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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

High frequency beam oscillation keyhole dynamics in laser melting revealed by in-situ x-ray imaging

The metal additive manufacturing industry is actively developing instruments and strategies to enable higher productivity, optimal build quality, and controllable as-built microstructure. A beam controlling technique, laser oscillation has shown potential in all these aspects in laser welding; however, few attempts have been made to understand the underlying physics of the oscillating keyholes/melt pools which are the prerequisites for these strategies to become a useful tool for laser-based additive manufacturing processes. Here, to address this gap, we utilized a synchrotron-based X-ray operando technique to image the dynamic keyhole oscillation in Ti-6Al-4V using a miniature powder bed fusion setup. We found good agreement between the experimental observations and simulations performed with a validated Lattice Boltzmann multiphysics model. The study revealed the continuous and periodic fluctuations in the characteristic keyhole parameters that are unique to the oscillating laser beam processing and responsible for the chevron pattern formation at solidification. In particular, despite the intrinsic longer-range fluctuation, the oscillating technique displayed potential for reducing keyhole instability, mitigating porosity formation, and altering surface topology. These insights on the oscillating keyhole dynamics can be useful for the future development and application of this technique.

36 MATERIALS SCIENCE↗

A MEMS dynamic mechanical analyzer for in situ viscoelastic characterization of 3D printed nanostructures

Cellular metamaterial structures with sub-micron features have shown the ability to become excellent energy absorbing materials for impact mitigation due to the enhanced mechanical properties of materials at the nanoscale. However, in order to optimize the design of these energy absorbing metamaterial structures we need to be able to measure the dynamic properties of the sub-micron features such as storage and loss moduli and the loss factor. Therefore, at scale testing is required to capture the scale, temperature, and strain rate dependent material properties of these nanoscale materials. This study presents the design, fabrication, and calibration of a MEMS-based dynamic mechanical analyzer (DMA) that can be directly integrated with the two photon lithography (TPL) process commonly used to fabricate metamaterial structures with nanoscale features. The MEMS-based DMA consists of a chevron style thermal actuator used to generate a tensile load on the structure and two differential capacitive sensors on each side of the structure used to measure load and displacement. This design demonstrated 1.5 ± 0.75 nm displacement resolution and 104 ± 52 nN load resolution, respectively. Dynamic mechanical analysis was successfully conducted on a single nanowire feature printed between the load and displacement stages of the MEMS device with testing frequencies ranging between 0.01–10 Hz and testing temperatures ranging between 22 °C–47 °C. These initial tests on an exemplar TPL part demonstrate that the printed nanowire behaves as a viscoelastic material wherein the transition from glassy to viscous behavior has already set in at the room temperature.

42 ENGINEERING↗

Programming liquid crystal elastomers for multistep ambidirectional deformability

Ambidirectionality, which is the ability of structural elements to move beyond a reference state in two opposite directions, is common in nature. However, conventional soft materials are typically limited to a single, unidirectional deformation unless complex hybrid constructs are used. We exploited the combination of mesogen self-assembly, polymer chain elasticity, and polymerization-induced stress to design liquid crystalline elastomers that exhibit two mesophases: chevron smectic C (cSmC) and smectic A (SmA). Inducing the cSmC-SmA–isotropic phase transition led to an unusual inversion of the strain field in the microstructure, resulting in opposite deformation modes (e.g., consecutive shrinkage or expansion and right-handed or left-handed twisting and tilting in opposite directions) and high-frequency nonmonotonic oscillations. Further, this ambidirectional movement is scalable and can be used to generate Gaussian transformations at the macroscale.

36 MATERIALS SCIENCE↗

Workshop to Plan R&D Support of Fuel/Basket Modification for Direct Disposal of Future DPCs

