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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Defining a compact dry cooler design to reduce LCOE contribution in a CSP facility

Concentrating solar power (CSP), when coupled with a supercritical carbon dioxide (sCO 2 ) power cycle and sensible heat storage, presents a renewable and clean alternative for utility-scale power generation. However, in order to be competitive in the current and future markets, CSP facilities must limit their levelized cost of electricity (LCOE) by minimizing capital costs and reducing operating costs over the lifetime of the plant. Targeting this goal, this study investigates the LCOE impact of the power cycle pre-cooler. This study considers a compact dry cooler with micro-channel technology on the CO 2 side and formed fin geometry on the air side, using directly-coupled centrifugal fans and a transition duct to improve air distribution across the fins as well as protect the fins from contaminants which may cause blockage, soiling, fouling, and damage. In an effort to better understand the dry cooler impact on LCOE, a sensitivity study was conducted using various combinations of end-to-end approach temperatures, air-side pressure drop values, CO 2 -side pressure drop values, fan types, cooler turndown control schemes, cooler module sizes, and design-point ambient temperatures. Furthemore, off-design cycle performance data was calculated for each dry cooler design using NPSS simulation software; cycle performance data were then input to System Advisor Model (SAM) along with the associated capital costs for LCOE prediction of a 100 MW system over a 30 year plant lifetime. Results of this study show the LCOE is most sensitive to air-side performance, followed by heat transfer effectiveness and capital cost. It was found that a power cycle with a mid- to high-performance dry cooler will produce the most competitive power-production costs. Designing at the extreme ends for approach temperature (or effectiveness), design-point ambient temperature, and compactness (footprint) produce higher LCOE values; mid-range values for these parameters balance performance, operating costs, and associated capital cost to optimize LCOE.

14 SOLAR ENERGY↗
DOE OSTI2016

Origin and heterogeneity of pore sizes in the Mount Simon Sandstone and Eau Claire Formation: Implications for multiphase fluid flow

The Mount Simon Sandstone and Eau Claire Formation represent a principal reservoir - caprock system for wastewater disposal, geologic CO 2 storage, and compressed air energy storage (CAES) in the Midwestern United States. Of primary concern to site performance is heterogeneity in flow properties that could lead to non-ideal injectivity and distribution of injected fluids (e.g., poor sweep efficiency). Using core samples from the Dallas Center Structure, Iowa, we investigate pore structure that governs flow properties of major lithofacies of these formations. Methods include gas porosimetry and permeametry, mercury intrusion porosimetry, thin section petrography, and X-ray diffraction. The lithofacies exhibit highly variable intra- and inter-informational distributions of pore throat and body sizes. Based on pore-throat size, samples fall into four distinct groups. Micropore-throat dominated samples are from the Eau Claire Formation, whereas the macropore-, mesopore-, and uniform-dominated samples are from the Mount Simon Sandstone. Complex paragenesis governs the high degree of pore and pore-throat size heterogeneity, due to an interplay of precipitation, non-uniform compaction, and later dissolution of cements. Furthermore, the cement dissolution event probably accounts for much of the current porosity in the unit. The unusually heterogeneous nature of the pore networks in the Mount Simon Sandstone indicates that there is a greater-than-normal opportunity for reservoir capillary trapping of non-wetting fluids — as quantified by CO 2 and air column heights — which should be taken into account when assessing the potential of the reservoir-caprock system for CO 2 storage and CAES.

58 GEOSCIENCES↗
DOE OSTI2017

Compact Nanoparticle Size Distribution Measurement System for Unmanned Aerial Systems (UAS)

Brechtel Manufacturing Incorporated (BMI) is developing a compact, nanoparticle sizer optimized for use on Unmanned Aerial Vehicles (UAVs) and other applications where space, weight, power and cost are significant barriers to deployment. The instrument will allow observations of size-resolved aerosol number concentration (0.005 < D p < 0.3 μm, D p is particle diameter). The new development helps address the need for reduced uncertainties in atmospheric radiative transfer and weather prediction model sensitivities to ambient aerosol properties by promoting the capability to perform aerosol measurements more often, in more locations, and at reduced cost. Applications of the new technology include vertical atmospheric profiling with UAVs, balloons and other mobile platforms to constrain weather forecast models, long-term air quality measurements, aerosol health effects studies, and routine monitoring of ambient aerosol properties in urban air sheds.

