Effect of the Starfish high altitude nuclear explosion on the F2-region.
Star Fish high altitude nuclear explosion effect on electron loss rate in F-2 region
ELECTRON DENSITY PROFILE↗
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Geolocation of the Ionospheric Irregularities in the Equatorial F Layer by Back Propagation of COSMIC‐2 Radio Occultation Signals
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S. Sokolovskiy↗
Boundary-Layer Transition Results from the F-16XL-2 Supersonic Laminar Flow Control Experiment
A variable-porosity suction glove has been flown on the F-16XL-2 aircraft to demonstrate the feasibility of this technology for the proposed High-Speed Civil Transport (HSCT). Boundary-layer transition data have been obtained on the titanium glove primarily at Mach 2.0 and altitudes of 53,000-55,000 ft. The objectives of this supersonic laminar flow control flight experiment have been to achieve 50- to 60-percent-chord laminar flow on a highly swept wing at supersonic speeds and to provide data to validate codes and suction design. The most successful laminar flow results have not been obtained at the glove design point (Mach 1.9 at an altitude of 50,000 ft). At Mach 2.0 and an altitude of 53,000 ft, which corresponds to a Reynolds number of 22.7 X 10(exp 6), optimum suction levels have allowed long runs of a minimum of 46-percent-chord laminar flow to be achieved. This paper discusses research variables that directly impact the ability to obtain laminar flow and techniques to correct for these variables.
Marshall, Laurie A.↗
Ion-neutral coupling in the high-latitude F region Evaluation of ion heating terms from Dynamics Explorer 2
Ion and neutral motions in the high latitude F layer were studied simultaneously during six passes of the Dynamics Explorer 2 spacecraft. The passes were made over the south polar cap in October 1981. An ion energy balance equation was defined to express the exchange of energy between the F layer and other atmospheric constituents. A momentum equation expressed the momentum exchange between the species. An approximate form of the energy balance equation was also formulated. The time constant for ion-neutral collisional momentum transfer significantly affected Joule heating in the F layer. Regions of large velocity disparities and ion temperature enhancements were detected as hot spots. The results indicate that a feedback mechanism may arise in terms of neutral compositional changes and enhanced ionospheric recombination. The approximate equation furnished values for ion heating rates which matched the data.
Killeen, T. L.↗
Supersonic boundary-layer transition on the LaRC F-106 and the DFRF F-15 aircraft. Part 2: Aerodynamic predictions
In the leading edge region, the measured pressure distributions exhibit extreme variations from strong suction peaks to a pressure maximum at the attachment line. These variations occur over short distances on the wing surface, and their character changes with changes in Mach number and angle of attack. The data/theory comparisons show that the character of the measured pressure distributions is well predicted for every Mach number and/or angle of attack condition considered. There is good agreement between theory and experiment for the location of the attachment line and suction peaks. The pressure magnitudes are well represented in the critical leading edge region, including the pressure maximum on the attachment line. The wing/body/inlet results agree well with the wing alone back to about 20 percent of chord where the upper surface suction peak typically occurs. The largest differences between theory and measurement always occur in the vicinity of suction peaks, with the difference being approximately 15 percent or less. In regions of largest error, the predicted pressures underestimate the suction peak strength for each case considered. The ability of the NCOREL code to reproduce wing pressure characteristics is shown.
