L sub 2 -stability of time-varying systems - Construction of multipliers with prescribed phase characteristics.
Stability of time varying systems by construction of multipliers with prescribed phase characteristics
Freedman, M. I.↗
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Impact of CuInP 2 S 6 –metal interfaces on the stabilization of polar phases and polarization switching
The multifunctionality of two-dimensional ferroelectric CuInP 2 S 6 (CIPS) arises from the existence of multiple polar phases combined with a high ionic conductivity that facilitates polarization switching in unusual ways. The van der Waals (vdW) layered structure provides ultrathin flakes and ideal interfaces to integrate with other materials for microelectronics and neuromorphic elements. However, device integration necessitates metal contacts to read, write, or transmit signals. In this work, we find that different types of metal–CIPS interfaces strongly impact the stabilization of specific polar phases and the field-induced transitions between the polarization states. Cu electrodes initially suppress the piezoresponse, whereas, at CIPS–Ag interfaces, the electromechanical signal is increased. Under electric fields, the Cu electrodes, Ag electrodes and surrounding CIPS surfaces can show distinct switching behavior as different phases and polarization orientations are stabilized. These findings highlight that metal–CIPS interfaces provide the opportunity to optimize functional material properties.
Ferroelectrics and multiferroics↗
Strain Effects in SrHfO 3 Films Grown by Hybrid Molecular Beam Epitaxy
Perovskite oxide heterostructures host a large number of interesting phenomena such as ferroelectricity, which are often driven by octahedral distortions in the crystal that may induce polarization. SrHfO 3 (SHO) is a perovskite oxide with a pseudocubic lattice parameter of 4.08 Å that previous density functional theory (DFT) calculations suggest can be stabilized in a ferroelectric P4mm phase when stabilized with sufficient compressive strain. Additionally, it is insulating and possesses a large band gap and a high dielectric constant, making it an ideal candidate for oxide electronic devices. Here, to test the viability of epitaxial strain as a driver of ferroic phase transitions, SHO films were grown by hybrid molecular beam epitaxy (hMBE) with a tetrakis(ethylmethylamino)hafnium(IV) source on GdScO 3 and TbScO 3 substrates. Strained SHO phases were characterized using X-ray diffraction, X-ray absorption spectroscopy, and scanning transmission electron microscopy to determine the space group of the strained films, with the results compared to those of DFT-optimized models of phase stability versus strain. Contrary to past reports, we find that compressively strained SrHfO 3 undergoes octahedral tilt distortions without associated ferroelectric polarization and most likely takes on the I4/mcm phase with the a 0 a 0 c – tilt pattern.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Gain, phase and frequency stability of DSS-42 and DSS-43 vor Voyage Uranus encounter
Theoretically rigorous definitions are derived of such parameters as RF signal path length, phase delay, and phase/frequency stability in a Cassegrainian antenna applicable to a narrow bandwidth channel, as well as algorithms for evaluating these parameters. This work was performed in support of the Voyager spacecraft encounter with Uranus in January 1986. The information was needed to provide Voyager/Uranus radio science researchers with a rotational basis for deciding the best strategy to operate the three antennas involved during the crucial 5-hour occultation period of the encounter. Such recommendations are made at the end of the article.
Cha, A. G.↗
Stability of oscillatory two phase Couette flow
We investigate the stability of two phase Couette flow of different liquids bounded between plane parallel plates. One of the plates has a time dependent velocity in its own plane, which is composed of a constant steady part and a time harmonic component. In the absence of time harmonic modulations, the flow can be unstable to an interfacial instability if the viscosities are different and the more viscous fluid occupies the thinner of the two layers. Using Floquet theory, we show analytically in the limit of long waves, that time periodic modulations in the basic flow can have a significant influence on flow stability. In particular, flows which are otherwise unstable for extensive ranges of viscosity ratios, can be stabilized completely by the inclusion of background modulations, a finding that can have useful consequences in many practical applications.
