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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Non-galvanic mass transport in molten fluoride salt isothermal corrosion cells

Mass transport of corrosion products between Ni-201 test samples and 316 L capsules in a 500-hour FLiNaK corrosion experiment has been investigated. In one experiment, the capsule and samples were electrically connected for galvanic coupling, while in the other they were electrically isolated using boron-nitride. Post-corrosion characterization of Ni-201 from the two experiments did not reveal any remarkable differences. Substantial transport of Fe and Cr from the 316 L to the Ni-201 via the salt was observed, with notable diffusion of these elements in the near-surface regions of the Ni-201 samples, while a Cr-rich film was also observed on their surfaces.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Chemical and Structural Insights into Solid Electrolyte Interphase Evolution for Sodium Metal Electrodes

The solid electrolyte interphase (SEI) critically governs the reversibility of sodium metal batteries, through dynamically mediating ion transport and interfacial reactions. However, its kinetic evolution under operating conditions, and how it influences interfacial stability, remains poorly understood. Here, in this study, we reveal that the SEI undergoes coupled chemical and mechanical changes during sodium plating and stripping, leading to spatial and temporal heterogeneity that drives interfacial degradation. Synchrotron operando grazing-incidence wide-angle X-ray scattering and soft X-ray absorption spectroscopy capture the sequential formation and dissolution of inorganic SEI phases (NaF, NaH, NaOH, Na 2 PO 3 F), accompanied by depth-dependent alterations in organic SEI components. Mesoscale modeling connects this evolving SEI heterogeneity to localized current density fluctuations and stress accumulation at the Na interface, identifying pathways to electrically isolated sodium formation. These findings show that SEI instability fundamentally limits reversibility in sodium metal batteries, and that controlling SEI chemistry–mechanics coupling is essential to achieving its durability.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Activity gradient driven mass transport in molten fluoride salt medium

Abstract The molten salt-cooled reactor concept has garnered significant interest and one of the current challenges limiting the deployment of these reactor concepts is the complex corrosion phenomenon observed in molten salt environments. One of these phenomena is activity gradient mass transport, which has been shown to affect dissimilar materials submerged in the same salt medium even when best efforts have been made to electrically isolate dissimilar materials from one another. This mechanism while shown experimentally, has not been predictively studied through a modeling approach. In this study, activity gradients in several 316L-X materials systems have been modeled and the mass transport predicted by the model has been confirmed through static isothermal corrosion testing in a molten fluoride salt medium.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Frictional drag between superconducting LaAlO 3 /SrTiO 3 nanowires

Here we report frictional drag measurements between two superconducting LaAlO 3 /SrTiO 3 nanowires. In these experiments, current passing through one nanowire induces a voltage across a nearby electrically isolated nanowire. The frictional drag signal contains both symmetric and anti-symmetric components. The anti-symmetric component arises from the rectification of quantum shot noise in the drive nanowire by the broken symmetry in the drag nanowire. The symmetric component in the drag resistance is ascribed to rectification of thermal noise in the drive nanowire during superconducting-normal transition. The suppression of the symmetric component is observed when a normal nanowire is used as either a drag or drive nanowire with the other nanowire superconducting. The absence of symmetric drag resistance between a normal drag nanowire and a superconducting drive nanowire suggests a higher electron-hole asymmetry in the superconducting LaAlO 3 /SrTiO 3 nanowire arising from the 1D nature of superconductivity at LaAlO 3 /SrTiO 3 interface.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Interlayer coherence in superconductor bilayers

We investigate the possibility and implications of interlayer coherence in electrically isolated superconducting bilayers. We find that in a mean-field approximation bilayers can have superconducting and excitonic order simultaneously if repulsive interactions between layers are sufficiently strong. The excitonic order implies interlayer phase coherence and can be studied in a representation of symmetric and antisymmetric bilayer states. When both orders are present we find several solutions of the mean-field equations with different values of the the symmetric and antisymmetric state pair amplitudes. The mixed state necessarily has nonzero pair amplitudes for electrons in different layers in spite of the repulsive interlayer interactions, and these are responsible for spatially indirect Andreev reflection processes in which an incoming electron in one layer can be reflected as a hole in the opposite layer. Furthermore, we evaluate layer diagonal and off-diagonal current-voltage relationships that can be used to identify this state experimentally.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Mechanical Design of the PIP-II ORBUMP Pulsed Dipole Magnet

