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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Classification of Particle Shapes from Lidar Depolarization Ratios in Convective Ice Clouds Compared to in situ Observations During CRYSTAL-FACE

This manuscript describes a method to class@ cirrus cloud ice particle shape using lidar depolarization measurements as a basis for segregating different particle shape regimes. Measurements from the ER-2 Cloud Physics Lidar (CPL) system during CRYSTAL-FACE provide the basis for this work. While the CPL onboard the ER-2 aircraft was providing remote sensing measurements of cirrus clouds, the Cloud Particle Imager (CPI) onboard the WB-57 aircraft was flying inside those same clouds to sample particle sizes. The results of classifying particle shapes using the CPL data are compared to the in situ measurements made using the CPI , and there is found to be good agreement between the particle shape inferred from the CPL data and that actually measured by the CPI. If proven practical, application of this technique to spaceborne observations could lead to large-scale classification of cirrus cloud particle shapes.

Noel, Vincent↗

Long-chain carboxylic acids in pyrolysates of Green River kerogen

Long-chain fatty acids (C10-C32), as well as C14-C21 isoprenoid acids (except for C18), have been identified in anhydrous and hydrous pyrolyses products of Green River kerogen (200-400 degrees C, 2-1000 hr). These kerogen-released fatty acids are characterized by a strong even/odd predominance (CPI: 4.8-10.2) with a maximum at C16 followed by lesser amounts of C18 and C22 acids. This distribution is different from that of unbound and bound geolipids extracted from Green River shale. The unbound fatty acids show a weak even/odd predominance (CPI: 1.64) with a maximum at C14, and bound fatty acids display an even/odd predominance (CPI: 2.8) with maxima at C18 and C30. These results suggest that fatty acids were incorporated into kerogen during sedimentation and early diagenesis and were protected from microbial and chemical changes over geological periods of time. Total quantities of fatty acids produced during heating of the kerogen ranged from 0.71 to 3.2 mg/g kerogen. Highest concentrations were obtained when kerogen was heated with water for 100 hr at 300 degrees C. Generally, their amounts did not decrease under hydrous conditions with increase in temperature or heating time, suggesting that significant decarboxylation did not occur under the pyrolysis conditions used, although hydrocarbons were extensively generated.

Non-NASA Center↗

Measuring Diffusion of Liquids by Common-Path Interferometry

A method of observing the interdiffusion of a pair of miscible liquids is based on the use of a common-path interferometer (CPI) to measure the spatially varying gradient of the index refraction in the interfacial region in which the interdiffusion takes place. Assuming that the indices of refraction of the two liquids are different and that the gradient of the index of refraction of the liquid is proportional to the gradient in the relative concentrations of either liquid, the diffusivity of the pair of liquids can be calculated from the temporal variation of the spatial variation of the index of refraction. This method yields robust measurements and does not require precise knowledge of the indices of refraction of the pure liquids. Moreover, the CPI instrumentation is compact and is optomechanically robust by virtue of its common- path design. The two liquids are placed in a transparent rectangular parallelepiped test cell. Initially, the interface between the liquids is a horizontal plane, above which lies pure liquid 2 (the less-dense liquid) and below which lies pure liquid 1 (the denser liquid). The subsequent interdiffusion of the liquids gives rise to a gradient of concentration and a corresponding gradient of the index of refraction in a mixing layer. For the purpose of observing the interdiffusion, the test cell is placed in the test section of the CPI, in which a collimated, polarized beam of light from a low-power laser is projected horizontally through a region that contains the mixing layer.

Rashidnia, Nasser↗

Mission Operations and Command Assurance: Automating an Operations TQM Task

Mission Operations and Command Assurance (MO&CA) is a Total Quality Management (TQM) task on JPL projects to instill quality into mission operations. The mission operations environment is inherently risky because each decision made is potentially mission critical. The flight operations environment generally requires operators to make rapid critical decisions and solve problems based on limited information, while closely following standard procedures. MO&CA's primary goal is to help improve the operational reliability and reduce risk of projects during flight. To achieve this goal, automation of the MO&CA task is required. MO&CA specifically embodies the TQM principle of continuous process improvement (CPI) in which processes are continually examined and analyzed for opportunities for improvement. The second way in which MO&CA implements CPI on JPL projects is on new projects or upgrades to existing projects.

mission↗

Mission Operations and Command Assurance: Automating an Operations TQM Task

A long-term program is in progress at JPL to reduce cost and risk of mission operations through defect prevention and error management. A major element of this program, Mission Operations and Command Assurance (MO&QA), provides a system level function on flight projects to instill quality in mission operations. MO&CA embodies the Total Quality Management (TQM) principle of Continuous Process Inprovement (CPI) and uses CPI in applying automation to mission operations to reduce risk and costs. MO&CA has led efforts to apply and has implemented automation in areas that impact the daily flight project environment including Incident Surprise Anomoly tracking and reporting; command data verification, tracking, and reporting; and command support data usage. MO&CA's future work in automation will take into account that future missions systems must be designed to avoid increasing error through the introduction of automation, while adapting to the demands of smaller flight teams.

