Roles of humidity and cathodic current in chromium poisoning of Sr-doped LaMnO3-based cathodes in solid oxide fuel cells
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Wang, Ruofan (ORCID:0000000272482155)↗
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The effect of humidity on reverse breakdown in 3D silicon sensors
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McDuff, H.↗
Simultaneous control of temperature and humidity in a confined space. I - Mathematical modeling of the dynamic behavior of temperature and humidity in a confined space.
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Nakanishi, E.↗
Sensitivity of occupant comfort models to humidity and their effect on cooling energy use
Residential building energy consumption in the United States has decreased steadily during the last several decades largely because of advances in building codes as well as voluntary efficiency and labeling programs, which have resulted in the reduction in building sensible loads. Building latent loads have not decreased by the same amount, and field and analytical research studies have concluded that high-efficiency, low-load homes often have elevated indoor humidity levels, possibly leading to occupant discomfort. There are discrepancies in the literature on occupant comfort as it relates to indoor humidity and recommended upper humidity limits. The choice of humidity limit could potentially change results and conclusions on the energy impacts of a new air conditioner or dehumidifier technology, changing ventilation rates, or an improved building envelope. In this study, we use building simulations to explore the impact of humidity control on cooling energy use in efficient residential buildings for different humidity limits. We look at limits based on humidity ratio (or dew point temperature), wet-bulb temperature, relative humidity, and constant slope lines based on the popular comfort models of both Fanger and Gagge. We quantify the additional energy use required to control humidity below these limits. We look at the sensitivity of the results to different temperature and humidity set points, occupant internal gains, moisture buffering levels, evaporator airflow rates, and dehumidifier energy factors. High-efficiency home predicted energy savings are more sensitive to the assumed humidity limit and cooling and dehumidification set points than the other parameters investigated in this paper.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Accelerated Aging Humidity Chamber for Nuclear Grade HEPA Filter Media
A unique accelerated aging humidity chamber for simulating the natural aging process of nuclear grade high efficiency particulate air (HEPA) filter media is being designed, implemented, and tested. The nuclear industry currently lacks information regarding the shelf life and service life of HEPA filter media. The Department of Energy recommends disposing of HEPA filters 10 years after the manufacture date for filters operated under dry conditions. Studies have shown the tensile strength and water repellency of HEPA filter media diminish with age. The chamber's principal function is to sustain an elevated relative humidity condition for an extended duration specified by the Arrhenius aging model. To accomplish this, various design parameters were established: (1) consistently achieve uniform humidity conditions within the chamber to equally expose media sheets, (2) ensure the chamber is sufficiently sealed to mitigate the uncontrolled infiltration of air, (3) confidently secure the media sheets to avert the introduction of unnecessary stressing/creasing, (4) fabricate the chamber from clear polycarbonate material to allow inspection of the media sheets, (5) provide a safe and ergonomic design for personnel, (6) ensure the chamber design is replicable and relatively easy to fabricate/assemble. A humidity source, fan, PID controller, humidity and temperature transmitters, and data loggers are required for proper operation and control of the chamber. The humidity source must accommodate target values up to 95% relative humidity throughout the chamber. The three humidity and temperature transmitters are strategically spaced throughout the chamber to ensure uniform conditions. The 10 cubic feet per minute (CFM) fan selected intends to accomplish the desired air change rate inside the chamber of approximately 20 air changes per hour (ACH). The 2 plenums on the upper and lower portions of the chamber utilize a perforated design to uniformly distribute air, promote air mixing, and control the air velocity entering the chamber. Industrial blueprint hanging clamps are being retrofitted to be seated within the chamber drawers and firmly secure the nuclear grade filter media. The aged media will be evaluated using autopsy methodology, and the results obtained intend to help clarify the useful life of nuclear grade HEPA filters. Nuclear grade high efficiency particulate air (HEPA) filters are defined as disposable, extended-media, dry-type filters with a rigid casing enclosing the full depth of the pleats and have a minimum particle removal efficiency of 99.97%. [1] - HEPA filters are constantly exposed to stressors and subsequently have been shown to degrade as the filter ages. Properties such as tensile strength and water repellency, along with others, are negatively impacted. [2] - Due to the scarcity of naturally