47 OTHER INSTRUMENTATION↗
NASA NTRS2023

A SmallSat Concept to Resolve Diurnal and Vertical Variations of Aerosols, Clouds, and Boundary Layer Height

A SmallSat mission concept is formulated here to carry out Time-varying Optical Measurements of Clouds and Aerosol Transport (TOMCAT) from space while embracing low-cost opportunities enabled by the revolution in Earth science observation technologies. TOMCAT’s “around-the-clock” measurements will provide needed insights and strong synergy with existing Earth observation satellites to 1) statistically resolve diurnal and vertical variation of cirrus cloud properties (key to Earth’s radiation budget), 2) determine the impacts of regional and seasonal planetary boundary layer (PBL) diurnal variation on surface air quality and low-level cloud distributions, and 3) characterize smoke and dust emission processes impacting their long-range transport on the subseasonal to seasonal time scales. Clouds, aerosol particles, and the PBL play critical roles in Earth’s climate system at multiple spatiotemporal scales. Yet their vertical variations as a function of local time are poorly measured from space. Active sensors for profiling the atmosphere typically utilize sun-synchronous low-Earth orbits (LEO) with rather limited temporal and spatial coverage, inhibiting the characterization of spatiotemporal variability. Pairing compact active lidar and passive multiangle remote sensing technologies from an inclined LEO platform enables measurements of the diurnal and vertical variability of aerosols, clouds, and aerosol-mixing-layer (or PBL) height in tropical-to-midlatitude regions where most of the world’s population resides. TOMCAT is conceived to bring potential societal benefits by delivering its data products in near–real time and offering on-demand hazard-monitoring capabilities to profile fire injection of smoke particles, the frontal lofting of dust particles, and the eruptive rise of volcanic plumes.

John E. Yorks↗
NASA NTRS1990

Advanced air revitalization system modeling and testing

To support manned lunar and Martian exploration, an extensive evaluation of air revitalization subsystems (ARS) is being conducted. The major operations under study include carbon dioxide removal and reduction; oxygen and nitrogen production, storage, and distribution; humidity and temperature control; and trace contaminant control. A comprehensive analysis program based on a generalized block flow model was developed to facilitate the evaluation of various processes and their interaction. ASPEN PLUS was used in modelling carbon dioxide removal and reduction. Several life support test stands were developed to test new and existing technologies for their potential applicability in space. The goal was to identify processes which use compact, lightweight equipment and maximize the recovery of oxygen and water. The carbon dioxide removal test stands include solid amine/vacuum desorption (SAVD), regenerative silver oxide chemisorption, and electrochemical carbon dioxide concentration (EDC). Membrane-based carbon dioxide removal and humidity control, catalytic reduction of carbon dioxide, and catalytic oxidation of trace contaminants were also investigated.

Dall-Baumann, Liese↗
DOE OSTI2022

Compatibility of Medium Density Polyethylene (MDPE) for Distribution of Gaseous Hydrogen

Hydrogen has emerged as a convenient energy storage medium and is being considered as an alternative for reducing the use of carbon-based fuels. Numerous projects are looking into distributing blends of natural gas and different amounts of gaseous hydrogen through the existing natural gas distribution system, which is widely composed of medium density polyethylene (MDPE) line pipes. The mechanical behavior of MDPE with hydrogen is not well understood; therefore, the effect of gaseous hydrogen on the mechanical properties of MDPE needs to be examined. In the current study, we investigate the effects of gaseous hydrogen on fatigue crack growth rate, fracture resistance, and fatigue life of MDPE in the presence of 3.4 MPa gaseous hydrogen. Fatigue crack growth behavior and fracture resistance are measured using compact tension specimens, while the fatigue life tests are carried out using circumferential notched tensile specimens. In addition, fatigue and fracture tests were conducted in air to determine the baseline properties of MDPE, which was then compared with the ones observed in gaseous hydrogen environment. After the completion of mechanical testing, fracture surfaces are also analyzed using optical and scanning electron microscopes to understand salient fracture features of MDPE with and without the presence of gaseous hydrogen.

Shrestha, Rakish↗
DOE OSTI2024

Optimizing Hydride Stability in U-ZrH x Nuclear Fuel: The “Goldilocks Radius”

Nuclear-powered microreactors show great promise for opening new nuclear energy markets due to the flexibility offered by their rapid/streamlined in-factory fabrication, transportability, and self-regulating nature. The economic benefits of any commercialized nuclear reactor, however, rely on the system’s ability to produce large amounts of heat and efficiently convert that heat into electrical power reliably for long periods of time. Uranium-zirconium hydride (U-ZrH x ) is currently being considered for compact reactor designs because it is a well-known nuclear fuel system that is self-moderating, but this fuel, which has historically been used for research reactors, has not been optimized for commercial power production. Here, this paper analyzes the hydride stability of standard 304 stainless steel–clad U-ZrH x fuel under commercially relevant conditions. Fuel element design parameters, including physical dimensions, as-fabricated hydrogen content, burnup, peak fuel temperature, temperature gradient, operational fuel cycle duration, and volumetric heat generation rate, are discussed with a focus on hydrogen distribution and phase stability within the fuel element. Hydride stability declines more rapidly as the coolant temperature, burnup, and fuel cycle duration increase. Using a fuel-cladding gap material with heat transfer properties superior to air, such as helium or sodium, is essential to prolonging fuel hydride stability. The fuel’s physical dimensions are also important. At very small fuel diameters, the H/Zr ratio in the fuel meat decreases too rapidly due to the hydrogen content’s dependence on fuel meat volume. Conversely, the fuel meat temperature and temperature gradient exacerbate hydrogen loss at very large fuel diameters. We find that the most important parameter to consider when optimizing the hydride stability of U-ZrH x fuel is the relationship between the fuel meat radius and the power density in the fuel. A simple equation is empirically determined that relates the “Goldilocks radius,” that is, the fuel radius for which the H/Zr ratio is most stable, to the power density in the fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

