise pressure

The response of reusable space shuttle insulation panels to random acoustic pressure fields are studied. The basic analytical approach in formulating the governing equations of motion uses a Rayleigh-Ritz technique. The input pressure field is modeled as a stationary Gaussian random process for which the cross-spectral density function is known empirically from experimental measurements. The response calculations are performed in both frequency and time domain.

Vaicaitis, R.↗

Pressure losses and heat transfer in non-circular channels with hydraulically smooth walls

The influence of channel geometry on pressure losses and heat transfer in noncircular channels with hydraulically smooth walls was studied. As a basic assumption for the description of this influence, integral geometrical criteria, selected according to experimental experience, were introduced. Using these geometrical criteria, a large set of experimental data for pressure losses and heat transfer in circular and annular channels with longitudinal fins was evaluated. In this way it as empirically proved that the criteria described channel geometry fairly well.

Malak, J.↗

Engineering flowfield method with angle-of-attack applications

An approximate inviscid flowfield method has been extended to include heat-transfer predictions using a technique to account for variable-entropy edge conditions. The engineering code computes the flowfield over hyperboloids, ellipsoids, paraboloids, and sphere cones at 0 deg angle of attack (AOA). For angle-of-attack applications, an approximation to sphere-cone streamline-spreading effects on the heat transfer along the windward and leeward rays and an empirical circumferential heating technique have been incorporated also in the method. The present engineering calculations yield good comparisons with existing pressure and heating data over sphere cones even at high incidence values with the restriction that the sonic-line location remain on the spherical cap.

Zoby, E. V.↗

Technique for Measuring Gas Conversion Factors

Technique for measuring calibration conversion factors for hydrocarbon mass flowmeters applied to widely used type of commercial thermal mass flowmeter for hydrocarbon gases. Values of conversion factors for two common hydrocarbons measured using this technique in good agreement with empirical values cited by manufacturer. Similar agreement expected for all other hydrocarbons. Technique based on Nernst theorem for matching partial pressure of oxygen in combustion product gases with that in normal air. Simple, quick, and relatively safe, particularly for toxic/poisonous hydrocarbons.

Singh, J. J.↗

Flight and wind-tunnel calibrations of a flush airdata sensor at high angles of attack and sideslip and at supersonic Mach numbers

A nonintrusive airdata-sensing system was calibrated in flight and wind-tunnel experiments to an angle of attack of 70 deg and to angles of sideslip of +/- 15 deg. Flight-calibration data have also been obtained to Mach 1.2. The sensor, known as the flush airdata sensor, was installed on the nosecap of an F-18 aircraft for flight tests and on a full-scale F-18 forebody for wind-tunnel tests. Flight tests occurred at the NASA Dryden Flight Research Facility, Edwards, California, using the F-18 High Alpha Research Vehicle. Wind-tunnel tests were conducted in the 30- by 60-ft wind tunnel at the NASA LaRC, Hampton, Virginia. The sensor consisted of 23 flush-mounted pressure ports arranged in concentric circles and located within 1.75 in. of the tip of the nosecap. An overdetermined mathematical model was used to relate the pressure measurements to the local airdata quantities. The mathematical model was based on potential flow over a sphere and was empirically adjusted based on flight and wind-tunnel data. For quasi-steady maneuvering, the mathematical model worked well throughout the subsonic, transonic, and low supersonic flight regimes. The model also worked well throughout the angles-of-attack and -sideslip regions studied.