aged HEPA filters available, it is crucial to develop accelerated aging methods which effectively mimic the natural degradation effects. - After accelerated aging, the filters are subject to testing in the Axial Flow Large Scale Test Stand (ALSTS) and other analysis techniques such as the same qualification tests performed directly after being manufactured. - Quality data is necessary for future decisions regarding the lifetime of nuclear grade HEPA filters. - The objective is to develop a prototype accelerated aging humidity chamber for nuclear grade HEPA filter media. The chamber should expose the media to commonly occurring stressors to expedite the degradation process caused by aging. PID yields reliable and reproducible results: - CFD model correlates well with actual performance; - Further analysis is needed to complete characterization; - Future work for the chamber is still to be completed. The data shown in Figure 5 and Table 1 indicate the system is functioning as designed. As can be determined from the system response evaluation in Table 1, the PID controller is yielding reliable and reproducible results at each set point. As the set point increases, the time constant and 20% settling time increase accordingly. From the results in Table 1, it stands to reason that the CFD model correlates well with the actual performance of the system. Each system response parameter for the 90%RH* CFD model is slightly lower than the parameters collected from the physical model tested at an equivalent set point. This is to be expected considering the inlet in the CFD model is a constant supply of water vapor, whereas the physical model uses a PID controller to monitor the amount of water vapor needed and reacts accordingly. More analysis is still to be done on the prototype chamber. A pressure test will be conducted in order to determine the hourly leak rate of the chamber. This test will involve constant air flow into the chamber until the desired pressure is reached. A uniformity test will also be conducted in order to ensure each filter medium is being exposed to equivalent relative humidity levels. This test will involve an array of humidity meters strategically oriented inside the chamber to record any possible gradients. Future work for the chamber includes dehumidification abilities, tests while fully loaded with filters, and temperature control. Once completed, the autopsy team at Institute of Clean Energy Technology will conduct necessary accelerated aging studies as needed.
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
Measure Guideline: Supplemental Dehumidification in Warm-Humid Climates
This document covers a description of the need and applied solutions for supplemental dehumidification in warm-humid climates, especially for energy efficient homes where the sensible cooling load has been dramatically reduced. In older homes in warm-humid climates, cooling loads are typically high and cooling equipment runs a lot to cool the air. The cooling process also removes indoor moisture, reducing indoor relative humidity. However, at current residential code levels, and especially for above-code programs, sensible cooling loads have been so dramatically reduced that the cooling system does not run a lot to cool the air, resulting in much less moisture being removed. In these new homes, cooling equipment is off for much longer periods of time especially during spring/fall seasons, summer shoulder months, rainy periods, some summer nights, and some winter days. In warm-humid climates, those long off periods allow indoor humidity to become elevated due to internally generated moisture and ventilation air change. Elevated indoor relative humidity impacts comfort, indoor air quality, and building material durability. Industry is responding with supplemental dehumidification options, but that effort is really in its infancy regarding year-round humidity control in low-energy homes. Available supplemental humidity control options are discussed. Some options are less expensive but may not control indoor humidity as well as more expensive and comprehensive options. The best performing option is one that avoids overcooling and avoids adding unnecessary heat to the space by using waste heat from the cooling system to reheat the cooled and dehumidified air to room-neutral temperature.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Measure Guideline: Supplemental Dehumidification in Warm-Humid Climates
This document covers a description of the need and applied solutions for supplemental dehumidification in warm-humid climates, especially for energy efficient homes where the sensible cooling load has been dramatically reduced. Cooling loads are typically high and cooling equipment runs a lot to cool the air in older homes in warm-humid climates. The cooling process also removes indoor moisture, reducing indoor relative humidity. However, at current residential code levels, and especially for above-code programs, sensible cooling loads have been so dramatically reduced that the cooling system does not run a lot to cool the air, resulting in much less moisture being removed. In these new homes, cooling equipment is off for much longer periods of time especially during spring/fall seasons, summer shoulder months, rainy periods, some summer nights, and winter days. In warm-humid climates, those long-off periods allow indoor humidity to become elevated due to internally generated moisture and ventilation air change. Elevated indoor relative humidity impacts comfort, indoor air quality, and building material durability. Industry is responding with supplemental dehumidification options, but that effort is really in its infancy regarding year-round humidity control in low-energy homes. Available supplemental humidity control options are discussed. Some options are less expensive but may not control indoor humidity as well as more expensive and comprehensive options. The best performing option is one that avoids overcooling and adding unnecessary heat to the space by using waste heat from the cooling system to reheat the cooled and dehumidified air to room-neutral temperature.