Coward, Adrian V.↗
Oscillations in two-component, two-phase flow.
Stability boundaries in oscillating two-phase flow of air-water mixtures
FLOW STABILITY↗
A tunable phase detector for short-term frequency stability measurements
Tunable phase detector for short term frequency stability measurements
FREQUENCY MEASUREMENT↗
Revealing the Nature of Binary-Phase on Structural Stability of Sodium Layered Oxide Cathodes
The emergence of layered sodium transition metal oxides featuring a multiphase structure presents a promising approach for cathode materials in sodium-ion batteries, showcasing notably improved energy storage capacity. However, the advancement of cathodes with multiphase structures faces obstacles due to the limited understanding of the integrated structural effects. Herein, the integrated structural effects by an in-depth structure-chemistry analysis in the developed layered cathode system Na x Cu 0.1 Co 0.1 Ni 0.25 Mn 0.4 Ti 0.15 O 2 with purposely designed P2/O3 phase integration, are comprehended. The results affirm that integrated phase ratio plays a pivotal role in electrochemical/structural stability, particularly at high voltage and with the incorporation of anionic redox. In contrast to previous reports advocating solely for the enhanced electrochemical performance in biphasic structures, it is demonstrated that an inappropriate composite structure is more destructive than a single-phase design. The in situ X-ray diffraction results, coupled with density functional theory computations further confirm that the biphasic structure with P2:O3 = 4:6 shows suppressed irreversible phase transition at high desodiated states and thus exhibits optimized electrochemical performance. Finally, these fundamental discoveries provide clues to the design of high-performance layered oxide cathodes for next-generation SIBs.
36 MATERIALS SCIENCE↗
Absolute Stability Analysis of a Phase Plane Controlled Spacecraft
Many aerospace attitude control systems utilize phase plane control schemes that include nonlinear elements such as dead zone and ideal relay. To evaluate phase plane control robustness, stability margin prediction methods must be developed. Absolute stability is extended to predict stability margins and to define an abort condition. A constrained optimization approach is also used to design flex filters for roll control. The design goal is to optimize vehicle tracking performance while maintaining adequate stability margins. Absolute stability is shown to provide satisfactory stability constraints for the optimization.
Jang, Jiann-Woei↗
On the dependence of travelling wave stability on basic state wave phase speed
The dependence of stability on basic state wave phase speed is examined in a nondivergent barotropic model on a sphere for planetary scale waves with phase speeds typical of waves observed in the atmosphere. Triad interactions are examined analytically and compared to numerical results from a full spectral model. A number of triads may result in growth of the perturbation components for each basic state wave; for each triad there is a basic state wave phase speed where it is resonant, identified as the point where the critical amplitude for instability to that perturbation becomes zero. Critical amplitudes for instability obtained using the full spectral model generally agree well with triad results. Since the basic state wave phase speed determines which triad will grow, spatial structure and critical amplitudes for instability for the growing disturbances depend strongly on basic state wave phase speed. The results of this idealized study suggest that phase speed may be an important factor in determining the stability of planetary scale waves in the atmosphere.