The Proton Improvement Plan II (PIP-II) project is a vital upgrade to the Fermilab accelerator complex. The magnet pulse rate of the PIP-II Injection system requires an increase from the current rate of 15 Hz to 20 Hz as well as a roughly 30% increase in the magnetic field of the new Orbital Bump (ORBUMP) pulsed dipole magnets in the Booster. Here, the ORBUMP magnet mechanical design is presented in this paper. The ORBUMP magnet is secured in a vacuum box and the core is made up of 0.127 mm thick, low carbon steel laminations with a C-5 inorganic magnesium phosphate coating. The core is clamped using external tie bars welded to the core end plates. ANSYS Finite Element Analysis (FEA) was used to evaluate the clamping design to minimize the deflection of the core post welding of the tie bars. The water-cooled, single turn coil, which shapes the magnetic field by acting as the pole tips, is critical for the integrated field homogeneity. The coil manufacturing tolerances and fabrication techniques were evaluated to ensure the magnetic properties of the magnet could be obtained. The coil is electrically isolated from the core using virgin Polyether ether ketone (PEEK) insulating material in the gap. An investigation into the high voltage performance of the virgin PEEK insulator was conducted via partial discharge testing using a 1:1 scale sample.

Karas, D. [Fermi National Accelerator Laboratory (↗
DOE OSTI2023

LiH formation and its impact on Li batteries revealed by cryogenic electron microscopy

Little is known about how evolved hydrogen affects the cycling of Li batteries. Hypotheses include the formation of LiH in the solid-electrolyte interphase (SEI) and dendritic growth of LiH. Here, we discover that LiH formation in Li batteries likely follows a different pathway: Hydrogen evolved during cycling reacts to nucleate and grow LiH within already deposited Li metal, consuming active Li. We provide the evidence that LiH formed in Li batteries electrically isolates active Li from the current collector that degrades battery capacity. We detect the coexistence of Li metal and LiH also on graphite and silicon anodes, showing that LiH forms in most Li battery anode chemistries. Last, we find that LiH has its own SEI layer that is chemically and structurally distinct from the SEI on Li metal. Our results highlight the formation mechanism and chemical origins of LiH, providing critical insight into how to prevent its formation.

25 ENERGY STORAGE↗
DOE OSTI2024

Communication—Controlling Etching of Germanium through Surface Charge Manipulation

Potassium hydroxide (KOH) aqueous solutions can effectively etch germanium. Etch rates were determined in an electrolytic etch cell. Electrically isolated Ge wafers were subject to an etch rate of 1.45 ± 0.07 nm min −1 , increasing to 12.6 ± 0.2 nm min −1 when grounded, 97 ± 2 nm min −1 when biased at −0.9 V, and 138 ± 2 nm min −1 with periodic biasing. Results suggest that the previously reported limited etching in KOH is associated with the recombination of holes with electrons injected from the surface reaction. The results of this study demonstrate that changing the hole concentration through biasing is an effective tool to control electrolytic etch rates, enabling future selective etching processes for germanium.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Literature Review of Optocouplers, Their polymer Components and Current Applicaitons

Optocouplers, also called optoisoloators and photocouplers, are devices that use a light emitting diode (LED) to conduct an electrical signal. The LED receives an electrical signal and emits light proportional to that signal. The light is then received by a photodetector and the signal is propagated. Optocouplers provide a high degree of electrical isolation and are therefore used extensively in commercial electronic equipment. Variations in optocouplers come from the type of photodetector used, the anatomy of the contents and the encapsulating polymers used. Current research involves investigating the tolerance of optocouplers to radiation for the purpose of improving spacecraft and satellites, as well as identifying failure mechanisms and improving design.

42 ENGINEERING↗
DOE OSTI2021

Reducing Energy Use and Making Energy More Efficient in the Native Village of Kiana (Final Technical Report)

The goal of the Remote Alaska Community Energy Efficiency (RACEE) Competition was to advance the implementation of affordable, resilient, and clean energy-efficient solutions for remote Alaska communities. RACEE assisted Kiana with its unique challenges, mostly the remote nature of their location paired with the harsh temperatures and isolated electrical grid resulting in high energy costs. In addition to the assistance from DOE, the Alaska Energy Authority (AEA) provided direct technical assistance to RACEE recipients throughout their projects. Before Kiana started work, AEA conducted energy audits in public buildings and facilities to identify which energy measures would be most effective for the community’s energy goals.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Optocouplers: Polymer Components, Current Applications and My Project Involvement [Slides]

Optocouplers, also called optoisolators and photocouplers, are devices that use a light emitting diode (LED) to conduct an electrical signal. The LED receives an electrical signal and emits light proportional to that signal. The light is then received by a phototransistor and the signal is propagated. Optocouplers provide a high degree of electrical isolation and are therefore used extensively in commercial electronic equipment. Variations in optocouplers come from the type of photodetector used, the anatomy of the contents and the encapsulating polymers used. Current research involves investigating the tolerance of optocouplers to radiation for the purpose of improving spacecraft and satellites, as well as identifying failure mechanisms and improving design. My project involvement at LANL includes conducting thermal and mechanical tests on three different cure profiles of epoxy to collect data about shrinkage, coefficient of thermal expansion, and degree of cure for a group wanting to produce their own optocoupler.