By 2030 about half of all spent nuclear fuel (SNF) arising from the current fleet of commercial power plants will be in dual-purpose canisters (DPCs), which are designed for storage and transportation but not for disposal. As an alternative to complete repackaging of the fuel for disposal, considerable cost savings and lower worker dose could be realized by directly disposing of this SNF in DPCs. The principal technical consideration is criticality control in a geologic repository, because the DPCs are large and depend on neutron absorbing basket components for criticality control. Neutron absorbing materials are generally aluminum-based, and under disposal conditions can degrade after a few hundred years contact with ground water. Simple modifications to the SNF assemblies or the DPC baskets could help to achieve direct disposal, and this is one of the approaches being studied to address the possibility of disposal criticality (SNL 2020a). Five fuel/basket modification concepts have been proposed (SNL 2020b) and a virtual workshop was conducted to solicit review and feedback on these concepts. The proposed solutions are: 1) zone loading of DPCs to limit reactivity, 2) replacing absorber plates with advanced neutron absorbing (ANA) material, 3) adding disposal control rods to pressurized water reactor (PWR) assemblies, 4) rechanneling boiling water reactor (BWR) assemblies with ANA material, and 5) basket insert plates (chevron inserts) made from ANA material. The presentations from the workshop are provided in this report, and the workshop discussions are summarized. This information includes prioritization of the proposed fuel/basket modification solutions, and prioritization of the associated model development, validation testing, and quality assurance activities. Information documented in this report will help to steer research and development efforts at Sandia National Laboratories, Oak Ridge National Laboratory, and Idaho National Laboratory that support the U.S. Department of Energy, Office of Nuclear Energy, Spent Fuel and Waste Science and Technology program

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Robust Carbon Dioxide Plume Imaging Using Joint Tomographic Inversion of Seismic Onset Time and Distributed Pressure and Temperature Measurements (Final Report)

We develop and demonstrate rapid and cost-effective methodologies for spatiotemporal tracking of CO2 plumes during geologic sequestration using joint inversion of seismic data and distributed pressure and temperature measurements. Key elements of our methodology are: (a) a computationally efficient approach to pressure and temperature propagation, (b) analysis of time lapse seismic data using a novel ‘seismic onset time’ approach to detect fluid front propagation, and (c) data assimilation and uncertainty assessment via joint inversion of pressure, temperature and time lapse seismic data, and (d) validating the numerical tomographic inversion using a CO2 injection demonstration projects, specifically data collected from the from the Petra Nova Parish Holdings CCUS project in the West Ranch Field, Texas and the Chester-16 reef CO2 injection site in Northern Michigan which is part of the DOE Midwestern Carbon Sequestration Project. The research team is led by Texas A&M University and includes Battelle as a subcontractor with support from Shell, Anadarko, Chevron and JX Nippon. A carbon dioxide (CO2) water-alternating-gas (WAG) pilot was conducted to gain insights into tertiary oil recovery potential via CO2 flood in the West Ranch Field as part of the Petra Nova project, the world’s largest post-combustion CO2 capture and utilization initiative. With a fluvial formation geology and large contrasts in permeability, this is a challenging and novel application of CO2 enhanced oil recovery (EOR). We build a predictive dynamic model of the subsurface that incorporates the multiphase and compositional data acquired during the pilot operation. The calibrated model is used for the carbon dioxide plume imaging. The study began with an initialization of the pilot sector model extracted from a calibrated full-field model. The pilot model calibration follows a two-step hierarchical workflow. First, we performed a large-scale update of the permeability distribution by integrating available bottomhole pressure and multiphase production data. In the second step, local permeability field is fine-tuned using a streamline-based method to match CO2 breakthrough times at the producers. The predictive capability of the calibrated model was verified through two blind validation tests: (1) the model showed good agreement with saturation logs acquired at two observation wells; and (2) the model reproduced the CO2 recovery as a fraction of the injected CO2. The use of seismic onset times has shown great promise for integrating near-continuous seismic surveys for updating geologic models. In this study, we analyze the impact of seismic survey frequency on the onset time approach aiming to extend the application of onset time to infrequent seismic surveys. In addition, we quantitatively examine the nonlinearity of the onset time method and compare it to the commonly used amplitude inversion method. We carry out a sensitivity analysis of seismic survey frequency based on the complete seismic survey data (over 175 surveys) of steam injection in a heavy oil reservoir (Peace River Unit) in Canada. Our results show that an adequate onset time map can be obtained from the infrequent seismic surveys by interpolation between seismic surveys as long as there is no change in the dominant underlying physics between the successive surveys. The study also shows that nonlinearity of the onset time method can be -smaller than that of the amplitude inversion method by several orders of magnitude. Application to the Brugge benchmark case shows that the onset time method obtains comparable permeability update as the traditional seismic amplitude inversion method with faster computation and improved convergence characteristics. We extend the streamline-based data integration approach to incorporate distributed temperature sensor (DTS) data using the concept of thermal tracer travel time. Then, a hierarchical workflow composed of evolutionary and streamline methods is employed to jointly history match the DTS and pressure data. Finally, CO2 saturation and streamline maps are used to visualize the CO2 plume movement during the sequestration process. The hierarchical workflow is applied to a carbon sequestration project in a carbonate reef reservoir within the Northern Niagaran Pinnacle Reef Trend in Michigan, USA. The monitoring data set consists of distributed temperature sensing (DTS) data acquired at the injection well and a monitoring well, flowing bottom-hole pressure data at the injection well, and time-lapse pressure measurements at several locations along the monitoring well. The history matching results indicate that the CO2 movement is mostly restricted to the intended zones of injection which is consistent with an independent warm-back analysis of the temperature data. In addition to employing simulation models and inverse methods for CO2 plume imaging, we also initialized a data-driven technology for detecting inter-well connectivity based on production and pressure data. Our machine-learning framework is built on the statistical recurrent unit (SRU) model and interprets well-based injection/production data into inter-well connectivity without relying on a geologic model. We test it on synthetic and field-scale CO2 EOR projects utilizing the water-alternating-gas (WAG) process. The validation of the proposed data-driven inter-well connectivity assessment is performed using synthetic data from simulation models where inter-well connectivity can be easily measured using the streamline-based flux allocation. The SRU model is shown to offer excellent prediction performance on the synthetic case. Despite significant measurement noise and frequent well shut-ins imposed in the field-scale case, the SRU model offers good prediction accuracy, the overall relative error of the phase production rates at most producers ranges from 10% to 30%. It is shown that the dominant connections identified by the data-driven method and streamline method are in close agreement. Texas A&M University, the lead organization in the project, was primarily responsible for the development of tomographic approaches for CO2 plume mapping in conjunction with distributed pressure, temperature and seismic onset time data. Battelle, as a subcontractor, was primarily responsible for the development of analytical and empirical methods for analyzing transient injection rate and pressure data from point/line sources such as injection and monitoring wells. An additional area of emphasis for Battelle was the use of machine learning for such tasks as inferring reservoir connectivity information from injection-production data, and identifying variable importance for machine learning-based proxy models developed from full-physics simulations. The two organizations also collaborated on the application of the tomographic inversion methodology for a field data set.