Moes, Timothy R.↗

Flight and wind-tunnel calibrations of a flush airdata sensor at high angles of attack and sideslip and at supersonic Mach numbers

A nonintrusive airdata-sensing system was calibrated in flight and wind-tunnel experiments to an angle of attack of 70 deg and to angles of sideslip of +/- 15 deg. Flight-calibration data have also been obtained to Mach 1.2. The sensor, known as the flush airdata sensor, was installed on the nosecap of an F-18 aircraft for flight tests and on a full-scale F-18 forebody for wind-tunnel tests. Flight tests occurred at the NASA Dryden Flight Research Facility, Edwards, California, using the F-18 High Alpha Research Vehicle. Wind-tunnel tests were conducted in the 30- by 60-ft wind tunnel at the NASA LaRC, Hampton, Virginia. The sensor consisted of 23 flush-mounted pressure ports arranged in concentric circles and located within 1.75 in. of the tip of the nosecap. An overdetermined mathematical model was used to relate the pressure measurements to the local airdata quantities. The mathematical model was based on potential flow over a sphere and was empirically adjusted based on flight and wind-tunnel data. For quasi-steady maneuvering, the mathematical model worked well throughout the subsonic, transonic, and low supersonic flight regimes. The model also worked well throughout the angle-of-attack and sideslip regions studied.

Moes, Timothy R.↗

Self-, N2- and Ar-broadening and line mixing in HCN and C2H2

Self-, N2- and Ar-broadening coefficients were measured for the stretch-bend infrared combination bands nu-1 + nu-1/2 (4004/cm) of HCN and nu-1 + nu-1/5 (4091/cm) of C2H2, using a tunable difference-frequency laser. At atmospheric pressures, the Q branches of these bands exhibit significant rotational narrowing or line mixing. The broadening coefficients are fit with empirical rotationally inelastic collision rate laws, which are then used to model the line mixing in the overlapped Q-branch profiles. Simple energy gap fitting laws appear to be suitable for the shorter-range intermolecular quadrupole-quadrupole and induction forces, whereas an energy-corrected-sudden scaling law works better for the longer-range dipole-dipole and dipole-quadrupole collision partners. In all cases, the line-coupling coefficients are substantially reduced from the rotationally inelastic rates fit to the broadening coefficients, indicating that 35-70 percent of the broadening may be due to other collisional mechanisms such as cross-relaxation to the degenerate H state vibrational level.