High Frequency Transverse Instabilities in Low NOx Gas Turbines

This program addresses the topic of combustion instabilities under the goal of developing “Low-NOx Combustion Technology for ‘Air-Breathing’ Advanced Turbines”. With recent advances in high-temperature withstanding materials, the push towards higher efficiency has resulted in efforts to design high temperature, low NOx gas turbines. The development of such low NOx systems is often plagued with combustion instabilities. These instabilities manifest with acoustic modes that are longitudinal, transverse or both. A large body of literature and work exists addressing the underlying mechanisms and models for longitudinal instabilities and these have been successfully implemented in the design tools for low NOx gas turbines. The flame response aspect of the thermoacoustic feedback loop was often modeled in an acoustically compact framework since for low frequencies, the flame length scale was small compared to the acoustic wavelength. This enabled simplification where the modeling focused only on the overall flame response and not the local spatial distribution of the flame response. In addition, additional mechanisms such as the direct effect of pressure fluctuations on the flame response could be neglected. In contrast, high frequency instabilities which often are transverse in nature, have received relatively less attention in the literature. The flame is no longer acoustically compact and thus the local distribution of heat release must be accurately understood. The flame responds to velocity fluctuations, equivalence ratio fluctuations as before, but also to pressure fluctuations through kinetic effects. These aspects of high-frequency instabilities make it a challenging problem that requires a detailed elucidation of the underlying mechanisms and creating models for them. In this program we significantly improved the understanding of these instabilities through a combination of experiments (informed by interactions with OEMs), modeling of measured data and reduced order modeling of flame response. The results from the program can be used as basis for robust design tools that are essential for successfully developing gas turbines that operate in an environmentally acceptable manner with mitigation strategies for high-frequency instabilities.

08 HYDROGEN↗
NASA NTRS1992

Ozone Measurements with the US EPA UV-DIAL: Preliminary Results

A compact airborne down-looking lidar system was developed at the Environmental Protection Agency in Las Vegas. This differential absorption lidar (DIAL) was designed to simultaneously measure range-resolved concentrations of ozone (O3) and sulfur dioxide (SO2) in the lower troposphere, together with an indication of the aerosol distribution. The five laser wavelengths (i.e., lambda(sub 1) = 277 nm, lambda(sub 2) = 292 nm, lambda(sub 3) = 313 nm, lambda(sub4) = 319 nm, lambda(sub 5) = 369 nm) were generated via Raman conversion of a focused KrF excimer laser. The system is currently installed in a truck-based mobile laboratory. For the ground testing, an opening in the truck floor together with a folding mirror under the truck makes a horizontal, or upwardly inclined direction of measurement possible. Initial ground testing has been performed in the vicinity of a Desert Research Institute (DRI) ambient air monitoring site, located at Cottonwood Cove approximately 85 km south east of Las Vegas, Nevada. At this site O3 and SO2 concentrations are continuously monitored with an average accuracy better than +/- 10 percent. A temporary ozone measurement station with identical accuracy was set up at a distance to get a second point of comparison for the range-resolved DIAL measurements.

Moosmueller, H.↗
DOE OSTI2018

Addressing Two-Phase Flow Maldistribution in Microchannel Heat and Mass Exchangers

Multiphase flow phenomena in single micro and minichannels have been widely studied. Characteristics of two-phase flow through a large array of microchannels are investigated here. An air–water mixture is used to represent the two phases flowing through a microchannel array representative of those employed in practical applications. Flow distribution of the air and water flow across 52 parallel microchannels of 0.4 mm hydraulic diameter is visually investigated using high-speed photography. Two microchannel configurations are studied and compared, with mixing features incorporated into the second configuration. Slug and annular flow regimes are observed in the channels. Void fractions and interfacial areas are calculated for each channel from these observations. The flow distribution is tracked at various lengths along the microchannel array sheets. Statistical distributions of void fraction and interfacial area along the microchannel array are measured. The design with mixing features yields improved flow distribution. Void fraction and interfacial area change along the length of the second configuration, indicating a change in fluid distribution among the channels. The void fraction and interfacial area results are used to predict the performance of different microchannel array configurations for heat and mass transfer applications. Results from this study can help inform the design of compact thermal-fluid energy systems.