Rose, Ollie J.↗
Credible Criticality Safety Margin in the 30B Package with LEU+ UF 6 and Hypothetical Water Ingress
The commercial nuclear industry is pursuing advancements in fuel and reactor design that increase the uranium enrichment above 5 wt. % 235 U. These advancements will necessitate the ability to transport bulk quantities of UF 6 at increased enrichments. Currently, the 30B cylinder is the primary container used by the industry for UF 6 storage and transportation and has a long history of successful shipments. This container can support up to 2,277 kg of UF 6 at a maximum enrichment of 5 wt. % 235 U. Previous evaluations have assessed the potential impact of criticality safety for 30B transport at higher enrichments but assumed moderator intrusion would not require evaluation. Although current regulations allow for the exception of moderator intrusion for UF 6 packages through the design and quality control of the package content, this exception is limited to enrichments up to 5 wt. % 235 U. Thus, an investigation of moderator intrusion into a 30B cylinder should be performed. Moderator intrusion into a 30B cylinder is a unique condition for criticality safety evaluation in transportation because of the violent chemical reactions that occur between UF 6 and H 2 O. The resulting intrusion is strongly dependent on the breach size, breach location, breach interface solid/ullage of the UF 6 content, the UF 6 distribution (which is temperature dependent), and temperature/pressure conditions which are dynamic in accident conditions. Additionally, the complexity of the HF-UO 2 F 2 -H 2 O interface that occurs during the event can influence the potential solubility of uranium in the system, as well as influence the amount of UF 6 reaction with H 2 O. With the operating experience from Orano Federal Services LLC, the UF 6 chemical expertise from Oak Ridge National Laboratory (ORNL), and the criticality safety expertise from ORNL, this paper evaluates the neutronic conditions (i.e., k eff ) that apply the understood chemistry and experimental conditions that occur during moderator intrusion of a breached 30B cylinder under postulated accidents. This report examines the historical evaluations of UF 6 transport and expands these evaluations for the enrichments expected for nuclear industry advancement. These simulations primarily feature a homogeneous mixture of UF 6 and H 2 O as an infinite media system and as a sphere with water reflection given an impurity limit of 0.5 wt. % UF 6 . This report demonstrates that this H/U limit is valid up to 8 wt. % enrichment for both H 2 O and HF as the moderating mixture. The water-reflected homogeneous mixed spheres evaluated demonstrate the amount of safety margin applied by restricting the 30B cylinder impurity limit to 0.5 wt. %. Additionally, this report evaluates moderator ingress scenarios of a 30B cylinder. The 30B cylinder simulations vary the cylinder orientation, the mass of UF 6 in the system, the mass of H 2 O in the system, and how much H 2 O has reacted with UF 6 . The moderator ingress of a 30B cylinder was evaluated for the water-reflected homogeneous mixed spheres to demonstrate the amount of safety margin applied by restricting the 30B cylinder impurity limit to 0.5 wt. %. These simulations are standard practice and are independent of the UF 6 -H 2 O reaction. This work also explored more complex simulations that layer the H 2 O over the UF 6 , which incorporates the amount of reacted UF 6 as a separate layer and considers solubility limits of UO 2 F 2 in H 2 O as it is produced. This approach is intended to simulate the postulated event of a large hairline crack occurring on a submerged cylinder. Finally, this work considers the potential of H 2 O mixing into the UF 6 solid heterogeneously using a sponge-like model. The water ingress into the UF 6 is treated as random size spheres, and the reaction products form into a layer over the spheres.
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
A snapshot of the polar ionosphere
This paper presents a picture of the north polar F layer and topside ionosphere obtained primarily from three satellites (Alouette 2, ISIS 1, ISIS 2) that passed over the region within a time interval of about 50 min on a magnetically quiet day. The horizontal distribution of electron densities at the peak of the F layer is found to be similar to synoptic results from the IGY. Energetic-particle and ionospheric-plasma data are also presented, and the F-layer data are discussed in terms of these measurements as well as in terms of electric-field and neutral N2 density measurements made by other satellites on other occasions. The major feature observed is a tongue of F-region ionization extending from the dayside across the polar cap, which is accounted for by antisunward drift due to magnetospheric convection. In the F layer and topside ionosphere, the main effect of auroral precipitation appears to be heating and expansion of the topside. A region of low F-layer density appears on the morning side of the polar cap, which may be due to convection and possibly also to enhanced N2 densities.