02 PETROLEUM↗

Front-End Engineering Design for Piperazine with the Advanced Stripper

This Department of Energy (DOE) funded project was executed with the goal of preparing a Front-End Engineering Design (FEED) for the capture and compression of 90% of the CO2 that would normally be emitted from an existing natural gas combined cycle (NGCC) plant. The FEED focused on the application of the piperazine advanced stripper (PZAS) process at Mustang Station of the Golden Spread Electric Cooperative (GSEC), which consists of two gas turbines with common heat recovery steam generator (HRSG). The University of Texas at Austin (UT) served as the prime contractor, and subcontracted AECOM Technical Services and Trimeric Corporation to support FEED development. This project team has worked together to advance PZAS for more than a decade. ExxonMobil, Chevron, and Total provided project co-funding. The objectives of this work included: 1. To advance engineering design such that a comprehensive estimate for the total installed cost of a full-scale PZAS CO2 Capture Plant with CO2 compression can be developed on an existing NGCC power plant. a. These detailed costs can also be used to qualify PZAS and other related second generation (2G) amine scrubbing processes for use on cogeneration facilities in refineries and chemical plants that use gas turbines with HRSGs to produce steam. b. These detailed costs will help qualify 2G amine scrubbing for use on NGCC power plants and establish a more accurate baseline cost to be used as a target by other capture technologies. 2. To provide cost details to be used in the economic optimization of the process features of PZAS and other 2G amine scrubbing processes. 3. To provide DOE with a more detailed understanding of carbon capture costs in a commercial application, enabling DOE to better design its R&D program to improve the economics for carbon capture. 4. To provide the host site and cost share partners with the information necessary to determine whether a commercial project to capture and use CO2 for enhanced oil recovery (EOR) or for sequestration can be justified (when accounting for the 45Q tax credit). A key component of the FEED is the estimated total installed cost, which provides a basis for the likely capital investment necessary to implement the PZAS carbon capture process at this location and scale. In combination with the included economic analysis, which accounts for potential revenue from the produced CO2, potential avenues to profitability are explored. The major findings of the FEED are as follows: The Mustang Station PZAS CO2 Capture Plant estimated total project cost of $698 MM of which $384 MM was direct costs. The annual operating costs were $32.6 MM. The total investment for a PZAS facility at Mustang Station is $725 MM. This estimate includes owner’s cost of $25 million and a contingency of $110 MM. • The study estimated the CO2 capture plant at Mustang Station would generate CO2 at $110/tonne for EOR, assuming a 12% IRR (internal rate of return) and an 85% capacity factor. For CO2 storage, the same case would achieve a 12% IRR at about $114/tonne. At a capacity factor of 52%, the storage and EOR cases would break even when carbon is priced ~$150/tonne. The economic analysis determined that the capacity factor and utility pricing, among other variable factors, had a significant effect on the economics and will need additional studied. • The energy penalty of the PZAS plant would be about 46 MW in connected power and 35 MW in operating load. The natural gas requirement (for the Gas Boiler package) would be about 354 MMBTU/hr. • The FEED revealed no major risks in process maturity. However, some areas were outlined for further engineering during detailed design, which included the Gas Boiler system, general arrangement and site layout, air coolers, schedule development, and optimization of the process for higher CO2 removal. • If PZAS were to be implemented at another host site, additional opportunities for cost reduction for would include cost reduction through use of cooling water and steam extraction.