Engineering↗
NASA NTRS1998

Diode laser absorption sensors for gas-dynamic and combustion flows

Recent advances in room-temperature, near-IR and visible diode laser sources for tele-communication, high-speed computer networks, and optical data storage applications are enabling a new generation of gas-dynamic and combustion-flow sensors based on laser absorption spectroscopy. In addition to conventional species concentration and density measurements, spectroscopic techniques for temperature, velocity, pressure and mass flux have been demonstrated in laboratory, industrial and technical flows. Combined with fibreoptic distribution networks and ultrasensitive detection strategies, compact and portable sensors are now appearing for a variety of applications. In many cases, the superior spectroscopic quality of the new laser sources compared with earlier cryogenic, mid-IR devices is allowing increased sensitivity of trace species measurements, high-precision spectroscopy of major gas constituents, and stable, autonomous measurement systems. The purpose of this article is to review recent progress in this field and suggest likely directions for future research and development. The various laser-source technologies are briefly reviewed as they relate to sensor applications. Basic theory for laser absorption measurements of gas-dynamic properties is reviewed and special detection strategies for the weak near-IR and visible absorption spectra are described. Typical sensor configurations are described and compared for various application scenarios, ranging from laboratory research to automated field and airborne packages. Recent applications of gas-dynamic sensors for air flows and fluxes of trace atmospheric species are presented. Applications of gas-dynamic and combustion sensors to research and development of high-speed flows aeropropulsion engines, and combustion emissions monitoring are presented in detail, along with emerging flow control systems based on these new sensors. Finally, technology in nonlinear frequency conversion, UV laser materials, room-temperature mid-IR materials and broadly tunable multisection devices is reviewed to suggest new sensor possibilities.

Non-NASA Center↗
DOE OSTI2013

Advanced Natural Gas Reciprocating Engine(s)

Energy independence and fuel savings are hallmarks of the nation’s energy strategy. The advancement of natural gas reciprocating engine power generation technology is critical to the nation’s future. A new engine platform that meets the efficiency, emissions, fuel flexibility, cost and reliability/maintainability targets will enable American manufacturers to have highly competitive products that provide substantial environmental and economic benefits in the US and in international markets. Along with Cummins and Waukesha, Caterpillar participated in a multiyear cooperative agreement with the Department of Energy to create a 50% efficiency natural gas powered reciprocating engine system with a 95% reduction in NOx emissions by the year 2013. This platform developed under this agreement will be a significant contributor to the US energy strategy and will enable gas engine technology to remain a highly competitive choice, meeting customer cost of electricity targets, and regulatory environmental standard. Engine development under the Advanced Reciprocating Engine System (ARES) program was divided into phases, with the ultimate goal being approached in a series of incremental steps. This incremental approach would promote the commercialization of ARES technologies as soon as they emerged from development and would provide a technical and commercial foundation of later-developing technologies. Demonstrations of the Phase I and Phase II technology were completed in 2004 and 2008, respectively. Program tasks in Phase III included component and system development and testing from 2009-2012. Two advanced ignition technology evaluations were investigated under the ARES program: laser ignition and distributed ignition (DIGN). In collaboration with Colorado State University (CSU), a laser ignition system was developed to provide ignition at lean burn and high boost conditions. Much work has been performed in Caterpillar’s DIGN program under the ARES program. This work has consisted of both modeling and single cylinder engine experiments to quantify DIGN performance. The air handling systems of natural gas engines dissipate a percentage of available energy as a result of both flow losses and turbomachinery inefficiencies. An analytical study was initiated to increase compressor efficiency by employing a 2-stage inter-cooled compressor. Caterpillar also studied a turbo-compound system that employs a power turbine to recover energy from the exhaust gases for improved engine efficiency. Several other component and system investigations were undertaken during the final phase of the program to reach the ultimate ARES goals. An intake valve actuation system was developed and tested to improve engine efficiency, durability and load acceptance. Analytical modeling and materials testing were performed to evaluate the performance of steel pistons and compacted graphite iron cylinder head. Effort was made to improve the detonation sensing system by studying and comparing the performance of different pressure sensors. To reduce unburned hydrocarbon emissions, different camshafts were designed and built to investigate the effect of exhaust valve opening timing and value overlap. 1-D & 3-D coupled simulation was used to study intake and exhaust manifold dynamics with the goal of reducing load in-balance between cylinders. Selective catalytic reduction with on-board reductant generation to reduce NOx emissions was also engine tested. An effective mean to successfully deploy ARES technologies into the energy markets is to deploy demonstration projects in the field. In 2010, NETL and Caterpillar agreed to include a new “opportunity fuel” deliverable and two field demonstrations in the ARES program. An Organic Rankine Cycle system was designed with production intent incorporating lessons learned from the Phase II demonstration. Unfortunately, business conditions caused Caterpillar to cancel this demonstration in 2011. Nonetheless, Caterpillar partnered with a local dealer to deploy an ARES class engine using syngas from a biomass gasifier as the DE-FC26-01CH11079 primary combustion fuel in Gleason, TN. Upon the successful start-up and commissioning of the demonstration unit, ownership of the system was transferred to the dealer. In order to further our understanding of syngas combustion, a fundamental combustion study on syngas combustion at high pressure and lean condition was conducted through the collaboration with University of Southern California. A Methane program was also developed to rate engine performance for various compositions of syngas using empirical data obtained at CSU. While much work remains in terms of extending and integrating these developments into commercial products, it is evident that engine manufacturers on our own or through private consortium efforts could not have overcome the financial hurdles to drive these improvements into reciprocating engine and system capabilities, helping maintain the natural gas reciprocating engine power generation technology as a strong option for electric power markets, both in the United States and worldwide.