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Assessment of the combination of temperature and relative humidity on kidney stone presentations
Highlights: • Temperature and relative humidity have opposing effects on evaporative water loss. • Wet-bulb temperatures best predicted kidney stone presentations. • Differences in predictive capacity of temperature metrics were greatest in summer. Temperature and relative humidity have opposing effects on evaporative water loss, the likely mediator of the temperature-dependence of nephrolithiasis. However, prior studies considered only dry-bulb temperatures when estimating the temperature-dependence of nephrolithiasis. We used distributed lag non-linear models and repeated 10-fold cross-validation to determine the daily temperature metric and corresponding adjustment for relative humidity that most accurately predicted kidney stone presentations during hot and cold periods in South Carolina from 1997 to 2015. We examined three metrics for wet-bulb temperatures and heat index, both of which measure the combination of temperature and humidity, and for dry-bulb temperatures: (1) daytime mean temperature; (2) 24-h mean temperature; and (3) most extreme 24-h temperature. For models using dry-bulb temperatures, we considered four treatments of relative humidity. Among 188,531 patients who presented with kidney stones, 24-h wet bulb temperature best predicted kidney stone presentation during summer. Mean cross-validated residuals were generally lower in summer for wet-bulb temperatures and heat index than the corresponding dry-bulb temperature metric, regardless of type of adjustment for relative humidity. Those dry-bulb models that additionally adjusted for relative humidity had higher mean residuals than other temperature metrics. The relative risk of kidney stone presentations at the 99th percentile of each temperature metric compared to the respective median temperature in summer months differed by temperature metric and relative humidity adjustment, and ranged from an excess risk of 8–14%. All metrics performed similarly in winter. The combination of temperature and relative humidity determine the risk of kidney stone presentations, particularly during periods of high heat and humidity. These results suggest that metrics that measure moist heat stress should be used to estimate the temperature-dependence of kidney stone presentations, but that the particular metric is relatively unimportant.
54 ENVIRONMENTAL SCIENCES↗
TH-AB-201-06: Examining the Influence of Humidity On Reference Ion Chamber Performance
Purpose: International dosimetry protocols require measurements made with a vented ionization chamber to be corrected for the influence of air density by using the standard temperature-pressure correction factor. The effect of humidity, on the other hand, is generally ignored with the provision that the relative humidity is between certain limits (15% to 80%). However, there is little experimental data in the published literature as to the true effect of humidity on modern reference-class ion chambers. This investigation used two different radiation beams – a Co-60 irradiator and a Sr-90 check source – to examine the effect of humidity on several versions of the standard Farmer-type ion chamber. Methods: An environmental cabinet controlled the humidity. For the Co-60 beam, the irradiation was external, whereas for the Sr-90 measurements, the source itself was placed within the cabinet. Extensive measurements were carried out to ensure that the experimental setup provided reproducible readings. Four chamber types were investigated: IBA FC65-G (×2), IBA FC65-P, PTW30013 & Exradin A19. The different wall materials provided potentially different mechanical responses (i.e., in terms of expansion/contraction) to the water content in the air. The relative humidity was varied between 8 % and 97 % and measurements were made with increasing and decreasing humidity to investigate possible hysteresis effects. Results: Measurements in Co-60 were consistent with the published data obtained with primary standard cavity chambers in ICRU Report 31. Ionization currents with Sr-90 showed no dependence with the relative humidity, within the measurement uncertainties. Very good repeatability of the ionization current was obtained over successive wet/dry cycles, no hysteresis was observed, and there was no dependence on chamber type. Conclusion: This null result is very encouraging as it indicates that humidity has no significant effect on these particular types of ionization chambers, consistent with recommendations in current megavoltage dosimetry protocols.