Whitteker, J. H.↗
BCS-BEC crossover driven by small Fermi pockets of a high- T c cuprate superconductor
Fermi arcs observed in underdoped cuprates have sparked debate over whether they represent segments of a large Fermi surface or small Fermi pockets. This ambiguity has long hindered their classification as either the conventional Bardeen-Cooper-Schrieffer (BCS) regime or the strongly coupled Bose-Einstein condensation (BEC) crossover limit. Here, using angle-resolved photoemission spectroscopy and quantum oscillations, we demonstrate the coexistence of a small Fermi pocket and a large superconducting gap in the clean inner CuO 2 layers of the four-layer cuprate Ba 2 Ca 3 Cu 4 O 8 (F,O) 2 . This coexistence constitutes a hallmark of the BCS-BEC crossover and has remained elusive for decades. Despite the presence of antiferromagnetic (AF) order, the superconducting gap in the small pocket is remarkably large, yielding a gap-to-Fermi energy ratio (Δ pocket /ε F ~ 0.6) and a critical-to-Fermi temperature ratio (T c /T F ~ 0.13) that reach the theoretical upper bound for two-dimensional superconductivity. Unexpectedly, this BCS-BEC crossover emerges not as the carrier density decreases but as it increases, abruptly within a narrow doping range of less than 1%. These results provide a long-sought microscopic foundation for the d-wave pairing mechanism in doped AF-Mott insulators.
Jeong, Junhyeok [University of Tokyo, Kashiwa (Jap↗
High-entropy Li-rich layered oxide cathode for Li-ion batteries
High-entropy oxides (HEOs) are emerging as promising cathode materials for Li-ion batteries (LIBs) due to their stable solid-state phase and compositional flexibility. Herein, we investigate the structural and electrochemical properties of a novel non-equimolar high-entropy cathode material, termed high-entropy Li-rich layered oxide (HE-LLO, Li 1.15 Na 0.05 Ni 0.19 Mn 0.56 Fe 0.02 Mg 0.02 Al 0.02 O 1.97 F 0.03 ), in comparison to a pristine Li-rich layered oxide (PR-LLO, Li1.2Ni0.2Mn0.6O2). The incorporation of multiple cations (Na + , Al 3+ , Mg 2+ , Fe 3+ ) and anion (F - ) into HE-LLO introduces compositional diversity, enhancing structural stability through the entropy stabilization effect. Theoretical calculations confirm a significantly higher configurational entropy in HE-LLO compared to PRLLO, supporting its high-entropy nature. Electrochemical evaluations demonstrate that HE-LLO exhibits considerable capacity retention, preserving 76.8 % of its discharge capacity at 0.5C after 200 cycles, compared to only 36.2 % for PR-LLO. Even under high-temperature conditions, HE-LLO outperformed PR-LLO, maintaining 76.1 % of its discharge capacity after 100 cycles at 5C, while PR-LLO retained only 12.4 %. These enhancements are attributed to the improved phase reversibility and higher Li + ion diffusion coefficients of HE-LLO, validated by ex-situ characterizations using a synchrotron X-ray technique, along with density functional theory (DFT) calculations. In conclusion, these findings highlight the promise of non-equimolar HEOs as a novel design strategy for highperformance cathode materials.
25 ENERGY STORAGE↗
Semigroup solution of the time dependent continuity equation for the ion density in the ionospheric F2 layer
Semigroup solution of time dependent continuity equation for ion density in ionospheric F 2 region
Kritt, B.↗
Taking into account the vertical drift of molecular ions when determining the kinetic parameters of ionization-recombination processes in the F2-layer maximum
Height distribution analysis for kinetic molecular ionization-recombination processes in F 2 region during solar activities
Klimov, N. N.↗
Magnetospheric convection and the high latitude F2 ionosphere
Behavior of the polar ionospheric F-layer as it is convected through the cleft, over the polar cap, and through the night side F-layer trough zone was investigated. Passage through the cleft adds of the order of 200,000 ions/cu cm in the vicinity of the F 2 peak and redistributes the ionization above approximately 400 km altitude to conform with an increased electron temperature. The F-layer is also raised of the order of 20 km in altitude by the convection electric field. In the night soft electron precipitation zone, the layer is lowered in altitude by the convection electric field, and then decays, primarily by chemical recombination, as it convects equatorward and around the dawn side of the earth. In the absence of ionization sources, decay by factors of the order of 100 to 1000 occur prior to entry into the sunlit hemisphere, thus forming the F-layer night trough.