automation↗

A Universal Design of Lithium Anode via Dynamic Stability Strategy for Practical All‐Solid‐State Batteries

Abstract All‐solid‐state Li‐metal battery (ASSLB) chemistry with thin solid‐state electrolyte (SSE) membranes features high energy density and intrinsic safety but suffers from severe dendrite formation and poor interface contact during cycling, which hampers the practical application of rechargeable ASSLB. Here, we propose a universal design of thin Li‐metal anode (LMA) via a dynamic stability strategy to address these issues. The ultra‐thin LMA (20 μm) is in situ constructed with uniform highly Li‐ion conductive solid‐electrolyte interphase and composite‐polymer interphase (CPI) via electroplating process. As a result, the passivation layer with poor Li‐ion conduction on Li anode can be dissolved and small surface resistance can be achieved due to the good compatibility of CPI to SSEs. The cycling of Li symmetric cell with Li 6 PS 5 Cl thin film electrolyte (<100 μm) shows a high critical current density of >2.0 mA cm −2 with excellent cycling stability at 1.0 mA cm −2 . The ASSLBs paring with Ni‐rich LiNi 0.6 Mn 0.2 Co 0.2 O 2 cathode demonstrated the feasibility of engineered LMA design by presenting good rate capability from 0.1 C to 1.0 C at room temperature, as well as long‐term cycling stability (81 % retention after 100 cycles). This work represents a general pathway to make thin dendrite‐free LMA available for high‐energy‐density ASSLBs.

Deng, Tao [Department of Chemical and Biomolecular↗

A Universal Design of Lithium Anode via Dynamic Stability Strategy for Practical All‐Solid‐State Batteries

Abstract All‐solid‐state Li‐metal battery (ASSLB) chemistry with thin solid‐state electrolyte (SSE) membranes features high energy density and intrinsic safety but suffers from severe dendrite formation and poor interface contact during cycling, which hampers the practical application of rechargeable ASSLB. Here, we propose a universal design of thin Li‐metal anode (LMA) via a dynamic stability strategy to address these issues. The ultra‐thin LMA (20 μm) is in situ constructed with uniform highly Li‐ion conductive solid‐electrolyte interphase and composite‐polymer interphase (CPI) via electroplating process. As a result, the passivation layer with poor Li‐ion conduction on Li anode can be dissolved and small surface resistance can be achieved due to the good compatibility of CPI to SSEs. The cycling of Li symmetric cell with Li 6 PS 5 Cl thin film electrolyte (<100 μm) shows a high critical current density of >2.0 mA cm −2 with excellent cycling stability at 1.0 mA cm −2 . The ASSLBs paring with Ni‐rich LiNi 0.6 Mn 0.2 Co 0.2 O 2 cathode demonstrated the feasibility of engineered LMA design by presenting good rate capability from 0.1 C to 1.0 C at room temperature, as well as long‐term cycling stability (81 % retention after 100 cycles). This work represents a general pathway to make thin dendrite‐free LMA available for high‐energy‐density ASSLBs.

Deng, Tao [Department of Chemical and Biomolecular↗

Excited quantum anomalous and spin Hall effect: dissociation of flat-bands-enabled excitonic insulator state

Quantum anomalous Hall effect (QAHE) and quantum spin Hall effect (QSHE) are two interesting physical manifestations of 2D materials that have an intrinsic nontrivial band topology. In principle, they are ground-state equilibrium properties characterized by Fermi level lying in a topological gap, below which all the occupied bands are summed to a non-zero topological invariant. In this work, we propose theoretical concepts and models of ‘excited’ QAHE (EQAHE) and EQSHE generated by dissociation of an excitonic insulator (EI) state with complete population inversion (CPI), a unique many-body ground state enabled by two yin-yang flat bands (FBs) of opposite chirality hosted in a diatomic Kagome lattice. The two FBs have a trivial gap in between, i.e. the system is a trivial insulator in the single-particle ground-state, but nontrivial gaps above and below, so that upon photoexcitation the quasi-Fermi levels of both electrons and holes will lie in a nontrivial gap achieved by the CPI-EI state, as demonstrated by exact diagonalization calculations. Then dissociation of singlet and triplet EI state will lead to EQAHE and EQSHE, respectively. Realizations of yin-yang FBs in real materials are also discussed.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Development of a closed pore insulation material

A closed pore ceramic foam insulation material (CPI) has been developed that offers possibilities for use as a reusable external heat shield for the NASA manned space shuttle. The outstanding characteristics of CPI are: (1) negligible water absorption due to a noninterconnecting network of cells; (2) high emittance at room and elevated temperature; (3) ability to survive at least 10 simulated reentry cycles to 1500 K using radiant heat lamps to simulate the reentry heat fluxes; (4) ability to survive, with no change in properties or appearance, at least 10 simulated plasma arc jet cycles to 1500 K (with the exception of some stress cracks induced either by the unduly severe nature of the initial arc splash heating pulse or by improper mechanical holding of the specimen in the test fixture); (5) strength (flexure); and (6) a low thermal conductivity throughout the temperature range of interest for the space shuttle.