42 ENGINEERING↗
DOE OSTI2023

Distributed Renewables for Arctic Energy: A Case Study

Alaska is a vast state that stretches into the Arctic Circle. Roughly 140,000 people in the state are dependent on isolated electric grids, traditionally burning expensive fossil fuels. This has negative impacts on air quality and climate. As the climate warms, fuel supply chains and traditional ways of life are threatened. Renewable electric sources offer a clean, resilient alternative with less volatile costs, but there are a variety of technical, social, economic, and political challenges to developing renewable energy systems in remote Arctic communities. Examples include harsh operating conditions, lack of local technical and managerial capacity, complex funding mechanisms, and glacial permitting processes. In this study, we interview one group of communities that are interested in adding renewable energy to their systems to understand the needs and challenges they face, and then another group that has successfully installed renewable energy, to understand how they overcame such challenges and the lessons they learned. Notable results include the importance of local buy-in, education, and technical involvement, procuring external funding sources, inter-community collaboration, installing bespoke systems, and working with reliable equipment suppliers. The goal of this report is to orient and inspire Arctic communities that want to begin their renewable transition, by providing helpful examples and points of contact.

17 WIND ENERGY↗
DOE OSTI2025

Mechanical Design of the PIP-II ORBUMP Pulsed Dipole Magnet

The Proton Improvement Plan-II (PIP-II) is a vital upgrade to Fermilab's accelerator complex. The upgrade is designed to power the world s most intense high-energy neutrino beam in future experiments. The magnet pulse repetition rate of the PIP-II injection system is being upgraded from 15 Hz to 20 Hz and requires a roughly 30% increase in the magnetic field of the new Orbital Bump (ORBUMP) magnets in the Booster. The magnet is secured in a vacuum box and the core is made up of 0.127 mm thick, low carbon steel laminations with a C-5 inorganic coating. The core is clamped using external tie bars welded to the core end plates. ANSYS Finite Element Analysis (FEA) was used to evaluate the clamping design to minimize the deflection of the core post welding of the tie bars. The water-cooled single turn coil is electrically isolated from the core using virgin PEEK insulating material in the gap. An investigation into the high voltage performance of the virgin PEEK insulator was conducted. The design of the coil which shapes the magnetic field by acting as the pole tips is critical for the integrated field homogeneity. The coil manufacturing tolerances and fabrication techniques were evaluated to ensure the magnetic properties of the magnet could be obtained. The ORBUMP magnet mechanical design is presented in this paper.

Karas, Dino [Fermilab] (ORCID:0000000304340670)↗
DOE OSTI2026

Unalakleet Microgrid Optimization for Tribal Community Resilience

The Unalakleet Microgrid Optimization Project aimed to strengthen the reliability and efficiency of the isolated electric power system that serves the Tribal community of Unalakleet, Alaska. The community relies entirely on a local wind-diesel microgrid, consisting of four 475 kW diesel generators and six 100 kW wind turbines, to provide electricity to approximately 745 residents and Tribal facilities. Because Unalakleet is not on a road system and is located nearly 400 miles from the nearest major power grid, maintaining a resilient and efficient local energy system is critical. The scope of this project included upgrading a portion of the transmission line between the wind farm and the power plant to increase voltage and reduce line losses, along with modernizing the Supervisory Control and Data Acquisition (SCADA) system to improve monitoring, control, and data management of the power system. These upgrades were designed to increase wind energy utilization, reduce diesel fuel consumption by tens of thousands of gallons annually, and improve overall grid stability. By allowing more of the community’s electricity to be supplied by local renewable wind resources, the project was designed to lower operating costs, reduce dependence on imported fuel, and strengthen the long-term resilience of the power system. These improvements represent an important step toward the community’s long-term energy vision of expanding renewable generation, incorporating energy storage, and eventually achieving “diesels-off” operation, where essential Tribal loads are powered primarily by local renewable resources.