Manney, Gloria L.↗
Stability Characterization of Advanced Injectors, Phase 1 Final Report
Stabilization characteristics of advanced injectors
Source record↗
Suppressing Phase Segregation and Improving Stability in Mixed-Halide Perovskites through Spinel Oxide-Directed Epitaxy
Mixed-cation mixed-halide perovskite compositions are essential for achieving the required bandgaps for high-efficiency multijunction photovoltaics, yet their stability remains limited by interfacial defects, phase segregation, and degradation. Here, we introduce spinel oxides as a new family of lattice-matched substrates that enable crystalline, phase-pure, compositionally-uniform, bromide-rich perovskite film growth. The effect of spinel oxides is two-fold: reducing defects at the bottom interface by templating film growth and inducing beneficial compressive strain through mismatch-dependent substrate-perovskite lattice coupling. Spinel oxide substrates facilitate growth of highly crystalline films and eliminate detrimental secondary phases across thicknesses. Using grazing incidence X-ray diffraction, X-ray fluorescence, cathodoluminescence–scanning electron microscopy, cryogenic photoluminescence, and density functional theory, we reveal that Mg-halide bonds at the bottom interface induce lattice mismatch-dependent compressive strain that suppresses halide segregation and further reduces defect formation. In addition, films grown on spinel oxides maintain over 87% of the perovskite phase after 12 h under 100% relative humidity, as monitored by in situ grazing incidence wide-angle X-ray scattering (GIWAXS), compared to less than 70% for control samples. This work extends lattice matching from vapor-deposited epitaxial semiconductors to solution-processed halide perovskites to establish a broadly applicable strategy for defect suppression, phase homogenization, and long-term stability. Based on the fundamental science explored here, we set the stage for the development of lattice-matched spinel oxide charge transport layers to be integrated into perovskite solar cells and other optoelectronic devices.
36 MATERIALS SCIENCE↗
Composition Effects on Phase Formation and Stability
In this report, results from experimental studies of the composition dependence of nucleation are presented. A model for nucleation that takes simultaneous account of the interfacial attachment processes at the growing cluster interface and diffusion into the region surrounding the developing cluster is presented and numerical results are discussed.
Kelton, Kenneth F.↗
Stabilization of Miscible Aqueous Phases via Diffusion‐Controlled Multifunctional Nanoparticle‐Ligand Complexation
Liquid‐in‐liquid structuring by harnessing miscible aqueous domains can be achieved by inducing thermodynamically defined phase separation using aqueous solutions of incompatible solutes, where immiscibility is dictated by the concentrations of the solutes. For instance, in aqueous two‐phase systems (ATPSs), the interfacial tension between the two different aqueous solutions is so small that it stabilizes the phase‐separated domains, but not their shape, thus falling short of designing tunable, robust structures. Here, we introduce a diffusion‐controlled strategy that enables liquid‐in‐liquid compartmentalization absent a thermodynamically defined interface or bulk liquid‐liquid phase separation using a barrier formed in situ at the initial contact boundary of an aqueous dispersion of multifunctional nanoparticles and a solution of multifunctional ligands in pure water or a water/alcohol mixture. The nanoparticles and ligands are entropically driven to disperse uniformly but interact at the initial contact boundary more rapidly than bulk mixing, forming a layer that establishes a barrier akin to a semi‐permeable membrane and allows the formation of tubular compartments. A wealth of opportunities is enabled by the proposed technique, where examples in separations, soft electronic devices, and ultralight porous electromagnetic shielding materials are shown.
cryogels↗
Ultra-stable, low phase noise dielectric resonator stabilized oscillators for military and commercial systems
EPSD has designed, fabricated and tested, ultra-stable, low phase noise microwave dielectric resonator oscillators (DRO's) at S, X, Ku, and K-bands, for potential application to high dynamic range and low radar cross section target detection radar systems. The phase noise and the temperature stability surpass commercially available DROs. Low phase noise signals are critical for CW Doppler radars, at both very close-in and large offset frequencies from the carrier. The oscillators were built without any temperature compensation techniques and exhibited a temperature stability of 25 parts per million (ppm) over an extended temperature range. The oscillators are lightweight, small and low cost compared to BAW & SAW oscillators, and can impact commercial systems such as telecommunications, built-in-test equipment, cellular phone and satellite communications systems. The key to obtaining this performance was a high Q factor resonant structure (RS) and careful circuit design techniques. The high Q RS consists of a dielectric resonator (DR) supported by a low loss spacer inside a metal cavity. The S and the X-band resonant structures demonstrated loaded Q values of 20,300 and 12,700, respectively.