20 FOSSIL-FUELED POWER PLANTS↗
NASA NTRS1999

Development of a Portable, Ground-based Ozone Lidar Instrument for Tropospheric Ozone Research and Educational Training

The objective of this research project is to develop a portable, eye-safe, ground-based ozone lidar instrument specialized for ozone differential absorption lidar (DIAL) measurements in the troposphere. This research project directly supports the goal of NASA's Earth Science Enterprise to understand the distribution and budget of tropospheric ozone (objective 1.5 of the Earth Science Strategic Enterprise Plan, 1998-2002). It can participate in ground validation experiments for TES, a tropospheric ozone satellite mission due to be launched in 2002. It can also be utilized for correlative ground measurements in future GTE (Global Tropospheric Experiment) and space-based ozone lidar missions, such as ORACLE. Multiple ground-based ozone lidar systems would improve the data obtained through current ozone-sonde networks. This prototype instrument could to serve as the basic unit for these and other future monitoring projects requiring multi-instrument networks, such as that proposed for the Global Tropospheric Ozone Project (GTOP). GTOP is currently being formulated by a scientific panel of the International Global Atmospheric Chemistry Project to meet its goal to better understand the processes that control the global distribution of tropospheric ozone. In order for the lidar to be widely deployed in networks, it must be fairly easy to use and maintain as well as being cost-competitive with a ground station launching ozonesondes several times a day. A second 2-year grant to continue this effort with students participating in ground tests and system improvements has been awarded by the Office of Equal Employment Opportunities (OEOP). This project also supports existing NASA lidar missions through its development of advanced, compact lidar technology. Innovations in both transmitters and receivers have been made in this project. Finally, this system could be modified in the future to probe more deeply into the stratosphere. This could be accomplished by increasing the emitted energy or optimizing the wavelengths for this purpose. In addition to NASA, this system has applications to the EPA, NOAA, and the DOD. An AFOSR grant has been awarded based on the results of this effort to fund advanced transmitter development at medium (20-40 mJ) energies. A second proposal to the DOD with a letter of support from Air Force Research Laboratory, has been submitted to extend this uv laser technology to 100 mJ levels. Thus, this project has enabled students and faculty at Hampton University to begin to develop research efforts in support of the mission of the DOD. This instrument will be based at Hampton University (HU) to meet our educational goal to train students in lidar technology as well as atmospheric ozone data analysis and interpretation. It will be also available for off-site measurement campaigns and will serve as a test bed for further instrument development. Later development beyond this grant to extend the scientific usefulness of the instrument may include incorporation of an aerosol channel and upgrading the laser to make stratospheric ozone measurements. Seven undergraduates, three graduate students, and one postdoctoral. researcher (formerly an HU student) have been active participants in this research effort.

Chyba, Thomas↗
NASA NTRS2017

Metastable Phase Relations in the System Ca(sub O)-Al2(sub O)3-MgO-TiO(sub 2): Applications to Ca- And Al-Rich Inclusions

Introduction: High temperature phases such as corundum, hibonite, grossite, and perovskite are among the earliest phases that condensed in the early solar nebula. Recent work has shown that defect-structured phases occur in some ultrarefractory inclusions as metastable, possibly more kinetically-favored alternatives to the thermodynamically predicted stable phase assemblages [1-4]. For example, Han et al. have shown that non-stoichiometry in hibonite is accommodated by extra "spinel" blocks in the structure instead of the equilibrium assemblages hibonite+corundum or hibonite+spinel. To explore these relations, we have conducted a series of experiments in the system CaO-Al2O3- MgO-TiO2. Here we discuss the compositions and mineralogy of the experimental samples and how they relate to phases in refractory inclusions with a focus on perovskite and spinel. Methods: For the series of annealing studies, a CaO-Al2O3 eutectic melt is allowed to react with a pure alumina crucible at 1,530degC for either 4 hours or 5 days, followed by quenching in air. Later experiments were similar except that additions of 5 wt% MgO, and CaTiO(sub 3) were used to explore the effect of minor elements on the phase assemblages. The experimental conditions resulted in reaction zones approximately 100-300 m wide consisting of a hibonite layer immediately adjacent to the corundum, followed by a grossite layer, and finally krotite with residual quenched melt. For the experiments with Mg, spinel is distributed in all layers but is mainly concentrated in the krotite layer. In the Ti-bearing experiments, perovskite precipitated in association with the krotite and residual melt. In addition to the experiments, we also analyzed perovskite grains in the FUN inclusion SHAL [5] and a large compact type A CAI from Allende. The experiments and refractory inclusions were analyzed using a JEOL 7600F SEM and quantitative analyses were obtained using the JEOL 8530F field-emission electron microprobe.