Knudsen, W. C.↗
MMS Measurements of the Vlasov Equation: Probing the Electron Pressure Divergence Within Thin Current Sheets
We investigate the kinetic structure of electron-scale current sheets found in the vicinity of the magnetopause and embedded in the magnetosheath within the reconnection exhaust. A new technique for computing terms of the Vlasov equation using Magnetospheric Multiscale (MMS) measurements is presented and applied to study phase space density gradients and the kinetic origins of the electron pressure divergence found within these current sheets. Crescent-shaped structures in ∇(⟂2)f(e) give rise to bipolar and quadrupolar signatures in v · ∇f(e) measured near the maximum ∇ · P(e) inside the current layers. The current density perpendicular to the magnetic field is strong (J⟂ ∼2 μA/sq.m), and the thickness of the current layers ranges from 3 to 5 electron inertial lengths. The electron flows supporting the current layers mainly result from the combination of E × B and diamagnetic drifts. We find nonzero J · E′ within the current sheets even though they are observed apart from typical diffusion region signatures.
Shuster, J. R.↗
Thermal-Barrier Coatings Containing Ytterbia
Resistance to thermal cycling increased. New outer ceramic coating layer for two-layer or graded thermal-barrier coating developed. Ceramic overlay zirconia stabilized with ytterbia and used in conjunction with NiCrAlY or NiCrAlYb bond coats. Two-layer system evaluated in furnace testing at temperatures cycled between 2,025 degrees F and 575 degrees F.
Stecura, Stephan↗
Materials Development for Hypersonic Flight Vehicles
The DARPA/Air Force Falcon program is planning to flight test several hypersonic technology vehicles (HTV) in the next several years. A Materials Integrated Product Team (MIPT) was formed to lead the development of key thermal protection system (TPS) and hot structures technologies. The technologies being addressed by the MIPT are in the following areas: 1) less than 3000 F leading edges, 2) greater than 3000 F refractory composite materials, 3) high temperature multi-layer insulation, 4) acreage TPS, and 5) high temperature seals. Technologies being developed in each of these areas are discussed in this paper.
Glass, David E.↗
Super Capacitor Development At NASA MSFC
A viewgraph presentation outlines super capacitor development at NASA Marshall Space Flight Center. The concept, proof of concept testing and the test set-ups are described. An overview of super capacitor classification is shown and several types of capacitors are detailed: Ni-C chemical double layer (CDL), Ru-Oxide pseudo-cap, and a Ru-Oxide 2 F 30 V capacitor.
Hall, David K.↗
Geometry and Unoccupied Electronic States of Ba and BaO on W(001)
A study aimed at understanding the geometrical and electronic properties of barium and oxygen coadsorbed on the tungsten(001) surface has been carried out by means of work-function measurements (Delta-phi), Auger-electron spectroscopy, low-energy electron diffraction, inverse photoelectron spectroscopy, and relativistic-electronic-structure calculations. A report of the experimental measurements and a comparison with theoretical results from embedded-cluster-model calculations are presented. Our experimental studies show that the work function of the W(001) surface (phi = 4.63 eV) is lowered to approximately 2.3-2.4 eV by coadsorption of 1 ML of Ba and O regardless of the order of deposition of these two species. The technique of IPS in the isochromat mode was used to determine the unoccupied electronic-energy band structure for ordered c (2 X 2) Ba and O layers on W(001). Several spectral features are observed above the Fermi level (E(F)), which we assign to transitions into Ba and W d-states. The measured two-dimensional electronic band structure is independent of the order of Ba and O deposition. Using embedded-cluster-model calculations, we investigated two possible adsorption configurations of an ordered c(2 X 2) adlayer of Ba and O on W(001): 'tilted,' where Ba and O are placed on alternate fourfold-hollow sites, and 'upright,' where the adsorbed atoms lay above the same site with Ba outer-most. The calculated densities of states for the tilted geometry show distinct peaks above E(F) originating from Ba and W d-orbitals and are in good agreement with the experimental results.