17 WIND ENERGY↗
DOE OSTI2026

Cathodic Protection Modeling for Hanford Underground Double-Shell Tank Farms

Hanford stores millions of gallons of radioactive and chemically hazardous waste from the production of weapon materials in tank farms consisting of underground carbon-steel storage tanks surrounded by reinforced concrete. Six of these Hanford tank farms use double-shell storage tanks (DSTs). The DST farms were constructed from 1968 to 1986 with a planned 40–50 year design life, so some are already operating beyond their initial life expectancy. Ultrasonic testing (UT) has indicated significant thinning on the bottom of the secondary (outer) liner of these tanks, believed to arise from groundwater intrusion driving concrete side corrosion. There is no direct access to the steel/concrete interface between the tank and the concrete pad, making it difficult to apply a chemical-based mitigation strategy or to conduct repairs, but cathodic protection (CP) is a possible method to inhibit further concrete-side corrosion. Hanford already uses CP to protect below grade steel piping within the tank farms and connected to the tanks, but this system was not designed to protect the tank bottoms. CP design must account for the structures surrounding the DSTs, including the steel reinforcing bars (rebar) within the concrete pad and vault, various process lines, and the existing CP system. In this study, finite element analysis (FEA) modeling was carried out to simulate CP protection of 1) a single tank and CP anode to develop options for modeling the rebar and to compare to a simpler circuit model and 2) the entire Hanford AN tank farm as a representative example consisting of seven tanks, associated piping, and both existing and new CP anodes. Both circuit and FEA models predict that significant protective current could be delivered to the bottoms of the tanks with the addition of tank-protection anodes below the depth of the tanks. Simulations with only the existing pipe-protection anodes active confirmed that only a very small current to the tank bottoms is predicted under present conditions. Multiple simplified representations of the dome and wall rebar were tested to reduce the computational complexity of the tank-farm simulations, resulting in modeling the rebar as edge elements with a prescribed effective circumference that matches the real rebar surface area. The geometry of the rebar is also simplified into horizontal hoops around the tank walls and radial rebar over the dome with increased effective circumference to retain the target surface area. This simplification was found to greatly reduce the complexity and solution time of the models without large changes in current distributions, especially to the tank bottom. A range of values were tested for model parameters such as soil and concrete resistivities and polarization resistance to investigate their impact on the current and electric potential distributions. Depending on the parameters used, FEA simulations predict some risk of overprotection, particularly on the piping system; since overprotection can also lead to surface damage associated with hydrogen gas generation at the interface (e.g. hydrogen embrittlement or damage to coatings), this needs to be considered when refining the design of the new CP system. Comparison between the FEA models and the circuit model representation demonstrated that the circuit model could not match the predicted FEA current distribution, even when using the exact same surface areas. This discrepancy appeared to be at least partly attributable to the impact of the relative positions of the tank components and anodes to each other and to the ground surface. The FEA model accounts for the relative positions since it solves the governing equations in three dimensions, but the circuit model cannot account for the positioning. In particular, the circuit model underpredicts the current to the tank bottom and overpredicts the current to the dome compared to FEA for the baseline geometry. The FEA models omitted the electrically isolated rebar in the bottom concrete slab. However, a circuit based stray current model estimated that only 2.1% of the total current through the slab would stray into the rebar, corresponding to ~0.21 A for a target current density of 2 mA/ft2 to the tank bottom. The estimated corrosion driven by this amount of stray current is predicted to yield a lifetime of >400 years for the minimum rebar diameter, assuming an acceptable cross-section area loss of 10%.

d'Entremont, Anna [Savannah River National Laborat↗
DOE OSTI2025

Photoconductive Semiconductor Switches: Materials, Physics, and Applications

Photoconductive semiconductor switching (PCSS) devices have unique characteristics to address the growing need for electrically isolated, optically gated, picosecond-scale jitter devices capable of operating at high voltage, current, and frequency. The state of the art in material selection, doping, triggering, and system integration in PCSSs is presented. The material properties and doping considerations of GaN, GaAs, SiC, diamond, and β-Ga2O3 in the fabrication of PCSS devices are discussed. A review of the current understanding of the physics of the high-gain mode known as lock-on is presented.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Motor and drive arrangement for refrigeration system

A heat exchanger system includes a heat exchanger coil circulating a first heat transfer fluid therethrough, and a fan at least partially surrounded by the heat exchanger coil to urge a flow of air through the heat exchanger coil to dissipate thermal energy from the first heat transfer fluid. A brushless direct current fan motor is located the fan to urge rotation of the fan and an ancillary electrical component operably connected to the heat exchanger system and electrically isolated from the first heat transfer fluid.

Feng, Yinshan↗