60 APPLIED LIFE SCIENCES↗
Evaluation of the Performance of Houses With and Without Supplemental Dehumidification in a Hot-Humid Climate
This report, Evaluation of the Performance of Houses with and without Supplemental Dehumidification in a Hot-Humid Climate, describes a research study that that was conducted by the Building Science Corporation (BSC) Building America Research Team. BSC seeks to research and report on the field monitoring of the performance of in-situ supplemental dehumidification systems in low energy, high performance, homes in a Hot-Humid climate. The purpose of this research project was to observe and compare the humidity control performance of new, single family, low energy, and high performance, homes. Specifically, the study sought to compare the interior conditions and mechanical systems operation between two distinct groups of houses, homes with a supplemental dehumidifier installed in addition to HVAC system, and homes without any supplemental dehumidification. The subjects of the study were ten single-family new construction homes in New Orleans, LA.Data logging equipment was installed at each home in 2012. Interior conditions and various end-use loads were monitored for one year. In terms of averages, the homes with dehumidifiers are limiting elevated levels of humidity in the living space. However, there was significant variation in humidity control between individual houses. An analysis of the equipment operation did not show a clear correlation between energy use and humidity levels. In general, no single explanatory variable appears to provide a consistent understanding of the humidity control in each house. Indoor humidity is likely due to all of the factors we have examined, and the specifics of how they are used by each occupant.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Building America Case Study: Evaluation of the Performance of Houses With and Without Supplemental Dehumidification in a Hot-Humid Climate, New Orleans, Louisiana (Fact Sheet)
This report, Evaluation of the Performance of Houses with and without Supplemental Dehumidification in a Hot-Humid Climate, describes a research study that that was conducted by the Building Science Corporation (BSC) Building America Research Team. BSC seeks to research and report on the field monitoring of the performance of in-situ supplemental dehumidification systems in low energy, high performance, homes in a Hot-Humid climate. The purpose of this research project was to observe and compare the humidity control performance of new, single family, low energy, and high performance, homes. Specifically, the study sought to compare the interior conditions and mechanical systems operation between two distinct groups of houses, homes with a supplemental dehumidifier installed in addition to HVAC system, and homes without any supplemental dehumidification. The subjects of the study were ten single-family new construction homes in New Orleans, LA. Data logging equipment was installed at each home in 2012. Interior conditions and various end-use loads were monitored for one year. In terms of averages, the homes with dehumidifiers are limiting elevated levels of humidity in the living space. However, there was significant variation in humidity control between individual houses. An analysis of the equipment operation did not show a clear correlation between energy use and humidity levels. In general, no single explanatory variable appears to provide a consistent understanding of the humidity control in each house. Indoor humidity is likely due to all of the factors we have examined, and the specifics of how they are used by each occupant.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Highly sensitive humidity sensing properties of carbon quantum dots films
Graphical abstract: Display Omitted Highlights: ► A humidity sensing device was fabricated based on carbon quantum dots (CQDs) films. ► The conductivity of the CQDs films shows a linear and rapid response to atmosphere humidity. ► The humidity sensing property was due to the hydrogen bonds between the functional groups on CQDs. -- Abstract: We reported the fabrication of a humidity sensing device based on carbon quantum dots (CQDs) film. The conductivity of the CQDs film has a linear and rapid response to relative humidity, providing the opportunity for the fabrication of humidity sensing devices. The mechanism of our humidity sensor was proposed to be the formation of hydrogen bonds between carbon quantum dots and water molecules in the humidity environment, which significantly promote the electrons migration. In a control experiment, this hypothesis was confirmed by comparing the humidity sensitivity of candle soot (i.e. carbon nanoparticles) with and without oxygen containing groups on the surfaces.