03 NATURAL GAS↗

Assessment of Heavy-Duty Fueling Methods and Components

Building on the successful commissioning and demonstration of NREL's heavy-duty (HD) fast flow research facility under the Innovating Hydrogen Station's Project, researchers advanced R&D activities to the next phase under a new project titled, Assessment of Heavy-Duty Fueling Methods and Components. This Cooperative Research and Development Agreement (CRADA) is led by NREL in partnership with NextEnergy, Argonne National Laboratory, and Chevron with NextEnergy representing a larger group of industry partners that includes AirLiquide, Hyundai, Nel, Nikola, Shell, and Toyota. The CRADA seeks to develop a comprehensive assessment of HD fuel cell electric vehicle fueling protocols and fueling hardware to understand the effects of fueling protocol architectures on station design, vehicle design, functional safety requirements, and the implications on the total cost of ownership (TCO) and techno economic assessment (TEA).

class 8 truck↗

Power Technologies for Rail Decarbonization Workshop: Summary Report

Argonne National Laboratory organized the Power Technologies for Rail Decarbonization Workshop for the U.S. Department of Energy (DOE) Vehicle Technologies Office. The workshop offered an inclusive venue for different stakeholders to convey their perspective on challenges and opportunities in decarbonizing the rail sector. The first day of the workshop focused on (1) rail decarbonization efforts in the DOE and collaboration opportunities, (2) technology pathways to decarbonize rail, and (3) prime mover and low-carbon options for rail. The second day was devoted to (1) prime mover and zero-carbon options for rail, and (2) rail logistics, infrastructure, and safety. Each day raised challenges and solutions through presentations from national leaders and discussions among panel members and the audience. Through this engagement with different stakeholders, we will produce a cross-disciplinary recommendation for the role of government agencies to contribute meaningful research to address current technology gaps. The workshop included up 139 active participants and featured keynote speakers and panelists from Association of American Railroads, Progress Rail Locomotive, Wabtec, Burlington Northern Santa Fe Railroad, Amtrak, Caterpillar, Cummins, Renewable Energy Group-Chevron, DOE’s Bioenergy Technologies Office, California Air Resources Board, Federal Railroad Administration and multiple DOE national laboratories. This summary report presents highlights from participant discussions covering the topics of technology pathways to decarbonize rail, prime mover and low-carbon options, prime mover and zero-carbon options, as well as rail logistics, infrastructure, and safety. The variety of input gathered from the stakeholder attendees is vital, as it helps inform DOE on rail decarbonization challenges and opportunities. Stakeholder feedback is balanced against DOE strategic directions and priorities with consideration of the roles of government and industry.

33 ADVANCED PROPULSION SYSTEMS↗

Assessment of Heavy-Duty Fueling Methods and Components

Chevron, NLR, ANL, and NextEnergy partnered in the development of a comprehensive assessment of heavy-duty (HD) fuel cell electric vehicle fueling protocols. The project leveraged and built upon existing international heavy-duty (HD) fueling protocols and fueling component development activities to deliver component performance assessments, modeling tools and methods evaluations, techno-economic assessments of industry-selected protocol structures and experimental validations of the strategies performed at NLR's HD hydrogen fueling station.