Keller, L. P.↗
DOE OSTI2024

Full Scale HEPA Filter Encapsulation in Ultra-High-Performance Grout - Proof of Concept

The Hanford Tank Waste Treatment and Immobilization Plant (WTP) currently being constructed to treat radioactive waste, includes vitrification facilities for both the high-level waste (HLW) and low activity waste (LAW) fractions. Operation of the WTP will produce contaminated high-efficiency particulate air filters (HEPA), as part of the solid secondary waste (SSW) stream. The HEPA filters receive off-gas from the vessel vent header and primary off-gas treatment system in LAW Facility and remove particulate contaminants including 99 Tc and 129 I salts. The current disposal method for HEPA filters is encapsulation in metal containers using cementitious material (CM) and disposal in the Integrated Disposal Facility (IDF). Results from the 2017 IDF Performance Assessment (PA) WRPS (2018) demonstrated that while compliance is maintained for the 1000 year compliance period mandated by DOE O 435.1 and its accompanying manual, release of constituents from the HEPA filters result in exceedance of the performance objective imposed as the groundwater regulatory limit at later times. For example, at about 1500 years post-closure, solid secondary waste (SSW), including HEPA filters is predicted to become a dominant contributor to 99 Tc release and over the 10,000-year sensitivity analysis period, SSW is the dominant contributor of 129 I release to the groundwater. The estimated release could potentially be reduced if the HEPA filters are not compacted and waste containers could be distributed throughout a large space, thereby diluting the contaminant release. Additionally, a better cementitious material could be used to encapsulate the HEPA filters. One alternative method for disposal of contaminated HEPA filters is encapsulation of the filters in ultra high-performance grout (UHPG). UHPG is a variation of ultra-high-performance concrete (UHPC) is commonly used in the prestressed concrete industry for large structural members. Recent studies of UHPG show it has excellent properties for containing radionuclides such as 99 Tc and 129 I Nichols and Kaplan (2021). This report presents the results of the first attempt to encapsulate a clean, full-size HEPA filter in UHPG and evaluate the effectiveness of the immobilization process and final waste form. A full-scale proof-of-concept simulated waste form was prepared by encapsulating a HEPA filter in a 110-gallon stainless steel (SS) drum using UHPG. A change from Type I/II PC to Type 1L PLC was made after American Rock Products informed the team that they would no longer be using Type I/II by the end of 2024 and the northwest was phasing out Type I/II PC overall. Type I/II PC used in previous studies of UHPG for encapsulation (Nichols and Kaplan 2021). After the UHPG was cured both the scaled mockup and the full-scale simulated waste forms were sectioned for visual examination. UHPG completely encapsulated the filters and bonded to the external surfaces of materials comprising the filters. No cracks were observed in the sectioned waste forms.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRSDate not supplied

