Geochemical solid characterization of drill cuttings, core and drilling mud from Marcellus Shale Energy development
Million tons of drill cuttings generated from shale gas development are currently disposed of in landfills, buried in-situ, or reused as road fill. Cuttings, core samples and operating drilling mud from the Marcellus Shale Energy and Environmental Laboratory in WV were studied to better characterize drill cuttings and to evaluate trace metal mobility in various disposal environments. Results showed that physical and chemical properties of drill cuttings are impacted by the host-rock formation, calcium sources and the residual drilling-mud. Barite in residual drilling mud forms a coating around rock cuttings and influences the mobility of Sr in drill cuttings. Trace metals in drill cuttings are primarily associated with pyrite and total organic carbon (TOC) phases in the shale. As a result, based on sequential extraction results, various trace metal mobilities are controlled by additional solid fractions in drill cuttings, such as pyrite, TOC, calcite, barite and exchangeable clays in the shale.