Pine, A. S.↗

Global Reference Atmospheric Model (GRAM) Advancements and Additions

Introduction:The Global Reference Atmospheric Model (GRAM) is one of the most widely used engineering models of the atmosphere. GRAM development and maintenance has been led by NASA Marshall Space Flight Center (MSFC). The NASA Science Mission Directorate (SMD) has provided funding support to upgrade the GRAMs since Fiscal Year 2018. NASA Langley Research Center has been working with MSFC on the upgrades.This presentation will provide details regarding the upgrades that have been made to the existing GRAMs, the development of new GRAMs, as well as the ongoing objectives, tasks, and milestones re-lated to the GRAM upgrades funded by NASA SMD. GRAM: The GRAMs are engineering-oriented atmospheric models that estimate mean values and statistical variations of the atmospheric properties for numerous planetary destinations.They provide mean values and variability for any point in the atmosphere as well as seasonal, geographic, and altitude variations. GRAM outputs include atmospheric density, temperature, pressure, winds, and chemical composition along a user-defined path.Theyhave been widely used by the engineering community because of their ability to create realistic dispersions. GRAMs have been integrated into high fidelity flight dynamic simulations of launch, entry, descent and landing (EDL), aerobraking and aerocapture. MSFC has been developing and updating GRAMs since 1974; GRAMs are currently available for Earth, Mars, Venus, Neptune, and Titan. GRAM Upgrade Status: Code Moderization.The planetary GRAMs are being rearchitected from Fortran to a common object-ori-entedC++ framework called the GRAM Suite. This new architecture creates a common GRAM library of data models and utilities. The first C++ releases of the existing planetary GRAMs (Mars, Venus, Neptune, and Titan-GRAM) in the GRAM Suite are straight conversions from the latest Fortran version. Model Upgrades.The focus of the model upgrade task is to improve the atmosphere models in the existing GRAMs and to establish a foundation for developing GRAMs for additional destinations. The GRAM ephemerishas been upgraded to the NASA Navigation and Ancillary Information Facility (NAIF) SPICE toolkit (version N0066). The calculation of the speed of sound has also been improved in the GRAMs. The GRAM team has received updated Mars General Circulation Model (MGCM) datasets from NASA Ames Research Center. Mars Global Ionosphere-Thermosphere Model (M-GITM) data is being obtained toreplace the Mars Thermospheric General Circulation Model (MTGCM) data in legacy Mars-GRAM. M-GITM and updated MGCM data will be incorporated into a future GRAM Suite release.Twoprojects that will improve the atmospheric model data in the GRAMs have been funded by the GRAM team since Fiscal Year 2020. Sanjay Limaye and Patrick Fry at the University of Wisconsin are reanalyzing the Venus Express radio occultation observations and analyzing the Akatsukiradio occultation observations.This will lead tothe calculation of number density, temperature, and pressure profiles for the 40-90 km altitude range. Kunio Sayanagi, Justin Garland, and Ryan McCabeat Hampton University are developing empirical global models for Venus,Jupiter, Saturn, Uranus, Neptune, and Titan that incorporates the latest data available for each of these planetary destinations. Upgraded GRAM Releases. GRAM Suite Version 1.0 was released in May 2020 and contains the rearchitected Neptune-GRAM, including the common GRAM framework and planet–specific code. GRAM Suite Version 1.1 was released in September 2020 and addedthe rearchitected Titan-GRAM to the GRAM Suite. A User Guide and Programmer’s Manualarereleased with all GRAMs. The rearchitected Mars and Venus-GRAMs will be released in upcomingversions of the GRAM Suite. New GRAM Releases. New GRAMs have been de-veloped for Uranus and Jupiter. Uranus-GRAM is based on an individual profile generated by Gary Allen (ARC) from Voyager 2 occultation data and will be released in GRAM Suite Version 1.2. Jupiter-GRAM is based on individual profile produced from Al Seiff’s Ju-piter model[1].Jupiter-GRAM will be released in GRAM Suite Version 1.3. Saturn-GRAM is currently under development and will be released in a future version of the GRAM Suite. Conclusions: GRAMs are vital and frequently used toolsets. Releases of the GRAM Suite, upgrades of the existing planetary GRAMs, and development of new planetary GRAMs are ongoing. NASA SMD funding has been essential to addressing current limitations and accomplishing GRAM developmental goals. Continua-tion ofSMD fundingwill ensure the development, up-grades, and maintenance of the GRAMs. References: [1] Seiff, A., et al. (1998) JGR, 103, 22,857-22,889. Acknowledgments: The authors gratefully acknowledge support from the NASA SMD

atmospheric models↗

Satellite characterization of global stratospheric sulfate aerosols released by Tonga volcano

Large volcanic eruptions create an enhanced layer of sulfate aerosols in the stratosphere. These sulfuric acid droplets persist for many months, altering the climate and stratospheric chemistry. Sulfate aerosols scatter sunlight back to space, cooling the surface of the Earth and absorb outgoing thermal radiation, heating the stratosphere. The calculation of the climate impact of sulfate aerosols depends on their physical properties such as droplet size and chemical composition. These properties are not well known, and this uncertainty contributes to the errors in climate model predictions. Here we derive the first empirical formula that predicts the composition of stratospheric sulfate aerosols from volcanic eruptions from the air temperature and water vapor pressure. Measurements of atmospheric infrared transmittance of the Hunga Tonga-Hunga Ha'apai sulfate aerosol plume by the Atmospheric Chemistry Experiment (ACE) satellite were analyzed to determine composition (weight percent of sulfuric acid) and median particle radius. These data are supplemented by measurements of the Raikoke and Nabro eruptions. Our analysis allows the properties of volcanic aerosols in the stratosphere to be predicted reliably in atmospheric models.