Uncrewed Lunar Surface Operations and Support Activities

Sustained human presence on the surface of the Moon and future missions to Mars require increased independence from surface crews and Earth-based mission control to operate efficiently, safely, and reliably. The time for surface crews to perform tasks will be limited. Extravehicular activities by surface personnel are burdensome and time-consuming, even when a continuous human presence on the surface occurs. Identifying and balancing human/automation roles and tasks and infusing automation and autonomy practices early in a system’s lifecycle will be essential to achieve mission objectives. Among these objectives are attaining a sustained human presence, improving performance and mission effectiveness, reducing operations and maintenance (O&M) costs, and ensuring operations that are robust to communication delays. To achieve these objectives, an operational shift toward increased automation and autonomy with less reliance on humans is needed. Uncrewed lunar surface operations and support activities occur when surface crews are not present or are independent of surface crew timeline activities requiring no surface crew oversight or intervention. These uncrewed surface opportunities can also be planned to minimize crew workload that avoids routine maintenance and support tasks, thus maximizing crew exploration time. Uncrewed preparations such as staging and prepositioning equipment and materials before the crew arrives could improve crew task efficiency. Additional opportunities exist to conduct uncrewed science, exploration, and utilization. Uncrewed surface architecture functions can include science and exploration; habitation; launch and landing support; surface communication and navigation; surface power generation and distribution; human surface mobility; lifting, handling, manipulating; excavation, construction, and site preparation; logistics management; maintenance and repair; surface resource utilization; integrated site operations and shared support services (e.g., site scheduling/prioritization, dust mitigation/contamination control, and surface safety). Early robotic lunar surface campaigns will provide information on the availability of resources, such as oxygen and water, and demonstrate surface-based technologies. After the Artemis III human lunar return mission, a series of landers will deliver surface systems, cargo, supplies, science packages, spare parts, and commodities. A balance of crewed and uncrewed surface operations will enable a sustained lunar surface presence at the South Pole of the Moon at a site that will be known as the Artemis Base Camp (ABC). It is envisioned that base camp operations on and around the Moon will then help prepare for the mission durations and activities needed to support the first human mission to Mars. Before long-duration crew missions to the base camp can occur, the necessary surface infrastructure will be pre-deployed and verified operational. Surface assets will be teleoperated and remotely managed from Earth. Additionally, robotic and short-duration crewed missions to the ABC will ensure the site’s merit to achieve long-term science objectives, availability of usable resources, and that terrain, seasonal variations, and illumination conditions are acceptable. ABC will consist of different areas where specific functions and services are rendered, including: • Launch and Landing Area • Habitation Area • Power Production Area • Resource Areas Launch and Landing Area—The launch and landing area will support associated functions for the arrival and departure of vehicles, such as crewed landing and ascent and uncrewed cargo deliveries and offloading. It will evolve from an unimproved site at the beginning of the exploration campaign to a more sustainable landing and launch area that can support repeated arrivals and departures. Initial uncrewed Lunar Terrain Vehicle (LTV) surface operations may include emplacement of navigation beacons and communication equipment, real-time video and photography of landing/liftoff events, and element repositioning, such as portable utility power (PUP) (applicable for other landed assets at other areas). Site preparations, such as surface leveling, soil compaction, and berm/path construction, may be needed for a more sustainable launch and landing area capable of accommodating vehicles that are increasingly more reusable and reduce the effects of plume surface interactions and ejecta impacts on nearby surface assets. During the ABC missions, cargo and logistics will be delivered to the lunar surface via robotic cargo landers before the crew arrives. These shipments, which can arrive in pressurized logistics carriers, will deliver the logistics necessary to support a crewed mission and include items such as food, water, equipment spares, etc. Providing the capability to retrieve, offload, and transport the logistics closer to the ABC site before the arrival of the crew will increase the overall efficiency of crew operations once they arrive. In the sustained phase of exploration, other supporting services may be needed, such as lander propellant servicing, surface power services, commodity refreshes, and additional inspection, maintenance, and repair capabilities, to sustain a cadence of extended personnel stays and cargo arrivals and departures. Habitation Area—Uncrewed support to surface habitation could involve supporting activation and pre-entry operations of the habitat while the crew is in orbit at the Gateway outpost preparing for a surface landing. Surface Habitat (SH) uncrewed operations may include bringing the cabin environment to a habitable temperature and air mix and activating other critical crew support systems. Potential crop production uncrewed tasks in the SH could also include autonomous watering and tending. Additionally, when the crew departs, the SH enters dormancy for the long period of uncrewed operation. A logistical staging area could also be collocated near the SH. If so, staging operations for crew supplies, waste re-location, and recycling operations may be opportunities for uncrewed operations. Power Production Area—The Fission Surface Power (FSP) element and its supporting distribution equipment provide power to surface elements as needed across the ABC to supplement day-to-day operations and survive lunar nights. Uncrewed support of this power system includes any initial LTV-assisted deployments of cables and other distributed equipment, associated electrical connections, and system testing and activation operations. Robotically performing some inspections, maintenance, or repair tasks on the power distribution equipment could reduce the surface crew workload. Resource Area— Uncrewed resource prospecting, mapping, and characterizing possible resource sites is likely to be time-consuming and represents an opportunity for uncrewed operations between crewed missions. Uncrewed mobile equipment operations will be needed in the extreme environments of permanently shadowed locations where resource extractions occur. As In-Situ Resource Utilization (ISRU) pilot plant operations begin, uncrewed surface support activities with available mobile and portable assets (LTV, PUP, etc.) will better support these operations. Any produced commodities can be stored at a centralized storage location for future use. Also associated with these operations is the use of mobile robotic excavators for resource acquisition and robotic/autonomous regolith processing. The waste tailings generated during excavation and regolith processing would also need to be transported and deposited at a dedicated location. Surface assets will continue operating between crew visits to maintain surface capabilities, conduct lunar surface science, technology demonstrations, and public outreach opportunities. Additionally, certain sustaining tasks that would consume valuable crew time could be performed before crew arrival, or after their departure. This capability may offer more affordable options to construct, activate, test, and maintain a broad set of surface assets. Telerobotically operated human surface mobility systems, such as the LTV and Pressurized Rover (PR), can be utilized for various tasks. Surface environmental conditions pose a distinct challenge for all these activities. Surface illumination and localized shadows are one such factor. Night-survival operations could consist of thermal management, battery pre-charging, and load shedding. Some surface systems may hibernate through the night and then awake and continue nominal operations. Uncrewed mobile assets may use a more adaptive approach to optimize their power and operations; one method is to follow the sunlight. Night-survival operations may be initiated remotely by teleoperation, automated, or accomplished by supervised autonomous operation. The ability to pre-deploy and control remote assets in orbit or on Mars before the arrival of the mission crew is a key capability that can be simulated on the moon. The base camp provides a venue where these advanced operational concepts, technologies, and autonomous methods and techniques, including the incorporation of time delays to simulate Earth-Mars latency can be replicated to help buy down future Mars mission risks. This paper will examine the evolution of uncrewed lunar surface operations and support activities. It will also discuss the lunar surface environmental conditions (thermal, lighting, terrain, topography, communications) along with the challenges they pose on uncrewed surface operations, and the performance of these activities with limited to minimal human interaction and/or teleoperation. Since lunar missions include Mars mission analogs, such investigation provides the framework for future uncrewed Mars mission support.