08 HYDROGEN↗

DESI Observations of the Andromeda Galaxy: Revealing the Immigration History of Our Nearest Neighbor

Abstract We present Dark Energy Spectroscopic Instrument (DESI) observations of the inner halo of M31, which reveal the kinematics of a recent merger—a galactic immigration event—in exquisite detail. Of the 11,416 sources studied in 3.75 hr of on-sky exposure time, 7438 are M31 sources with well-measured radial velocities. The observations reveal intricate coherent kinematic structure in the positions and velocities of individual stars: streams, wedges, and chevrons. While hints of coherent structures have been previously detected in M31, this is the first time they have been seen with such detail and clarity in a galaxy beyond the Milky Way. We find clear kinematic evidence for shell structures in the Giant Stellar Stream, the Northeast Shelf, and Western Shelf regions. The kinematics are remarkably similar to the predictions of dynamical models constructed to explain the spatial morphology of the inner halo. The results are consistent with the interpretation that much of the substructure in the inner halo of M31 is produced by a single galactic immigration event 1–2 Gyr ago. Significant numbers of metal-rich stars ([Fe/H] > − 0.5) are present in all of the detected substructures, suggesting that the immigrating galaxy had an extended star formation history. We also investigate the ability of the shells and Giant Stellar Stream to constrain the gravitational potential of M31, and estimate the mass within a projected radius of 125 kpc to be log 10 M NFW ( < 125 kpc ) / M ⊙ = 11.80 − 0.10 + 0.12 . The results herald a new era in our ability to study stars on a galactic scale and the immigration histories of galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

Magnetohydrodynamic Wave Mode Conversion in a Pseudostreamer Structure

The interaction of a fast magnetoacoustic wave with a magnetic null point in a pseudostreamer magnetic configuration is modeled. The incident fast wave is excited by an impulsive velocity driver located in the corona outside the Alfvén-acoustic equipartition layer. The fast wave front experiences refraction and wraps around the null point, while the front segment approaching the null point along the magnetic bisector passes through it. In the equipartition layer surrounding the null point, part of the fast wave energy is converted into slow magnetoacoustic waves. Slow waves propagate outward from the null point along the magnetic separatrices. The fronts of slow waves exhibit a characteristic chevron shape. The fast-to-slow mode conversion efficiency increases with the width of the initial perturbation, following a power-law dependence with an index of approximately 1.06. For initial wave amplitudes below about 10% of the local Alfvén speed, the dependence of the conversion efficiency on the initial amplitude is weak. After interacting with the null point, the amplitudes of the fast waves decrease significantly owing to energy conversion and the spreading of wave energy over a broad spatial domain. In contrast, the energy of slow waves remains concentrated in the vicinity of the magnetic separatrices, resulting in less pronounced geometric attenuation of these waves. These findings are consistent with observational reports of the interaction of a coronal fast wave with a pseudostreamer.

Zhong, Yu [Univ. of Warwick, Coventry (United King↗

Quarterly Technical Progress Report Piperazine Advanced Stripper (PZAS™) Front End Engineering Design

EXECUTIVE SUMMARY This document summarizes the status of Cooperative Agreement DE-FE0031844, “Piperazine Advanced Stripper (PZAS™) Front-End Engineering Design,” during the reporting period of January 1 through March 31, 2020. The objective of this project is to develop accurate installed costs by conducting a Front-End Engineering Design (FEED) of PZAS™ at Golden Spread Electric Cooperative’s (GSEC) Mustang Station located in Denver City, TX. Complementary benefits include positioning the technology for a commercial project with the 45Q tax credits, qualifying PZAS™ for use on a Natural Gas Combined Cycle (NGCC) Cogen facility, and to provide cost detail to optimize PZAS™ and help guide R&D of second-generation solvent CO2 capture technologies. Results from the FEED will be used to evaluate the economic feasibility of the process at Mustang Station. This project is funded by the U.S. DOE National Energy Technology Laboratory under the aforementioned Cooperative Agreement. Exxon, Total, Chevron, UOP-Honeywell, and the University of Texas (UT) are project co-funders. AECOM and Trimeric are project team members; UT is the prime contractor. Summary of Progress Cooperative Agreement DE-FE0031844 was established in October 2019. The current reporting period, January 1 through March 31, 2020, is the second technical progress reporting period for the project. Several milestones were accomplished during this reporting period, including: • Kickoff Meeting with DOE on February 3, 2020. • Kickoff Meeting with GSEC on March 30, 2020. (Note: Due to Covid-19 travel restrictions and shelter-in-place guidelines, the kickoff meeting was conducted remotely via videoconferencing. See attached notes from that telecon.) • Updated Project Management Plan March 2020, submitted with this quarterly report Other activities during the quarter included progress on contracting and other legal agreements (e.g., non-disclosure agreements), internal kickoff meetings at both AECOM and Trimeric, and development of a Technical Implementation Plan (TIP). The TIP will help the team to make critical, early process decisions and, ultimately, to develop a project and process design basis. Note that all agreements between project team participants are complete as of this submittal, except the vendor agreement with Kiewit (steam cycle modeling). Plans for Next Reporting Period Activities during the next reporting period (April 1, 2020 through June 30, 2020) include: the completion of the Project Design Basis and progress towards the Process Design Basis/Process Design Package (PDP). The Project Design Basis is due as a deliverable and milestone during the next reporting period.