Tobin, A.↗

GSFC specification electronic data processing magnetic recording tape

The design requirements are given for magnetic oxide coated, electronic data processing tape, wound on reels. Magnetic recording tape types covered by this specification are intended for use on digital tape transports using the Non-Return-to-Zero-change-on-ones (NRZI) recording method for recording densities up to and including 800 characters per inch (cpi) and the Phase-Encoding (PE) recording method for a recording density of 1600 cpi.

Tinari, D. F.↗

Adhesive properties of a semi-crystalline polyimide

Adhesive and film properties of a new semi-crystalline polyimide, designated LARC-CPI, having a glass transition temperature of 222 C and a crystalline melt temperature of 350 C are presented. The films exhibited excellent resistance to solvents and strong base. Compact tension specimens from LARC-CPI moldings displayed a fracture energy of 37.8 lb/sq in. Titanium tensile shear specimens gave strengths of 6250 psi initially at 25 C, 7120 psi at 25 C after 1000 hours at 232 C, 2800 psi at 232 C after annealing for 5 hours at 300 C, and 3670 psi at 232 C after 100 hours at 316 C in air.

Hergenrother, P. M.↗

Theoretical study of the spectroscopy of the alkali oxides LiO, NaO, and KO

A state-averaged complete-active-space self-consistent-field multireference configuration-interaction method is presented to characterize the bound-bound emission from the CPi-2 state into the two lowest ionic states of LiO, NaO, and KO. Ab initio calculations use the experimental results obtained by Woodward et al. (1989) of the emitting state as CPi-2, but indicate that the tentative experimental band assignments are incorrect.

Langhoff, Stephen R.↗

Analysis of plasma measurements for the Geotail mission

The CPI plasma measurements from the Geotail spacecraft are currently used by a number of scientists in support of varied research projects. Measurements from the CPI hot plasma analyzer have been processed to compute one-minute averages of plasma densities, temperatures, and velocities for the period 1 Oct. 1992 - 31 July 1993. These parameters are used in a preliminary survey of the magnetotail for distances from earth of 10 to 210 earth radii. The cold plasmas within the magnetotail drift towards the midplane and are thought to be a principal source for the hot plasma sheet. A remarkable result from Geotail is the observation of cold ion beams coexisting as distinct components in the presence of hot plasma-sheet plasmas. The development and evolution of plasmoids is a topic of considerable interest in studies of the magnetotail and magnetospheric substorms. A number of possible plasmoids have been identified in the Geotail data set based upon reversals of the Z component of the magnetic field as observed with the MGF instrumentation. An intensive study of the electron and ion velocity distributions and the plasma parameters for several of these events reveals unexpected features. Collaborative work with several Geotail instrument teams and other researchers is also ongoing.

Frank, Louis A.↗

Mission operations and command assurance - Automating an operations TQM task

A long-term program is in progress at JPL to reduce cost and risk of mission operations through defect prevention and error management. A major element of this program, Mission Operations and Command Assurance (MO&CA), provides a system level function on flight projects to instill quality in mission operations. MO&CA embodies the total quality management TQM principle of continuous process improvement (CPI) and uses CPI in applying automation to mission operations to reduce risk and costs. MO&CA has led efforts to apply and has implemented automation in areas that impact the daily flight project work environment including Incident Surprise Anomaly tracking and reporting; command data verification, tracking and reporting; and command support data usage. MO&CA's future work in automation will take into account that future mission operations systems must be designed to avoid increasing error through the introduction of automation, while adapting to the demands of smaller flight teams.