Mark E Lewis↗
DOE OSTI2022

The CMS Magnetic Field Measuring and Monitoring Systems

This review article describes the performance of the magnetic field measuring and monitoring systems for the Compact Muon Solenoid (CMS) detector. To cross-check the magnetic flux distribution obtained with the CMS magnet model, four systems for measuring the magnetic flux density in the detector volume were used. The magnetic induction inside the 6 m diameter superconducting solenoid was measured and is currently monitored by four nuclear magnetic resonance (NMR) probes installed using special tubes outside the barrel hadron calorimeter. Two more NRM probes were installed at the faces of the tracking system. The field inside the superconducting solenoid was precisely measured in 2006 in a cylindrical volume of 3.448 m in diameter and 7 m in length using 10 three-dimensional (3D) B-sensors based on the Hall effect. These B-sensors were installed on each of the two propeller arms of an automated field-mapping machine. In addition to these measurement systems, a system for monitoring the magnetic field during the CMS detector operation has been developed. Inside the solenoid in the horizontal plane, 4 3D B-sensors were installed at the faces of the tracking detector. Twelve 3D B-sensors were installed on the surfaces of the flux-return yoke nose disks. Seventy 3D B-sensors were installed in the air gaps of the CMS magnet yoke. A specially developed flux loop technique was used for the most complex measurements of the magnetic flux density inside the steel blocks of the CMS magnet yoke. The flux loops are installed in 22 sections of the flux-return yoke blocks. The areas enclosed by these coils varied from 0.3 to 1.59 m$^{2}$ in the blocks of the barrel wheels and from 0.5 to 1.12 m$^{2}$ in the blocks of the yoke endcap disks. The development of these systems and the results of the magnetic flux density measurements across the CMS magnet are presented and discussed in this review article.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS2006

Generating Breathable Air Through Dissociation of N2O

A nitrous oxide-based oxygen-supply system (NOBOSS) is an apparatus in which a breathable mixture comprising 2/3 volume parts of N2 and 1/3 volume part of O2 is generated through dissociation of N2O. The NOBOSS concept can be adapted to a variety of applications in which there are requirements for relatively compact, lightweight systems to supply breathable air. These could include air-supply systems for firefighters, divers, astronauts, and workers who must be protected against biological and chemical hazards. A NOBOSS stands in contrast to compressed-gas and cryogenic air-supply systems. Compressed-gas systems necessarily include massive tanks that can hold only relatively small amounts of gases. Alternatively, gases can be stored compactly in greater quantities and at low pressures when they are liquefied, but then cryogenic equipment is needed to maintain them in liquid form. Overcoming the disadvantages of both compressed-gas and cryogenic systems, the NOBOSS exploits the fact that N2O can be stored in liquid form at room temperature and moderate pressure. The mass of N2O that can be stored in a tank of a given mass is about 20 times the mass of compressed air that can be stored in a tank of equal mass. In a NOBOSS, N2O is exothermically dissociated to N2 and O2 in a main catalytic reactor. In order to ensure the dissociation of N2O to the maximum possible extent, the temperature of the reactor must be kept above 400 C. At the same time, to minimize concentrations of nitrogen oxides (which are toxic), it is necessary to keep the reactor temperature at or below 540 C. To keep the temperature within the required range throughout the reactor and, in particular, to prevent the formation of hot spots that would be generated by local concentrations of the exothermic dissociation reaction, the N2O is introduced into the reactor through an injector tube that features carefully spaced holes to distribute the input flow of N2O widely throughout the reactor. A NOBOSS includes one or more "destroyer" subsystems for removing any nitrogen oxides that remain downstream of the main N2O-dissociation reactor. A destroyer includes a carbon bed in series with a catalytic reactor, and is in thermal contact with the main N2O-dissociation reactor. The gas mixture that leaves the main reactor first goes through a carbon bed, which adsorbs all of the trace NO and most of the trace NO2. The gas mixture then goes through the destroyer catalytic reactor, wherein most or all of the remaining NO2 is dissociated. A NOBOSS can be designed to regulate its reactor temperature across a range of flow rates. One such system includes three destroyer loops; these loops act, in combination with a heat sink, to remove heat from the main N2O-dissociation reactor. In this system, the N2O and product gases play an additional role as coolants; thus, as needed, the coolant flow increases in proportion to the rate of generation of heat, helping to keep the main-reactor temperature below 540 C.

Zubrin, Robert↗