Rochelle, Gary T.↗

Mechanical Characterization of Fe-Co-2V (Hiperco): Fatigue/Monotonic Testing Hardness Testing and Fractography

Fe-Co-2V is a popular metallic alloy used in electromagnetic applications. However, there is a lack of mechanical fatigue characterization of this alloy in the literature. In this work, Fe-Co-2V specimens with rectangular cross-sections were carefully prepared in accordance with standards. They were measured for surface roughness and then subjected to quasi-static monotonic testing, as well as fatigue testing at both 0.5 Hz and 1 Hz frequencies. Both Rockwell hardness and Vickers micro- hardness testing were performed. Additionally, scanning electron microscopy imaging of the fractured surfaces was done. The quasi-static testing revealed a flat yield region characteristic of Laders bands. Here, the fatigue results did not show significant differences or sensitivity to change in frequency, although the fatigue life was higher on average for the 0.5 Hz. However, the fatigue results differed from published work at 0.33 Hz. The fractography revealed purely brittle fracture, with clear chevron marks and fracture initiation always starting at the surface. Lastly, it was identified that the C, D, and F Rockwell hardness scales were appropriate for testing this material and that the grain size necessitated the use of the upper end of indentation force for Vickers micro-hardness testing.

36 MATERIALS SCIENCE↗

Energy I-Corps Annual Report 2022

The U.S. Department of Energy Office of Technology Transitions is pleased to provide an update on the Energy I-Corps program. Now in its eighth year, Energy I-Corps addresses critical gaps in workforce development for our National Lab researchers. It provides meaningful real-world opportunities for the application of commercialization and entrepreneurial skills to DOE technologies. As of November 2022, 191 teams from 12 National Labs have participated in Energy I-Corps over the course of 15 cohorts and the pilot. Since its inception, Energy I-Corps participants have learned from more than 180 industry mentors and conducted over 13,600 discovery interviews with companies like: EPRI, Shell, Ford, World Bank, Breakthrough Energy, John Deere, Siemens Gamesa, Chevron, Eaton, Samsung, Lowes, Johns Manville, LEGO, U.S. Army, Trane, Tesla, GM, Dow Chemical, 3M, Whirlpool, GE, Home Depot, and Amazon. Over 20 teams have launched new businesses based on their Energy I-Corps technology. Post Energy I-Corps, technologies have attracted over $140M in post-program funding and executed over 75 licenses.

cohort↗

Heat Transfer Experiments of Ribbed, Serpentine Cooling Passages with Supercritical CO2