P Bernath↗

Understanding Flow Characteristics in Metal Additive Manufacturing

In fluid flow, the frictional effects from interior surfaces of flow components create pressure loss across the surface. Understanding this inherent pressure loss due to friction and other phenomena is important when designing a flow system. For conventional manufacturing, friction loss has been empirically studied and is well known in the engineering community. However, newer manufacturing techniques, such as laser powder bed fusion (LPBF), an additive manufacturing technique, need to be understood. The inherent flow conditions resulting from the additive processes were studied. Test samples were printed with the flow path oriented in the vertical direction with different channel diameters to characterize the inherent fundamental flow properties of the process. Moody diagrams were replicated for a greater understanding of possibilities and shortfalls when implementing LPBF into design applications. Experimental flow testing revealed that greater effective sand grain roughness resulted from this process when compared to conventional machining methods. This roughness did not correlate well to the average roughness measured with a laser scanning microscope but was consistent with the average particle size of the powder metal feedstock.

42 ENGINEERING↗

Modeling the near acoustic field of a rocket during launch

The design of launch pad structures is critically dependent upon the stresses imposed by the acoustical pressure field generated by the rocket engines during launch. The purpose of this effort is to better describe the acoustical field in the immediate launch area. Since the problem is not analytically tractable, empirical modeling will be employed so that useful results may be obtained for structural design purposes. The plume of the rocket is considered to be a volumetric acoustic source, and is broken down into incremental contributing volumes. A computer program has been written to sum all the contributions to find the total sound pressure level at an arbitrary point. A constant density source is initially assumed and the acoustic field evaluated for several cases to verify the correct operation of the program.

Mauritzen, David W.↗

Contrasting actions of pressor agents in severe autonomic failure

BACKGROUND: Orthostatic hypotension is the most disabling symptom of autonomic failure. The choice of a pressor agent is largely empiric, and it would be of great value to define predictors of a response. PATIENTS AND METHODS: In 35 patients with severe orthostatic hypotension due to multiple system atrophy or pure autonomic failure, we determined the effect on seated systolic blood pressure (SBP) of placebo, phenylpropanolamine (12.5 mg and 25 mg), yohimbine (5.4 mg), indomethacin (50 mg), ibuprofen (600 mg), caffeine (250 mg), and methylphenidate (5 mg). In a subgroup of patients, we compared the pressor effect of midodrine (5 mg) with the effect of phenylpropanolamine (12.5 mg). RESULTS: There were no significant differences in the pressor responses between patients with multiple system atrophy or pure autonomic failure. When compared with placebo, the pressor response was significant for phenylpropanolamine, yohimbine, and indomethacin. In a subgroup of patients, we confirmed that this pressor effect of phenylpropanolamine, yohimbine, and indomethacin corresponded to a significant increase in standing SBP. The pressor responses to ibuprofen, caffeine, and methylphenidate were not significantly different from placebo. Phenylpropanolamine and midodrine elicited similar pressor responses. There were no significant associations between drug response and autonomic function testing, postprandial hypotension, or plasma catecholamine levels. CONCLUSIONS: We conclude that significant increases in systolic blood pressure can be obtained in patients with orthostatic hypotension due to primary autonomic failure with phenylpropanolamine in low doses or yohimbine or indomethacin in moderate doses. The response to a pressor agent cannot be predicted by autonomic function testing or plasma catecholamines. Therefore, empiric testing with a sequence of medications, based on the risk of side effects in the individual patient and the probability of a response, is a useful approach.

Clinical Trial↗

Coupled Thermo–Hydro–Mechanical Modeling of Hydro-Shearing Stimulation in an Enhanced Geothermal System in the Raft River Geothermal Field, USA