Lamouri, A.↗
Understanding the Space Weathering of Mercury Through Laboratory Experiments
Introduction: Airless surfaces across the solar system are continually modified by energetic particles from solar wind and micrometeoroid bombardment [1,2]. This process is known as space weathering, and it alters the chemical, microstructural, and optical properties of surface regoliths on airless bodies, including Mercury. On the Moon and S-type asteroids, the reflectance spectral signatures of space weathering include reddening (increasing reflectance with increasing wavelength), darkening (lowering of reflectance), and the attenuation of characteristic absorption bands [2]. Such spectral changes are driven by the production of Fe-bearing nanoparticles(npFe) through both solar wind irradiation and micrometeoroid bombardment. While our understanding of space weathering for the Moon and near-Earth S-types asteroids is advanced, insight into how these processes operate on other planetary bodies is limited. In particular, Mercury experiences a uniquely intense space weathering environment than planetary counterparts at 1 AU, including a moreintense solar wind flux and higher velocity micrometeoroid impacts [4]. Additionally, Mercury has a surface composition unique in the inner solar system, including regions of the surface with very low albedo known as the low reflectance material (LRM), which is enriched in carbon, likely graphite, up to 4wt.% [5].In addition, the concentration of Fe across Mercury’s surface islow (<2 wt.%) compared to the Moonor S-type asteroids asteroids[6]. Our understanding of the effects of space weathering on C-rich and Fe-poor phases is limited. Since Fe plays a critical role inthe development of space weathering characteristicson other airless surfaces(e.g., npFe), its limited availability may significantly affect the development of space weathering features in Mercury surface materials. We can simulate space weathering processes in the laboratory to explore their effects on the microstructural, chemical, and spectral characteristics of Mercury surface materials[7]. Here we used pulsed laser irradiation to simulate the short duration, high-temperature events associated with micrometeoroid impacts. We performed coordinated analyses including reflectance spectroscopy and electron microscopy to investigate the spectral, chemical, and microstructural changes in these mercurian analog samples. Methods: For these experiments, we usedforsteritic olivine with varying FeOcontents, a mineral phase proposed to be abundant on the surface of Mercury. We mixed each sample with graphite to simulate LRM regions of the surface. Wesynthesized the olivinesamplesat 1-bar at NASA’s Johnson Space Centerand prepared pressed powder pellets for laser irradiation [8].We prepared three samples, each with a base layer of olivineto maintain structural integrity and topped witha surface layer containing the graphite-olivine mixture: 1) Sample SC-001 San Carlos olivine(Fo90.91),2)Sample F-S-002 with0.05 wt.% FeO olivine, and 3) F-T-004 with 0.53 wt.% FeO olivine. Each sample was mixed with 5 wt.% powdered graphite and had grain sizes ranging from 45to 125μm. We irradiated each sample usinga pulsed Nd-YAG laser, (l=1064 nm, ~6 ns pulse duration, energy of 48 mJ/pulse) while undervacuumat Northern Arizona University. The laser was rastered1x and then 5x over the surfaceof each sample to simulate progressive space weathering. We collected in situreflectance spectra from the samples after each laser pulse witha Nicolet IS50 Fourier-Transform Infrared spectrometer (lfrom 0.65-2.5 μm). We used an FEI Nova NanoSEM200scanning electron microscope (SEM) and a Hitachi TM4000 Plus benchtop SEM at Purdue University to image the surface morphology and topography of the samples. We extracted thin sections for analysis in the transmission electron microscope(TEM)using the FEI Helios NanoLab 660 focused ion beam (FIB) SEM at the University of Arizona.We performed analysis of the microstructural and chemical characteristics of the samples using the 200 keV JEOL 2500 scanning TEM at Johnson Space Center. Reflectance Spectroscopy Results:Reflectance spectra for each sample are shown in Fig. 1.SC-001:The spectrum of the unirradiated sample exhibits a weak 1.0 μm absorption feature, associated with Fe2+in the olivine,and low overall reflectance (Fig. 1a). Thereflectance and the depth of the absorption band increases after 1x laser raster but are at their lowest after 5x laser rasters.F-T-004:The unirradiated sample has a blue-sloped spectrum with low reflectance without identifiable absorption features (Fig. 1b). With progressive laser irradiation, the sample reflectance increases and becomes strongly red-sloped.F-S-002:The unirradiated sample exhibits a dark, blue-slopedspectrum. The brightness of the sample increases significantly from <0.2average reflectance over >0.8 reflectance in the most irradiated sampleand thespectral slope also becomesslightly reddened (Fig. 1c). Microstructural and Chemical Analysis: Two primary alteration textures were observed in the samples exposed to simulated space weathering: 1) fluffy C-rich,and 2) vesiculated melt. The fluffy C-rich texture is composed oflow-densitydeposits distributed across the surface of the sample(Fig. 2A). Analysis of a FIB section extracted from a low-density C-rich region in sample SC-001 reveals multiple globule-type deposits, discrete from stacked graphite, likely produced via melting from the laser irradiation [9].The vesiculated melt textureis smooth and uniformly distributed across isolated regions of the sample surface. The vesicles measure up to 100s of nmin diameter. Analysis of a FIB section from this texture was extracted from sample F-T-004 reveals a layer of amorphous melt material, close to 100 nm thick and uniform across the FIB section (Fig. 2B). Isolated regions of this melt layer contain small nanoparticles, <5 nm in diameter. Chemical analysis through energy dispersive X-ray spectroscopy reveals the composition of this layer is enriched in Si and depleted in Mg and O compared to the underlying sample. Implications for Space Weathering on Mercury: Previous experiments simulating space weathering of Mercury have showndarkening and reddening of spectra[7,10].However, our use of low-Fe materials and graphite to create a sample set more analogous to the mercurian surface. Our results indicate that sample composition plays a significant and important role in the space weathering of Mercury. In particular, our spectral data demonstrates a strong correlation between spectral slope, Fe content, and simulated space weathering. While the variation in FeO content between samples F-S-002 and F-T-004 is <0.6 wt.%, the spectra deviate from flat to strongly red-sloped(F-T-004). This reddeningmay be linked to the presence of very small nanoparticles observed in the melt textures extracted from sample F-T-004. For the SC-001 sample, the fluffy C-rich textures may be developed by the amalgamation of small graphite particles into these unique morphologies. Such observations indicate that space weathering on Mercury may result in both familiar and new microstructural and chemical characteristics. References: [1]Hapke B. (2001) J. Geophys. Res.-Planet.,106,10039–10073. [2]Pieters C.M. and Noble S.K. (2016) J. Geophys. Res-Planet., 121, 1865–1884. [3] Lucey P.G., and Riner, M.A. (2011) Icarus,212, 451-462.[4]CintalaM.J.(1992)J. Geophys. Res.-Planet.,97,947–973.[5]Klima R.L.et al.(2018)Geophys.Res.Letters, 45, 2945–2953. [6]Nittler L.R., et al. (2011) Science 333, 1847-1850.[7]Sasaki S. and Kurahashi E. (2004) Space weathering on Mercury, Adv.Space Res., 33, 2152-2155.[8] Vander KaadenK.E., et al. (2018) LPSCXLIX, Abstract 1230. [9] McGlaun M.L. et al. (2019) LPSCL, Abstract 2019. [10] TrangD.et al. (2018)LPSCXLIX,Abstract2083
M S Thompson↗