36 MATERIALS SCIENCE↗
Software Compensates Electronic-Nose Readings for Humidity
A computer program corrects for the effects of humidity on the readouts of an array of chemical sensors (an "electronic nose"). To enable the use of this program, the array must incorporate an independent humidity sensor in addition to sensors designed to detect analytes other than water vapor. The basic principle of the program was described in "Compensating for Effects of Humidity on Electronic Noses" (NPO-30615), NASA Tech Briefs, Vol. 28, No. 6 (June 2004), page 63. To recapitulate: The output of the humidity sensor is used to generate values that are subtracted from the outputs of the other sensors to correct for contributions of humidity to those readings. Hence, in principle, what remains after corrections are the contributions of the analytes only. The outputs of the non-humidity sensors are then deconvolved to obtain the concentrations of the analytes. In addition, the humidity reading is retained as an analyte reading in its own right. This subtraction of the humidity background increases the ability of the software to identify such events as spills in which contaminants may be present in small concentrations and accompanied by large changes in humidity.
Zhou, Hanying↗
Compensating for Effects of Humidity on Electronic Noses
A method of compensating for the effects of humidity on the readouts of electronic noses has been devised and tested. The method is especially appropriate for use in environments in which humidity is not or cannot be controlled for example, in the vicinity of a chemical spill, which can be accompanied by large local changes in humidity. Heretofore, it has been common practice to treat water vapor as merely another analyte, the concentration of which is determined, along with that of the other analytes, in a computational process based on deconvolution. This practice works well, but leaves room for improvement: changes in humidity can give rise to large changes in electronic-nose responses. If corrections for humidity are not made, the large humidity-induced responses may swamp smaller responses associated with low concentrations of analytes. The present method offers an improvement. The underlying concept is simple: One augments an electronic nose with a separate humidity and a separate temperature sensor. The outputs of the humidity and temperature sensors are used to generate values that are subtracted from the readings of the other sensors in an electronic nose to correct for the temperature-dependent contributions of humidity to those readings. Hence, in principle, what remains after corrections are the contributions of the analytes only. Laboratory experiments on a first-generation electronic nose have shown that this method is effective and improves the success rate of identification of analyte/ water mixtures. Work on a second-generation device was in progress at the time of reporting the information for this article.
Homer, Margie↗
Frost Growth and Densification on a Flat Surface in Laminar Flow with Variable Humidity
Experiments are performed concerning frost growth and densification in laminar flow over a flat surface under conditions of constant and variable humidity. The flat plate test specimen is made of aluminum-6031, and has dimensions of 0.3 mx0.3 mx6.35 mm. Results for the first variable humidity case are obtained for a plate temperature of 255.4 K, air velocity of 1.77 m/s, air temperature of 295.1 K, and a relative humidity continuously ranging from 81 to 54%. The second variable humidity test case corresponds to plate temperature of 255.4 K, air velocity of 2.44 m/s, air temperature of 291.8 K, and a relative humidity ranging from 66 to 59%. Results for the constant humidity case are obtained for a plate temperature of 263.7 K, air velocity of 1.7 m/s, air temperature of 295 K, and a relative humidity of 71.6 %. Comparisons of the data with the author's frost model extended to accommodate variable humidity suggest satisfactory agreement between the theory and the data for both constant and variable humidity.
Kandula, M.↗
Impact of Relative Humidity during Spin-Deposition of Metal Oxide Thin Films from Aqueous Solution Precursors
Relative humidity during the spin-processing of thin film solution precursors is often not controlled or measured, and its effect on film thickness is generally unappreciated. Herein, we report that the relative humidity during spin-processing has a marked impact on the film thickness of amorphous metal oxide (aluminum oxide and lanthanum zirconium oxide) and hafnium oxide-sulfate (HafSOx) thin films deposited from aqueous precursors. In the humidity range studied [20–95% relative humidity (RH)], film thicknesses varied by a factor of nearly 3, and this effect is independent of the metal precursor identity. Our data suggest that film thickness depends linearly on evaporation rate (100 – RH) for all systems studied, suggesting this effect is predominantly due to the unique characteristics of water as a solvent. In situ X-ray reflectivity studies of HafSOx films deposited under different humidities reveal that, while the thickness varies significantly with humidity, the density of the as-deposited films is similar, suggesting that humidity primarily affects the relative amount of material deposited. Because reproducible film thickness is critical for many applications, our data highlight the importance of controlling humidity during spin-processing.