The Raft River Enhanced Geothermal System (EGS) demonstration project aims to improve the geothermal production by enhancing the reservoir permeability via shear stimulation in well RRG-9. In this paper, we performed a series of 3D thermo– hydro–mechanical (THM) simulations to investigate the influence of hydraulic and thermal effects on the development of this EGS. The model includes synthetic fracture populations based on borehole televiewer images and in-situ stress measurements from well RRG-9. Fracture permeability evolution is determined using an empirical permeability law developed from laboratory experiments. The model was calibrated by comparing the hydraulic response to field observations, including wellhead pressure, injection rate, and well injectivity. Particularly, we analyzed the enhancement of reservoir permeability and the spatial extent of the stimulation zone for the given injection schedule. Our results indicate that the permeability enhancement of fractured geothermal reservoir is caused by the combined effects of injection-induced cooling and fluid pressure increase. The decrease of temperature plays a dominant role in reactivation of natural fractures under the hydro-shearing mechanism, while the higher injection pressure promotes shear failure and enlarges the stimulation zone. Finally, for the specified extensional stress state, the model favors greatest permeability enhancement along the maximum horizontal principal stress, a moderate vertical enhancement, and a smaller gain along the minimum horizontal principal stress.

58 GEOSCIENCES↗

Viscous effect on airfoils for unsteady transonic flows

The viscous effect on aerodynamic performance of an arbitrary airfoil executing low frequency maneuvers during transonic flight was investigated. The small disturbance code, LTRAN2, was modified by using a conventional integral method, BLAYER, for the boundary layer and an empirical relation, viscous wedge, for simulating the suddenly thickened boundary layer behind the shock. Before the shock, only the boundary layer displacement thickness was evaluated. After the shock, the empirical wedge thickness was superimposed on the boundary layer thickness along the surface as well as in the wake region. The pressure coefficients were calculated for both steady and unsteady states. The viscous solution takes fewer iterations to obtain the converged steady state solution. Comparisons made with experimental data and the inviscid solution show that the viscous solution agrees better with the experimental data with about the same (or slightly less) amount of computational time.

Lee, S. C.↗

A Method of Determining Aerodynamic-Influence Coefficients from Wind-Tunnel Data for Wings at Supersonic Speeds

A method is described for determining aerodynamic-influence coefficients from wind-tunnel data for calculating the steady-state load distribution on a wing with arbitrary angle-of-attack distribution at supersonic speeds. The method combines linearized theory with empirical adjustments in order to give accurate results over a wide range of angles of attack. The experimented data required are pressure distributions measured on a flat wing of the desired planform at the desired Mach number and over the desired range of angles of attack. The method has been tested by applying it to wind-tunnel data measured at Mach numbers of 1.61 and 2.01 on wings of the same planform but of different surface shapes. Influence coefficients adjusted to fit the flat wing gave good predictions of the spanwise and chord-wise distributions of loadings measured on twisted and cambered wings.

Gainer, Patrick A.↗

New interpretations of shock-associated noise with and without screech

Anomalous trends in present convergent nozzle (Mach 1) shock associated noise analyses and predictions, with particular emphasis on the roles of screech and jet temperature, are discussed. Experimentally measured values of shock associated noise are used to reassess data trends, including both frequency and sound pressure level. The data used includes model-scale nozzles, varying in nominal diameter from 5 cm to 13 cm, and full scale engine nozzles up to 48 cm. All data were obtained at static conditions. From this reassessment of the measured data, new empirical methods for the prediction of shock associated noise are developed. Separate procedures are presented for screech free and screech contaminated shock associated noise. In the present approach, shock associated noise spectra are developed from considerations that include the peak sound pressure level and its frequency, the low frequency sound pressure level slope, and the high frequency sound pressure level slope or roll-off; the latter is shown to vary with directivity angle.

Vonglahn, U.↗

Pressure dither in venting analyses

Venting analyses simulate the time-dependent flow of air or another gas from one compartment to another, or to an ambient profile. The flow through the vent connecting the compartments is assumed to be one-dimensional, quasi-steady, and isentropic with an empirical discharge coefficient included to account for irreversible flow losses. When a venting analysis is performed numerically, an upper limit on the accuracy exists due to the effects of the numerical integration method. Because this manifests itself in a first-order method by a rapid oscillation about the true answer, this phenomenon is referred to as pressure dither. This paper explores the origin of the phenomenon and gives simple formulae for predicting when it will occur and the greatest achievable accuracy for a given time step.

Fay, John F.↗