The results of heat transfer experiments with supercritical CO2 (sCO2) to capture the performance of ribbed, serpentine cooling passages for Reynolds numbers in the range of 100,000 - 400,000 are presented. The oxy-combustion turbine operating in an Allam-Fetvedt cycle has a turbine inlet temperature exceeding 1100°C, necessitating internally cooled turbine blades due to material creep strength limits. Reynolds numbers for sCO2, with its combination of high fluid density and low viscosity, can be up to an order of magnitude higher than comparable internal cooling conditions for an air-breathing engine where the majority of experimental data exists. To improve the prediction of cooling performance through turbulated passages, a test rig was designed and constructed with interchangeable insert capability for operation in sCO2 with heat transfer from a heater outlet flow stream to a lower temperature recuperator outlet flow stream. The inserts included serpentine passage geometry with five passes, one of the inserts including chevron ribs and the other a plain wall. The multi-pass serpentine geometry allowed for the evaluation of the effects 180 deg. tip turns have on the return passage flow characteristics, as they can depart significantly from fully-developed flow characteristics. The test procedure included the use of a modified Wilson plot method, with hot flow stream conditions kept effectively constant so that monitored changes in the overall thermal resistance could be attributed to manipulations in cooling flow stream conditions. Conditions during testing consisted of test section pressures of approximately 180 bar, cooling flow stream temperature of 175°C and hot flow stream temperature of 410°C. Test points at discrete cool flow Reynolds numbers up to 400,000 demonstrated an expected trend of decreased fluid thermal resistance with increasing Reynolds number, while at comparable Reynolds number there was an exhibited lower thermal resistance and higher passage pressure drop for the ribbed insert compared to the plain-walled insert. Processing of test data included establishment of Nusselt number enhancement ratios, so that for different internal cooling passage dimensions in the actual turbine blade at comparable Reynolds number the ratio could be applied to predict cooling performance.

Marshall, Michael↗

High-Resolution Simulations of Geological CO 2 Injection: Application to the SPE11 Benchmark

Geological carbon sequestration (GCS) will play a critical role in decarbonization and in facilitating the transition to clean energy systems. Because CO 2 is highly mobile, ensuring its safe and permanent injection into subsurface geological formations involves monitoring over larger spatial domains and longer time periods than is typical for hydrocarbon reservoirs. This can benefit from simulation tools capable of modeling key CO 2 trapping mechanisms, particularly those optimized for speed and scalability on high-performance computing systems. Using isothermal versions of the SPE11B and SPE11C benchmark cases, we conduct a mesh refinement study simulating CO 2 injection into kilometer-scale rock formations at centimeter resolution with the GEOS open-source simulation framework. We focus on how mesh refinement improves the accuracy of convective mixing in both 2D and 3D simulations. The computational costs associated with achieving a converged solution highlight the need for predictive upscaling techniques. A systematic performance scaling analysis—including both central processing unit (CPU) and graphics processing unit (GPU) architectures—complements the “Results” section.

Geosciences↗

Unravelling the origins of shale nanoporosity using small-angle neutron scattering (SANS)

Hydrocarbon production from tight rocks is constrained by slow diffusion within the shale matrix, limited by small pore sizes and low permeability. The nanopore proportion and size distribution significantly influence matrix permeability, a key property for optimizing hydrocarbon recovery and supporting hydrogen production while minimizing environmental impacts. Small-angle neutron scattering (SANS) has been an important tool for exploring the characteristics and structure of shale nanopores. This study used SANS to analyze nanoporosity and pore size distribution (<100 nm) in tight rocks with varying compositions to determine the influence of rock heterogeneity on SANS measurements. Results showed that nanoporosity correlates with clay content, with the highest clay-rich shale (52.48 wt% clay) exhibiting 8.8 % nanoporosity. SANS also revealed more nanopores than traditional nitrogen adsorption measurements, affirming its ability to reflect bulk mineralogy and upholding the relevance of experimental findings using this technique to optimize field operational approaches.

03 NATURAL GAS↗

Pressure stability in explicitly coupled simulations of poromechanics with application to CO 2 sequestration

We study in detail the pressure stabilizing effects of the non-iterated fixed-stress splitting in poromechanical problems which are nearly undrained and incompressible. When applied in conjunction with a spatial discretization which does not satisfy the discrete inf–sup condition, namely a mixed piecewise linear–piecewise constant spatial discretization, the explicit fixed-stress scheme can have a pressure stabilizing effect in transient problems. This effect disappears, however, upon time step refinement or the attainment of steady state. The interpretation of the scheme as an Augmented Lagrangian method similar to Uzawa iteration for incompressible flow helps explain these results. Moreover, due to the slowly evolving solution within undrained seal regions, we show that the explicit fixed-stress scheme requires very large time steps to reveal its pressure stabilizing effect in examples of geologic CO 2 sequestration. We note that large time steps can result in large errors in drained regions, such as the aquifer or reservoir regions of these examples, and can prevent convergence of nonlinear solvers in the case of multiphase flows, which can make the explicit scheme an unreliable source of pressure stabilization. We conclude by demonstrating that pressure jump stabilization is as effective in the explicit fixed-stress setting as in the fully implicit setting for undrained problems, while maintaining the stability and convergence of the fixed-stress split for drained problems.

58 GEOSCIENCES↗