36 MATERIALS SCIENCE↗
Synergistic Retrieval of Temperature and Humidity Profiles from Space-Based and Ground-Based Infrared Sounders Using an Optimal Estimation Method
The atmospheric temperature and humidity profiles of the troposphere are generally measured by radiosondes and satellites, which are essential for analyzing and predicting weather. Nevertheless, the insufficient observation frequencies and low detection accuracy of the boundary layer restricts the description of atmospheric state changes by the temperature and humidity profiles. Therefore, this work focus on retrieving the temperature and humidity profiles using observations of the FengYun-4 (FY-4) Geostationary Interferometric Infrared Sounder (GIIRS) combined with ground-based infrared spectral observations from the Atmospheric Emitted Radiance Interferometer (AERI), which are more accurate than space-based individual retrieval results and have a wider effective retrieval range than ground-based individual retrieval results. Based on the synergistic observations, which are made by matching the space-based and ground-based data with those of different spatial and temporal resolutions, a synergistic retrieval process is proposed to obtain the temperature and humidity profiles at a high frequency under clear-sky conditions based on the optimal estimation method. In this research, using the line-by-line radiative transfer model (LBLRTM) as the forward model for observing simulations, a retrieval experiment was carried out in Qingdao, China, where an AERI is situated. Taking radiosonde data as a reference for comparing the retrieval results of the temperature and humidity profiles of the troposphere, the root-mean-square error (RMSE) of the synergistic retrieval algorithm below 400 hPa is within 2 K for temperature and within 12% for relative humidity. Compared with the GIIRS individual retrieval, the RMSE of temperature and relative humidity for the synergistic method is reduced by 0.13–1.5 K and 2.7–4.4% at 500 hPa, and 0.13–2.1 K and 2.5–7.2% at 900 hPa. Moreover, the forecast index (FI) calculated from the retrieval results shows reasonable consistency with the FIs calculated from the ERA5 reanalysis and from radiosonde data. The synergistic retrieval results have higher temporal resolution than space-based retrieval results and can reflect the changes in the atmospheric state more accurately. Overall, the results demonstrated the promising potential of the synergistic retrieval of temperature and humidity profiles at high accuracy and high temporal resolution under clear-sky conditions from FY-4/GIIRS and AERI.
54 ENVIRONMENTAL SCIENCES↗
Control of Radioactive Methyl Iodide Gases by Mesoporous Hybrid Adsorbents at High Humid Condition - 19329
During the operation of nuclear facility as well as decommissioning stage, various radioactive gaseous wastes are generated. It is generally recognized that radioiodine is potentially one of the most hazardous gas on the human body and environment. Iodine-131 release in the gaseous effluents at the nuclear facilities had been a critical environmental concern. Reducing iodine release is a critical issue in radioactive waste system evaluation, especially in their adherence to the 'as low as reasonably achievable' (ALARA) criteria because radioiodine among these gaseous wastes has radiological harm. Therefore, numerous studies for the removal of radioiodine from the off-gas stream of nuclear facilities have been performed with formation processes and chemical structure. There has been some concern regarding the use of TEDA-impregnated activated carbon as an adsorbent for radioiodine removal, because of the low ignition point of TEDA and the possible release of TEDA from the charcoal in continuously flowing air streams. Therefore, the TEDA-impregnated activated carbon cannot use to trap radioiodine generated from high humid condition, due to the rapid drop of the removal efficiency. It is obvious that high humid can be expected during design basis event such as loss-of-coolant accident (LOCA). Therefore, investigation on the retention of organic radioiodine (CH3I131) by various activated carbons at high humid condition has extensively been performed so far. But there are no good results on the adsorption of methyl iodide at high humid condition up to now. As a result, the promising approach to the problem of iodine removal under high humid conditions is to use organic-inorganic hybrid adsorbents in which are enough retention characteristics from hydrophobic property. In order to develop the best removal efficiency for the control of radioiodine gas generated from a high humid process, a hydrophobic adsorbents was developed and the performance test of adsorbent using radioactive methyl iodide tracer was also performed. Demonstration test of adsorbent using radioactive methyl iodide tracer was performed at high humid conditions up to 97% relative humidity. (authors)
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