Welz, Linda↗

Restoration and Archiving of Data from the Plasma Composition Experiment on the International Sun-Earth Explorer One (ISEE 1)

The objective of this project has been to complete the archiving of energetic (10 eV/epsilon - 18 keV/epsilon) ion composition data from the Lockheed Plasma Composition Experiment on the International Sun-Earth Explorer One (ISEE 1) satellite, using a particular data format that had previously been approved by NASA and the NSSDC. That same format, a combination of ion velocity moments and differential flux spectra, had been used in 1991 to archive, at the NSSDC, the first 28 months (the "Prime" period of ISEE investigations) of data from the Lockheed instrument under NASA Contract NAS5-33047. With the completion of this project, the almost 4 1/2-year time span of these unique data is now covered by a very compact set, approximately 1 gigabyte in total, of electronic files with physical quantities, all in ASCII. The files are organized by data type and time of data acquisition, in Universal Time, and named according to year and day of year. Each calendar day has five separate files (five types of data), the lengths of which vary from day to day, depending on the instrument mode of operation. The data format and file structure are described in detail in appendices 1 and 2. The physical medium consists of high-density (6250 cpi) 9-track magnetic tapes, complemented by a set of hardcopy line plots of certain plasma parameters. In this case there are five tapes, to be added to the six previous ones from 1991, and 25 booklets of plots, one per month, to be added to the previous 28. The tapes, including an extra standard-density (1600 cpi) tape with electronic versions of the Data User's Guide and self-guiding VAX/VMS command files, and the hardcopy plots are being boxed for shipment to the NSSDC.

Lennartsson, O. W.↗

Analysis of TRMM Microphysical Measurements: Tropical Rainfall Measuring Mission (TRMM)

SPEC Incorporated participated in three of the four TRMM field campaigns (TEFLUN-A, TEFLUN-B and KWAJEX), installing and operating a cloud particle imager (CPI) and a high volume precipitation spectrometer (HVPS) on the SPEC Learjet in TEFLUN-A, the University of North Dakota Citation in TEFLUN-B and KWAJEX, and a CPI on the NASA DC-8 in KWAJEX. This report presents and discusses new software tools and algorithms that were developed to analyze microphysical data collected during these field campaigns, as well as scientific interpretations of the data themselves. Software algorithms were developed to improve the analysis of microphysical measurements collected by the TRMM aircraft during the field campaigns. Particular attention was paid to developing and/or improving algorithms used to compute particle size distributions and ice water content. Software was also developed in support of production of the TRMM Common Microphysical Product (CMP) data files. CMP data files for TEFLUN-A field campaign were produced and submitted to the DAAC. Typical microphysical properties of convective and stratiform regions from TEFLUN-A and KWAJEX clouds were produced. In general, it was found that in the upper cloud region near -20 to -25 C, stratiform clouds contain very high (greater than 1 per cubic centimeter) concentrations of small ice particles, which are suspected to be a residual from homogeneous freezing and sedimentation of small drops in a convective updraft. In the upper cloud region near -20 to -25 C, convective clouds contain aggregates, which are not found lower in the cloud. Stratiform clouds contain aggregates at all levels, with the majority in the lowest levels. Convective cloud regions contain much higher LWC and drop concentrations than stratiform regions at all levels, and higher LWC in the middle and upper regions. Stratiform clouds contain higher IWC than convective clouds only at the lowest level. Irregular shaped ice particles are found in very high concentrations throughout both convective and stratiform cloud regions. A striking difference in particle shape in cirrus formed in situ, cirrus formed from maritime anvils and cirrus formed from continental anvils. Over 50% of the mass of in situ cirrus ice particles is composed of bullet rosettes, while bullet rosettes are virtually non-existent in maritime and tropical anvils. Tropical anvils are composed of mostly singular, plates, capped columns, and blocky irregular shapes, while continental anvils have a much higher percentage of aggregates, some of which are chains of small spheroidal particles that appear to result from homogeneous freezing of drops. A correlation between high electric fields in continental anvils and the formation of aggregates is hypothesized.

Source record↗

Lightweight Electronic Camera for Research on Clouds

"Micro-CPI" (wherein "CPI" signifies "cloud-particle imager") is the name of a small, lightweight electronic camera that has been proposed for use in research on clouds. It would acquire and digitize high-resolution (3- m-pixel) images of ice particles and water drops at a rate up to 1,000 particles (and/or drops) per second.

Lawson, Paul↗

A Classification of Ice Crystal Habits Using Combined Lidar and Scanning Polarimeter Observations during the SEAC4RS Campaign

Using collocated NASA Cloud Physics Lidar (CPL) and Research Scanning Polarimeter (RSP) data from the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) campaign, a new observational-based method was developed which uses a K-means clustering technique to classify ice crystal habit types into seven categories: column, plates, rosettes, spheroids, and three different type of irregulars. Intercompared with the collocated SPEC, Inc., Cloud Particle Imager (CPI) data, the frequency of the detected ice crystal habits from the proposed method presented in the study agrees within 5% with the CPI-reported values for columns, irregulars, rosettes, and spheroids, with more disagreement for plates. This study suggests that a detailed ice crystal habit retrieval could be applied to combined space-based lidar and polarimeter observations such as CALIPSO and POLDER in addition to future missions such as the Aerosols, Clouds, Convection, and Precipitation (A-CCP).

Natalie Midzak↗