Mizan, Muhammad↗
The NASA/GSFC hydrogen maser program: A review of recent data
Data is presented on the phase and frequency stability, over time periods extending to one week, of the new NR field operable hydrogen masers developed by the Applied Physics Laboratory (APL) and the older NX and NP field operable hydrogen masers developed by Goddard Space Flight Center and maintained and upgraded by Bendix Field Engineering Corporation (BFEC). Data is presented on the NR masers in the laboratory showing frequency stabilities well into the 10 to the -15th power range and phase stabilities well into the 100 ps range for periods of up to one day. Data is presented on upgraded NP masers in the laboratory showing that the frequency stability has been improved substantially to virtually the NR level. VLBI data is presented on the phase difference between NX-2 at Owens Valley, California and NR-2 at Fort Davis, Texas for a one week period showing, after removal of a constant frequency drift, a 350 ps RMS phase stability.
Chiu, M.↗
Performance Testing of TRL4-6 LISA Laser System
The Laser Interferometer Space Antenna (LISA) is an ESA-led future mission to measure gravitational waves from astronomical sources in space. LISA has been adopted as a formal mission by ESA in January 2024, and is expected to become a formal project at NASA within 2024. The laser system (LS), which includes four laser heads (LH) each containing a laser optical module (LOM) and laser electronics module (LEM), a frequency reference system (FRS, optical frequency reference) and four power monitor detectors (PMON), is one of the three U.S. contributions to LISA from NASA. The Lasers and Electro-Optics Branch at NASA GSFC has been developing and managing the design of the LISA LS. Currently, the TRL (technology readiness level) of the NASA LISA laser system is transitioning from 4 to 6. TRL 4/5 LISA LOM was sent to ESA in early 2023 and has undergone optical performance testing. [1] By late summer of 2024, NASA plans to deliver the TRL 6 LOM to ESA for performance evaluation. Since the delivery of the TRL4/5 LOM to ESA, we have taken steps to advance the TRL of the overall LS and have also started end-to-end system level testing involving other subsystems. They include 1) optical performance test of TRL6 LOM and TRL 5 LEM under thermal cycling, 2) end-to-end test of the laser head (LH) and the GSE (ground support equipment) FRS, driven by TRL 4 FRS electronics (FRS-E) provided by Ball Aerospace, 3) end-to-end test of the laser head (LH) with the GSE phase meter system (PMS) provided by Albert Einstein Institute, and 4) optical performance test of the LH with the PMON subsystem developed by NASA. The FRS, PMS, and PMON provide necessary frequency stability, relative phase stability between lasers, and output power stability, respectively. Since they are all vital for the sensitive laser interferometry performed in LISA, it is necessary to perform these system level testing by combining the LH and other subsystems, and to prove the optical performance at an early stage during the LS development. Our recent work has successfully demonstrated the intra-connectivity of the LS, as well as critical external interface with the PMS to meet the LISA’s performance requirements. In this talk, we will report on the latest status of the LH testing and system level test. We will also discuss the paths to bring each subsystem to TRL6+ and plans for future system level testing.
LISA↗
The stability of two-phase flow over a swept-wing
We use numerical and asymptotic techniques to study the stability of a two-phase air/water flow above a flat porous plate. This flow is a model of the boundary layer which forms on a yawed cylinder and can be used as a useful approximation to the air flow over swept wings during heavy rainfall. We show that the interface between the water and air layers can significantly destabilize the flow, leading to traveling wave disturbances which move along the attachment line. This instability occurs for lower Reynolds numbers than in the case of the absence of a water layer. We also investigate the instability of inviscid stationary modes. We calculate the effective wavenumber and orientation of the stationary disturbance when the fluids have identical physical properties. Using perturbation methods we obtain corrections due to a small stratification in viscosity, thus quantifying the interfacial effects. Our analytical results are in agreement with the numerical solution which we obtain for arbitrary fluid properties.
Coward, Adrian↗